US8685767B2 - Surface plasmon dispersion engineering via double-metallic AU/AG layers for nitride light-emitting diodes - Google Patents
Surface plasmon dispersion engineering via double-metallic AU/AG layers for nitride light-emitting diodes Download PDFInfo
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- US8685767B2 US8685767B2 US12/963,117 US96311710A US8685767B2 US 8685767 B2 US8685767 B2 US 8685767B2 US 96311710 A US96311710 A US 96311710A US 8685767 B2 US8685767 B2 US 8685767B2
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/81—Bodies
- H10H20/811—Bodies having quantum effect structures or superlattices, e.g. tunnel junctions
- H10H20/812—Bodies having quantum effect structures or superlattices, e.g. tunnel junctions within the light-emitting regions, e.g. having quantum confinement structures
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/81—Bodies
- H10H20/822—Materials of the light-emitting regions
- H10H20/824—Materials of the light-emitting regions comprising only Group III-V materials, e.g. GaP
- H10H20/825—Materials of the light-emitting regions comprising only Group III-V materials, e.g. GaP containing nitrogen, e.g. GaN
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/83—Electrodes
- H10H20/832—Electrodes characterised by their material
Definitions
- III-Nitride semiconductors have significant applications for solid state lighting and lasers, power electronics, thermoelectricity, and solar cell applications.
- InGaN quantum wells (QWs) have been widely employed as an active region in nitride light-emitting diodes (LEDs) for solid state lighting application.
- the internal quantum efficiency in InGaN QWs LEDs is limited by: 1) high dislocation density leading to large non-radiative recombination rate, and 2) charge separation due to the existence of the electrostatic field in the QW leading to significant reduction of the radiative recombination rate.
- Another approach to enhance the radiative recombination rate and internal quantum efficiency of InGaN QWs active region is by employing surface-plasmon (SP) based LEDs. Since the InGaN QWs are coupled to surface plasmon mode at the interface of metallic film and semiconductor, the radiative recombination rate in the QWs can be enhanced due to the increased photon density of states near the surface plasmon frequency resulting from Purcell effect enhancement factor. The peak Purcell enhancement factor occurs at the surface plasmon frequency of a structure. Recent experiments have reported significant Purcell enhancement factor for InGaN/GaN QW by using a single Ag metallic layer, leading to an increase in internal quantum efficiency and radiative recombination rate.
- SP surface-plasmon
- Another recent approach based on metallo-dielectric stacked structures, proposes “tuning” the surface plasmon frequency by using one or more metal layers each spaced apart by a dielectric layer. Tuning can be accomplished by changing the combination of dielectric and metallic material as well as the thickness of the dielectric spacer layer.
- the Purcell enhancement factor based on this approach becomes reduced for the frequency regimes away from the surface plasmon frequency of the particular metal in use.
- the metallo-dielectric approach also requires complex processing for hybrid deposition of both dielectric and metallic layers, since the deposition environment for the metal is different than the deposition environment of the dielectric.
- a double-metallic deposition process is used whereby adjacent layers of different metals are deposited on a substrate.
- the surface plasmon frequency of a base layer of a first metal is tuned by the surface plasmon frequency of a second layer of a second metal formed thereon.
- the amount of tuning is dependent upon the thickness of the metallic layers, and thus tuning can be achieved by varying the thicknesses of one or both of the metallic layers.
- a double-metallic Au/Ag layer comprising a base layer of gold (Au) followed by a second layer of silver (Ag) formed thereon is deposited on top of InGaN/GaN quantum wells (QWs) on a sapphire/GaN substrate.
- QWs quantum wells
- This tunes the Purcell peak enhancement of the spontaneous recombination rate for nitride light-emitting diodes (LEDs).
- the dispersion relation is calculated by using a transfer matrix method.
- the Purcell peak enhancement factor is widely tuned between the surface plasmon frequencies of Au/GaN ( ⁇ sp — Au ) and Ag/GaN ( ⁇ sp — Au ). This approach can be widely applied for different combinations of double-metallic layers with varied surface plasmon resonant frequency.
- FIG. 1 illustrates a surface plasmon (SP) dispersion curves of thin Ag (Au) film on GaN substrate with Ag (Au) film thicknesses of 40, 10, and 5 nm;
- FIG. 2 illustrates (a) Surface plasmon dispersion curves and (b) Purcell factor as a function of energy for double-metallic Au/Ag layers on GaN substrate with Au/Ag layer thicknesses of 10 nm/10 nm, 5 nm/15 nm, 3 nm/17 nm, and 1 nm/19 nm.
- FIG. 3 illustrate electric fields for double-metallic (a) Au (3 nm)/Ag (17 nm) and (b) Ag (3 nm)/Au (17 nm) layers on a InGaN/GaN substrate; and
- FIG. 4 illustrates (a) photoluminescence (PL) spectra comparison of InGaN QWs coated with 50-nm silver and control sample (with no metal coating), and (b) the enhancement ratios of PL intensities of the InGaN QWs with metal coating and without metal coating as a function of the wavelength for various double-metallic Au/Ag layers thicknesses.
- PL photoluminescence
- This invention presents a novel approach to achieve wide-spectrum tuning of the surface plasmon resonant frequency for III-Nitride photonics devices by employing double-metallic layers, comprising different adjacent metals, on GaN.
- the use of double metallic Au/Ag layers enables tuning with the green spectrum regime for LEDs.
- FIG. 1 shows the surface plasmon dispersion curves (energy versus wave vector) of a single thin Ag (or Au) film on a GaN substrate as a function of the Ag (or Au) thicknesses of 40 nm, 10 nm, and 5 nm.
- FIG. 2( a ) shows the surface plasmon dispersion curves of thin double metallic Au/Ag layers on a GaN substrate with Au/Ag layer thicknesses of 0 nm/20 nm (i.e., Ag-only), 10 nm/10 nm, 5 nm/15 nm, 3 nm/17 nm, 1 nm/19 nm, and 20 nm/0 nm (i.e., Au-only).
- the dispersion curve can be engineered with different surface plasmon frequencies between ⁇ sp — Ag and ⁇ sp — Au .
- FIG. 2( b ) plots the Purcell factor as a function of energy for thin Au/Ag layers on a GaN substrate with Au/Ag layer thickness of 0 nm/20 nm (Ag-only), and 10 nm/10 nm, 5 nm/15 nm, 3 nm/17 nm, 1 nm/19 nm, and 20 nm/0 nm (Au-only).
- FIG. 2( b ) indicates that the Purcell enhancement factor can be tuned between the surface plasmon frequencies of Ag/GaN ( ⁇ sp — Ag ) and Au/GaN ( ⁇ sp — Au ) without decreasing the Purcell factor.
- the ratio of the thickness of the double metallic Au/Ag film determines the surface plasmon resonant frequency.
- FIGS. 3( a ) and 3 ( b ) show the electric field for the double-metallic layers of Au (3 nm)/Ag (17 nm) and Ag (3 nm)/Au (17 nm) on InGaN/GaN, respectively.
- PL measurements were performed by exciting the InGaN QWs with a 410 nm InGaN diode laser from the bottom of the substrate as shown in the inset of FIG. 4( a ).
- a silicon photo-detector was used to collect the emission from the sample.
- PL measurements were performed for InGaN QWs deposited with different metallic layers as follows: 1) 50-nm Ag, 2) 4-nm Au/46-nm Ag, 3) 8-nm Au/42-nm Ag, 4) 12-nm Au/38-nm Ag, and 5) 50-nm Ag.
- the PL measurements for these samples were compared with the corresponding control InGaN QWs without metal deposition.
- FIG. 4( a ) shows the PL spectrum for the InGaN/GaN QWs coated with 50-nm silver, which is compared with the control InGaN QW sample without metal coating. From FIG. 4( a ), significant PL intensity enhancement is observed by depositing Ag on top of InGaN/GaN QWs at peak emission wavelength of 480 nm.
- FIG. 4( b ) plots the enhancement ratios of PL intensities of the InGaN QWs with metal coating and without metal coating as a function of the wavelength.
- the Ag-coated InGaN QW sample shows larger enhancement at shorter wavelength due to the higher surface plasmon frequency.
- the peak enhancement ratio shifts to the longer wavelength region as shown in FIG. 4( b ).
- the Au-coated InGaN QWs shows the minimum enhancement ratio between 1.1-1.6, which is due to the reflection from the Au layer.
- the use of double-metallic layers (comprising the different metal layers) on top of a semiconductor presents a novel approach to tuning the surface plasmon frequency between the two individual surface plasmon frequencies of the metals on top of the semiconductor.
- the Purcell enhancement factor for Au/Ag with varied thickness ratios on GaN shows that the tuning of the surface plasmon frequency without the decrease of the Purcell enhancement factor is achieved.
- the concept of tuning of the surface plasmon frequency using double-metallic Au/Ag layers deposited on top of GaN can be extended with other metallic layers on GaN to tune to other SP frequencies including from UV up to the red spectral regime, from about 200 nm up to 100 micron.
- This novel approach realizes surface plasmon based LEDs with significantly enhanced radiative recombination rate and radiative efficiency for a wide frequency range in the visible spectral regime.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/963,117 US8685767B2 (en) | 2009-12-08 | 2010-12-08 | Surface plasmon dispersion engineering via double-metallic AU/AG layers for nitride light-emitting diodes |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26752909P | 2009-12-08 | 2009-12-08 | |
| US12/963,117 US8685767B2 (en) | 2009-12-08 | 2010-12-08 | Surface plasmon dispersion engineering via double-metallic AU/AG layers for nitride light-emitting diodes |
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| Publication Number | Publication Date |
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| US20110133157A1 US20110133157A1 (en) | 2011-06-09 |
| US8685767B2 true US8685767B2 (en) | 2014-04-01 |
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| US12/963,117 Expired - Fee Related US8685767B2 (en) | 2009-12-08 | 2010-12-08 | Surface plasmon dispersion engineering via double-metallic AU/AG layers for nitride light-emitting diodes |
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| US (1) | US8685767B2 (en) |
| WO (1) | WO2011072011A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2701467C1 (en) * | 2018-12-25 | 2019-09-26 | федеральное государственное автономное образовательное учреждение высшего образования "Санкт-Петербургский национальный исследовательский университет информационных технологий, механики и оптики" (Университет ИТМО) | Transparent conductive oxide |
| RU2701468C1 (en) * | 2018-12-25 | 2019-09-26 | федеральное государственное автономное образовательное учреждение высшего образования "Санкт-Петербургский национальный исследовательский университет информационных технологий, механики и оптики" (Университет ИТМО) | Transparent conductive oxide with gold nanoparticles |
| CN112183018A (en) * | 2020-09-30 | 2021-01-05 | 华南理工大学 | Simulation method for electric-thermal combined modeling of multi-gate-finger gallium nitride device |
Citations (14)
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| US20060038191A1 (en) | 2004-08-20 | 2006-02-23 | Matsushita Electric Industrial Co., Ltd. | Semiconductor light emitting device |
| US20060273327A1 (en) | 2005-06-02 | 2006-12-07 | Samsung Electro-Mechanics Co., Ltd. | Light emitting diode |
| US20070115474A1 (en) | 2003-10-09 | 2007-05-24 | Commissariat A L'energie | Microsensors and nanosensors for chemical and biological species with surface plasmons |
| US7242030B2 (en) | 2004-12-30 | 2007-07-10 | Industrial Technology Research Institute | Quantum dot/quantum well light emitting diode |
| US20070181889A1 (en) | 2006-02-08 | 2007-08-09 | Kenji Orita | Semiconductor light emitting device and method for manufacturing the same |
| US20080142782A1 (en) | 2006-12-15 | 2008-06-19 | Samsung Electro-Mechanics Co., Ltd. | Light emitting device |
| US7521273B2 (en) | 2003-04-15 | 2009-04-21 | Luminus Devices, Inc. | Light emitting device methods |
| US20090101931A1 (en) | 2004-09-22 | 2009-04-23 | Luxtaltek Corporation | Light Emitting Diode Structures |
| US20090114940A1 (en) * | 2007-11-01 | 2009-05-07 | National Taiwan University | Light-Emitting Device |
| WO2009096919A1 (en) | 2008-01-30 | 2009-08-06 | Hewlett-Packard Development Company, L.P. | Plasmon enhanced light-emitting diodes |
| US20090250685A1 (en) | 2008-04-02 | 2009-10-08 | Yong-Tae Moon | Light emitting device |
| US20090261317A1 (en) | 2005-09-06 | 2009-10-22 | Roberto Paiella | Enhancement of Light Emission Efficiency by Tunable Surface Plasmons |
| US20090267049A1 (en) | 2008-04-24 | 2009-10-29 | Hans Cho | Plasmon Enhanced Nanowire Light Emitting Diode |
| US20090315069A1 (en) | 2004-12-13 | 2009-12-24 | Hanbeam Co., Ltd. | Thin gallium nitride light emitting diode device |
-
2010
- 2010-12-08 US US12/963,117 patent/US8685767B2/en not_active Expired - Fee Related
- 2010-12-08 WO PCT/US2010/059457 patent/WO2011072011A1/en active Application Filing
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7521273B2 (en) | 2003-04-15 | 2009-04-21 | Luminus Devices, Inc. | Light emitting device methods |
| US20070115474A1 (en) | 2003-10-09 | 2007-05-24 | Commissariat A L'energie | Microsensors and nanosensors for chemical and biological species with surface plasmons |
| US20060038191A1 (en) | 2004-08-20 | 2006-02-23 | Matsushita Electric Industrial Co., Ltd. | Semiconductor light emitting device |
| US20090101931A1 (en) | 2004-09-22 | 2009-04-23 | Luxtaltek Corporation | Light Emitting Diode Structures |
| US20090315069A1 (en) | 2004-12-13 | 2009-12-24 | Hanbeam Co., Ltd. | Thin gallium nitride light emitting diode device |
| US7242030B2 (en) | 2004-12-30 | 2007-07-10 | Industrial Technology Research Institute | Quantum dot/quantum well light emitting diode |
| US20060273327A1 (en) | 2005-06-02 | 2006-12-07 | Samsung Electro-Mechanics Co., Ltd. | Light emitting diode |
| US20090261317A1 (en) | 2005-09-06 | 2009-10-22 | Roberto Paiella | Enhancement of Light Emission Efficiency by Tunable Surface Plasmons |
| US20070181889A1 (en) | 2006-02-08 | 2007-08-09 | Kenji Orita | Semiconductor light emitting device and method for manufacturing the same |
| US20080142782A1 (en) | 2006-12-15 | 2008-06-19 | Samsung Electro-Mechanics Co., Ltd. | Light emitting device |
| US20090114940A1 (en) * | 2007-11-01 | 2009-05-07 | National Taiwan University | Light-Emitting Device |
| WO2009096919A1 (en) | 2008-01-30 | 2009-08-06 | Hewlett-Packard Development Company, L.P. | Plasmon enhanced light-emitting diodes |
| US20090250685A1 (en) | 2008-04-02 | 2009-10-08 | Yong-Tae Moon | Light emitting device |
| US20090267049A1 (en) | 2008-04-24 | 2009-10-29 | Hans Cho | Plasmon Enhanced Nanowire Light Emitting Diode |
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| Publication number | Publication date |
|---|---|
| WO2011072011A1 (en) | 2011-06-16 |
| US20110133157A1 (en) | 2011-06-09 |
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