US6692554B1 - Methane storage device - Google Patents
Methane storage device Download PDFInfo
- Publication number
- US6692554B1 US6692554B1 US10/315,790 US31579002A US6692554B1 US 6692554 B1 US6692554 B1 US 6692554B1 US 31579002 A US31579002 A US 31579002A US 6692554 B1 US6692554 B1 US 6692554B1
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- US
- United States
- Prior art keywords
- housing
- inlet port
- methane
- outlet port
- interior chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0415—Beds in cartridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0446—Means for feeding or distributing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/34—Specific shapes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7022—Aliphatic hydrocarbons
- B01D2257/7025—Methane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
- B01D2258/018—Natural gas engines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40086—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4516—Gas separation or purification devices adapted for specific applications for fuel vapour recovery systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4525—Gas separation or purification devices adapted for specific applications for storage and dispensing systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4566—Gas separation or purification devices adapted for specific applications for use in transportation means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/42—Foam filter materials
Definitions
- This invention generally relates to a methane storage device to store methane emitted into an air induction system of an engine in an automobile.
- the emission standard limits the, amount of hydrocarbons, carbon dioxide and particulate matter that can be emitted from the vehicle's tailpipe. Due to laws requiring the reduction of the levels of hydrocarbons that vehicles may emit into the atmosphere, it is necessary for automotive designers to consider alternate fuel technology to control emissions.
- One such alternate fuel technology that has been developed is the use of natural gas to run vehicles.
- Natural gas which contains primarily over 70% methane is one of the cleanest fuels known in the automotive industry. Natural gas is used on vehicles as compressed natural gas (CNG), as the gas is compressed at over 3000 psi and stored in a fuel cylinder aboard the vehicle. Exhaust emissions from Natural Gas Vehicles (NGV) are much lower than those from equivalent gasoline-powered vehicles. For instance, NGV emissions of carbon monoxide are approximately 70% lower, non-methane organic gas emissions are 89% lower, and oxides of nitrogen emissions are 87% lower. In addition to these reductions in pollutants, NGVs also emit significantly lower amounts of greenhouse gases and toxins than gasoline vehicles do.
- CNG compressed natural gas
- NGV Natural Gas Vehicles
- tailpipe emissions are significantly lower for NGV, hydrocarbons including methane are released from the engine, even when the engine is not operating. Hydrocarbons, primarily methane remaining from engine reactions can leak out of the engine through the engine's air intake systems. Although such emissions are not as significant as the tailpipe emissions, it is desirable to reduce the amount of methane leaked from the air intake systems as methane is known to cause green house effect.
- hydrocarbons emitted from the engine's air intake system are controlled by placing a hydrocarbon adsorbing material in the air intake tube.
- these hydrocarbon adsorbing materials are formed from carbon or zeolite and are capable of adsorbing most of the hydrocarbons released by the engine.
- methane has a very low efficiency of storage in hydrocarbon adsorbing materials. This low efficiency of storage is primarily due to the non reactive nature of the methane molecule. Although it may be possible to store methane in these hydrocarbon adsorbing materials it requires expensive processes.
- an air induction system of an automotive internal combustion engine comprises a methane storage device for storing evaporative methane emitted by the engine.
- the methane storage device is connected to the air intake tube of the air induction system.
- the methane storage device has a housing having an interior chamber.
- the interior chamber is substantially filled with a reticulated material that is capable of trapping methane.
- the housing is provided with an inlet port to introduce methane inside the interior chamber.
- the housing is also provided with an outlet port to purge the methane vapors to the engine.
- a method of trapping methane in the air induction system is provided.
- FIG. 1 is a block representation of the various components of an air induction system of an automobile's internal combustion engine, having a first embodiment of a methane storage device;
- FIG. 2 is a block representation of the various components of an air induction system of an automobile's internal combustion engine, with an alternate embodiment of a reticulated material inside the methane storage device;
- FIG. 3 is block representation of the air induction system and the methane storage device of FIG. 1, wherein the inlet and the outlet ports are on opposite ends of the methane storage device;
- FIG. 4 is block representation of the air induction system and the methane storage device of FIG. 1, wherein the inlet port is at a higher level than the outlet port of the methane storage device;
- FIG. 5 is a block representation of the various components of an air induction system of an automobile's internal combustion engine, showing a second embodiment of a methane storage device.
- an air induction system installed in the vicinity of an internal combustion engine 11 in an automobile is generally shown and represented by reference numeral 10 .
- the air induction system 10 functions to filter and meter the air intake flow from the outside into the engine 11 .
- the direction of the air flow from the outside to the engine 11 is shown by reference numeral 12 .
- the air induction system 10 comprises a dirty air duct 13 for drawing ambient air, an air cleaner 14 for cleaning the ambient air and an air intake duct 16 .
- One end 18 of the air intake duct 16 is connected to the air cleaner 14 and the other end 20 to an intake manifold 22 of the engine 11 .
- the air induction system 10 may comprise other components such as a mass air flow sensor, a flow conditioning device and a throttle body.
- the air 12 enters the air induction system 10 through the dirty air duct 13 , located upstream of the intake manifold 22 .
- natural gas vehicles In case of natural gas vehicles (NGV) or hybrid vehicles using both gasoline fuels and natural gas fuel, the natural gas is compressed at about 3000 psi and stored in a fuel container aboard the vehicle installed in the rear, undercarriage, or on the roof (not shown).
- NSV natural gas vehicles
- the natural gas leaves the cylinders and travels through a high-pressure fuel regulator located in the engine compartment.
- the natural gas is injected at atmospheric pressure through a specially designed natural gas mixer 24 where it is properly mixed with air 12 injected by the intake manifold 22 . Natural gas then flows into the engine's combustion chamber and is ignited to create the power required to drive the vehicle.
- the methane storage device 30 is formed of a housing 32 .
- the housing 32 has an upper portion 34 and a lower portion 36 .
- the upper portion 34 and the lower portion 36 have been divided by an imaginary line 35 .
- Upper portion 34 and lower portion 36 of the housing 32 are described relative to the air intake duct 16 .
- the portion of the housing 32 away from the air intake duct 16 is the upper portion 34 and the portion of the housing 32 towards the air intake duct 16 is the lower portion 36 of the housing.
- the housing 32 defines a sealed interior chamber 38 .
- the housing 32 is formed of metal such as aluminum etc. Alternatively, it could be formed of plastic or plastic composites.
- a reticulated material 40 is any material having a complex net like structure such that a complex pathway is created for the methane vapors and facilitates the trapping of the methane vapors in the net like structure.
- the reticulated material 40 is medium to high density foam material, having a density in the range of 40 to 100 ppi.
- the reticulated material 40 may also be provided with baffles or ribs 42 such that the methane vapors 26 have to travel a longer distance inside the chamber.
- the travel path of the methane vapors inside the reticulated material 40 with baffles 42 is shown by reference number 44 .
- the reticulated material 40 is tightly packed inside the interior chamber 38 of the housing 32 , such that there is minimum or no flow rate between the reticulated material 40 and the interior chamber 38 .
- the housing 32 is provided with an inlet port 46 .
- the inlet port 46 is connected to the air intake duct 16 with an inlet line 48 .
- the housing 32 is provided with an outlet port 50 .
- the outlet port 50 is connected to the air intake duct 16 with an outlet line 52 .
- the inlet port 46 and the outlet port 50 extend into the interior chamber 38 of the housing 32 such that the methane vapors 26 are directly introduced into the reticulated material 40 .
- the inlet port 46 formed on the housing 32 is spaced apart from the outlet port 50 .
- both the inlet port 46 and the outlet port 48 are located in the lower portion 36 of the housing 32 and on a bottom wall of the housing.
- the inlet port 46 and the outlet port 50 are positioned on opposite walls of the housing 32 such that the methane vapors 26 enter the housing 32 on one side and exit the housing 32 on the other side.
- the outlet port 50 be located lower than the inlet port 46 , such that the methane vapors do not enter the outlet port 50 and are stored away from the outlet port 50 . It is preferred that the outlet port 50 is located in the lower portion 36 of the housing 32 . As clearly shown in FIG. 4, the inlet port 4 , 46 is located at the upper portion 34 of the housing 32 . Therefore, the methane vapors 26 are trapped away from the outlet port 50 , which is located on the lower portion 36 of the housing 32 .
- the air intake duct 16 is provided with a first valve 54 .
- the first valve 54 is positioned in the air intake duct 16 upstream, from the inlet line 48 .
- the first valve 54 also shuts off such that methane vapors 26 are forced into the methane storage device 30 through the inlet line 48 .
- the outlet port 50 is provided with a second valve 56 . Therefore, when the engine 11 is shut off, the second valve 56 closes such that no methane vapor 26 escapes the methane storage device 30 .
- the second valve 56 can be located in the air intake duct 16 , downstream from the first valve 54 .
- the methane vapor is introduced through the inlet port 46 at a very slow rate.
- the rate of introduction of the methane vapor is less than 15 sccm.
- a slow introduction rate will help methane vapors 26 to migrate to the upper portion 34 of the housing 32 and away from the outlet port 50 . Higher the methane vapors are in the housing 32 , more efficient is the storage of the methane vapors.
- the preferred embodiment of the methane storage device 30 is also self-regenerating. Rather than adsorbing methane and trapping them in until the methane storage device 30 is saturated, the methane vapors may be relatively easily released from the device. The release occurs when the engine is operating and pulling air into the air intake duct 16 at a moderate to high rate. Preferably, to remove the vapor, the air has a higher flow rate than the rate at which methane vapor was introduced into the methane storage device 30 .
- the methane storage device 30 When air passes through the methane storage device 30 at a moderate to high rate, the methane vapors 26 trapped in the reticulated material 40 are pulled out and travel down the housing 32 to the outlet port 50 into the air intake duct 16 to the engine 11 , where they are burned off.
- the preferred embodiment of the invention is self-regenerating, and the methane storage device 30 does not have to be replaced over the lifetime of the vehicle as a result of hydrocarbon build-up.
- FIG. 5 represents an alternate embodiment of the methane storage device and is represented by reference numeral 100 .
- the various components of the air induction system 10 are represented by the same reference numeral as the previous embodiment.
- methane storage device 100 also has a housing 110 .
- the housing 110 has an upper portion 112 and a lower portion 114 and defines an interior chamber 116 .
- the hydrocarbon vapors released into the air intake duct 16 are trapped by a reticulated material 118 .
- the reticulated material 118 is identical to the reticulated material 40 described above.
- the methane storage device 100 is provided with a first inlet port 120 formed on the housing.
- the first inlet port 120 is connected to the air inlet duct by an inlet line 122 .
- the vapors are released back to the air intake duct 16 through an outlet port 124 formed on the housing 110 and spaced apart from the first inlet port 120 .
- the outlet port 124 is connected to the air intake duct 16 through an outlet line 126 .
- the methane storage device 100 is different from the first embodiment in that it is provided with a second inlet port 128 .
- the second inlet port 128 is preferably located away from the first inlet port 120 and the outlet port 124 .
- the second inlet port 128 is connected to the air intake duct 16 , through a second inlet line 130 .
- the second inlet port 128 is used to introduce hydrocarbon vapors such as methane or other hydrocarbons into the methane storage device 100 .
- the second inlet port is located on the upper portion of the housing 110 .
- the present invention provides for an efficient way of storing methane at ambient temperature and pressure. This is achieved by providing a methane storage device and connecting the device to the air induction system 10 .
- a reticulated material in the methane storage device helps trap and release the vapors stored.
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- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
Description
Claims (19)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US10/315,790 US6692554B1 (en) | 2002-12-10 | 2002-12-10 | Methane storage device |
Applications Claiming Priority (1)
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US10/315,790 US6692554B1 (en) | 2002-12-10 | 2002-12-10 | Methane storage device |
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US6692554B1 true US6692554B1 (en) | 2004-02-17 |
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US10/315,790 Expired - Fee Related US6692554B1 (en) | 2002-12-10 | 2002-12-10 | Methane storage device |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040082873A1 (en) * | 2002-09-16 | 2004-04-29 | Mikael Nilsson | Scrubber |
US20040182240A1 (en) * | 2003-03-19 | 2004-09-23 | Bause Daniel E. | Evaporative emissions filter |
US20050145224A1 (en) * | 2003-03-19 | 2005-07-07 | Zulauf Gary B. | Evaporative emissions filter |
US20060042468A1 (en) * | 2004-08-26 | 2006-03-02 | Smith Robert L | Adsorptive assembly and method of making the same |
US20080016768A1 (en) * | 2006-07-18 | 2008-01-24 | Togna Keith A | Chemically-modified mixed fuels, methods of production and used thereof |
US20080086173A1 (en) * | 2006-08-18 | 2008-04-10 | Jerry Ok | Package for an Implantable Neural Stimulation Device |
US20080128029A1 (en) * | 2006-12-05 | 2008-06-05 | Walter T. Gorman Llc | Method, system and computer product for ensuring backup generator fuel availability |
US20090272361A1 (en) * | 2005-11-17 | 2009-11-05 | Basf Catalysts, Llc | Hydrocarbon Adsorption Filter for Air Intake System Evaporative Emission Control |
US20090283427A1 (en) * | 2007-06-06 | 2009-11-19 | Farone William A | Natural gas storage apparatus and method of use |
US20100316538A1 (en) * | 2009-06-11 | 2010-12-16 | Basf Corporation | Polymeric Trap with Adsorbent |
US8496738B1 (en) * | 2010-01-27 | 2013-07-30 | Pacific Consolidated Industries, Inc. | Nitrogen and oxygen separation using vacuum swing adsorption |
US9562649B2 (en) | 2012-04-25 | 2017-02-07 | Saudi Arabian Oil Company | Adsorbed natural gas storage facility |
CN107882616A (en) * | 2016-09-29 | 2018-04-06 | 福特环球技术公司 | Method and system for HC traps |
CN115355444A (en) * | 2022-09-08 | 2022-11-18 | 燕山大学 | Method for efficiently storing methane gas |
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US20040082873A1 (en) * | 2002-09-16 | 2004-04-29 | Mikael Nilsson | Scrubber |
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