US8097353B2 - Power generation system - Google Patents
Power generation system Download PDFInfo
- Publication number
- US8097353B2 US8097353B2 US12/070,516 US7051608A US8097353B2 US 8097353 B2 US8097353 B2 US 8097353B2 US 7051608 A US7051608 A US 7051608A US 8097353 B2 US8097353 B2 US 8097353B2
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- United States
- Prior art keywords
- lock
- fuel container
- fuel
- unit
- power generation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related, expires
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to a power generation system in which an interface with a fuel container is provided.
- the fuel cells convert chemical energy into electric energy by allowing the fuel and oxygen to react electrochemically.
- water is generated as a by-product of the reaction and is discharged because the fuel cells use the electrochemical reaction in which the chemical energy of the fuel is directly converted into the electric energy.
- the updated data cannot be written when the fuel cartridge is removed intentionally while the fuel cell module is activated.
- the data of the fuel cartridge can be written in the IC chip at every certain time.
- the timing when the fuel cartridge is to be detached is not known, the writing needs to be carried out all the time in order to update the data to be written in the chip just before detaching the fuel cartridge. Therefore, there is a problem that the electricity is wasted by always carrying out the writing operation and the operation time of the fuel cell module is reduced.
- the advantage of the present invention is that the updated data relating to the fuel and the like can be recorded in the fuel container efficiently in the power generation system.
- a power generation system comprises an attachment part to attach a fuel container which stores a fuel, a lock mechanism to detect a lock or a lock release of the fuel container which is attached to the attachment part and a data recording unit to record a data in a storage medium provided at the fuel container based on a detection of the lock release by the lock mechanism.
- the data may include as least one of a remaining amount data of the fuel in the fuel container, a data of number of times of attaching the fuel container and a data of date and time of using the fuel container.
- the data recording unit may read the data from the storage medium provided at the fuel container.
- the power generation system may further comprise a control circuit which stops a supply of the fuel from the fuel container by the lock mechanism detecting the lock release.
- the lock mechanism may comprise a lock unit to lock the fuel container and a lock recognizing unit which allows the control circuit to recognize that the lock unit locks the fuel container.
- the lock unit may comprise a connecting unit which is positioned at different positions between a case where the fuel container is locked and a case where the lock of the fuel container is released, and the lock recognizing unit may become in an electrically conductive condition with the connecting unit when the fuel container is locked by the lock unit and becomes in an electrically non-conductive condition with the connecting unit when the lock of the fuel container is released by the lock unit.
- the lock unit may comprise a connecting unit which is positioned at different positions between a case where the fuel container is locked and a case where the lock of the fuel container is released
- the lock recognizing unit may comprise a plurality of electrodes which are non-conductive with one another
- the connecting unit may make the plurality of electrodes be electrically conductive when the fuel container is locked by the lock unit and the connecting unit makes the plurality of electrodes be electrically non-conductive when the lock of the fuel container is released by the lock unit.
- the lock mechanism may comprise an engaging hole and a lock unit to lock the fuel container by engaging with the engaging hole.
- the power generation system may further comprise a control circuit which stops a supply of the fuel from the fuel container by the lock mechanism detecting the lock release
- the lock mechanism may comprise a lock unit to lock the fuel container and a lock recognizing unit which allows the control circuit to recognize that the lock unit locks the fuel container, the lock unit may be positioned at different positions between a case where the fuel container is locked and a case where the lock is released, the lock recognizing unit may become in either one of an electrically conductive condition and an electrically non-conductive condition according to the position of the lock unit, and the control circuit may detect whether the fuel container is locked or the lock is released by recognizing the conductive condition or the non-conductive condition of the lock recognizing unit.
- the power generation system may further comprise a control circuit which stops a supply of the fuel from one fuel container among a plurality of the fuel containers, in which the lock release is detected by detecting the lock release by using the lock mechanism which corresponds to the one fuel container, and which supplies the fuel from another fuel container.
- the power generation system may further comprise an electronic device.
- a power generation system comprises an attachment part to attach a fuel container which stores a fuel, a lock unit to lock the fuel container to the attachment part, a lock release start recognizing unit which allows to recognize that the lock unit starts to release the lock of the fuel container and a data recording unit to record a data in a storage medium provided at the fuel container based on a lock mechanism detecting a start of the lock release by the lock release start recognizing unit after the lock release of the fuel container is started and before the lock release is completed.
- the lock unit may comprise a connecting unit which is positioned at different positions between a case where the fuel container is locked and a case where the lock of the fuel container is started to be released, and the lock release start recognizing unit may become in an electrically conductive condition with the connecting unit when the fuel container is locked by the lock unit and becomes in an electrically non-conductive condition with the connecting unit when the lock of the fuel container is started to be released by the lock unit.
- the lock unit may comprise a connecting unit which is positioned at different positions between a case where the fuel container is locked and a case where the lock of the fuel container is started to be released
- the lock release start recognizing unit may comprise a plurality of electrodes which are non-conductive to one another
- the connecting unit may allow the plurality of electrodes be electrically conductive when the fuel container is locked by the lock unit and the connecting unit allows the plurality of electrodes be electrically non-conductive when the lock of the fuel container is started to be released by the lock unit.
- the lock unit may lock the fuel container by engaging with an engaging hole.
- the power generation system may further comprise an electronic device.
- FIG. 1 is an outside perspective view showing a state where two fuel containers 1 A and 1 B are attached to a power generation module 2 .
- FIG. 2 is an outside perspective view showing a state where the fuel container 1 A which is one of the fuel containers is detached from the power generation module 2 .
- FIG. 3A is an upper sectional view showing a locked state where a lock unit 31 A of a lock mechanism 3 A is engaged with the first fuel container 1 A.
- FIG. 3B is a front view showing a state where contact portions 341 A and 341 A of a connecting unit 34 A are connected to the electrode 35 A in the condition shown in FIG. 3A .
- FIG. 4A is an upper sectional view showing a state where the lock of the first fuel container 1 A is released by the lock unit 31 A of the lock mechanism 3 A.
- FIG. 4B is a front view showing a state where the contact portions 341 A and 341 A of the connecting unit 34 A are detached from the electrode 35 A in the condition shown in FIG. 4A .
- FIG. 5 is a perspective view of an inner mechanism of the power generation module 2 .
- FIG. 6 is an exploded perspective view of FIG. 5 .
- FIG. 7 is a block diagram showing a basic structure of a power generation system 500 .
- FIG. 8 is a perspective view when a notebook type personal computer 600 is seen from the front.
- FIG. 9 is a perspective view when the notebook type personal computer 600 is seen from the back.
- FIGS. 10A and 10B are a flowchart showing an operation of the first and the second fuel pumps P 1 and P 3 and the first and the second water pumps P 2 and P 4 and a switching operation process of a micro valve V 1 at the time of start-up.
- FIG. 11 is a flowchart showing an operation of the first and the second fuel pumps P 1 and P 3 and the first and the second water pumps P 2 and P 4 and a switching operation process of the micro valve V 1 when changing the first fuel container 1 A.
- FIG. 12 is an outside perspective view showing a state where the two fuel containers 1 A and 1 B are attached to another power generation module 2 X.
- FIG. 13A is an upper sectional view showing the locked state where the lock unit 31 A of the lock mechanism 3 A is engaged with the first fuel container 1 A.
- FIG. 13B is a front view showing a state where the contact portions 341 A and 341 A of the connecting unit 34 A are connected to the electrode 35 A in the condition shown in FIG. 13A .
- FIG. 14A is an upper sectional view showing a state where the lock of the first fuel container 1 A is not released by the lock unit 31 A of the lick mechanism 3 A by sliding the lock unit 31 A which is shown in FIG. 13A and where the contact portions 341 A and 341 A of the connecting unit 34 A are detached from the electrodes 35 A and 35 A and are non-conductive.
- FIG. 14B is a front view showing a state where the contact portions 341 A and 341 A of the connecting unit 34 A are detached from the electrode 35 A in the condition shown in FIG. 14A .
- FIG. 15A is an upper sectional view showing a state where the lock of the first fuel container 1 A is released by the lock unit 31 A of the lock mechanism 3 A by further sliding the lock unit 31 A which is shown in FIG. 14A .
- FIG. 15B is a front view showing a state where the contact portions 341 A and 341 A of the connecting unit 34 A are detached from the electrode 35 A in the condition shown in FIG. 15A .
- FIG. 1 is an outside perspective view showing a state where two fuel containers 1 A and 1 B are attached to the power generation module 2 and FIG. 2 is an outside perspective view showing a state where the fuel container 1 A which is one of the fuel containers is detached from the power generation module 2 .
- a left-right direction means the longitudinal direction of the power generation module 2 which is the X direction shown in FIG. 1
- an up-down direction means the height direction of the power generation module 2 which is the Y direction shown in FIG. 1
- a front-rear direction means the width direction of the power generation module 2 which is the Z direction shown in FIG. 1 .
- the front surface and the back surface are based on the view when the power generation module 2 is seen from the direction of FIG. 1 .
- the two fuel containers (hereinafter, called the first fuel container 1 A and the second fuel container 1 B) have similar structure. Therefore, only the structure of the first fuel container 1 A is described in the following description, and the alphabet letter B is attached to the same numbers for the second fuel container 1 B which has a similar structure as the first fuel container 1 A or which has a structure symmetrical to the first fuel container 1 A, and the descriptions are omitted.
- the first fuel container 1 A is detachable from the power generation module 2 , and comprises a fuel reservoir unit 11 A to store the fuel 18 and a water reservoir unit 12 A to store the water 19 which are constituted of two hollow spaces one in the right and the other in the left inside thereof.
- the fuel 18 is mainly a simple chemical fuel or a mixture of chemical fuel and water.
- alcohol such as methanol, ethanol or the like
- ether such as dimethyl ether or the like
- a compound including hydrogen atom in its composition such as gasoline
- gasoline can be used as the chemical fuel.
- the mixture of chemical fuel and water a mixture in which methanol and water are equally mixed is used as the material for chemical reaction.
- a chemical fuel such as methanol or the like is used.
- the first fuel container 1 A is a transparent or a translucent unit, and is constituted of a synthetic resin material such as a polyethylene, a polypropylene, a polycarbonate, an acrylic or the like, for example.
- the fuel discharge unit 13 A which is provided on the back surface 1 a side and penetrates the back surface 1 a to communicate with the fuel reservoir 11 A in which the fuel 18 is stored and which discharges the fuel 18 to the after mentioned power generation module 2
- the water discharge 14 A which is provided on the back surface 1 a side and penetrates the back surface 1 a to communicate with the water reservoir unit 12 A in which the water 19 is stored and which discharges the water 19 to the power generation module 2 are respectively formed one in the right and the other in the left.
- the fuel discharge 13 A and the water discharge 14 A are formed evenly with the back surface 1 a so as not to protrude with respect to the back surface 1 a.
- a fuel outlet (omitted from the drawing) which is a through hole for discharging the fuel 18 in the fuel reservoir unit 11 A is formed at the fuel discharge unit 13 A, and a check valve (omitted from the drawing) for blocking the fuel from redundantly discharging outside from inside of the fuel reservoir unit 11 A is fitted at the fuel outlet.
- the check valve is a duck-bill valve in which a material having flexibility and elasticity is formed in a duck-bill shape, and the check valve is fitted in the fuel discharge unit 13 A in a state where the tip of the duck-bill shape is facing inside of the fuel reservoir unit 11 A.
- the ethylene-propylene-diene rubber (EPDM), a butyl rubber or the like is suggested as the material having flexibility and elasticity, and butyl rubber is preferably selected in practical use because butyl rubber generally exhibits low gas permeability among macromolecular elastic materials.
- the volume of the check valve can be made small because it does not have a complicated mechanical structure, and the cost reduction can be attempted.
- an insertion hole which allows inside of the fuel reservoir unit 11 A to communicate with outside can be provided at the check valve in advance when the fuel supply unit 24 A which is provided at the after mentioned power generation module 2 is inserted, or the structure may be such that the insertion hole is formed for the first time by inserting the fuel supply unit 24 A.
- the insertion hole In a case where the insertion hole is provided in advance, a pressure is applied in the closing direction of the insertion hole at the periphery of the insertion hole by the inner pressure of the fuel 18 inside the fuel reservoir unit 11 A when the fuel 18 is filled inside the fuel reservoir unit 11 A. Therefore, the fuel 18 will not redundantly leak outside of the fuel container 1 A from the insertion hole.
- the fuel 18 is discharged to the power generation module 2 from the fuel reservoir unit 11 A via the fuel discharge unit 13 A and the fuel supply unit 24 A by the fuel supply unit 24 A of the power generation module 2 being inserted in the fuel discharge unit 13 A.
- a water outlet (omitted from the drawing) which is a through hole for discharging the water 19 in the water reservoir unit 12 A is formed at the water discharge unit 14 A, and a check valve (omitted from the drawing) for blocking the water 19 from redundantly discharging outside from inside of the water reservoir unit 12 A is fitted at the water outlet.
- the same check valve as the one provided at the above described fuel discharge unit 13 A can be used here.
- the water 19 is discharged to the power generation module 2 from the water reservoir unit 12 A via the water discharge unit 14 A and the water supply unit 25 A by the water supply 25 A of the after mentioned power generation module 2 being inserted in the water discharge unit 14 A.
- the IC (integrated circuit) chip 15 A which is a storage medium is provided at the position corresponding to the IC chip interface (hereinafter, called the IC chip I/F 28 A) which is provided at the attachment part 21 A of the after mentioned power generation module 2 .
- Data including at least either one of the remaining amount of the fuel 18 and the water 19 in the first fuel container 1 A, the number of times of attachment, the date and time of use and the like is to be written and read in the IC chip 15 A by the IC chip I/F 28 A which is the data recording unit.
- the IC chip 15 B which is the storage medium is provided at the position corresponding to the IC chip interface (hereinafter, called the IC chip I/F 28 B) which is provided at the attachment part 21 B of the after mentioned power generation module 2 .
- Data such as the remaining amount of the fuel 18 and the water 19 in the second fuel container 1 B, the number of times of attachment, the date and time of use and the like are to be written (recorded) and read in the IC chip 15 B by the IC chip I/F 28 B which is the data recording unit.
- a pair of groove portions 16 A and 17 A in which a pair of fixing parts 26 A and 27 A provided at the after mentioned power generation module 2 are respectively fitted are formed on the right and left side surfaces 1 b and 1 c of the first fuel container 1 A.
- Convex portions 161 A and 171 A which are respectively fitted in holes 261 A and 271 A formed at the fixed parts 26 A and 27 A are respectively formed at the groove portions 16 A and 17 A. Therefore, the first fuel container 1 A is attached to the power generation module 2 by fitting the fixing parts 26 A and 27 A in the groove portions 16 A and 17 A of the first fuel container 1 A, respectively, and by fitting the convex portions 161 A and 171 A in the holes 261 A and 271 A, respectively.
- the power generation module 2 is detachably provided to the first fuel container 1 A, and the power generation module 2 generates electricity by the fuel 18 and the water 19 being supplied from the first fuel container 1 A.
- the attachment parts 21 A and 21 B where the first and the second fuel containers 1 A and 1 B are respectively attached are provided at the power generation module 2 , one in the right and the other in the left.
- the power generation module 2 comprises a longitudinal unit 22 which extends along in a right-left direction of each fuel containers 1 A and 1 B and a shorter unit 23 which extends along in a front-rear direction of the first and the second fuel containers 1 A and 1 B at the right-left center position of the longitudinal unit 22 , and the power generation module 2 is formed in a T-shape in a plan view.
- the first fuel container 1 A is attached at the attachment part 21 A in the left side
- the second fuel container 1 B is attached at the attachment part 21 B in the right side.
- the second fuel container 1 B is attached in the same direction as the first fuel container 1 A. Therefore, at the left side portion and the right side portion of the power generation module 2 with respect to the right-left center line a of the shorter unit 23 , the after mentioned fuel supply 24 A and 24 B, the water supply 25 A and 25 B, the lock mechanism 3 A and 3 B and the like are respectively provided at the position corresponding to the first or the second fuel container 1 A or 1 B which is respectively attached to the right and left side portions of the power generation module 2 .
- the fuel supply unit 24 A to supply the fuel 18 to the power generation module 2 by being inserted in the fuel reservoir unit 11 A and the water supply unit 25 A to supply the water 19 to the power generation module 2 by being inserted in the water reservoir unit 12 A are provided, one in the right and the other in the left, so as to correspond with the fuel discharge unit 13 A and the water discharge unit 14 A of the first fuel container 1 A.
- the fuel supply unit 24 A is formed in a core-like shape, and a fuel supply unit which is made by carrying out the hydrophilizing process to a material having liquid absorbability with respect to the fuel 18 , for example, the porous material in which the spherical powder of about 100 ⁇ m made of stainless steel such as SUS316 or the like is consolidated by sintering, is suggested.
- the water supply unit 25 A is also formed in a core-like shape, and a water supply unit which is made of the above described material having liquid absorbability with respect to the water 19 is suggested.
- the IC chip I/F 28 A is provided between the fuel supply unit 24 A and the water supply unit 25 A at the position corresponding to the IC chip 15 A of the first fuel container 1 A which is to be attached.
- the IC chip I/F 28 A detects whether the first fuel container 1 A is attached or not by the IC chip 15 A after the lock by the lock mechanism 3 A is detected. Then, when the lock by the after mentioned lock mechanism 3 A is detected and when the IC chip I/F 28 A detects that the first fuel container 1 A is attached to the attachment part 21 A, the IC chip I/F 28 A receives the signal of the after mentioned control circuit 47 (see FIG.
- the IC chip I/F 28 A receives the signal of the control circuit 47 and writes the remaining amount data of the fuel 18 and the water 19 and the like of the first fuel container 1 A in the IC chip 15 A before the first fuel container 1 A is detached from the attachment part 21 A.
- a pair of fixing parts 26 A and 27 A which are respectively fitted in the groove portions 16 A and 17 A which are formed on the right and left side surfaces 1 b and 1 c , one on the right side and the other on the left side, of the first fuel container 1 A are formed. Further, the holes 261 A and 271 A which are respectively formed at the fixing parts 26 A and 27 A and in which the convex portions 161 A and 171 A respectively provided at the groove portions 16 A and 17 A are fitted are formed at the attachment part 21 A.
- a pair of fixing parts 26 A and 27 A are respectively disposed on the left side surface 22 b of the longitudinal unit 22 and the left side surface 23 b of the shorter unit 23 so as to face one another, and are formed so that the narrow parts are protruded toward the fuel container 1 A side.
- the groove portions 16 A and 17 A correspond with the form of each fixing parts 26 A and 27 A, and the groove portions 16 A and 17 A are formed so as to be wider toward the power generation module 2 side so that the groove portions 16 A and 17 A can be easily inserted in the tips of the fixing parts 26 A and 27 A, respectively.
- FIG. 3A is an upper sectional view showing a locked state where the lock unit 31 A of the lock mechanism 3 A is engaged with the first fuel container 1 A
- FIG. 3B is a front view showing a state where the contact portions 341 A and 341 A of the connecting unit 34 A having a plate spring are connected to the electrode 35 A in the condition shown in FIG. 3A
- FIG. 4A is an upper sectional view showing a state where the lock of the first fuel container 1 A is released by the lock unit 31 A of the lock mechanism 3 A
- FIG. 4B is a front view showing a state where the contact portions 341 A and 341 A of the connecting unit 34 A are detached from the electrode 35 A in the condition shown in FIG. 4A .
- the lock mechanism 3 A which makes the first fuel container 1 A be fixable is provided.
- the lock mechanism 3 A electrically detects the lock and the lock release of the attachment of the first fuel container 1 A to the attachment part 21 A.
- the lock mechanism 3 A comprises the lock unit 31 A which is provided on the front surface 23 d of the shorter unit 23 , the engaging hole 32 A which is formed on the right side surface 1 c of the first fuel container 1 A and in which the lock unit 31 A is engageable and the like.
- the lock unit 31 A is formed of a resin such as a polyacetal or the like having good slidability, and is fitted in the slide hole 33 A which is formed by penetrating the front surface 23 d and the left side surface 23 b of the shorter unit 23 so as to move freely in the right and left directions.
- the lock unit 31 A comprises two protrusions 311 A and 312 A which respectively protrude in the right and left and a knob 313 A which is protruded from the front surface 23 d and which is slidable by a user.
- the connecting unit 34 A is fixed on the back surface of the lock unit 31 A.
- the connecting unit 34 A is made of metal in which gold plating is carried out, and is fixed by heat welding or the like.
- the connecting unit 34 A comprises two contact portions 341 A and 341 A which contact with the after mentioned electrodes 35 A and 35 A and the lock recognizing unit 36 A having an insulated board and a joining unit 342 A which joins the two contact portions 341 A and 341 A, which is formed in the lock unit 31 A side in a convex shape and which is attached on the back surface of the lock unit 31 A.
- the lock recognizing unit 36 A is disposed inside of the shorter unit 23 , and the electrodes 35 A and 35 A which are separated so as to be electrically insulated to one another are fixed by having a predetermined space between one another on the lock recognizing unit 36 A.
- the after mentioned control circuit 47 has a function to detect whether the electrodes 35 A and 35 A are in the insulated condition or in the conductive condition to one another.
- the control circuit 47 outputs a predetermined voltage to one of the electrodes 35 A and 35 A, and determines that the electrodes 35 A and 35 A are in the insulated condition when the other electrode 35 A is floating, and determines that they are in the conductive condition when the other electrode 35 A is equipotential with the electrode 35 A in which the voltage is output.
- the connecting unit 34 A which is fixed to the lock unit 31 A can move freely in the right and left directions on the electrodes 35 A and 35 A and on the lock recognizing unit 36 A between the electrodes 35 A and 35 A by the sliding movement of the lock unit 31 A.
- the protrusion 311 A in the left side of the lock unit 31 A protrudes from the left side of the sliding hole 33 A and the contact portions 341 A and 341 A of the connecting unit 34 A contact with the electrodes 35 A and 35 A to be conductive by the lock unit 31 A sliding in the left side.
- the control circuit 47 determines that the lock unit 31 A is in the locked condition. Further, when the first fuel container 1 A is attached to the attachment part 21 A at this time, the protrusion 311 A in the left side of the lock unit 31 A engages with the engaging hole 32 A of the first fuel container 1 A and the first fuel container 1 A is locked so as not to disengage from the power generation module 2 .
- the protrusion 311 A in the left side of the lock unit 31 A is pulled out from the engaging hole 32 A of the first fuel container 1 A and the lock is released, and the first fuel container 1 A can be detached from the power generation module 2 .
- FIG. 5 is a perspective view of the inner structure of the power generation module 2
- FIG. 6 is an exploded perspective view of FIG. 5 .
- a flow path control unit 41 In the longitudinal portion 22 of the power generation module 2 , a flow path control unit 41 , a micro reforming unit 42 , a power generation cell 43 , an air filter 44 (see FIG. 7 ), a DC/DC converter 45 , a secondary battery 46 , the control circuit 47 (see FIG. 7 ) and the like are housed. In the shorter unit 23 , an air pump 48 is housed.
- the flow path control unit 41 is constituted of a multi layered substrate 411 in which a plurality of substrates are stacked.
- the flow path control unit 41 is formed with the multi layered substrate 411 , and comprises the first fuel pump P 1 to supply the fuel 18 from the first fuel container 1 A, the first water pump P 2 to supply the water 19 , the second fuel pump P 3 to supply the fuel 18 from the second fuel container 1 B, the second water pump P 4 to supply the water 19 , a micro valve V 1 which is connected to the first fuel pump P 1 , the first water pump P 2 , the second fuel pump P 3 and the second water pump P 4 and micro valves V 2 and V 3 which are connected to the after mentioned air pump 48 as shown in the after mentioned FIG. 7 .
- the first fuel pump P 1 , the first water pump P 2 , the second fuel pump P 3 and the second water pump P 4 are not shown in FIGS. 5 and 6 because they are disposed inside of the multi layered substrate 411 .
- the micro valves V 1 to V 3 are mounted on the upper surface of the multi layered substrate 411 .
- the micro valve V 1 is an on-off valve by which the fluid is allowed to flow or blocked by opening and closing the valve
- the micro valves V 2 and V 3 are the control valves (variable valves) to control the flowing amount of the fluid.
- the micro reforming unit 42 is surface mounted on the upper surface of the multi layered substrate 411 .
- the vaporizer 421 , the reformer 422 , the carbon-monoxide remover 423 and the combustor 424 which are shown in the after mentioned FIG. 7 are unitized to constitute the micro reforming unit 42 .
- the vaporizer 421 communicates with the reformer 422
- the reformer 422 communicates with the carbon-monoxide remover 423 .
- the micro reforming unit 42 is housed inside of the heat insulated package.
- each ports for each flow paths of the flow path control unit 41 to communicate with the vaporizer 421 , the reformer 422 , the carbon-monoxide remover 423 and the combustor 424 are provided.
- the power generation cell 43 is surface mounted along with the micro reforming unit 42 .
- the power generation cell 43 is a fuel cell in which a fuel electrode 431 which carries the catalyst, an oxygen electrode 432 which carries the catalyst and an electrolyte film 433 which is held between the fuel electrode 431 and the oxygen electrode 432 which are shown in the after mentioned FIG. 7 are unitized.
- On the lower surface of the power generation cell 43 each port (omitted from the drawing) which communicate with the fuel electrode 431 and the oxygen electrode 4432 are provided.
- the secondary battery 46 , the control circuit 47 and the DC/DC converter 45 are surface mounted on the upper surface of the multi layered substrate 411 .
- the air pump 48 is surface mounted at the center position on the lower surface of the multi layered substrate 411 via the air filter 44 (see FIG. 7 ), and is housed inside of the shorter unit 23 .
- a port 481 from which the aspirated air is exhausted to the air pump 48 is formed at the air pump 48 , and the air aspirated through the air filter 44 is to be supplied to each unit through the flow path in the multi layered substrate 411 via the port 481 .
- FIG. 7 is a block diagram showing the basic structure of the power generation system 500 .
- the power generation system 500 comprises the first and the second fuel containers 1 A and 1 B and the power generation module 2 which generates electricity by the fuel 18 and the water 19 being supplied from the first and the second fuel containers 1 A and 1 B.
- the power generation module 2 comprises the flow path control unit 41 , the micro reforming unit 42 including the vaporizer 421 , the reformer 422 , the carbon-monoxide remover 423 and the combustor 424 , the power generation cell 43 , the secondary battery 46 , the control circuit 47 , the DC/DC converter 45 , the air pump 48 , the air filter 44 and the like.
- the flow path control unit 41 comprises the first fuel pump P 1 and the first water pump P 2 which are connected to the first fuel container 1 A, the second fuel pump P 3 and the second water pump P 4 which are connected to the second fuel container 1 B and the micro valves V 1 to V 3 .
- the first fuel pump P 1 is connected to the fuel supply unit 24 A which is provided at the attachment part 21 A of the power generation module 2
- the first water pump P 2 is connected to the water supply unit 25 A
- the second fuel pump P 2 is connected to the fuel supply unit 24 B which is provided at the attachment part 21 B of the second fuel pump P 2
- the second water pump P 4 is connected to the water supply unit 25 B.
- the micro valve V 1 is provided between the first and the second fuel pumps P 1 and P 3 and the first and the second water pumps P 2 and P 4 and the vaporizer 421 .
- the micro valve V 1 blocks the fuel 18 and the water 19 from flowing into the vaporizer 421 from the first and the second fuel pump P 1 , P 3 and the first and the second water pump P 2 , P 4 or allows this flow of the fuel 18 and the water 19 by its opening and closing operation.
- the vaporizer 421 generates the fuel gas (a mixture of vaporized fuel and moisture) by vaporizing the fuel 18 and the water 19 which are supplied from the first fuel container 1 A and the second fuel container 1 B, and the reformer 422 generates the reformed gas including hydrogen by reforming the fuel gas which is supplied from the vaporizer 421 as shown in the chemical reaction formula (1).
- the carbon-monoxide remover 423 removes the carbon-monoxide which is generated in small amount by the chemical reaction formula (2) which occurs sequentially following the chemical reaction formula (1) by oxidizing the carbon-monoxide as shown in the chemical reaction formula (3).
- the combustor 424 is a device which combusts the remained hydrogen among the hydrogen supplied to the power generation cell 43 without occurrence of the after mentioned electrochemical reaction. Further, the combustor 424 sets each of the vaporizer 421 , the reformer 422 and the carbon-monoxide remover 423 so as to be heated to the suitable temperature so that they reach the temperature needed for the vaporizer 421 to vaporize the fuel 18 and the water 19 , for the reformer 422 to carry out the reaction of chemical reaction formula (1) in a good condition, and for the carbon-monoxide remover 423 to carry out the reaction of chemical reaction formula (3) in a good condition.
- Hydrogen which is supplied from the carbon-monoxide remover 423 is supplied to the oxygen electrode 432 of the power generation cell 43 , and air is supplied to the fuel electrode 431 from outside by the air pump 48 .
- hydrogen in the gas mixture is separated into hydrogen ion and electron by being effected by the action of catalyst particle of the oxygen electrode 432 as shown in the electrochemical reaction formula (4).
- the hydrogen ion is conductive to the fuel electrode 431 through the electrolyte film 433 , and the electron is taken out as the electrical energy (generated electricity) by the oxygen electrode 432 .
- the micro valves V 3 and V 3 are respectively connected to the air pump 48 via each of the flow rate sensors S 1 and S 2 .
- the micro valve V 2 is provided between the air pump 48 and the carbon-monoxide remover 423 , and blocks or adjusts the flowing of the air into the carbon-monoxide remover 423 from the air pump 48 by its opening/closing operation.
- the micro valve V 3 is provided between the air pump 48 and the combustor 424 , and blocks or adjusts the flowing of the air into the combustor 424 from the air pump 48 by its opening/closing operation.
- the control circuit 47 is constituted of the standard type CPU (Central Processing Unit), the RAM (Random Access Memory), the ROM (Read Only Memory) and the like, for example.
- the first and the second fuel pumps P 1 and P 3 , the first and the second water pumps P 2 and P 4 and the air pump 48 are electrically connected to the control circuit 47 via a driver (omitted from the drawing).
- the control circuit 47 controls the pumping operation (including the adjustment of delivery rate) of each of the first and the second fuel pumps P 1 and P 3 , the first and the second water pumps P 2 and P 4 and the air pump 48 .
- the lock recognizing units 36 A and 36 B of the lock mechanisms 3 A and 3 B and the IC chip I/F 28 A and 28 B are electrically connected to the control circuit 47 .
- the control circuit 47 detects the lock or the lock release by the lock mechanisms 3 A and 3 B by the presence or absence of the electrical connection. Particularly, when the contact portions 341 A and 341 A of the connecting unit 34 A of the lock mechanisms 3 A and 3 B are respectively connected to the electrodes 35 A and 35 A, the control circuit 47 detects that the lock units 31 A and 31 B are in the locked condition, and when the contact portions 341 A and 341 A of the connecting unit 34 A are separated from the electrodes 35 A and 35 A, the control circuit 47 detects that the lock of the lock units 31 A and 31 B are released.
- control circuit 47 detects whether the first or the second fuel container 1 A or 1 B is attached to the attachment part 21 A or 21 B by the IC chip I/F 28 A or 28 B detecting the IC chip 15 A or 15 B.
- control circuit 47 detects that the first or the second fuel container is locked by the lock mechanism 3 A or 3 B, and when the control circuit 47 detects that the first and the second fuel container 1 A or 1 B is attached by the IC chip I/F 28 A or 28 B detecting the IC chip 15 A or 15 B, the control circuit 47 controls so as to read the remaining amount data of the fuel 18 and the water 19 and the like which are stored in the IC chip 15 A or 15 B in the IC chip I/F 28 A or 28 B. Then, when each remaining amount is less than a predetermined amount needed for the power generation, the control circuit 47 does not activate the power generation system 500 or stops the operation of the power generation system 500 .
- the control circuit 47 activates the power generation system 500 or controls so as to maintain the operation of the power generation system 500 .
- the control circuit 47 detects that the lock of the first or the second fuel container is released by the lock mechanism 3 A or 3 B, and when the control circuit 47 detects that the first or the second fuel container 1 A or 1 B is attached by the IC chip I/F 28 A or 28 B detecting the IC chip 15 A or 15 B
- the control circuit 47 calculates the remaining amount of the fuel 18 and the water 19 in the fuel container 1 A or 1 B from the sent amount of the fuel 18 and the water 19 , and controls so as to write the remaining amount of the fuel 18 and the water 19 in the IC chip 15 A or 15 B by the IC chip I/F 28 A or 28 B according to the detection by the lock mechanism 3 A or 3 B before the first or the second fuel container 1 A or 1 B which is in the middle of solution sending is detached.
- the micro valves V 1 to V 3 are electrically connected to the control circuit 47 via a driver (omitted from the drawing), and the flow rate sensors S 1 and S 2 are also electrically connected to the control circuit 47 .
- the control circuit 47 detects the locked condition by the lock mechanism 3 A or 3 B which is described above, and when it is confirmed that at least one of the first fuel container 1 A and the second fuel container 1 B is attached and that the remaining amount of the attached fuel container is pertinent, the control circuit 47 selects either one of the combination of the first fuel pump P 1 and the first water pump P 2 and the combination of the second fuel pump P 3 and the second water pump P 4 according to the after mentioned step S 14 or step S 17 , and starts to supply the fuel and the like to the micro reforming unit 42 .
- control circuit 47 can recognize the flow rate of air by receiving the measurement result of the flow rate sensors S 1 and S 2 by driving the micro valves V 1 to V 3 along with the above movement of the pumps, and the control circuit 47 controls the opening/closing movement (including the adjustment of opening rate) of the micro valves V 1 to V 3 .
- control circuit 47 calculates each remaining amount of the fuel 18 and the water 19 of the first fuel container 1 A and each remaining amount of the fuel 18 and the water 19 of the second fuel container 1 B from the sent amount of the solutions, and used the fuel 18 and the water 91 in the first fuel container 1 A side first by operating the micro valve V 1 , the first fuel pump P 1 and the first water pump P 2 when the remaining amount in the first fuel container 1 A side is less than the remaining amount in the second fuel container 1 B side.
- control circuit 47 controls so as to use the fuel 18 and the water 19 in the second fuel container 1 B side by operating the micro valve V 1 , the second fuel pump P 3 and the second water pump P 4 when the remaining amount in the second fuel container 1 B side is less than the remaining amount in the first fuel container 1 A side.
- an electrical heater which heats the vaporizer 421 , the reformer 422 and the carbon-monoxide remover 423 is electrically connected to the control circuit 47 via a driver when the power generation cell 43 and the reformer 42 are stated-up and until the combustion heat of the combustor 424 is normalized.
- the control circuit 47 controls the heat release value of the electrical heater and its stoppage, and also the control circuit 47 can detect the temperature of each reactor of the vaporizer 421 , the reformer 422 and the carbon-monoxide remover 423 by measuring the resistance value of the electrical heater which changes depending on the temperature.
- the electrical heater may stop or reduce its heat value when the combustor 424 starts combustion and when the heating is stabilized.
- the DC/DC converter 45 is connected to the power generation cell 43 , and an outside power source (omitted from the drawing), that is, an outside device (load) which can operate by receiving the electricity supply from the power generation system 500 is connected to the DC/DC converter 45 .
- the DC/DC converter 45 is a device which converts the voltage which is output from the power generation cell 43 into a predetermined voltage according to the standard of the outside electronic device and outputs the converted voltage to the outside electronic device.
- the DC/DC converter 45 is connected to the control circuit 47 , and the control circuit 47 can detect the input electricity which is input to the DC/DC converter 45 from the power generation cell 43 .
- the secondary battery 46 is connected to the DC/DC converter 45 , and the electrical energy obtained at the power generation cell 43 is stored in the secondary battery 46 and the electricity can be supplied from the secondary battery 46 to the outside electronic device as an alternative to the power generation cell 43 when the generation of electrical energy in the power generation cell 43 is stopped.
- the control circuit 47 , each drivers, each sensors S 1 and S 2 and the electrical heater of the micro reforming unit 42 are electrically driven by a part of output of the secondary battery 46 via the DC/DC converter 45 , and they are electrically driven by a part of the output of the power generation cell 43 via the DC/DC converter 45 when the output of the power generation cell 43 is normalized.
- the power generation system 500 having the above structure is equipped in the desk-top type personal computer, the notebook type personal computer, the cell phone, the PDA (Personal Digital Assistant), the electrical planner, the watch, the digital still camera, the digital video camera, the game device, the game machine, the electronic device for household and other electronic devices (outside electronic devices), and is used as the power source to operate the outside electronic devices.
- the PDA Personal Digital Assistant
- the electrical planner the watch, the digital still camera, the digital video camera, the game device, the game machine, the electronic device for household and other electronic devices (outside electronic devices), and is used as the power source to operate the outside electronic devices.
- FIGS. 8 and 9 a case where the present invention is applied for the notebook type personal computer 600 is shown in FIGS. 8 and 9 .
- FIG. 8 is a perspective view of a case where the notebook type personal computer 600 is seen from the front
- FIG. 9 is a perspective view of a case where the notebook type personal computer 600 is seen from the back.
- the power generation module 2 is installed in the back surface of the notebook type personal computer 600 , and the first and the second fuel containers 1 A and 1 B are attachable to the power generation module 2 .
- the power generation system 500 operates by the operation signal being input to the control circuit 47 from the outside electronic device via the communication terminal and the communication electrode. This allows the control circuit 47 to operate the first and the second fuel pumps P 1 and P 3 , the first and the second water pumps P 2 and P 4 and the air pump 48 , and also to allow the electrical heater to generate heat. While the power generation system 500 is operating, the control circuit 47 controls the temperature so that each electrical heater be at the predetermined temperature according to the temperature data which is fed back from each electrical heaters.
- FIGS. 10A and 10B are a flowchart showing the activation of the first and the second fuel pumps P 1 and P 3 and the first and the second water pumps P 2 and P 4 and the switching operation process of the micro valve V 1 at the time of start-up.
- the control circuit 47 carries out the confirmation of the lock or the lock release by the lock mechanisms 3 A and 3 B (step S 1 ), and determines whether at least one of the lock mechanisms 3 A and 3 B in the right and left is locked or not (step S 2 ). Particularly, the control circuit 47 determines whether the electrodes 35 A and 35 A are made to be conductive or not and whether the electrodes 35 B and 35 B are made to be conductive or not by at least one of the lock unit 31 A and 31 B of the right and left lock mechanism 3 A and 3 B. The control circuit 47 determines that either of the lock mechanisms 3 A and 3 B is not locked when either of the electrodes is not conductive, and carries out the error notification of “lock released” (step S 3 ).
- the control circuit 47 determines that at least one of the lock units is locked, and the control circuit 47 carries out the confirmation of presence or absence of the fuel containers 1 A and 1 B by the IC chip I/F 28 A or 28 B which is in the locked side (step S 4 ).
- the confirmation of the presence or absence of the fuel containers 1 A and 1 B is carried out by the IC chip I/F 28 A or 28 B determining whether at least one of the fuel containers 1 A and 1 B is attached to the attachment part 21 A or 21 B or not by detecting the IC chip 15 A or 15 B (step S 5 ).
- the control circuit 47 carries out the error notification of “no fuel container” (step S 6 ).
- the control circuit 47 detects the remaining amount of the fuel 18 and the water 19 of the attached fuel container 1 A or 1 B (step S 7 ).
- the control circuit 47 assumes that the remaining amount of the fuel 18 and the water 19 is less than the amount (a predetermined amount) by which the power generation cell 43 can generate electricity.
- control circuit 47 determines whether the remaining amount of the fuel 18 and the water 19 of both the first and the second fuel contains 1 A and 1 B are less than the predetermined amount which is the amount just needed for the power generation or not (step S 8 ).
- the control circuit 47 carries out the error notification of “change fuel container” (step S 9 ).
- the control circuit 47 first detects whether the first fuel container 1 A is attached or not by the IC chip I/F 28 A (step S 10 ).
- the control circuit 47 When the first fuel container 1 A is not attached, the control circuit 47 carries out the error notification of “first fuel container not attached” (step S 11 ). Then, the control circuit 47 determines whether the remaining amount of the fuel 18 and the water 19 of the second fuel container 1 B is less than the predetermined amount which is the amount just needed for power generation or not (step S 12 ), and carries out the error notification of “change second fuel container” (step S 13 ) when the remaining amount is less than the predetermined amount. When the remaining amount of the fuel 18 and the water 19 of the second fuel container 1 B is more or equal to the predetermined amount, the control circuit 47 selects the second fuel pump P 3 and the second water pump P 4 and connects the micro valve V 1 to the second fuel container 1 B (step S 14 ).
- the control circuit 47 determines whether the second fuel container 1 B is attached or not (step S 15 ). When it is determined that the second fuel container 1 B is attached, the control circuit 47 determines whether the remaining amount of the fuel 18 and the water 19 of the second fuel container 1 B is more or equal to the remaining amount of the fuel 18 and the water 19 of the first fuel container 1 A or not (step S 16 ). When it is determined that the remaining amount of the second fuel container 1 B is less than the remaining amount of the first fuel container, the control circuit 47 selects the second fuel pump P 3 and the second water pump P 4 and connects the micro valve V 1 to the second fuel container 1 B (step S 14 ).
- control circuit 47 selects the first fuel pump P 1 and the first water pump P 2 and connects the micro valve V 1 to the first fuel container 1 A (step S 17 ).
- step S 18 the control circuit 47 determines whether the remaining amount of the fuel 18 and the fuel 19 of the first fuel container 1 A is less than the predetermined amount which is the amount just needed for power generation or not (step S 19 ), and the control circuit 47 selects the first fuel pump P 1 and the first water pump P 2 and connects the micro valve V 1 to the first fuel container 1 A when the remaining amount is more or equal to the predetermined amount (step S 17 ).
- step S 20 the control circuit 47 carries out the error notification of “change fuel container”
- control circuit 47 executes the flow of FIGS. 10A and 10B periodically, and detects the lock or the lock release of the lock mechanisms 3 A and 3 B, monitors the attachment or non-attachment of the first and the second fuel containers 1 A and 1 B and switches the micro valve V 1 to the fuel container 1 A or 1 B which is to be used by operating the first fuel pump P 1 and the first water pump P 2 or the second fuel pump P 3 and the second water pump P 4 according to the remaining amount of each fuel containers 1 A and 1 B.
- control circuit 47 repeats the above flow until the fuel 18 and the water 19 of one of the fuel containers (for example, the first fuel container) is used up or until one of the fuel containers (for example, the first fuel container 1 A) is detached, the control circuit 47 uses the fuel 18 and the water 19 of the other fuel container (for example, the second fuel container). Similarly, the control circuit 47 repeats the above flow until the fuel 18 and the water 19 of the other fuel container (for example, the second fuel container 1 B) are used up or until the other fuel container (for example, the second fuel container 1 B) is detached.
- the control circuit 47 carries out the error notification which indicates to change the fuel container, and the power generation system 500 is stopped.
- the power generation system 500 is activated and the above flow is executed, and the continuous operation can be carried out.
- the operation will be described by referring to a case where both the first fuel container 1 A and the second fuel container 1 B are respectively attached to the attachment parts 21 A and 21 B, where the remaining amount of the first fuel container 1 A is less or equal to the remaining amount of the second fuel container 1 B and is the amount just needed for power generation and where the first fuel pump P 1 and the first water pump P 2 are activated as an example in the following description.
- the fuel 18 in the fuel reservoir unit 11 A of the first fuel container 1 A is sent to the vaporizer 421 of the micro reforming unit 42 from the fuel supply unit 24 A via the micro valve V 1
- the water 19 in the water reservoir unit 12 A is sent to the vaporizer 421 of the micro reforming unit 42 from the water supply unit 25 A via the micro valve V 1 .
- outside air is sent to the combustor 424 via the micro valve V 3 and is sent to the carbon-monoxide remover 423 via the micro valve V 2 . Further, outside air is sent to the air electrode 432 of the power generation cell 43 by the activation of the air pump 48 .
- the control circuit 47 controls each micro valves V 2 and V 3 so that the air flow be the predetermined flow rate based on the flow rate data which is fed back from each flow rate sensors S 1 and S 2 .
- the supplied fuel 18 and water 19 are heated and vaporized (evaporation), and are supplied to the reformer 422 by becoming a gas mixture of methanol and water (water vapor).
- carbon-dioxide and hydrogen are generated by the methanol and the water vapor in the gas mixture which is supplied from the vaporizer 421 reacting by the catalyst (see the above chemical reaction formula (1)). Further, carbon-monoxide is sequentially generated following the chemical reaction formula (1) in the reformer 422 (see the above chemical reaction formula (2)). Then, the gas mixture of carbon-monoxide, carbon-dioxide, hydrogen and the like which is generated in the reformer 422 is supplied to the carbon-monoxide remover 423 .
- carbon-dioxide and hydrogen are generated from carbon-monoxide and water vapor in the gas mixture which is supplied from the reformer 422 , and also carbon-dioxide is generated by carbon-monoxide which is specifically selected from the gas mixture reacting with oxygen which is included in air supplied from the micro valve V 2 (see the above chemical reaction formula (3)).
- carbon-dioxide and hydrogen are generated from the fuel 18 which came through the vaporizer 421 , the reformer 422 and the carbon-monoxide remover 423 of the micro reforming unit 42 .
- the reformed gas carbon-dioxide, hydrogen and the like which is generated in the micro reforming unit 42 is supplied to the fuel electrode 431 of the power generation cell 43 after being humidified by the humidifier. Then, hydrogen in the reformed gas is separated into hydrogen ion and electron as shown in the above chemical reaction formula (4).
- the air which is supplied via the air pump 48 is supplied to the air electrode 432 of the power generation cell 43 .
- Oxygen in the air which is supplied to the air electrode 432 of the power generation cell 43 reacts with the hydrogen ion and electrode as shown in the above chemical reaction formula (5), and water is generated as a byproduct.
- the hydrogen which is unreacted in the fuel 431 side is sent to the combustor 424 as the off gas and is burnt, and is used as energy to arbitrary heat the micro reformation unit 42 .
- the exhaust gas which is obtained by the off gas being combusted in the combustor 424 is exhausted outside.
- the supplied air is exhausted along with water which is a byproduct.
- the electrical energy which is generated by the power generation cell 43 is charged to the secondary battery 46 . Further, the generated electrical energy is supplied to the DC/DC converter 45 , is converted into a predetermined voltage of direct current by the DC/DC converter 45 , and is supplied to the outside electronic device. The outside electronic device operates by the supplied electrical energy.
- the operation is the same as the above described operation for the case where the remaining amount of the first fuel container 1 A is more than the remaining amount of the second fuel container 1 B and when the second fuel pump P 3 is activated except that the fuel 18 is supplied from the second fuel container 1 B. Therefore, the description is omitted.
- FIG. 11 is a flowchart showing the activation of the first and the second fuel pumps P 1 and P 3 and the first and the second water pumps P 2 and P 4 and the switching operation process of the micro valve V 1 when the first fuel container 1 A is being changed.
- step S 31 when the control circuit 47 detects that the contact portions 341 A and 342 A of the lock unit 31 A in the first fuel container 1 A side are separated from the electrodes 35 A and 35 A and that the lock is released (step S 31 ), the control circuit 47 determines whether at least one lock mechanism ( 3 A or 3 B) of the right and left lock mechanisms 3 A and 3 B is locked to not (step S 32 ).
- the control circuit 47 confirms the presence or absence of the first fuel container 1 A by the IC chip I/F 28 A (step S 33 ) when the lock of the lock mechanism 3 B in the second fuel container 1 B side is released.
- the confirmation of the presence or absence of the first fuel container 1 A is carried out by the IC chip I/F 28 A detecting the IC chip 15 A to determined whether the first fuel container 1 A is attached to the attachment part 21 A or not (step S 34 ).
- the control circuit 47 carries out the error notification of “system malfunction” (step S 35 ).
- the IC chip I/F 28 A stores data of the remaining amount of the fuel 18 and the water 19 , the number of times of attachment and the like of the first fuel container A in the IC chip 15 A (step S 36 ). After this, the activated first fuel pump P 1 and the first water pump P 2 are stopped (step S 37 ).
- the control circuit 47 confirms the presence or absence of the second fuel container 1 B by the IC chip I/F 28 B (step S 38 ).
- the confirmation of presence or absence of the second fuel container 1 B is carried out by the IC chip I/F 28 B detecting the IC chip 15 B to determine whether the second fuel container 1 B is attached to the attached part 21 B or not (step S 39 ).
- the control circuit 47 carries out the error notification of “no fuel container” (step S 40 ).
- the control circuit 47 detects the remaining amount of the fuel 18 and the water 19 of the second fuel container 1 B (step S 41 ).
- the control circuit 47 determines whether the remaining amount of the fuel 18 and the water 19 of the second fuel container 1 B is more or equal to the predetermined amount which is needed for the power generation or not (step S 42 ), and carries out the error notification of “change fuel container” (step S 43 ) when the remaining amount is less than the predetermined amount.
- the control circuit 47 selects the second fuel pump P 3 and the second water pump P 4 , and connects the micro valve V 1 to the second fuel container 1 B side (step S 44 ).
- the updated data of the remaining amount and the like can be stored in the IC chip 15 A and 15 B because data such as the remaining amount of the fuel 18 and the water 19 and the like are promptly written in the IC chip 15 A and 15 B by the IC chip I/F 28 A and 28 B before the fuel containers 1 A and 1 B are detached from the attachment part 21 A and 21 B. Therefore, when the detached fuel container 1 A and 1 B are reused, the updated data of the remaining amount and the like can be detected by reading the data promptly without newly measuring the data and the like of the remaining amount and the like of the fuel containers 1 A and 1 B.
- the lock mechanisms 3 A and 3 B in the above described embodiment respectively include the lock units 31 A and 31 B and carry out the slide electrode type detection.
- the detection may be carried out by the optic sensor or the tact switch.
- the present invention may be a power generation module 2 X having a structure in which each open/close covers 51 and 51 which respectively cover the first fuel container 1 A and the second fuel container 1 B are fixed by being locked by the lock mechanisms 3 A and 3 B, respectively.
- the rotation axis 53 is respectively provided at the lower end in the right and left of the open/close cover 51 , the rotation axis 53 are housed in the round holes which are provided on both sides of the attachment part 21 A of the power generation module 2 X, and the open/close cover 51 has a mechanism in which the open/close cover 51 is rotateable around the rotation axis 53 of the power generation module 2 X.
- the protrusion 311 A (or 311 B) which is provided so as to correspond with the lock groove 52 engages with one of a pair of lock grooves 52 provided at both right and left ends of the open/close cover 51 .
- a small protrusion which corresponds to the other of the lock grooves 52 is provided at the power generation module 2 X.
- the fuel container 1 A (or 1 B) is completely cover with the power generation module 2 X and is protected by being housed in the engaging hole 32 A (ore 32 B). Further, even when the color of the fuel container 1 A (or 1 B) is different from the color of the electronic device which operates by the power generation module 2 X, the design can be improved as long as the color of the open/close cover 51 which houses the fuel container 1 A (or 1 B) accommodates the color of the electronic device.
- a system which is provided with two fuel containers, the first fuel container 1 A and the second fuel container 1 B, is described as an example.
- the system may be provided with three or more fuel containers.
- the system may be provided with only one fuel container.
- the micro reforming unit 42 is provided and the fuel 18 is supplied to the power generation cell 43 after being reformed.
- the power generation module may be a direct type power generation cell which directly supplies fuel to the power generation cell 43 from the first and the second fuel containers 1 A and 1 B without having the micro reforming unit 42 provided.
- the lock is released at the same time when the electrode 35 A and 35 A or the electrodes 35 B and 35 B become non-conductive with the contact portions 341 A and 341 A or the contact portions 341 B and 341 B, respectively, and the IC chip I/F 28 A or 28 B writes the data of the corresponding first fuel container 1 A or the second fuel container 1 B right after the lock is released.
- the locked condition may be maintained even when the electrodes 35 A and 35 A or the electrodes 35 B and 35 B become non-conductive with the contact portions 341 A and 341 A or the contact portions 341 B and 341 B.
- the lock mechanisms 3 A and 3 B may set so as to have three modes which are the locked and conductive mode in which the first fuel container 1 A or the second fuel container 1 B is in the locked condition by the lock unit 31 A or 31 B and in which the electrodes 35 A and 35 A or the electrodes 35 B and 35 B are in the conductive (contact) condition with the contact portions 341 A and 341 A or the contact portions 341 B and 341 B as shown in FIGS.
- the locked and non-conductive mode in which the first fuel container 1 A or the second fuel container 1 B is in the locked condition by the lock unit 31 A or 31 B by sliding the lock unit 31 A or 31 B and in which the electrodes 35 A and 35 A or the electrodes 35 B and 35 B are in the non-conductive (non-contact) condition with the contact portions 341 A and 341 A or the contact portions 341 B and 341 B as shown in FIGS.
- the IC chip I/F 28 A or 28 B which is the data recording unit is set so as to write the data such as the remaining amount of the fuel 18 and the water 19 in the first fuel container 1 A or the second fuel container 1 B, the number of times of attachment, the date and time of use and the like in the IC chip 15 A or 15 B.
- the first fuel container 1 A or the second fuel container 1 B is maintained to be locked even when the electrodes 35 A and 35 A or the electrodes 35 B and 35 B are in the non-conductive condition with the contact portions 341 A and 341 A or the contact portions 341 B and 341 B, that is, a time lag of moving to the condition shown in FIGS. 15A and 15B from the condition shown in FIGS. 14A and 14B occurs. Therefore, when writing of data is started after the lock mechanism is in the condition shown in FIGS. 14A and 14B and when the writing of data is competed before the lock mechanism is in the lock released and non-conductive mode as shown in FIGS. 15A and 15B , there is no chance that the first fuel container 1 A or the second fuel container 1 B is detached during the writing because the first fuel container 1 A or the second fuel container 1 B is locked while data is being written.
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Abstract
Description
CH3OH+H2O→3H2+CO2 (1)
H2+CO2→H2O+CO (2)
2CO+O2→2CO2 (3)
H2→2H++2e − (4)
2H++1/2O2+2e −→H2O (5)
Claims (15)
Applications Claiming Priority (2)
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JP2007-046906 | 2007-02-27 | ||
JP2007046906A JP2008210677A (en) | 2007-02-27 | 2007-02-27 | Attaching and detaching structure and power generation system |
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US20080206629A1 US20080206629A1 (en) | 2008-08-28 |
US8097353B2 true US8097353B2 (en) | 2012-01-17 |
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US12/070,516 Expired - Fee Related US8097353B2 (en) | 2007-02-27 | 2008-02-19 | Power generation system |
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JP5294407B2 (en) * | 2009-02-18 | 2013-09-18 | セイコーインスツル株式会社 | Fuel cell |
US9705151B2 (en) * | 2014-03-28 | 2017-07-11 | Infineon Technologies Ag | Battery, a battery element and a method for forming a battery |
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JP4765268B2 (en) * | 2004-06-01 | 2011-09-07 | 大日本印刷株式会社 | Replacement fuel tank and fuel cell system |
JP2006092986A (en) * | 2004-09-27 | 2006-04-06 | Seiko Epson Corp | Fuel cartridge, residual quantity detecting device for fuel cell, fuel cell system, and electronic apparatus |
JP2006302735A (en) * | 2005-04-22 | 2006-11-02 | Matsushita Electric Ind Co Ltd | Electronic equipment equipped with fuel cell |
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- 2007-02-27 JP JP2007046906A patent/JP2008210677A/en active Pending
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JP2003045468A (en) | 2001-08-01 | 2003-02-14 | Matsushita Electric Ind Co Ltd | Fuel cell device, fuel vessel used for it and fuel supply machine for it |
US6725151B2 (en) * | 2002-02-13 | 2004-04-20 | Nissan Motor Co., Ltd. | Fuel cell vehicle and method for predicting possible running distance |
US20060127733A1 (en) * | 2004-06-25 | 2006-06-15 | Ultracell Corporation | Fuel cartridge connectivity |
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US20080206629A1 (en) | 2008-08-28 |
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