US733028A - Electrolytically coating iron with zinc. - Google Patents

Electrolytically coating iron with zinc. Download PDF

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Publication number
US733028A
US733028A US10333202A US1902103332A US733028A US 733028 A US733028 A US 733028A US 10333202 A US10333202 A US 10333202A US 1902103332 A US1902103332 A US 1902103332A US 733028 A US733028 A US 733028A
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zinc
iron
coating iron
electrolytically coating
electrolytically
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US10333202A
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Emanuel Goldberg
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/22—Electroplating: Baths therefor from solutions of zinc

Definitions

  • My invention relates to an improved process for electrolytically coating iron with zinc, the improvement consisting in adding to the electrolyte used an organic compound containing nitrogen.
  • My invention also consists in such further features, steps, and methods as will be hereinafter pointed out.
  • Suitable compounds for my invention are ainins, amids, cyanids, nitriles,or like comrectly or indirectly to an organic radical.
  • the pyridin bases have given the best results.
  • An electrolytic bath is prepared by dissolving ten grams of zinc chlorid and ten cubic centimeters of pyridin in about one liter of water and adding enough hydrochloric acid to dissolve the double salt of zinc chlorid and "pyridin which is formed. To separate the as cathode the iron object to be coated with zinc, which must be freed from fat and oxid.
  • the maximum current densityused may be increased.
  • the process of coating iron electrolytically which consists in forming a bath containing a zinc compound combined with a compound having nitrogen bound to an organic radical and introducing the iron into the bath and passing the electric current.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Description

pounds in which the nitrogen is attached di- EMANUEL GOLDBERG,
Patented July 7, 1903.
PATENT OFFICE.
OF MOSCOW, RUSSIA.
ELECTROLYTICALLY COATING IRON WITH ZINC.
'srncrmcarron forming part of Letters Patent No. 733,028, dated July '7, 1903.
Application filed April 17, 1902. Serial No. 103,332. (No specimensd To all whom zit/may concern.-
Be it known that I, EMANUEL GOLDBERG, chemist, a subject of the Russian Emperor, residing at 32 Miasnitskaia, Moscow, Russia, have invented a certain new and useful Improvement in Electrolytically Coating Iron with Zinc; and I do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to which it appertains to make and use the same.
My invention relates to an improved process for electrolytically coating iron with zinc, the improvement consisting in adding to the electrolyte used an organic compound containing nitrogen.
The known methods for electrolytically coating iron with zinc have not given satisfactory results, as the metal coating obtained in this manner either is deposited in a form which is not white or adheres badly to the surface to be electroplated. By the present invention, however, a pure white coating of zinc which adheres well to the surface of the My invention for this purpose consists in adding to the electrolyte wherein the iron is to be coated a compound containing nitrogen bound to an organic radical, examples of which nitrogen compound are given below.
My invention also consists in such further features, steps, and methods as will be hereinafter pointed out.
Suitable compounds for my invention are ainins, amids, cyanids, nitriles,or like comrectly or indirectly to an organic radical. The pyridin bases have given the best results.
The process is illustrated by the following example:
An electrolytic bath is prepared by dissolving ten grams of zinc chlorid and ten cubic centimeters of pyridin in about one liter of water and adding enough hydrochloric acid to dissolve the double salt of zinc chlorid and "pyridin which is formed. To separate the as cathode the iron object to be coated with zinc, which must be freed from fat and oxid.
When the concentration of the bath is increased, the maximum current densityused may be increased.
Thus far I have not been able to accurately determine the chemical reasons for the industrial advantages which result from the employment of the class of compounds in which a nitrogen compound is bound to an organic radical. However, it seems that when carrying out my process the zinc is at an intermediate stage combined with the organic compounds, or there is formed an intermediate double compound of zinc chlorid with an organic base, to which is due a more extensive decomposition and a more copious separation of zinc, supplying a zinc precipitate, which forms a very strongly-adhering coating.
A simple experiment will show that when coating an object with zinc with a one-percent. solution of zinc chlorid and employing the current densities which are permissible in the art a black spongy deposit is formed. If, however, one of the nitrogen compounds set forth in this description is added to the zinc salt in accordance with my invention, a pure white, dense, and in many cases even a shining and bright deposit of zinc is obtained.
Having thus described the nature of this invention and the best means I know of carrying the same into practical effect, I claim 1. The process of electrolytically coating iron, which consists in passing an electric current through the iron as a cathode in the presence of a zinc anode and an electrolyte containing a compound having nitrogen bound to an organic radical.
2. The process of coating iron electrolytically, which consists in forming a bath containing a zinc compound combined with a compound having nitrogen bound to an organic radical and introducing the iron into the bath and passing the electric current.
through the same in the presence of a zinc anode.
In testimony whereof I have affixed my sig nature in presence of two witnesses.
EMANUEL GOLDBERG.
Witnesses WOLDEMAR HAUPT, HENRY IIASPER.
US10333202A 1902-04-17 1902-04-17 Electrolytically coating iron with zinc. Expired - Lifetime US733028A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2543545A (en) * 1948-04-02 1951-02-27 Meaker Company Electrodeposition bath for bright zinc
US2673178A (en) * 1950-09-01 1954-03-23 Daniel W Duncan Electrolysis of zinc chloride
US3265596A (en) * 1963-02-11 1966-08-09 Ibm Cobalt-nickel alloy plating baths
US3884774A (en) * 1973-02-01 1975-05-20 Lea Ronal Inc Electrolytic deposition of zinc

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2543545A (en) * 1948-04-02 1951-02-27 Meaker Company Electrodeposition bath for bright zinc
US2673178A (en) * 1950-09-01 1954-03-23 Daniel W Duncan Electrolysis of zinc chloride
US3265596A (en) * 1963-02-11 1966-08-09 Ibm Cobalt-nickel alloy plating baths
US3884774A (en) * 1973-02-01 1975-05-20 Lea Ronal Inc Electrolytic deposition of zinc

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