US7662439B2 - Method for feeding liquid to a flame spraying apparatus - Google Patents
Method for feeding liquid to a flame spraying apparatus Download PDFInfo
- Publication number
- US7662439B2 US7662439B2 US10/544,933 US54493305A US7662439B2 US 7662439 B2 US7662439 B2 US 7662439B2 US 54493305 A US54493305 A US 54493305A US 7662439 B2 US7662439 B2 US 7662439B2
- Authority
- US
- United States
- Prior art keywords
- liquid
- pressure
- flame spraying
- generating part
- pressure generating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active, expires
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 143
- 238000010285 flame spraying Methods 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 12
- 239000013307 optical fiber Substances 0.000 claims abstract description 4
- 230000005484 gravity Effects 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 7
- 238000012544 monitoring process Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B15/00—Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
- B05B15/20—Arrangements for agitating the material to be sprayed, e.g. for stirring, mixing or homogenising
- B05B15/25—Arrangements for agitating the material to be sprayed, e.g. for stirring, mixing or homogenising using moving elements, e.g. rotating blades
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/16—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
- B05B7/20—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion
- B05B7/201—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion downstream of the nozzle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/2489—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device an atomising fluid, e.g. a gas, being supplied to the discharge device
- B05B7/2497—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device an atomising fluid, e.g. a gas, being supplied to the discharge device several liquids from different sources being supplied to the discharge device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/26—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device
Definitions
- the invention relates to a method for feeding liquid in flame spraying.
- the invention also relates to a liquid feeding device, as well as to a flame spraying apparatus.
- a flame is directed to the target that is being treated, and a desired material or additive is fed to said flame typically in liquid format.
- Said material meets the target to be treated typically in particle format, steam or gas.
- the properties of the target can be changed.
- the properties, such as colour, of the surface layer of an optical fibre structure, such as a fibre preform or optical fibre can be changed by means of flame spraying.
- a flame spraying apparatus comprises at least one nozzle by means of which a flame is directed to the target to be treated.
- the nozzle comprises several channels that are positioned co-axially. Different components are introduced to the flame through different channels, wherein different material are brought in contact with each other only after the opening of the nozzle.
- a liquid material is supplied via the innermost channel of the nozzle, and fuel gas, such as hydrogen, is supplied via a ring-like channel surrounding said channel.
- fuel gas such as hydrogen
- the feeding of liquid utilized in flame spraying must be accurate and it must endure back-pressure.
- the pressure of the supplied liquid is generated by means of a pump or it is based on height difference.
- piston-type solutions yielding of the feeder as well as leakage resulting therefrom have been detected when high pressures have been used, which have occurred for example when liquid has been pumped through capillaries.
- fluctuation of the pressure level of the liquid often takes place.
- the throttling of the liquid flow may also cause problems when the possibility of cavitation in the liquid flow increases.
- the present invention provides a method, a liquid feeding device, and a flame spraying apparatus.
- the basic idea of the invention is to supply the liquid used in flame spraying in a flow of substantially constant magnitude into a space in which prevails the air pressure that surrounds the device, i.e. said space is unpressurized. Via said space the liquid is transferred to the structure, in which the inflow plane is located on substantially higher level than the outflow plane.
- said structure By means of said structure is it possible to utilize earth's gravity to attain such a pressure in the liquid that is proportional to the density of the liquid and to the height difference of the liquid pillar.
- the liquid feeding device is constructed in such a manner that it comprises at least a dosing part and a pressure generating part connected thereto.
- the dosing part is connected to the pressure generating part in such a manner that the pressure generated in the pressure generating part is not exerted to said dosing part.
- the dosing part generates a substantially accurate volume flow in the pressure generating part, said volume flow being substantially equal to the liquid flow produced by the liquid feeding device in the flame spraying apparatus.
- the pressure generating part has the shape of a rather high container, such as a tubular container, in which pressure is generated by the height difference between the original liquid level and the upper liquid level.
- the pressure is generated in the liquid substantially by means of gravitational force, wherein the use of external force in the generation of pressure can be reduced.
- the liquid remains in the pressure generating part according to the invention for some time before it is conveyed to the flame spraying, wherein the composition of the liquid blends and becomes balanced, which is especially advantageous when a number of different kinds of liquids are fed into the pressure generating part.
- the gas bubbles possibly occurring in the liquid are also removed from the liquid during the dwelling in the pressure generating part. It is advantageous that the state of the liquid is such that there are no gas bubbles therein when the liquid enters the flame spraying device, because in this way it is possible to attain as steady spraying as possible.
- the dosing part is subjected to a substantially smaller pressure when compared to the pressure of the liquid fed by the liquid feeding device. This has a very advantageous effect on the durability and feasibility of the dosing part.
- the pressure generating part advantageously functions also as a balancing unit for the liquid flow.
- the dosing part supplies liquid to the pressure generating part within a long period of time in a steady volume flow, although said volume flow of the liquid supplied by the dosing unit can momentarily vary to a certain extent.
- the pressure generating part it is, however, possible to produce a substantially constant pressure in the liquid despite of the short-term variations in the volume flow caused by the dosing part.
- the liquid feeding device according to the invention functions well when liquid is supplied approximately 4 to 10 ml/min in the nozzle of the flame spraying device, in which the diameter of the liquid channel is under 1 mm.
- the invention is not, however, restricted to the amount of liquid to be supplied, or to the diameter of the liquid channel of the nozzle.
- FIG. 1 shows an embodiment of the liquid feeding device according to the invention
- FIG. 2 shows a cross-section of one embodiment of a nozzle of the flame spraying device when seen in a direction parallel to the flow direction
- FIG. 3 shows the cross-section of the nozzle of FIG. 2 in a side view
- FIGS. 4 to 9 show other embodiments of the liquid feeding device according to the invention.
- FIG. 1 shows an embodiment of the liquid feeding device according to the invention.
- the liquid feeding device according to said example comprises at least a pressure generating part 1 and a dosing part 2 .
- the function of the dosing part 2 is to feed liquid to the pressure generating part in such a manner that the pressure in the pressure generating part remains substantially constant.
- the dosing part 2 comprises at least a channel 3 for feeding liquid and a pump member P for moving the liquid. It is possible to use any suitable pump type, such as a hose pump, a film pump or a piston pump as the pump member P.
- the example shows two liquid containers 4 from which the liquids are pumped to the pressure generating part 1 .
- the Figure does not show the structures located in connection with the liquid containers 4 that are intended for supply of replacement air, such as valves equipped with filters.
- the pressure generating part 1 has a tubular shape and it is positioned in such a manner that its first end is located on a higher level than the second end.
- the upper end of the pressure generating part 1 is arranged in connection with the surrounding space, typically by means of filters, wherein for example the air pressure of the surrounding space functions as a starting level for the pressure of the pressure generating part.
- the pressure generating part is positioned in an angle of 40 to 70°, but naturally it can also arranged in another position.
- the pressure generating part 1 can be formed in many different ways, as presented for example in FIGS. 8 and 9 , wherein the properties of the liquid feeding device can be adjusted so that they comply well both with the entire process and the properties of the dosing part 2 .
- the inner diameter of the pressure generating part 1 is approximately 5 to 10 mm, and its height is approximately 1 to 1.5 meters, but the suitable diameter and height is selected according to the use.
- the height of the pressure generating part 1 is mainly affected by the desired pressure level of the liquid. By means of a small diameter it is possible to attain a small volume for the pressure generating part 1 , wherein a large amount of liquid is not required for generating the pressure. By means of a larger diameter of the pressure generating part, a larger volume is attained for the pressure generating part, wherein the liquid feeding device is better suitable for such uses in which large liquid flows are required.
- the pressure generating part 1 is designed in such a manner that the diameter of its lower part is smaller and the upper part has a larger diameter, such as for example in the embodiments of FIGS. 8 and 9 .
- the pressure is generated with a relatively small amount of liquid.
- said large upper part makes- it possible to use a dosing part 2 that generates a more irregular liquid flow, because the extension of the pressure generating part 1 balances the surface variation produced by the irregularly supplied liquid, and thus substantially standardizes the pressure as well.
- FIGS. 2 and 3 One principle view of a typical nozzle 9 is shown in FIGS. 2 and 3 .
- the nozzle is composed of two or several tubular channels 10 , 11 , which are placed within each other in a substantially coaxial manner.
- the number of the channels 10 , 11 depends on the number of different materials used in the flame spraying, the number of the materials in use being typically two to five (gas or liquid). It has been observed that the liquid feeding device according to the invention functions well for example when liquid is fed 4 to 10 ml/min via the innermost channel 10 of the nozzle 9 whose diameter is under 1 mm.
- the substantially constant pressure generated in the liquid by the liquid feeding device enables the capillary function of the channel, wherein the liquid ends up in the end of the channel 10 on the side of the flame spraying in a substantially steady volume flow.
- the liquid is absorbed from the outer channel 11 surrounding said innermost channel 10 towards the target to be treated as a result of the supplied strong material flow.
- the fuel gas such as hydrogen that is used in the process is typically fed from the outer channel 11 .
- the material to be supplied is “absorbed” and distributed evenly in the flow, and it reaches high speed before meeting the target.
- the invention is not dependent on the type of the nozzle 9 in use, or on that from which channel 10 , 11 of the nozzle each material is fed.
- the outlet port 8 connecting the pressure generating part 1 to the process in such a manner that the liquid flow provided by the same is substantially equal to the liquid flow produced by the dosing part 2 within a longer period of time.
- the pressure generating part 1 is provided with such an amount of liquid that the height of the liquid pillar produced by the same corresponds to the desired pressure.
- the temporary increase in the liquid level that takes place in the pressure generating part 1 brings about an increase in the pressure in the outlet port as well as an increase in the liquid flow. As a result of this the liquid level and thus also the pressure level return to the determined level.
- Such a solution is simple and gives a sufficient accuracy for various uses, especially when the densities of the liquid or liquids in use do not vary significantly.
- another way of determining the pressure is to determine the height of the liquid level, in which it is possible to utilize various known solutions, such as for example optical 5 a or electric sensors. Such a solution is relatively simple and sufficiently accurate for various uses, especially when the densities of the liquid or liquids in use do not vary. Furthermore, said arrangement is advantageously also suitable for monitoring the liquid level. If the density of the liquid varies, it is advantageous to determine the density of the liquid, which can be implemented for example in connection with the dosing part 2 .
- One way is to measure the mass of the liquid container 4 , wherein when the volume flow produced by the pump P is known, it is possible to determine the density of the liquid. Thereafter it is possible to determine the pressure on the basis of the density of the liquid and the liquid level, and by controlling the liquid flow of the dosing part 2 it is possible to influence the liquid level as well as the pressure.
- FIG. 5 show a third advantageous way of determining the pressure of the liquid in the pressure generating part 1 by means of a pressure sensor 5 b (or pressure meter), said pressure sensor being connected to the lower part of the pressure generating part.
- a pressure sensor 5 b or pressure meter
- the pressure sensor 5 b On the basis of the information obtained from the pressure sensor 5 b it is possible to adjust the liquid flow of the dosing part 2 or dosing parts to reduce or increase said flow.
- the liquid is fed to further processing, i.e. typically to a flame spraying apparatus in which the pressurized liquid is sprayed through the nozzle 9 towards the material to be processed.
- the travel of the liquid away from the pressure generating part 1 is adjusted with a closing means V, such as a valve, which is advantageously arranged such that is can be closed entirely.
- control CU of the device can be implemented in various ways, and the actual control unit can also be positioned in various different locations.
- control CU can be arranged in connection with the control unit of the rest of the flame spraying apparatus, but the control can also be arranged in connection with the sensor 5 a, 5 b, or the pump P, or the control can be implemented with a separate unit.
- the pressure generating part 1 generates a substantially constant pressure in the liquid to be supplied.
- the apparatus is typically equipped with structures such as overflow channels 6 and overflow containers 7 illustrated in the Figures.
- the liquid flow can also be controlled in possible problem and interference situations.
- the overflow container 7 is dimensioned in such a manner that there is enough room therein for the liquid contained in the liquid container 4 or liquid containers.
- the apparatus typically comprises such structures that are not shown in the Figures, such as the above-mentioned structures for supplying replacement air and gas removal valves, as well as possible sensors used for monitoring liquid levels.
- FIG. 6 shows yet another embodiment for implementing the liquid feeding device according to the invention. As can be seen in said example, it is possible to change for example the mutual placement of different liquid channels 3 , 6 by maintaining the basic idea of the invention.
- FIG. 7 shows yet another embodiment for implementing the liquid feeding device according to the invention.
- the liquid feeding channel 3 b close to the original level of liquid.
- Said embodiment is preferably used for adding such additives whose proportion in the total amount of liquid in use is small, and the proportioning of which is desired to be arranged so that it reacts to the control as well as possible.
- the invention is not restricted to the structure of the nozzle 9 used in the flame spraying apparatus or to the number of the liquid feeding devices. There may be only one or several liquid feeding devices according to the invention per one flame spraying apparatus, for example one for each nozzle 9 of the flame spraying apparatus.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Nozzles (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Treatment Of Fiber Materials (AREA)
- Spray Control Apparatus (AREA)
Abstract
Description
Claims (2)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20030200A FI114854B (en) | 2003-02-11 | 2003-02-11 | A method of supplying liquid to a flame spraying apparatus |
| FI20030200 | 2003-02-11 | ||
| PCT/FI2004/050012 WO2004071672A1 (en) | 2003-02-11 | 2004-02-11 | A method for feeding liquid to a flame spraying apparatus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20060172078A1 US20060172078A1 (en) | 2006-08-03 |
| US7662439B2 true US7662439B2 (en) | 2010-02-16 |
Family
ID=8565586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/544,933 Active 2027-05-05 US7662439B2 (en) | 2003-02-11 | 2004-02-11 | Method for feeding liquid to a flame spraying apparatus |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7662439B2 (en) |
| EP (1) | EP1596992B1 (en) |
| JP (1) | JP4705565B2 (en) |
| CN (1) | CN100434191C (en) |
| AT (1) | ATE427787T1 (en) |
| DE (1) | DE602004020450D1 (en) |
| FI (1) | FI114854B (en) |
| WO (1) | WO2004071672A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7768083B2 (en) | 2006-01-20 | 2010-08-03 | Allegro Microsystems, Inc. | Arrangements for an integrated sensor |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3501097A (en) | 1966-12-29 | 1970-03-17 | Metco Inc | Powder feed device for flame spray guns |
| EP0058571A1 (en) | 1981-02-18 | 1982-08-25 | National Research Development Corporation | Method and apparatus for delivering a controlled flow rate of reactant to a vapour deposition process |
| US4391860A (en) | 1981-01-21 | 1983-07-05 | Eutectic Corporation | Device for the controlled feeding of powder material |
| US4500038A (en) | 1982-11-01 | 1985-02-19 | Avco Corporation | Powder feed system with recirculator for plasma spray apparatus |
| US4540120A (en) | 1983-07-14 | 1985-09-10 | Metco, Inc. | Powder feed system for flame spray guns |
| US5803360A (en) * | 1995-11-27 | 1998-09-08 | Spitznagel; Max W. A. | Apparatus for providing enhanced spray capabilities for a gravity-fed spray gun |
| US7083332B2 (en) * | 2001-01-09 | 2006-08-01 | Takahiko Mukouda | Connector component for multi-core optical fiber, ferrule, and method for manufacturing the same |
| US7112758B2 (en) * | 2003-01-10 | 2006-09-26 | The University Of Connecticut | Apparatus and method for solution plasma spraying |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5759659A (en) * | 1980-09-25 | 1982-04-10 | Komatsu Ltd | Gas spray coating device for liquid |
| CN2052589U (en) * | 1989-04-06 | 1990-02-07 | 曹炼 | Isolation transformer of superminiature simulated power source |
| JPH03127019A (en) * | 1989-10-13 | 1991-05-30 | Sumitomo Electric Ind Ltd | Optical fiber for phase modulator |
| JP3833792B2 (en) * | 1997-10-29 | 2006-10-18 | トヨタ自動車株式会社 | Coating apparatus and coating method for applying multicolor pattern coating |
| JP2000061820A (en) * | 1998-08-17 | 2000-02-29 | Seiko Epson Corp | Chemical supply device |
| DE19909159C1 (en) * | 1999-03-02 | 2000-11-30 | Siemens Ag | Optical fiber arrangement |
| JP4253831B2 (en) * | 1999-03-19 | 2009-04-15 | 三浦工業株式会社 | Water softener |
| CN1115203C (en) * | 2001-08-31 | 2003-07-23 | 中国人民解放军第二炮兵工程学院 | Multifunctional supersonic flame spraying method and its intelligent control system |
-
2003
- 2003-02-11 FI FI20030200A patent/FI114854B/en active IP Right Grant
-
2004
- 2004-02-11 AT AT04710051T patent/ATE427787T1/en not_active IP Right Cessation
- 2004-02-11 CN CNB2004800037072A patent/CN100434191C/en not_active Expired - Lifetime
- 2004-02-11 US US10/544,933 patent/US7662439B2/en active Active
- 2004-02-11 WO PCT/FI2004/050012 patent/WO2004071672A1/en active Application Filing
- 2004-02-11 JP JP2006502082A patent/JP4705565B2/en not_active Expired - Lifetime
- 2004-02-11 DE DE602004020450T patent/DE602004020450D1/en not_active Expired - Lifetime
- 2004-02-11 EP EP04710051A patent/EP1596992B1/en not_active Expired - Lifetime
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3501097A (en) | 1966-12-29 | 1970-03-17 | Metco Inc | Powder feed device for flame spray guns |
| US4391860A (en) | 1981-01-21 | 1983-07-05 | Eutectic Corporation | Device for the controlled feeding of powder material |
| EP0058571A1 (en) | 1981-02-18 | 1982-08-25 | National Research Development Corporation | Method and apparatus for delivering a controlled flow rate of reactant to a vapour deposition process |
| US4500038A (en) | 1982-11-01 | 1985-02-19 | Avco Corporation | Powder feed system with recirculator for plasma spray apparatus |
| US4540120A (en) | 1983-07-14 | 1985-09-10 | Metco, Inc. | Powder feed system for flame spray guns |
| US5803360A (en) * | 1995-11-27 | 1998-09-08 | Spitznagel; Max W. A. | Apparatus for providing enhanced spray capabilities for a gravity-fed spray gun |
| US7083332B2 (en) * | 2001-01-09 | 2006-08-01 | Takahiko Mukouda | Connector component for multi-core optical fiber, ferrule, and method for manufacturing the same |
| US7112758B2 (en) * | 2003-01-10 | 2006-09-26 | The University Of Connecticut | Apparatus and method for solution plasma spraying |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE427787T1 (en) | 2009-04-15 |
| FI114854B (en) | 2005-01-14 |
| US20060172078A1 (en) | 2006-08-03 |
| JP2006517466A (en) | 2006-07-27 |
| JP4705565B2 (en) | 2011-06-22 |
| CN1747790A (en) | 2006-03-15 |
| FI20030200A0 (en) | 2003-02-11 |
| FI20030200L (en) | 2004-08-12 |
| EP1596992B1 (en) | 2009-04-08 |
| CN100434191C (en) | 2008-11-19 |
| DE602004020450D1 (en) | 2009-05-20 |
| EP1596992A1 (en) | 2005-11-23 |
| WO2004071672A1 (en) | 2004-08-26 |
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