US7628876B2 - Friction stir weld bonding of metal-polymer-metal laminates - Google Patents
Friction stir weld bonding of metal-polymer-metal laminates Download PDFInfo
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- US7628876B2 US7628876B2 US11/549,686 US54968606A US7628876B2 US 7628876 B2 US7628876 B2 US 7628876B2 US 54968606 A US54968606 A US 54968606A US 7628876 B2 US7628876 B2 US 7628876B2
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 251
- 239000002184 metal Substances 0.000 title claims abstract description 251
- 238000003756 stirring Methods 0.000 title claims abstract description 63
- 239000010410 layer Substances 0.000 claims abstract description 92
- 229920000642 polymer Polymers 0.000 claims abstract description 66
- 238000013016 damping Methods 0.000 claims abstract description 7
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- 229920006254 polymer film Polymers 0.000 abstract description 8
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- 229910000838 Al alloy Inorganic materials 0.000 description 1
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- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/12—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating the heat being generated by friction; Friction welding
- B23K20/122—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating the heat being generated by friction; Friction welding using a non-consumable tool, e.g. friction stir welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/16—Composite materials, e.g. fibre reinforced
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/16—Composite materials, e.g. fibre reinforced
- B23K2103/166—Multilayered materials
- B23K2103/172—Multilayered materials wherein at least one of the layers is non-metallic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/56—Damping, energy absorption
Definitions
- This invention pertains to making welded connections between metal layers or sheets that are separated by a layer of polymeric material. More specifically, this invention relates to a practice of making friction stir welds between metal sheets separated by a polymeric layer such as an adhesive layer, or a layer of viscoelastic vibration damping material, or the like. The invention also pertains to making welded connections between such a metal-polymer-metal laminates and a solid metal object or another metal-polymer-metal laminate.
- the sheets may be of the same or different metal alloy composition.
- the interposed polymer layer is an adhesive for bonding the metal sheets in a sandwich-like assembly. While the adhesive joins the sheets, it may also provide a corrosion resistant layer when the sheets are of different composition.
- the polymer layer may be a viscoelastic material for providing sound and vibration damping properties to the laminated metal sheet assembly.
- Resistance spot welding and rivet bonding are two methods of joining sheets that have been laminated for sound deadening or for increasing the resistance to peeling of adhesively bonded sheets.
- Each of these joining methods has disadvantages, and it is an object of this invention to provide an alternative method of providing bonds between facing metal sheets separated by a polymer layer. Furthermore, it is an object of this invention to provide an improved method of bonding a metal-polymer-metal laminate to a solid metal article or of bonding two metal-polymer-metal laminates.
- This invention is applicable to the joining of two or more metal workpieces with a polymer layer between facing surfaces of at least two of the workpieces.
- the metal workpieces will typically, but not necessarily, be in the form of sheets or plates and the workpieces may be of the same or dissimilar metal alloy compositions.
- the layer or film of polymer is an adhesive layer for bonding facing surfaces of the workpieces.
- the polymer layer serves a different function; the polymer layer may, for example, be a viscoelastic composition for sound and vibration dampening. But whatever the function of the polymer layer, a spot weld or linear weld is formed between the metal workpieces through the polymer layer by a friction stir welding practice.
- the polymer layer may be formulated so as to have electrical conductivity, but the practice of this invention does not have to utilize such conductivity.
- Friction stir welding uses a rotating tool that is sized and shaped for a welding application.
- the tool is characterized by a round shank with an end that serves as a shoulder for a smaller diameter, axially extending probe.
- the rotating probe is pressed into a metal surface or between abutting metal surfaces and the rotating shoulder of the tool may also engage the workpiece.
- the friction between the rotating tool and the contacted metal locally heats the workpiece(s) to momentarily soften, plasticize, and stir the metal.
- the stirred materials coalesce behind or around the probe when the tool is moved forwardly or retracted.
- the rotating probe is shaped to penetrate through one metal sheet, displace the underlying polymer film, and penetrate into the second metal sheet.
- the shoulder of the tool may then engage the upper surface of the first metal sheet further heating the weld site.
- the rotating tool is withdrawn the plasticized sheet metal at the interfaces of the two sheets unites to form a spot weld that joins the sheets through the otherwise intervening polymer film.
- a linear weld is formed when the rotating tool is moved in a path between or through the workpieces and then retracted after traveling a predetermined distance.
- a series of such friction stir spot welds or linear welds can be formed around the periphery or at other suitable locations or patterns of the sheet metal-polymer film sandwich assembly.
- the welds provide both a temporary bond between the sheets until the adhesive is cured and, thereafter, a supplementary bond resistant to peeling of the metal sheets.
- the friction stir welds serve to join the sheets against the interposed polymer layer.
- the friction stir welding tool including its probe is shaped to penetrate and plasticize the metal layers to be joined, and it is formed of a suitable hard and temperature resistant material to perform its function.
- a single tool may be used to successively form specified spot welds or linear welds between facing metal sheets or workpieces. Or a group of such rotating tools can be used in combination to make a group of welds at the same time.
- the practice of this invention is applicable to welding the facing metal sheets in a single metal-polymer-metal laminate. And it can be used when more metal layers are involved, with or without more intervening polymer layers. For example, two overlying metal-polymer-metal layered laminates with six material layers may be welded. In this example, the probe of the welding tool penetrates through the three layers of the upper laminate workpiece and through two layers of the lower laminate and into the bottom metal layer. Thus, the tool displaces two intervening polymer layers and ultimately forms a weld spanning from the top metal layer of the first laminate to the bottom metal layer of the second laminate.
- a single three-layer laminate is bonded to an underlying (or overlying) metal workpiece, with or without a second polymer layer.
- the friction stir tool penetrates all intervening layers to form a weld between a top metal layer and a bottom metal layer of the assembled pieces.
- the metal In friction stir welding the metal is softened and plasticized, and may contain a small portion of liquid phase material, such as the low-melting point intermetallic phases in an aluminum-magnesium alloy system, but it is not fully melted.
- the resultant welds may not be as strong as conventional metal to metal welds that do not involve the formation of low-strength intermetallic phases during friction stir welding.
- the adhesive properties of the polymer layer often supplement the strength of the weld.
- a further advantage of friction stir spot or linear welding applied to metal sheet-polymer film-metal sheet assemblies is that the metal layers can be of different alloys. They remain separated over most of their facing surfaces to minimize interfacial corrosion, while they are joined in friction stir welds of minimal contacting surface area.
- FIG. 1 is an oblique view of a friction stir weld tool retracted above the upper sheet of a metal sheet-polymer film-metal sheet assembly in a process of forming a series of spot welds along one edge of the sandwich structure.
- FIGS. 2A-2C are three cross-sectional views at a local joining region of metal sheet-polymer film-metal sheet assembly schematically illustrating the progressive movement of the friction stir weld tool in making a single spot weld between the metal sheets.
- FIG. 3 is a schematic cross-sectional view at a local joining region of a first metal-polymer-metal laminate overlying a second laminate for friction stir welding. This figure is intended to illustrate the depth to which the friction stir tool penetrates the overlying two laminates in the tool's fully inserted position for a spot weld.
- FIG. 4 is a cross-sectional view at a local joining region of a metal-polymer-metal laminate overlying a metal sheet for friction stir welding. This figure is intended to illustrate the depth to which the friction stir tool penetrates the laminate and metal sheet in the tool's fully inserted position for a spot weld.
- This invention uses a friction stir welding process to form spot welds or linear welds between facing metal sheets separated by a polymer layer.
- the need to form such welded bonds arises because assemblies of two facing metal sheets separated by a polymer layer are useful in making many articles of manufacture.
- a laminate of two thin steel sheets with an interposed viscoelastic polymer sound damping layer can be formed into useful automotive panels or other parts.
- a combination of two sheets of different metal compositions, selected for complementary performance characteristics can be separated with an adhesive layer for corrosion resistance or improved joint properties and formed into useful sheet or panel structures.
- the practice of the invention pertains to friction stir welding of a plurality of metal layers with one or more interposed polymer layers.
- the resulting linear or spot weld extends from an upper metal layer through intervening polymer and metal layers to a bottom metal layer or article.
- two overlying metal-polymer-metal laminates may be welded with the weld extending from a top metal layer through two polymer layers and two metal layers to a bottom metal layer or article.
- a metal-polymer-metal laminate may be welded to a metal body with or without an interposed polymer layer. The practice of the invention will be illustrated first in joining two metal sheets separated by a polymer layer.
- the practice of the invention uses one or more friction stir welding machines, each typically comprising a motor-driven rotating welding tool and fixturing means for positioning the tool against an assembly of the laminated metal sheets.
- the sandwich sheet assembly usually, but not necessarily, comprises two facing metal sheets of like shape (which is determined by the intended use of the laminated structure) with an interposed co-extensive polymer layer or film.
- the thickness of each sheet is predetermined for its intended application and is often in the range of about 0.5 to about 4 millimeters (mm).
- the thickness of the polymer layer is likewise determined by its function and is usually no thicker than the metal sheets.
- the laminated assembly is suitably supported on a table or fixture for the imposition of the force of the friction stir weld tool(s) in forming one or more spot welds or linear weld seams between the facing metal sheets.
- the welding end of the rotatable friction stir tool has a hard probe that is suitably rod or cone shaped with a rounded (for example, hemispherical) or flat end.
- the tool and especially the probe must have sufficient hardness, wear resistance, and high temperature strength to form repeated welds in the sheet metal assembly where the plasticizing heat for formation of the weld(s) arises from high force frictional contact between the rotating tool and the held-in-place sheet metal assembly.
- the probe is often suitably formed of a tool steel or a refractory material.
- FIG. 1 illustrates a portion of a laminated sheet metal assembly 10 .
- the assembly would be supported on a suitable holding table or fixture which is not shown in the figure to simplify the illustration.
- the laminated sheet metal assembly 10 includes an upper metal sheet 12 , a lower metal sheet 14 and an interposed polymer layer 16 .
- metal sheets 12 and 14 may each be of an aluminum alloy, each about 1.0 mm thick and of major surface area and shape for forming into a desired panel structure.
- Polymer layer 16 may be of a suitable adhesive or sound and vibration damping composition and pre-applied to one of the sheets to a nominal coating thickness of about 0.2 mm before the other sheet is placed on the polymer coating layer.
- the thicknesses of the metal sheets and polymer layers in the drawing figures are somewhat enlarged for easier viewing.
- the facing metal sheets of the laminated assembly are to be bonded together with a series of spot welds along the periphery of the sheet assembly.
- a rotatable friction stir welding tool is used in forming a sequence of friction stir spot welds between metal sheets 12 and 14 with included polymer layer 16 .
- Friction stir welding tool 22 would be motor driven and suitably supported for accurate engagement with selected surface locations on the top surface of upper sheet 12 .
- Such tools are known and, for simplicity of illustration, only the lower end of rotatable tool 22 and probe 24 with hemispherical tip (hemispherical tip 26 is better seen in FIGS. 2A-2C ) are shown.
- friction stir welding tool 22 has formed two friction stir spot welds which are indicated schematically by circles 28 on the top surface 20 of upper sheet 12 .
- Circles 28 illustrate that the friction stir welding process has momentarily plasticized and stirred the aluminum metal in sheet 12 and in sheet 14 at the locations of the circles 28 .
- the metal has changed only in that it was temporarily softened and plasticized by friction stir welding tool 22 in forming two welds. Since the approximate thickness of the metal sheets 12 , 14 and polymer layer 16 laminate is about 2.2 mm, the length of probe 24 is suitably about 1.8 mm. By way of example, the diameter of probe 24 may be about 3 mm. As illustrated in FIG. 1 the friction stir weld tool 22 is about to be moved to the right to form a third weld between sheets 12 and 14 .
- FIGS. 2A-2C are cross-sectional views of a small portion of laminated sheet metal assembly 10 at a representative predetermined location for the formation of a friction stir spot weld, for example a third weld between sheets 12 and 14 .
- a friction stir spot weld for example a third weld between sheets 12 and 14 .
- FIG. 2A the rounded tip 26 of probe 24 is being pressed into upper surface 20 of sheet 12 .
- the speed of rotation of tool 22 and the pressure applied by probe 24 are determined by experience or experiment to soften the engaged metal of sheet 12 and to penetrate and plasticize it. While this plasticization is not readily illustrated in FIGS. 2A and 2B , the metal is plasticized to permit probe 24 to penetrate sheet 12 .
- probe 24 has penetrated through metal sheet 12 and polymer layer 16 and entered lower metal sheet 14 .
- the length of probe 24 is made sufficient to penetrate at least part way through the thickness of lower sheet 14 as seen in FIG. 2B .
- Probe 24 is thus now stirring and plasticizing the surrounding metal in both metal sheets 12 and 14 and has shoved aside the polymer material contacted by the probe 24 .
- the rotating shoulder portion 30 surrounding the probe 24 at the lower end of tool 22 now also engages the underlying upper surface 20 of metal sheet 12 thereby further heating the metal. After friction stir tool probe 24 has suitably stirred metal in both metal sheets 12 , 14 it is retracted while still rotating.
- FIG. 2C schematically illustrates the friction stir weld site in the laminate body formed of metal sheet 12 , polymer layer 16 and metal sheet 14 .
- Retracted friction stir weld probe 24 is shown poised above sheet 12 leaving a probe-shaped hole 32 .
- the probe 24 is ready to be moved to the next weld site.
- the stirred metal in sheets 12 and 14 has flowed together to form annular weld 34 around hole 32 .
- Weld 34 extends from sheet 12 past the displaced portion of polymer layer 16 to sheet 14 and thus locally bonds metal sheet 12 to metal sheet 14 with metal from the two sheets.
- the polymer layer 16 surrounds weld 34 but is not incorporated in it.
- the stir action of tool 22 has slightly depressed the underlying surface of metal sheet 12 and displaced metal into an annular ridge 36 on the upper surface 20 of metal sheet 12 .
- a suitable friction stir welding probe is devised and shaped to penetrate though one metal sheet and into or through a second metal sheet or surface.
- the rotating probe displaces the portion of the polymer layer that it encounters and softens and stirs the metal regions that it engages for forming a weld.
- Softened metal from each of the facing sheets flows to make a suitably strong weld when the tool is retracted from the weld location.
- a series of spot welds were formed by successively working the sheet at predetermined spot weld locations.
- the tool can be slowly moved in the metal sheets to form a progressive linear weld.
- a group or cluster of rotating welding tools can be used in unison to simultaneously form a number of spot or linear welds.
- FIG. 3 illustrates another embodiment of the invention.
- Friction stir welding tool 110 is used to form a spot weld at overlapping peripheral edges of a first metal laminate 112 and a second metal laminate 114 .
- first metal laminate 112 has an upper metal sheet 116 , a lower metal sheet 118 and an interposed polymer layer 120 .
- the second metal laminate has an upper metal sheet 122 , a lower metal sheet 124 , and an interposed polymer layer 126 .
- the preformed metal laminates are to be bonded with lower metal sheet 118 of first metal laminate 112 facing the upper metal sheet 122 of second metal laminate 114 .
- each of the metal sheets 116 , 118 , 122 , and 124 is joined.
- the total thickness of the overlapping assembly of metal laminates 112 , 114 is about 2.4 mm.
- the friction stir welding tool 110 must be sized and shaped to form such a weld.
- the probe 128 of rotating friction stir weld tool 110 has penetrated through metal sheets 116 , 118 , 122 and polymer layers 120 , 126 , and entered lowest metal layer 124 .
- the shoulder 130 of rotating friction stir weld tool 110 is bearing on the upper side of metal sheet 116 and heating the sheet by frictional contact.
- the rotation of tool 110 displaces polymer material in layers 120 , 126 from the weld site and stirs and plasticizes adjacent metal in sheets 116 , 118 , 122 , and 124 .
- a small hole remains (similar to that schematically illustrated at 32 in FIG. 2C ) enclosed by an annular weld containing metal contributed by the friction heated and plasticized regions of the four metal sheets 116 , 118 , 122 , and 124 .
- FIG. 4 illustrates still another embodiment of the invention.
- Friction stir welding tool 210 is used to form a spot weld at overlapping peripheral edges of a metal laminate 212 and another metal workpiece, in this case a metal sheet 214 .
- first metal laminate 212 has an upper metal sheet 216 , a lower metal sheet 218 and an interposed polymer layer 220 .
- the edge of metal sheet 214 faces the edge of the bottom sheet 218 of the metal laminate 212 .
- a spot weld is to be formed attaching each of the metal sheets 216 , 218 , and 214 .
- each of the metal sheets 216 , 218 is about 0.5 mm thick
- metal sheet 214 is about 1.0 mm thick
- polymer layer 220 is about 0.2 mm thick
- the total thickness of the overlapping assembly of metal laminate 212 and metal sheet 214 is about 2.2 mm.
- the friction stir welding tool 210 is sized and shaped to form such a spot weld.
- the probe 228 of rotating friction stir weld tool 210 has penetrated through metal sheets 216 and 218 and polymer layer 220 , and entered metal sheet 214 at the bottom of the assembled workpieces.
- the shoulder 230 of rotating friction stir weld tool 210 is bearing on the upper side of metal sheet 216 and heating the sheet by frictional contact.
- the rotation of tool 210 displaces polymer material in layer 220 from the weld site and stirs and plasticizes adjacent metal in sheets 216 , 218 , and 214 .
- a small hole remains (similar to hole 32 illustrated in FIG.
- the rotating friction stir welding tool 210 can enter from the bottom surface of metal sheet 214 to make a weld between metal sheet 214 and metal laminate 212 .
- a hole remains where the probe of the tool penetrated the metal sheets and polymer layer(s). But weld metal surrounding the hole joins the metal workpieces from the top to the bottom metal member of the assembled layers.
- plasticized metal typically flows in behind the moving tool along the weld path. Any residual hole will be at the end of the path where the tool is retracted from the metal laminate and other layers.
- this invention can be utilized to form welds between the outer metal sheets or layers of a metal-polymer-metal laminate. And the method can be used to weld several metal sheets or layers with one or more interposed polymer layers where the formed weld extends from a top metal layer to a bottom metal layer enclosing the assembly of included polymer layer(s).
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Abstract
Description
Claims (17)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/549,686 US7628876B2 (en) | 2005-10-25 | 2006-10-16 | Friction stir weld bonding of metal-polymer-metal laminates |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US73049905P | 2005-10-25 | 2005-10-25 | |
| US11/549,686 US7628876B2 (en) | 2005-10-25 | 2006-10-16 | Friction stir weld bonding of metal-polymer-metal laminates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| US20070187469A1 US20070187469A1 (en) | 2007-08-16 |
| US7628876B2 true US7628876B2 (en) | 2009-12-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/549,686 Active 2027-10-29 US7628876B2 (en) | 2005-10-25 | 2006-10-16 | Friction stir weld bonding of metal-polymer-metal laminates |
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| US (1) | US7628876B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20240326154A1 (en) * | 2023-03-31 | 2024-10-03 | Airbus Operations Gmbh | Friction stir welding method and device, as well as workpiece comprising a butt weld seam |
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|---|---|---|---|---|
| US20090200359A1 (en) * | 2008-02-13 | 2009-08-13 | Gm Global Technology Operations, Inc. | Reducing sheet distortion in friction stir processing |
| EP2328749B1 (en) | 2008-08-18 | 2019-09-25 | Productive Research LLC. | Formable light weight composites |
| US8678267B2 (en) * | 2008-10-10 | 2014-03-25 | The Boeing Company | System and method for integrally forming a stiffener with a fiber metal laminate |
| US7997472B2 (en) * | 2008-10-14 | 2011-08-16 | GM Global Technology Operations LLC | Friction stir welding using an adhesive, copper, tin and zinc interlayer |
| JP5911019B2 (en) | 2009-12-28 | 2016-04-27 | プロダクティブ リサーチ エルエルシー. | Process for welding composite materials and articles derived therefrom |
| JP5849054B2 (en) * | 2010-02-15 | 2016-01-27 | プロダクティブ リサーチ エルエルシー. | Moldable lightweight composite system and method |
| US8402633B2 (en) * | 2010-06-11 | 2013-03-26 | GM Global Technology Operations LLC | Method for repairing self-piercing riveted workpieces |
| WO2012115872A1 (en) | 2011-02-21 | 2012-08-30 | Productive Research Llc | Composite materials including regions differing in properties and methods |
| JP2012218009A (en) * | 2011-04-05 | 2012-11-12 | Suzuki Motor Corp | Method of bonding dissimilar metal materials and bonded body of dissimilar metal materials |
| US9095927B2 (en) * | 2011-08-19 | 2015-08-04 | Nippon Light Metal Company, Ltd. | Friction stir welding method |
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| US20070187469A1 (en) | 2007-08-16 |
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