US8993A - Improvement in the construction of retorts for chemical furnaces - Google Patents
Improvement in the construction of retorts for chemical furnaces Download PDFInfo
- Publication number
- US8993A US8993A US8993DA US8993A US 8993 A US8993 A US 8993A US 8993D A US8993D A US 8993DA US 8993 A US8993 A US 8993A
- Authority
- US
- United States
- Prior art keywords
- retorts
- heat
- zinc
- retort
- furnaces
- Prior art date
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- Expired - Lifetime
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- 238000010276 construction Methods 0.000 title description 18
- 239000000126 substance Substances 0.000 title description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 60
- 239000011701 zinc Substances 0.000 description 60
- 229910052725 zinc Inorganic materials 0.000 description 60
- 239000007789 gas Substances 0.000 description 50
- 238000000034 method Methods 0.000 description 42
- 206010022000 Influenza Diseases 0.000 description 30
- 239000002184 metal Substances 0.000 description 28
- 229910052751 metal Inorganic materials 0.000 description 28
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 239000000463 material Substances 0.000 description 20
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 229910052802 copper Inorganic materials 0.000 description 12
- 239000010949 copper Substances 0.000 description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 12
- 230000001105 regulatory Effects 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 208000006379 Syphilis Diseases 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000005286 illumination Methods 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 10
- 235000011149 sulphuric acid Nutrition 0.000 description 10
- 239000001117 sulphuric acid Substances 0.000 description 10
- 229910001369 Brass Inorganic materials 0.000 description 8
- 229920002456 HOTAIR Polymers 0.000 description 8
- 239000005864 Sulphur Substances 0.000 description 8
- 239000010951 brass Substances 0.000 description 8
- 238000001354 calcination Methods 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- 238000000859 sublimation Methods 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 239000002918 waste heat Substances 0.000 description 8
- 239000003610 charcoal Substances 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000007670 refining Methods 0.000 description 6
- 238000000137 annealing Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 210000000988 Bone and Bones Anatomy 0.000 description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 2
- 229910000776 Common brass Inorganic materials 0.000 description 2
- 210000003414 Extremities Anatomy 0.000 description 2
- 210000001503 Joints Anatomy 0.000 description 2
- 210000000088 Lip Anatomy 0.000 description 2
- 241000255972 Pieris <butterfly> Species 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000001473 noxious Effects 0.000 description 2
- 230000001590 oxidative Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 239000003415 peat Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000000717 retained Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000005418 vegetable material Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/004—Heating the product
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
Definitions
- Fig. 2 is a sectional elevation through the line A'eA of Fig. l, the vertical flues to carry'off the vapor from the retorts being denoted by dotted lines.
- Fig. is a general exterior elevation on the side B o'f Fig. 1.
- Fig. 4 is a cross-section through the line c c of Figs. l, 2, and 3 ⁇ of anest of four retorts, showing the horizontal lues that conduct the fire heat below and above each retort.
- Fig. 5 is a plan showing the construction of the dividing-piers bet Ween each two retorts, with Vertical ues connected one to each retort.
- Gis a plan at the in ner end of retorts, fitted' to carry down the oxide of zinc in vapor or the vapor of sulphur in sublimation.
- This mode of fitting the retorts may be inverted,and have connections to upper horizontal lines to carry off the sulphurous gases evolved in calcining metals orother gases in the opposite direction if needful.
- Fig; 7 is a sectional elevation of an extended arch to condense the vapors of sublimation or the oxides of metals in vapor.
- the other detached figures are separately referred to, and the like letters and numbers as marks of reference apply tothe same parts in each of the figures, as follows:
- D D are pot-furnaces, built in the usual manner, but set at an elevation to lead the heat by flues a, formedby divisions 1 l, each with a. damper, 2, into the fire-chamber of the reverberatory furnace F, which may be used for melting, puddling, or refining metal, the fire act-ing on the material on the bed b conjointly with the surplus heat from the pot-furnaces.
- the heat from the furnace E is carried on by exit-fines c, formed by small piers 3 (shown by dotted lines in Fig. l) that support the end arch of the furnace.v These iiues continue over an arch, F, into a chamber, d.
- G G are piers and arches iilled into form a level platform of masonry, e e, ⁇ above the arches, built with a central ue or barrel arch, 4, shown in Fig. 4, and by dotted lines in Figs. 1, 2, and 3, as passing on the bases of the piers.
- j' is a pipe across through the masonry near the exit of the furnace E, opening into lengthwise pipes g g, formed or laid in the masonry over the arches G, and connecting4 at their sides into cross-pipes 7i, extending outside the masonry.
- the pipe f is to be connected at either end to any blower competent to drive a blast through all the pipes, for a purpose shown hereinafter.
- H H is a double range of retorts on the platform e, each shown as made of clayvin three sections, but may be any number'of sections or parts, or may be made ot' iron, as hereinafter stated.
- 'i t' are thefwalls at each outer end of the re torts and furnaces, and 5 (see Figs. 2 and 4) are the sides of -the lower half of each retort ,that inclose the hearth 6.
- v ln theue-chamber d a stop, 9, directs the fire heat into the flues 10, under rthe hearths of the lower range of retorts H H, where the heat, acting and passing through the whole range, enters the lower part of the vertical flue l at the farther end of therange, in which a stop, 11, turns the current of heatback into and .through the second tier of flues, 12, above the crowns of the lower retorts and under the hearths of the upper range of retorts, into the part of the chamberd above the stop 9, which passes the current into the flues 13 through the crowns of the upper range of retorts and into the part of the iiue I above the stop 11.
- K K are piers of the same material as the retorts, each having vertical fines 14, so fitted that each flue communicates withone retort by an opening, 16.
- the vertical flues 14 are closed on their upper ends by stoppers or other means that can Lbe removed to clean out the lines, andthe-lowerends ofthese vertical flues descend to openings through and into'the barrel-arch 4, to lead the gaseous products of the retorts away for use, as hereinafter shown.
- rllhe heat acquired by the masonry when in use heats the air in its passage from the principal pipe f.
- the retorts are covered over with brick-work or any similar substance and aretied together by plates and tie-bars in any convenient manner.
- At 7c k are vertical pipes from the air-pipes L., with branches Z, one opening into each retort, the access and quantity of air allowed to pass into the retort being regulated by cocks 17.
- the iluc 13 opens into a horizon ⁇ tal flue passing under the evaporatingpans L and above the arch M, which is used for a purpose hereinafter shown. After the current of fire heat has passed under the evaporating-pans it passes into the chamber N over the arch O, which chamber N contains a boil er, Q, that is heated by the current of heat beneath it when the heat is so used.
- the current in this case passes off by the due m into the chimney l?, and a furnacemay be made in the boiler, if found needful; vbut if the steam from the boiler is not in use for the precedent and subsequent operations, the dampers 19 are set to close the flues m to the chimney. In this.
- At r r are doors, of any usual form, to open and close the retorts H. Vhen the retorts are' used to calci ne the sulphureted ores of metals.
- the arch or barrel 4 is ,to be continued, as shown in Figsl, 2, and .3, to the vertical flue 23, Figs. l and 2, which receives a regulated amount of steam through the pipes 27 and cocks 28, and, this iiue communicates by side openings, 24, to the chambers 25 of the nest of chambers S, (shown in plan in Fig. 1 and in longitudinal sectional elevation in Fig. 2,) and arranged to pass the sulphurous or other gas with steam from the pipes 27, if required, over any material on the floors of the chambers 25, and convert the materialsinto their respective compounds, the gas passing through all the chambers intoa vertical cross-fine, 26.
- the floors of the chambers 25 are perforated to pass any condensation or liquid matter into the chamber 29, whence it may be removed by a pipe, 30, or .by the door 31.
- the vertical cross-fine 26 is connected by apipe, 32, to the exhausting pump or blower R, made as shown in Fig-2, the pipe 32. passing into vthe semi-v4 .'circnlarfende'd case having twocovers fitted to receive two arbors, 33, on one end'of each of which is a tooth-wheel. These gear together, and on ,the end of one arbor 33 is a drum, s, to communicate any competent power and rotate the arbors 33 and tooth-wheels.
- the barrel-arch 4 beneath, running through and at right angles with the foundation of the piers, is to be used for receiving gases from the retorts, and conveying them to the chamber S as it receives them by the continuations downward of the vertical iiues 14 in the dividingpiers K, and this arch 4 may also be used in like manner for a variety of other purposes hereinafter set forth.
- the large arch M under the evaporatingpans L, and the arch O under the boiler N may be used as kilns or ovens, and in these the retorts themselves may be dried and baked for use, or any other articles may be dried and baked by the surplus heat from the retorts, or
- auxiliary fires beneath or in the arches or the heat from the retorts may be made to operate in conjunction'with the auxiliary fires, and when the evaporating-pans are not wanted to be used the heat may be carried down on one side and beneath the floors of the arches, and up on the opposite side, as shown by dotted lines in Fig. 2, the current of heat being regulated by dampers in any usual way.
- the original intention in these improvements was to produce or form the white oxide of zinc for use as a paint or pigment, by either burning the metallic zinc, and condensing the vapor, or by treating the sulphate of zinc produced by the action of sulphuric acid and water on metallic zinc, so as to convert this into a white oxide, and also have the hydrogen gas for use.
- the first process will now be described. Any or all of the retorts may be used for this purpose, and are to be fitted with openings in the place of the flue-piers K, as shown in Figs. 6 and 7 ,with lips 53 across the inner end of each hearth, and the arches G below made to extend to the center, and with-v out the barrel-arch or horizontal flue 4 running through them.
- These arches G thus made continuous may be lengthened at either end, as shown in Fig. 7, and coated inside with any cement that will form a smooth surface on the crowns, sides, and iioors.
- the outer end or ends of these arches are to be connected by an opening, 35, into one sideof a cold chimney, W, of any proper size to form a chamber, 36, and above this the chimney is to be fitted to carry one or more wire or cloth screens, 37, so fitted as to shake horizontally by a handle, and above these an exhausting-pump is to be tted exactly similar to the one already described as placed in the chimney V, and used in the same manner to form a suction-draft from the retorts H through the openings between the ends of each two hearths, and through the lengthened arches G to the chimney V.
- any one or more of the arches G that are not otherwise used is to have a competent tight tank tted into it, to contain the dilute sulphurc acid and zinc, with a pipe to conduct the hydrogen gas into one of the retorts for'carbonization, as is hereinafter described, or may be conducted away in any other direction for any other purpose.
- the sulphate of zinc which is the result of this process, is to be placed in the evaporating-pans L and heated by the heat passing under the pans in the nue or iiues 18, and chloride of lime is to be introduced to oxidize any iron that may be present.
- the liquid is then to be decanted into other similar vessels and allowed to settle and precipitate the oxide of iron or othersforeign substances, after which the liquid is to be decanted into a third set of vessels and treated with ammonia or other alkaline substances. These combine with the sulphuric acid and liberate the zinc, which falls to the bottom of the vessel in the form of an oxide. The sulphate is then to be deeanted off as much as possible. These decantings may be effected by Siphon-pipes and cocks, or by any usual means.
- the zine which has fallen to the bottoni of the third set of vessels as an 'oxide or hydrate, is to be taken out and placed in strong sacking bags and pressed by a hydraulic press, or any competent press, to drive out as much as possible of the sulphate that may remain in the mass, which is then to be placed in clean water, into which steam is to be introduced, and the mass stirred and agitated in several washings, that the water may carry off as much as it will absorb of any remaining sulphate. Vhen sufficiently washed,
- any ores of zinc, wastages containing zinc, or any dresses of zinc may be used; and after producing the hydrogen gas the sulphate ⁇ may be converted into white oxide, and the several mixtures of materials used in the process may be reserved and treated so as to avoid waste of the ammonia (if ammonia is used) by evaporation, as usual, and using it over again and by appropriating one portion of the retorts to the first process of oxidizing the metal, and a second portion to burning the hydrate or oxide, a third portion of the retorts may be appropriated to receive the hydrogen gas evolved in the second process, and carbonize it by combination with any proper material in the retort, whence the gas may be allowed to pass either up or down by the flues 14, and conveyed to a gasometer, in the usual way, for use in illumination.
- the ores are irst to be calcined in one or more of the retorts with the door closed, and steam or hot air, or both, are to be passed in by the cocks, as described, the sulphurous gas going off by the lues 14 and arch 4 to be used in any ot' the modes herein described. Vhen sufficiently calcined, the
- ores are to be taken to the reverberatory furnace E and reduced as usual, and then taken to the retorts and subjected to the saine treatment as before, after which they are to be taken through the reverberatory or smelting furnace and through the refinery working in the usual manner, the main points of the application and arrangement of the retorts and furnaces being, first, that by the retorts H H the sulphurous gases evolved are made useful in the manner described; and, second, that the first or calcining operations are effected by what is ordinarily the wasted heat from the rst and second furnaces acting through the retorts on the ores under treatment, so that the operations of ealcining, snielting, and refining can all be in progress by the same fires.
- the mode of effecting all these processes by the furnacefires is shown in the detached Fig. 8, where a:
- the metal is to be oxidized in either of the first furnaces, X or E, by the fires and by hot air and steam from the pipes o and k, after which the oxides so formed are to be burned in the retorts, then ground and floated in the usual manner, then returned to the retorts to be formed into litharge or red lead by the more brief or more lengthened operation of the heat and heated air when red lead is to be formed.
- These processes are to be conducted as in the ordinary manner, the same advantages being derived from the construction of the retorts and the useof the waste heat from the rst furnaces, as is shown in the other operations herein described. It will be understood that in thus working lead the ilues 14 will not be needed.
- the other uses to which the appara-4 tus may be applied are as follows:
- the sulphurous gases evolved in any of the former processes, or the gases evolved in the sublimation of sulphur in the retorts, may be taken by the fines 14 and barrel-arch 4 to condensing-chambers, by connections of any 'proper kind, and condensed to form the sulphur of commerce, or the gases may be converted into sulphurie acid by the usual known mea-ns, and the acid may be used for converting theores or metal of Zinc into sulphate of zinc, by placing either of them in the same r chamber where the acid is formed, the hydrogen gas evolved beingused as described.
- the retorts may be used for producing gas for illumination from coals or other fit materials, and when so employed a portion of the retorts may be used to vaporize the ammoniacal residunin of the process, by heating the mass and conveying away the vapor for con densation to form the liquid ammonia of commerce, by any convenient or usual means.
- Oxidous ores of metal may be deoxidized in these retorts preparatory'to the subsequent processes, for conversion into metallic forms by either or both of the first furnaces.
- Vegetable materials of any kind may be subjected to destructive distillation in these retorts, and the gaseous products be taken off for use upward by the flues 14, or downward by these and the arch 4.
- the matter left in the retorts, being converted into charcoal and bones or peat, may be reduced to bone-black or charcoal.
- the ammoniacal vapor from either of these may be taken off by any convenient means for condensation into liquid ammonia.
- the detached Figs. 9 and 10 are a lengthwise and cross section of an arrangement by which retorts of this character may be applied to the conversion of copper and zinc into brass, with the advantages of saving the vapor of the zinc which sublimes in the mixing, and condensing it into white oxide, and of using the secondary or now wasted heat of the fire to anneal the brass in the several stages of roll- I ing or working it.
- 3S is the furnace, set on one side of an arch, 39, which supports a melting-retort, 40, having no flue under the hearth, but iiues 12 in the crown of the retort 40, which open into the flue 10 under the hearth of the lower one of two annealing-retorts, 41.
- the heat passes into a chamber, 42, which directs the heat into the ilues 12 above the crown of the lower and under the hearth of the upper retort, into a chamber, 43, whence the heat passes by the upper iiues, 13, over the crown of the upper retort, into the chimney 44.
- At 45 is the feeding-door in i'ront of the retort 40, and 46 is a damper or sliding door, as usual .v
- rPhe Hue 50 opens into the'areh 39, which is to be iitted with a door, 52, at each end, of cloth or gauze to retain the iioccules of the gaseous vapor from the zin'c.
- the vapor of the zinc goes off by the opening' 4S, and is condensed in the arch 39 into a white oxide that may be taken out for use,
- the retorts 41 heated by the surplus heat, will anneal the brass when made to permit successive rollings inthe manu facture, as usual, and this arrangement is equally available for refining copper and annealing it in the process of rolling; or iron melted in the furnaces and castinto form may be annealed in the same way.
- Metals, glass, or other materials may be annealed and other substances heated or baked in these retorts.
- the retorts H and flue-piers K may be made of iron and arranged in the same manner, so as to be equally effective; and in somecases it may be useful to put in the lower nue-pier, K, only, andallow two ilues to open at the bottom of the top tier, so that the operations going on in the top retorts may be seen all through by merely opening both doors of the two top retorts.
- a eross-lip, 53 may be placed at the inner end of each top retort, as shown in Fig. 7, to rise a little above the hearth, and prevent any substance falling into the descending iiues 14.
- the lower fluepier, K may be left out, and the upper kept in, as by thus reversing these positions the gases evolved may be taken upward from each four retorts by the ilues 14, into any proper reservoir or chalnber for ulterior operations, or if the sulphurous gases are taken downward, the barrel-arch 4: may be tapped laterally by pipes to lead the gas into any proper vessel in the arches Gr for the production of sulph-uric acid by the usual means.
- these retorts may be heated by any proper fire, whether it is the waste heat of a furnace or a separate re.
- Vhat I desire to secure by ⁇ Letters Patent isi
- IVM IVM. SnRRnLL, LEMUEL NV. SERRELL.
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Description
2 Sheets-Sheet l.
J. AKRILL.
Patented June 8, 1852 Mizax-wx mi Norms PETERS no, PHOTO-urna. wAsHnNuToN. n c.
2 Sheets-Sheet 2.
J. AKRILL. CONSTRUCTION CF RBTCRTS FCR CHEMICAL FURNACBS.
No. 8,993. Patented June 8, 1852.
M Lw ma Norms Parras co. vuoroumq, WASHINGTON UNITED STATES PATENT OFFICE.
JOHN AKRILL, or WILLIAMSBURG, NEW YORK.
IIviPIOVI-IIIIIENT IN THE CONSTRUCTION OF RETORTS FOR CHEMICAL FURNACES.
2"@ a/ZZ whom t may concern:
Be it known that I, JOHN AKRILL, of W'illiamsburg, Kings county, State of New York, (manufacturer,) have invented, made, -and applied to use certain new and useful Im-l provements inthe Construction of Retorts, which I have arranged and applied with furnaces and chambers, expressly as the means to effect all the following operations: rst, the conversion of metallic zinc into white oxide of zinc for use as a paint or pigment; second, the obtaining hydrogen gas for illumination from metallic zinc and sulphurie acid, and converting the sulphate of zinc formed-by the process into white oxide; third, the calcination of sulphureted ores, and the conversion of the evolved sulphurous vgases to profitable uses; fourth, the conversion of ores`of copper into the metallic form; fifth, the formation of oxides of lead; sixth, the sublimation of sulphur and condensing t-he gas evolved for any use; seventh, the production of gas' for illumination from any usual materials, and the con version of the ammoniaeal residuum into the liquid ammonia of commerce; eighth, the deoxidizing oxidous ores of metal previous to conversion into the metallic form; ninth, the destructive distillation of animal, earthy, and vegetable matters for conversion into charcoal, and the conversion of the expelled ammoniacal vapors into the liquid ammonia of commerce; tenth, the mixing of copper with zinc or other alloys to form common brass, with a means to save'the vapor of the zinc and con dense it into oxide; eleventh, the annealing of metals. glass, &c. It is to be distinctly understood that no one of these processes is new in itself, and is expressly disclaimed as such herein, the intent of these improvements beingA simply to effect these several processes by new and economical means. These objects are attained by a peculiar arrangement of potzfurnaces or refinery-furnaces and reverberatory or puddling furnaces, or any effective furnace acting to heat retorts, evaporators, boilers, and kilns or ovens, with chambers for receiving metallic zinc or ore of zinc or other material to be operated on by sul phurous gas, water, and steam, such chambers having attached a peculiar form of mechanical exhaustion to effect a draft in and through all the several preceding parts, which are used primarily, successively, continuously, and combined in a manner for which I seek Letters Patent of the United States, and that the construction, arrangement, and operation of the means by whichthese several consecutive and combined operations are effected are fully and substantially set forth and shown in the following description, and in the drawings annexed to and making part 'of this my specification of my said improvements, wherein- Figure l is a general plan of -all the parts in place, with the position of some of the parts beneath denoted by dotted lines. Fig. 2 is a sectional elevation through the line A'eA of Fig. l, the vertical flues to carry'off the vapor from the retorts being denoted by dotted lines. Fig. is a general exterior elevation on the side B o'f Fig. 1. Fig. 4 is a cross-section through the line c c of Figs. l, 2, and 3 `of anest of four retorts, showing the horizontal lues that conduct the fire heat below and above each retort. Fig. 5 is a plan showing the construction of the dividing-piers bet Ween each two retorts, with Vertical ues connected one to each retort. Fig. Gis a plan at the in ner end of retorts, fitted' to carry down the oxide of zinc in vapor or the vapor of sulphur in sublimation. This mode of fitting the retorts may be inverted,and have connections to upper horizontal lines to carry off the sulphurous gases evolved in calcining metals orother gases in the opposite direction if needful. Fig; 7 is a sectional elevation of an extended arch to condense the vapors of sublimation or the oxides of metals in vapor. The other detached figures are separately referred to, and the like letters and numbers as marks of reference apply tothe same parts in each of the figures, as follows:
D D are pot-furnaces, built in the usual manner, but set at an elevation to lead the heat by flues a, formedby divisions 1 l, each with a. damper, 2, into the fire-chamber of the reverberatory furnace F, which may be used for melting, puddling, or refining metal, the fire act-ing on the material on the bed b conjointly with the surplus heat from the pot-furnaces. The heat from the furnace E is carried on by exit-fines c, formed by small piers 3 (shown by dotted lines in Fig. l) that support the end arch of the furnace.v These iiues continue over an arch, F, into a chamber, d.
G G are piers and arches iilled into form a level platform of masonry, e e,\above the arches, built with a central ue or barrel arch, 4, shown in Fig. 4, and by dotted lines in Figs. 1, 2, and 3, as passing on the bases of the piers.
j' is a pipe across through the masonry near the exit of the furnace E, opening into lengthwise pipes g g, formed or laid in the masonry over the arches G, and connecting4 at their sides into cross-pipes 7i, extending outside the masonry. The pipe f is to be connected at either end to any blower competent to drive a blast through all the pipes, for a purpose shown hereinafter.
H H is a double range of retorts on the platform e, each shown as made of clayvin three sections, but may be any number'of sections or parts, or may be made ot' iron, as hereinafter stated.
'i t' are thefwalls at each outer end of the re torts and furnaces, and 5 (see Figs. 2 and 4) are the sides of -the lower half of each retort ,that inclose the hearth 6.
7 is the crown and legs forming the upper half of each retort and covering the hearth.
8 is a groove formed one half in the upper sides, 5, of the hearth-pieces, and one half onv the under side of the-legs-7, to introduce any proper luting that will effectively close the joints between lthe two parts.
v ln theue-chamber d a stop, 9, directs the fire heat into the flues 10, under rthe hearths of the lower range of retorts H H, where the heat, acting and passing through the whole range, enters the lower part of the vertical flue l at the farther end of therange, in which a stop, 11, turns the current of heatback into and .through the second tier of flues, 12, above the crowns of the lower retorts and under the hearths of the upper range of retorts, into the part of the chamberd above the stop 9, which passes the current into the flues 13 through the crowns of the upper range of retorts and into the part of the iiue I above the stop 11.
K K are piers of the same material as the retorts, each having vertical fines 14, so fitted that each flue communicates withone retort by an opening, 16. Each pieris made with Aprojecting faces on each side to enter the retorts by rabbets 15, fitted to receive the inner ends of the retort and form a close `joint all round by any proper luting. The vertical flues 14 are closed on their upper ends by stoppers or other means that can Lbe removed to clean out the lines, andthe-lowerends ofthese vertical flues descend to openings through and into'the barrel-arch 4, to lead the gaseous products of the retorts away for use, as hereinafter shown.
rllhe heat acquired by the masonry when in use heats the air in its passage from the principal pipe f. The retorts are covered over with brick-work or any similar substance and aretied together by plates and tie-bars in any convenient manner.
At 7c k are vertical pipes from the air-pipes L., with branches Z, one opening into each retort, the access and quantity of air allowed to pass into the retort being regulated by cocks 17. At 18 the iluc 13 opens into a horizon` tal flue passing under the evaporatingpans L and above the arch M, which is used for a purpose hereinafter shown. After the current of lire heat has passed under the evaporating-pans it passes into the chamber N over the arch O, which chamber N contains a boil er, Q, that is heated by the current of heat beneath it when the heat is so used. The current in this case passes off by the due m into the chimney l?, and a furnacemay be made in the boiler, if found needful; vbut if the steam from the boiler is not in use for the precedent and subsequent operations, the dampers 19 are set to close the flues m to the chimney. In this.
case the draft and current of heat pass by the auxiliary iiue'u over the boiler and into the chimney P, the dampers 20 being open to pass the draft when the dampers 19 areshut, or the reverse if the heat is to operate on the boiler.
At o o Aare steampipes from each end of the boiler, passing along at each end of the two tiers of retorts, having branches p p and cocks 21 for passing a regulated supply of steam into the upperV retorts H Il and lower branches, q q, and'cocksl 22, (see Fig. 3,) to supply steam to the lower tier of retorts. At r r are doors, of any usual form, to open and close the retorts H. Vhen the retorts are' used to calci ne the sulphureted ores of metals. the arch or barrel 4 is ,to be continued, as shown in Figsl, 2, and .3, to the vertical flue 23, Figs. l and 2, which receives a regulated amount of steam through the pipes 27 and cocks 28, and, this iiue communicates by side openings, 24, to the chambers 25 of the nest of chambers S, (shown in plan in Fig. 1 and in longitudinal sectional elevation in Fig. 2,) and arranged to pass the sulphurous or other gas with steam from the pipes 27, if required, over any material on the floors of the chambers 25, and convert the materialsinto their respective compounds, the gas passing through all the chambers intoa vertical cross-fine, 26. The floors of the chambers 25 are perforated to pass any condensation or liquid matter into the chamber 29, whence it may be removed by a pipe, 30, or .by the door 31. The vertical cross-fine 26 is connected by apipe, 32, to the exhausting pump or blower R, made as shown in Fig-2, the pipe 32. passing into vthe semi-v4 .'circnlarfende'd case having twocovers fitted to receive two arbors, 33, on one end'of each of which is a tooth-wheel. These gear together, and on ,the end of one arbor 33 is a drum, s, to communicate any competent power and rotate the arbors 33 and tooth-wheels. These arbors carry within the case R a pair of rotary valves, T, formed in a shape approximating that of the numcral'8,.but so proportioned and set that as they rotate with the arbors 33 the convex parts t of eachl pass into the concave parts u of the other', the operation being that 4the portion of sulphurous or other gas in surplus from the precedent operations andlcoming from the last flue by the pipe 32, is partially drawn in on the entering side by the rotation of the valves T T, and carried round to the exit-nozzle c, by which the gas escapes or is forced `into a shallow chamber, U, beneath a grating or perforated floor, 34, which may sustain any articles that can be advantageously treated with or operated on by the sulphurous gas, which afterward finally passes off by the chimney V.
In the construction and arrangement of the parts, as before described, it will be seen that what is ordinarily the waste heat from the first furnaces, D D, goes by the lues a a t0 augment the heat in the reverberatory furnace E, and that the conjoined heat, which is now often allowed to escape up a chimney, is led through the ues c and 10, under the hearths of the lower range of retorts H, through the flues 12, between the crowns of the lower tier and the hearths of the second tier, then by the flues 13 over the crowns of the upper tier, by this means heating the whole of the retorts to a high temperature without the current of fire heat coming in contact with the contents of the retorts, these contents being thus subjected to the action of confined and quiescent heat, without being affected by the operation of a current of heat containing oxygen or other gases to interfere with the operations of the heat on the articles under treatment. The
current of unexpended heat, passing from the extremity of the iiue 13 by the upper part of the flue I, goes through the fines 18 under the evaporating-pans L, and heating these evaporates the aqueous contents to any requireddegree, thence passing by the fines into the chamber N to heat the water in the boiler Q for use, as herein shown. By this arrangement the greater part of what has hitherto been waste heat from the furnaces D and E is applied to useful purposes.
The construction and arrangement of the parts having been thus specied the uses of them are now to be described. The rst space between the first furnaces, D, and 'the reverberatory furnace E and the arch F between that and the retorts are merely to connect the parts and carry the lues so as to allow access for repairing or rebuilding either furnace Without disturbing the nest of retorts H, and are mere matters of practical convenience. The barrel-arch 4 beneath, running through and at right angles with the foundation of the piers, is to be used for receiving gases from the retorts, and conveying them to the chamber S as it receives them by the continuations downward of the vertical iiues 14 in the dividingpiers K, and this arch 4 may also be used in like manner for a variety of other purposes hereinafter set forth.
The large arch M under the evaporatingpans L, and the arch O under the boiler N may be used as kilns or ovens, and in these the retorts themselves may be dried and baked for use, or any other articles may be dried and baked by the surplus heat from the retorts, or
by auxiliary fires beneath or in the arches, or the heat from the retorts may be made to operate in conjunction'with the auxiliary fires, and when the evaporating-pans are not wanted to be used the heat may be carried down on one side and beneath the floors of the arches, and up on the opposite side, as shown by dotted lines in Fig. 2, the current of heat being regulated by dampers in any usual way.
The materials of these retorts and the means for and manner of making them preparatory to drying and using them will probably form the subject of a separate patent hereafter, as being a separate invention. Therefore these details are not given herein.
The original intention in these improvements was to produce or form the white oxide of zinc for use as a paint or pigment, by either burning the metallic zinc, and condensing the vapor, or by treating the sulphate of zinc produced by the action of sulphuric acid and water on metallic zinc, so as to convert this into a white oxide, and also have the hydrogen gas for use. The first process will now be described. Any or all of the retorts may be used for this purpose, and are to be fitted with openings in the place of the flue-piers K, as shown in Figs. 6 and 7 ,with lips 53 across the inner end of each hearth, and the arches G below made to extend to the center, and with-v out the barrel-arch or horizontal flue 4 running through them. These arches G thus made continuous may be lengthened at either end, as shown in Fig. 7, and coated inside with any cement that will form a smooth surface on the crowns, sides, and iioors. The outer end or ends of these arches are to be connected by an opening, 35, into one sideof a cold chimney, W, of any proper size to form a chamber, 36, and above this the chimney is to be fitted to carry one or more wire or cloth screens, 37, so fitted as to shake horizontally by a handle, and above these an exhausting-pump is to be tted exactly similar to the one already described as placed in the chimney V, and used in the same manner to form a suction-draft from the retorts H through the openings between the ends of each two hearths, and through the lengthened arches G to the chimney V. The operation and effect of this arrangement consequent on the mode of constructing the retorts and using the heat is that when the retorts are heated to a white heat, the metallic zincwhen put in is soon brought to a volatilizing or white heat in the retorts and steam or hot air, or both, let in by the cocks 17 01' 21 22. The metal unites with these in the form of a vapory oxide, and descending through the open ings between each heart-h by the suction-draft in the chimney WV, the vapor is condensed in the chambers formed by the arches G, the floccules are retained by the screens 37, and shaken down into the chamber 36 in a state of white oxide iit for use as a paint. In this mode of constructing and using the retorts, ues, and arches, any portion of the oxides that may condense upon and adhere to their surfaces may be removed in any convenient manner.
The principal objection to the use of hydrogen gas for any purpose, when evolved from metallic zinc by sulphuric acid and water, is believed to be that in this or any similar known process the cost of the gas is enhanced by the fact that the sulphate of zinc, which is the result of this process, has not hitherto been converted to any profitable use. This mode of producing hydrogen gas is well known, and forms no part of the invention hereinafter claimed; but the inode of making profit from the sulphate of Zinc, which is the result of the process, is next to be stated as connected with the apparatus herein described and shown. Metallic zinc in any usual proportions is to be placed in dilute sulphuric acid, and the hydrogen gas evolved by this'operation is to be applied to any useful purpose in any usual manner. For this part of the process any one or more of the arches G that are not otherwise used, is to have a competent tight tank tted into it, to contain the dilute sulphurc acid and zinc, with a pipe to conduct the hydrogen gas into one of the retorts for'carbonization, as is hereinafter described, or may be conducted away in any other direction for any other purpose. The sulphate of zinc, which is the result of this process, is to be placed in the evaporating-pans L and heated by the heat passing under the pans in the nue or iiues 18, and chloride of lime is to be introduced to oxidize any iron that may be present. The liquid is then to be decanted into other similar vessels and allowed to settle and precipitate the oxide of iron or othersforeign substances, after which the liquid is to be decanted into a third set of vessels and treated with ammonia or other alkaline substances. These combine with the sulphuric acid and liberate the zinc, which falls to the bottom of the vessel in the form of an oxide. The sulphate is then to be deeanted off as much as possible. These decantings may be effected by Siphon-pipes and cocks, or by any usual means. The zine which has fallen to the bottoni of the third set of vessels as an 'oxide or hydrate, is to be taken out and placed in strong sacking bags and pressed by a hydraulic press, or any competent press, to drive out as much as possible of the sulphate that may remain in the mass, which is then to be placed in clean water, into which steam is to be introduced, and the mass stirred and agitated in several washings, that the water may carry off as much as it will absorb of any remaining sulphate. Vhen sufficiently washed,
as much of the water'used as possible is to be lues 14 must -be closed, and the vapors expelled by the heat must be allowed to escape by not entirely closing the door of the retort, or by a regulated aperture in the door. Vhen nearly or quiteat white heat, the aqueous and foreign vapors will be expelled and the masses be in the condition of a white oxide of zinc, which is to be taken out and allowed to cool, and will be in a fit state for use as a paint or pigment in any usual manner.
In this process any ores of zinc, wastages containing zinc, or any dresses of zinc may be used; and after producing the hydrogen gas the sulphate `may be converted into white oxide, and the several mixtures of materials used in the process may be reserved and treated so as to avoid waste of the ammonia (if ammonia is used) by evaporation, as usual, and using it over again and by appropriating one portion of the retorts to the first process of oxidizing the metal, and a second portion to burning the hydrate or oxide, a third portion of the retorts may be appropriated to receive the hydrogen gas evolved in the second process, and carbonize it by combination with any proper material in the retort, whence the gas may be allowed to pass either up or down by the flues 14, and conveyed to a gasometer, in the usual way, for use in illumination.
rllhe next use to which these retorts H H are to be applied is the calcination of sulphureted ores of metals, and when so employed the ores under treatment are subjected to any required degree of heat in the presence of a regulated supply of steam and hot air, by the cocks 21, 22, or 17, the sulphurous gases evolvedy in the process going off by the fines 14 and barrelarch l to the chambers S, as before described. If these retorts are applied to preparing sulphureted ores of copper for conversion into the metallic state, the ores are irst to be calcined in one or more of the retorts with the door closed, and steam or hot air, or both, are to be passed in by the cocks, as described, the sulphurous gas going off by the lues 14 and arch 4 to be used in any ot' the modes herein described. Vhen sufficiently calcined, the
ores are to be taken to the reverberatory furnace E and reduced as usual, and then taken to the retorts and subjected to the saine treatment as before, after which they are to be taken through the reverberatory or smelting furnace and through the refinery working in the usual manner, the main points of the application and arrangement of the retorts and furnaces being, first, that by the retorts H H the sulphurous gases evolved are made useful in the manner described; and, second, that the first or calcining operations are effected by what is ordinarily the wasted heat from the rst and second furnaces acting through the retorts on the ores under treatment, so that the operations of ealcining, snielting, and refining can all be in progress by the same fires. The mode of effecting all these processes by the furnacefires is shown in the detached Fig. 8, where a:
is the refining-furnace acting with the reverberatory furnace E, the`conj oined surplus heat going off to heat the retorts by the iiues c.
In forming oxides of lead for any use, the metal is to be oxidized in either of the first furnaces, X or E, by the fires and by hot air and steam from the pipes o and k, after which the oxides so formed are to be burned in the retorts, then ground and floated in the usual manner, then returned to the retorts to be formed into litharge or red lead by the more brief or more lengthened operation of the heat and heated air when red lead is to be formed. These processes are to be conducted as in the ordinary manner, the same advantages being derived from the construction of the retorts and the useof the waste heat from the rst furnaces, as is shown in the other operations herein described. It will be understood that in thus working lead the ilues 14 will not be needed. The other uses to which the appara-4 tus may be applied are as follows:
The sulphurous gases evolved in any of the former processes, or the gases evolved in the sublimation of sulphur in the retorts, may be taken by the fines 14 and barrel-arch 4 to condensing-chambers, by connections of any 'proper kind, and condensed to form the sulphur of commerce, or the gases may be converted into sulphurie acid by the usual known mea-ns, and the acid may be used for converting theores or metal of Zinc into sulphate of zinc, by placing either of them in the same r chamber where the acid is formed, the hydrogen gas evolved beingused as described.
The retorts may be used for producing gas for illumination from coals or other fit materials, and when so employed a portion of the retorts may be used to vaporize the ammoniacal residunin of the process, by heating the mass and conveying away the vapor for con densation to form the liquid ammonia of commerce, by any convenient or usual means. Oxidous ores of metal may be deoxidized in these retorts preparatory'to the subsequent processes, for conversion into metallic forms by either or both of the first furnaces.
Vegetable materials of any kind may be subjected to destructive distillation in these retorts, and the gaseous products be taken off for use upward by the flues 14, or downward by these and the arch 4. The matter left in the retorts, being converted into charcoal and bones or peat, may be reduced to bone-black or charcoal. The ammoniacal vapor from either of these may be taken off by any convenient means for condensation into liquid ammonia.
The detached Figs. 9 and 10 are a lengthwise and cross section of an arrangement by which retorts of this character may be applied to the conversion of copper and zinc into brass, with the advantages of saving the vapor of the zinc which sublimes in the mixing, and condensing it into white oxide, and of using the secondary or now wasted heat of the fire to anneal the brass in the several stages of roll- I ing or working it. In these iigures, 3S is the furnace, set on one side of an arch, 39, which supports a melting-retort, 40, having no flue under the hearth, but iiues 12 in the crown of the retort 40, which open into the flue 10 under the hearth of the lower one of two annealing-retorts, 41. The heat passes into a chamber, 42, which directs the heat into the ilues 12 above the crown of the lower and under the hearth of the upper retort, into a chamber, 43, whence the heat passes by the upper iiues, 13, over the crown of the upper retort, into the chimney 44.
At 45 is the feeding-door in i'ront of the retort 40, and 46 is a damper or sliding door, as usual .v
47 is the top hole and plug to let out melted metal.
48 is an opening at thebaek end of the retort 40, with a damper or sliding door, 49, to regulate the eXit ofthe gaseous vapor from the zinc into a descending fiue, 50,with a door, 51. rPhe Hue 50 opens into the'areh 39, which is to be iitted with a door, 52, at each end, of cloth or gauze to retain the iioccules of the gaseous vapor from the zin'c. By this arrangement the copper to form brass is melted in the retort 40, and the zine added, as usual, with the slide 49 open. The vapor of the zinc goes off by the opening' 4S, and is condensed in the arch 39 into a white oxide that may be taken out for use, The retorts 41, heated by the surplus heat, will anneal the brass when made to permit successive rollings inthe manu facture, as usual, and this arrangement is equally available for refining copper and annealing it in the process of rolling; or iron melted in the furnaces and castinto form may be annealed in the same way.
Metals, glass, or other materials may be annealed and other substances heated or baked in these retorts.
lf any one retort becomes damaged in use, it can be removed and another put in by merely removing the wall and door in front instead of disturbing the whole nest or pile, and if it is intended to use the arrangement to produce gas for illumination, the retorts H and flue-piers K may be made of iron and arranged in the same manner, so as to be equally effective; and in somecases it may be useful to put in the lower nue-pier, K, only, andallow two ilues to open at the bottom of the top tier, so that the operations going on in the top retorts may be seen all through by merely opening both doors of the two top retorts. In this case a eross-lip, 53, may be placed at the inner end of each top retort, as shown in Fig. 7, to rise a little above the hearth, and prevent any substance falling into the descending iiues 14.
If the retorts are applied to subliming sulphnr or any similar operation, the lower fluepier, K, may be left out, and the upper kept in, as by thus reversing these positions the gases evolved may be taken upward from each four retorts by the ilues 14, into any proper reservoir or chalnber for ulterior operations, or if the sulphurous gases are taken downward, the barrel-arch 4: may be tapped laterally by pipes to lead the gas into any proper vessel in the arches Gr for the production of sulph-uric acid by the usual means.
Having described the construction, operation, uses, and effects of my inventiomand arrangements by which it will be seen that what is ordinarily wasted heat from any principal furnace or furnaces is by these arrangements made eifectively available for a great variety of purposes, and that these ends are attained not by so applying such waste heat-in any ordinary manner, but by using the herein-described new form and arrangement oi" retorts and flues, iirst, to use the heat, and seeond, to carry off and make useful a variety of gaseous products that are now deemed useless and noxious, and preventing these from coining in contact with the iire; and having stated various uses to which these improvements are applicable, so far as I now know of such uses, I do not mean to confine or limit myself to the described uses or to the number of retorts shown in the drawings, but to apply these improvements to any and all purposes, in any number and in any manner in which they may be found available, by varying the mechanical details to suitl particular purposes.
I am aware that I have herein described many and various uses to which these retorts are applicable, but these uses are merely detailed herein to illustrate the advantages and conveniences of my retorts, and to enable others to arrange the additional parts necessary in their various applications.
It will be seen that these retorts may be heated by any proper fire, whether it is the waste heat of a furnace or a separate re.
The main features ofA my invention are, the
forming retorts in one or more pieces, so that `they set together without needing masonrywork to form the flues, and each retort is supported and kept from warping or getting out of shape by its square form, making of any number, as it were, one solid piece, with all the necessary flues, and at the same time, if a retort wears out, all that is necessary is to put in a new one, which occupies the place of the old one, andforms its own ilues without needing separate parts or masonry-work, which at all times is expensive, and cannot always be built in particular situations, is liable to get out of repair and requires much more space and greater thickness of the parts, whereas my retorts are comparatively light, compact, easily repaired, and withal very tight, and elfective in use, and possess advantages consequent upon their peculiar construction, which I am not aware have ever before been obtained by any other form of retort.
I disclaim all processes to which these retorts are applicable, and all chemical compounds and mode of working the same, which are herein described, and I disclaim all the apparatus shown herein except as follows:
Vhat I desire to secure by `Letters Patent isi The retorts H, formed by the arch 7 and bed 6, with the sides 5 5, and perforated with the cross-dues 10, 12, or 13, below the bed and above the arch of each retort, said retorts being formed and operating as herein set forth, and being used for any purpose for which they may be available.
In witness whereof I have hereunto set my signature this 4th day of March, 1851.
JOHN AKRILL.
NTitnesses:
IVM. SnRRnLL, LEMUEL NV. SERRELL.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5964521A (en) * | 1997-01-14 | 1999-10-12 | Catalina Lighting, Inc. | Halogen torchiere lamp diffuser apparatus |
US20100188568A1 (en) * | 2007-07-05 | 2010-07-29 | Hironobu Abe | Digital video transport system |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5964521A (en) * | 1997-01-14 | 1999-10-12 | Catalina Lighting, Inc. | Halogen torchiere lamp diffuser apparatus |
US20100188568A1 (en) * | 2007-07-05 | 2010-07-29 | Hironobu Abe | Digital video transport system |
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