US865608A - Process of baking carbon electrodes and heating by electricity and combustion. - Google Patents

Process of baking carbon electrodes and heating by electricity and combustion. Download PDF

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US865608A
US865608A US25688805A US1905256888A US865608A US 865608 A US865608 A US 865608A US 25688805 A US25688805 A US 25688805A US 1905256888 A US1905256888 A US 1905256888A US 865608 A US865608 A US 865608A
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electrodes
combustion
heating
furnace
packing
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Edgar F Price
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof

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  • green or partially baked electrodes are placed around a resistance-core and within a suitable packing and an electric current is then passed through the core and in some cases through the packing and electrodes, which are thereby heated to the required temperature.
  • the electrodes are taken directly from the molds or press to the electric furnace and the baking is effected entirely by electricity, the expense is greater than when a combustion furnace is employed. If the electrodes have been initially baked by combustion, they are ordinarily'allowed to cool and the heat stored in them is dissipated and'lost before they are placed in the electric furnace. I v
  • the electrodes are initially heated by products of combustion and while hot are electrically heated to the required temperature.
  • the electrodes to be baked are'preferably embedded in a nonoxidizing, refractory packing, supported on the hearth of a-combustion furnace.
  • the final heating may be effected by an electric current passed through a resistance core, around and in proximity to which the electrodes are arranged. If an electrically-conductive packing is employed, a portion of the electric current will shunt from the core through the packing and electrodes, the resistance of which will increase the supply of heat;
  • the required temperature may also be pro Jerusalem without employing a core, by arranging the electrodes transversely in a conductive packing and passing the electric current directly through the electrodes and interposed layers of packing. as described in UL S. Patent'749,418, granted January 12, 1904, to F. G. Acheson.
  • heating gasesof the proper temperature are preferably passed around the charge both before and during the period of electric heating, the initial heating being thus effected solely by the combustion of fuel and the. final heating jointly by combustion and electricity.
  • Figure l is a horizontal section through a furnace for baking electrodes, with the electrodes, packing and resistance core in place, on the line II of Fig. 2;
  • Fig. 2 is a transverse vertical section on the line II-II of Fig. 1 and
  • Fig. 3 is a horizontal section through a similar furnace in which the electrodes are placed transverse to the path of the electric current.
  • the combustion furnace may be 'ofany usual or preferred type, that shown comprising side walls 1, end walls 2 and a hearth 3.
  • the side walls contain-door openings 4 which are brickedup during the operation of the furnace.
  • the hearth contains longitudinal, parallel flues 5, which receive and carry hot products of combustion and deliver them into the furnace chamber through openings 6 at one end. The products I thence pass longitudinally through the furnace and escape from the other end through a stack, not shown.
  • the carbon electrode bars 7 are placed end to end within a refractory non-oxidizing packing 8, which may consist either of granular coke, anthracite coal or' other material which is electrically conductive or will be converted into a conductor when heated, or of a nonconductor,- such as magnesia or sand;
  • the electrodes are grouped around a central resistance conductor 9, which may be of broken coke, the ends of which are in contact with electric terminals 10, preferably carbon bars, extending through theend walls of the furnace.
  • the electrodes, packing and core are supported on the furnace hearth between side and end walls 11, preferably of tile, which are spaced away from the side and end walls of the furnace.
  • the molded electrodes, packing and core are placed in position and hot products of combustion are passed through the hearth-fines and furnace chamber, therebyinitially heating the electrodes, packing and resistance conductor and increasing the'electrical conductivity of each.
  • the maximum economy is generally effected by supplying heating gases during the second stage of the process at a temperature at least equal to that of the surfaces from which the electrically-generated heat would otherwise be dissipated. If the gases are below this temperature, electric heat is lost, and if they are above it the transfer and loss of heat through the outer furnace-walls is unnecessarily increased.
  • I I i The furnace shown in Fig. 3 is identical with that previously described, but the resistance core is omitted and the electrodes 7 are placed transversely within an electrically-conductive packing 8. The end electrodes are in contact with the terminals 10 and the electric heating is effected by the resistance of the electrodes and packing, only.
  • Carbon electrodes can be baked at a much lower cost by the present process than by those described in my previous patents, since the initial heating is effected at a relatively low cost by combustion of fuel while the final high temperature is obtained by electricity, the heat supplied by combustion nevertheless being retained.
  • the initial heating is also advantageous in that it increases the electrical conductivity of the electrode-bars, packing and core, if used, thereby enabling the electric current to be supplied at a lower potential.
  • the electrodes to be baked may themselves constitute the resistance cbnductors specified in claim 1.
  • bakingcarbon electrodes which consists in placing the electrodes in proximity to a resistance conductor, initially heating the electrodes and resistance conductor by combustion, and heating the .hot electrodes to a higher temperature by passing an electric current through said resistance conductor and electrodes, as set forth.

Description

No. 865,608. PATENTED SEPT. 10, 1907.
E. F. PRICE. PROCESS OF BAKING CARBON ELECTRODES AND HEATING BY ELECTRICITY AND COMBUSTION. APPLICATION nun APR. 22, 1905.
2 SHEETSSHEET 1.
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d. 264 by 7 Z w No. 865,608. PATENTED SEPT. 10, 1907.
- E. I. PRICE. PROCESS OF BAKING CARBON ELECTRODES AND HEATING BY ELECTRICITY AND COMBUSTION.
APPLICATION FILED APR. 22, 1905.
2 SHEETS-SHEET 2.
ya. I
NITED STATES PATENT OFFICE.
EDGAR F. PRICE, OF NIAGABA FALLSJNEW YORK.
PR OCESS OF BAKING dARBON EILIELCYPRODES AND HEATING BY ELECTRICITY. AND
COMBUSTION.
Specification of Letters Patent.
Patented Sept. 10, 1907.
Application filed April 22, 1905. Serial No. 256,888.
tricity and Combustion, of which the following is a specification f In United States Letters Patent Numbers 752 357 and 752,358, granted to me February 16, 1904, l have described and-claimed certain processes of electrically baking the carbon electrodes which are used in carbid and other electric furnaces. In these processes. the
green or partially baked electrodes are placed around a resistance-core and within a suitable packing and an electric current is then passed through the core and in some cases through the packing and electrodes, which are thereby heated to the required temperature. If
the electrodes are taken directly from the molds or press to the electric furnace and the baking is effected entirely by electricity, the expense is greater than when a combustion furnace is employed. If the electrodes have been initially baked by combustion, they are ordinarily'allowed to cool and the heat stored in them is dissipated and'lost before they are placed in the electric furnace. I v
According to the present process, the electrodes are initially heated by products of combustion and while hot are electrically heated to the required temperature. The electrodes to be baked are'preferably embedded in a nonoxidizing, refractory packing, supported on the hearth of a-combustion furnace. The final heating may be effected by an electric current passed through a resistance core, around and in proximity to which the electrodes are arranged. If an electrically-conductive packing is employed, a portion of the electric current will shunt from the core through the packing and electrodes, the resistance of which will increase the supply of heat; The required temperature may also be pro duced without employing a core, by arranging the electrodes transversely in a conductive packing and passing the electric current directly through the electrodes and interposed layers of packing. as described in UL S. Patent'749,418, granted January 12, 1904, to F. G. Acheson.
In the electric furnaces now employed for the production of graphite, carborundum and calcium carbid, a considerable portion of the heat is conducted through the charge and furnace walls and lost, thereby materi-' ally decreasing the efliciencyof the furnace and increasing the cost of the product. This loss may be prevented by surl-ounding the electric furnace with a combustion furnace or heating fiues, and thus maintaining around the electric furnace a heat bufier or stratum of products of combustion having substantially the same temperature as the outer surface of the electric furnace walls. While the loss of heat from the outer surfaces of the walls of the combustion chamber or flues may then be equal to that normally dissipated from the electric furnace, the lost heat will be supplied by the direct combustion-of fuel and a considerable economy will thus be effected. For this reason, in the specific process of baking carbons heretofore referred to, heating gasesof the proper temperature are preferably passed around the charge both before and during the period of electric heating, the initial heating being thus effected solely by the combustion of fuel and the. final heating jointly by combustion and electricity.
Referring to the accompanying drawings-Figure l is a horizontal section through a furnace for baking electrodes, with the electrodes, packing and resistance core in place, on the line II of Fig. 2; Fig. 2 is a transverse vertical section on the line II-II of Fig. 1 and Fig. 3 is a horizontal section through a similar furnace in which the electrodes are placed transverse to the path of the electric current. I i
The combustion furnace may be 'ofany usual or preferred type, that shown comprising side walls 1, end walls 2 and a hearth 3. The side walls contain-door openings 4 which are brickedup during the operation of the furnace. The hearth contains longitudinal, parallel flues 5, which receive and carry hot products of combustion and deliver them into the furnace chamber through openings 6 at one end. The products I thence pass longitudinally through the furnace and escape from the other end through a stack, not shown.
In the furnace shown in Figs. 1, 2, the carbon electrode bars 7 are placed end to end within a refractory non-oxidizing packing 8, which may consist either of granular coke, anthracite coal or' other material which is electrically conductive or will be converted into a conductor when heated, or of a nonconductor,- such as magnesia or sand; The electrodes are grouped around a central resistance conductor 9, which may be of broken coke, the ends of which are in contact with electric terminals 10, preferably carbon bars, extending through theend walls of the furnace. The electrodes, packing and core are supported on the furnace hearth between side and end walls 11, preferably of tile, which are spaced away from the side and end walls of the furnace. In employing this furnace to carry out the process, the molded electrodes, packing and core are placed in position and hot products of combustion are passed through the hearth-fines and furnace chamber, therebyinitially heating the electrodes, packing and resistance conductor and increasing the'electrical conductivity of each. An electric '7 by the heat radiated from the core and by the current shunted through the packing and electrodes, if a con ductive packing be employed. It is preferable to simultaneously'supply hot products of combustionto the furnace and pass electric current through the core, the baking being thereby quickly and economically effected. The maximum economy is generally effected by supplying heating gases during the second stage of the process at a temperature at least equal to that of the surfaces from which the electrically-generated heat would otherwise be dissipated. If the gases are below this temperature, electric heat is lost, and if they are above it the transfer and loss of heat through the outer furnace-walls is unnecessarily increased. I I i The furnace shown in Fig. 3 is identical with that previously described, but the resistance core is omitted and the electrodes 7 are placed transversely within an electrically-conductive packing 8. The end electrodes are in contact with the terminals 10 and the electric heating is effected by the resistance of the electrodes and packing, only.
Carbon electrodes can be baked at a much lower cost by the present process than by those described in my previous patents, since the initial heating is effected at a relatively low cost by combustion of fuel while the final high temperature is obtained by electricity, the heat supplied by combustion nevertheless being retained. The initial heating is also advantageous in that it increases the electrical conductivity of the electrode-bars, packing and core, if used, thereby enabling the electric current to be supplied at a lower potential. The electrodes to be baked may themselves constitute the resistance cbnductors specified in claim 1.
I claim:- I
1. The process of baking carbon electrodes, which consists in initially heating the electrodes and a resistance conductor or conductors by combustion, and heating the liot'electrodes to a higher temperature-by passing an electric current through said conductor or conductors, as set forth.
2. The process of baking carbon electrodes, which consists in placing the electrodes in proximity to a resistance conductor, initially heating'the electrodes by combustion, and heating the hot electrodes to a higher temperature by passing an electric current throughv said resistance conductor-{as set forth.
3. The process of baking carbon electrodes, which consists in initially heating the electrodes by combustion, and heating the hot electrodes to a higher temperature by passing an electric current through them, as set forth.
4. The process of bakingcarbon electrodes, which consists in placing the electrodes in proximity to a resistance conductor, initially heating the electrodes and resistance conductor by combustion, and heating the .hot electrodes to a higher temperature by passing an electric current through said resistance conductor and electrodes, as set forth.
5. The process of baking carbon electrodes, which consists in placing the electrodes transverse to the path of current-flow, with intermediate layers of an electricallyconductive packing, initiallyheating the electrodes by combustion, and heating the hot electrodes to a higher temperature by passing an electric current through said electrodes and packing, as set forth.
- 6. The process of baking carbon electrodes, which consists in embedding the electrodes transverse to the path of current-flow in an electrically-conductive packing, initially heating the electrodes by combustion, and heating the hot electrodes to a higher temperature by passing an electric current through said electrodes and packing, as
set forth. I
' 7. The process of baking carbon electrodes, which con sists in initially heating the electrodes by combustion, heating the hot' electrodes to a higher temperature by electricity, and preventing the escape of electricallygenerated heat by a gaseous medium heated by combustion, as set forth.
8. The process of baking carbon electrodes, which con sists in initially heating the electrodes by combustion, heating the hot electrodes to a higher temperature by passing an electric current through a resistance conductor, and preventing the escape-of electrically-generated heat by maintaining hot products of combustion around the zone of electric heating, asset forth.
9. The process of baking carbon electrodes, which consists in initially heatingthe electrodes by combustion, heating the hot electrodes to a higher temperature by passing an electric current through a resistance conductor, and maintaining in contact with the surfaces which tend to dissipate electrically-generated heat, products of combustion having a temperature substantially equal to that of said surfaces, as setforth.
In testimony whereof, I 'ai'flixv my signature in presence of two witnesses.
EDGAR F. PRICE.
Witnesses:
C. C. Mosrrna, D. Bunonss.
US25688805A 1905-04-22 1905-04-22 Process of baking carbon electrodes and heating by electricity and combustion. Expired - Lifetime US865608A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2529041A (en) * 1946-12-16 1950-11-07 Ind De L Aluminium Sa Method of artificially producing carbonaceous composition pieces
US2644020A (en) * 1950-03-28 1953-06-30 Union Carbide & Carbon Corp Graphitization of carbon articles
US3998933A (en) * 1974-09-16 1976-12-21 Union Carbide Corporation Coke particle filter for pitch fumes to form electrodes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2529041A (en) * 1946-12-16 1950-11-07 Ind De L Aluminium Sa Method of artificially producing carbonaceous composition pieces
US2644020A (en) * 1950-03-28 1953-06-30 Union Carbide & Carbon Corp Graphitization of carbon articles
US3998933A (en) * 1974-09-16 1976-12-21 Union Carbide Corporation Coke particle filter for pitch fumes to form electrodes

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