US659261A - Process of producing glue or gelatin free from fat. - Google Patents
Process of producing glue or gelatin free from fat. Download PDFInfo
- Publication number
- US659261A US659261A US66292297A US1897662922A US659261A US 659261 A US659261 A US 659261A US 66292297 A US66292297 A US 66292297A US 1897662922 A US1897662922 A US 1897662922A US 659261 A US659261 A US 659261A
- Authority
- US
- United States
- Prior art keywords
- glue
- acid
- alkali
- lime
- fat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003292 glue Substances 0.000 title description 36
- 108010010803 Gelatin Proteins 0.000 title description 9
- 229920000159 gelatin Polymers 0.000 title description 9
- 239000008273 gelatin Substances 0.000 title description 9
- 235000019322 gelatine Nutrition 0.000 title description 9
- 235000011852 gelatine desserts Nutrition 0.000 title description 9
- 238000000034 method Methods 0.000 title description 9
- 239000000463 material Substances 0.000 description 26
- 239000002253 acid Substances 0.000 description 22
- 239000003513 alkali Substances 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 11
- 159000000013 aluminium salts Chemical class 0.000 description 10
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 9
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 9
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 8
- 238000009835 boiling Methods 0.000 description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 7
- 235000011941 Tilia x europaea Nutrition 0.000 description 7
- 239000004571 lime Substances 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003518 caustics Substances 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 210000000845 cartilage Anatomy 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09H—PREPARATION OF GLUE OR GELATINE
- C09H3/00—Isolation of glue or gelatine from raw materials, e.g. by extracting, by heating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S530/00—Chemistry: natural resins or derivatives; peptides or proteins; lignins or reaction products thereof
- Y10S530/827—Proteins from mammals or birds
- Y10S530/84—Bones; tendons; teeth; cartilage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S530/00—Chemistry: natural resins or derivatives; peptides or proteins; lignins or reaction products thereof
- Y10S530/827—Proteins from mammals or birds
- Y10S530/842—Skin; hair; nails; sebaceous glands; cerumen
Definitions
- This invention relates to a method of producing a glue or a gelatin which is of a light color and free from fat.
- the glue or the gelatin is made of the material usually employed for the purpose-thatis to say, animal skins soakedin lime or lye, so-called spetches, or limed cartilaginous materials.
- the method has properly for its purpose a preparatory treatment of the spetches or the cartilaginous material in order to remove the caustic lime or alkali and to bind the fat.
- a preparatory treatment of the spetches or the cartilaginous material in order to remove the caustic lime or alkali and to bind the fat.
- Pieces of skin prepared in a lime-bath or in a lye, so-called spetches, or cartilaginous materials treated in the same manner are first washed with a sufficient quantity of a solution of an acid or an acid salt-for instance, a bisulfate of potassium, sodium, or-
- lime or alkali which but slowly and with difficulty can be washed off with water, is readily and quickly removed by the use of water with acids or acid salts; but a clear glue free from fatty matters cannot be obtained in this mannor, since the slight excess of these stronglyacid materials required for neutralizing the caustic substances in the intcriorof the glue material decomposes the lime or alkali soap always present in the glue material, and fatty matters subsequently are admitted into the glue in boiling.
- the washing fluid After the greater part of the caustic lime or alkali has herewith been neutralized the washing fluid, then showing a neutral or a slightly-alkaline reaction, is absented and the glue material is Washed with water containing 0.5 to five pounds of sulfate of aluminium or of a chemically-equivalent quantity of another aluminium saltfor instance, alum or chlorid or acetate of aluminium-and the washing is continued until the caustic lime or alkali that might rest in the material has been neutralized with the aluminium salt, after which the glue material is taken up and by boiling converted into glue or gelatinin the usual manner.
- the quantities of the acid or the acid salt and the aluminium salt must be greater or less as the spetches or the cartilage contain a greater or less quantity of lime or alkali.
- the material is treated in any usual manner for the production of glue or gelatin, as mentioned above.
- the invention does not embrace the treatment of the glue material with an acid or an acid salt alone or with an aluminium salt alone, but first with a solution of an acid or an acid salt for removing, the greater part of the caustic lime or alkali and then with asolution of an aluminium salt for neutralizing as completely as possible the caustic lime or alkali that might rest in the material.
- the method of producing glue or gelatin of alight colorand free from fat from spetches or cartilage consisting in first neutralizing a part of the lime or alkali by washing the spetches or the cartilage with a solution of an acid or an acid salt and then permitting the glue material to come in contact with a solution of an aluminium salt, which may be added in so great a quantity, that a glue or gelatin solution prepared at the boiling, shows a neutral or alkaline reaction and finally manufacturing, in the usual manner, glue or gelatin from the material thus treated.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
NITED STATES ATENT Fries.
CARL THEODOR SETTERBERG, OF STOCKHOLM, SWEDEN.
PROCESS OF PRODUCING GLUE OR GELATIN FREE FROM FATS.
SPECIFICATION forming part of Letters Patent N 0. 659,261, dated October 9, 1900.
Application filed December 21, 1897. Serial No. 662,922 (No specimens.)
T0 aZZ whom it may concern.-
Beit known that I, CARL THEODOR SETTER- BERG, Dr. Ph., a subject of the King of Sweden and Norway, and a resident of Regeringsgatan 47, Stockholm, in the Kingdom of Sweden, have invented certain new and useful Improvements in Methods of Producing Glue or Gelatin Free from Fat, (for which I have obtained a patent in Sweden, No. 5,821, dated August 4, 1894, and in Norway, No. 4,244, dated February 28, 1895,) of which the following is a specification.
This invention relates to a method of producing a glue or a gelatin which is of a light color and free from fat. The glue or the gelatin is made of the material usually employed for the purpose-thatis to say, animal skins soakedin lime or lye, so-called spetches, or limed cartilaginous materials.
The method has properly for its purpose a preparatory treatment of the spetches or the cartilaginous material in order to remove the caustic lime or alkali and to bind the fat. After the treatment of the glue material according to the method in question itis treated in the usual manner for producing glue orgelatin.
Pieces of skin prepared in a lime-bath or in a lye, so-called spetches, or cartilaginous materials treated in the same manner are first washed with a sufficient quantity of a solution of an acid or an acid salt-for instance, a bisulfate of potassium, sodium, or-
am monium-to neutralize the greater portion of the caustic lime or alkali in the glue-producing materials mention ed. The water used in washing will then react neutrally or slightly alkaline. The said glue-producing materials are subsequently washed with a solution or solutions of aluminium salts in such quantity that the caustic alkali or lime remaining in the interior of the glue-producing materials will be neutralized as completely as possible, while a glue solution prepared from the glue material will not show an acid reaction. Should too small a quantity of the aluminium salt have been added and a considerable amount of caustic lime or alkali consequently remain in the glue material and enter in the glue solution in the course of the glue boiling,
lime or alkali, which but slowly and with difficulty can be washed off with water, is readily and quickly removed by the use of water with acids or acid salts; but a clear glue free from fatty matters cannot be obtained in this mannor, since the slight excess of these stronglyacid materials required for neutralizing the caustic substances in the intcriorof the glue material decomposes the lime or alkali soap always present in the glue material, and fatty matters subsequently are admitted into the glue in boiling. For this reason a far better plan is to neutralize the greater portion only of the caustic materials by means of acids or acid salts, and subsequently as completely as possible neutralize the last remainder by means ofaluminium salts, the latter not only serving to neutralize the caustic materials, but also already in cold state forming compounds with the lime or alkali soap present in the glue-producing materials- This reaction, however, will be more complete during the glue-boiling, the basic aluminium salts, which in the neutralizing process have become deposited on the surface of the glue material, then removing the fatty matter,
probably in the shape of insoluble aluminium soap. If an excess of acid substances or salts of aluminium has been added, so as to cause the glue solution to show an acid reaction, the fatty matters cannot be removed in this manner, probably on account of the free acid decomposing the aluminium soap. An excess of acid matters therefore must be carefully avoided. Caustic lime or alkali is well I known to spoil the glue in glue boiling, and
therefore should be neutralized as completely as possible. To be sure this neutralization might be efiected by salts of aluminium alone; but long time and an excessive quantity of said salts would in this case be required, this method therefore being both expensive and impracticable.
The method mentioned above is carried out as follows: Three hundred pounds of spetches are washed in a suitable Washing-machine with water and six to twelve pounds sulfuric acid of Baum or of a chemically-equivalent quantity of another acidfor instance, hydrochloric acid, nitric acid, acetic acid, or of a salt containing free acid, as bisulfate of sodium, potassium, or ammonium. After the greater part of the caustic lime or alkali has herewith been neutralized the washing fluid, then showing a neutral or a slightly-alkaline reaction, is absented and the glue material is Washed with water containing 0.5 to five pounds of sulfate of aluminium or of a chemically-equivalent quantity of another aluminium saltfor instance, alum or chlorid or acetate of aluminium-and the washing is continued until the caustic lime or alkali that might rest in the material has been neutralized with the aluminium salt, after which the glue material is taken up and by boiling converted into glue or gelatinin the usual manner. If by the boiling some considerable quantity of caustic lime or alkali should rest in the glue material, it maybe neutralized with two to ten ounces of an aluminium salt. If the glue solution obtained at the boiling shows an acid reaction, too great a quantity of the acid orof the aluminium salt has been added and a useless glue or gelatin is obtained.
It is evident that the quantities of the acid or the acid salt and the aluminium salt must be greater or less as the spetches or the cartilage contain a greater or less quantity of lime or alkali.
After the treatment of the glue material in the manner described the material is treated in any usual manner for the production of glue or gelatin, as mentioned above.
The invention does not embrace the treatment of the glue material with an acid or an acid salt alone or with an aluminium salt alone, but first with a solution of an acid or an acid salt for removing, the greater part of the caustic lime or alkali and then with asolution of an aluminium salt for neutralizing as completely as possible the caustic lime or alkali that might rest in the material.
Having now described my invention, what I claim as new, and desire to secure by Letters Patent, is
The method of producing glue or gelatin of alight colorand free from fat from spetches or cartilage, consisting in first neutralizing a part of the lime or alkali by washing the spetches or the cartilage with a solution of an acid or an acid salt and then permitting the glue material to come in contact with a solution of an aluminium salt, which may be added in so great a quantity, that a glue or gelatin solution prepared at the boiling, shows a neutral or alkaline reaction and finally manufacturing, in the usual manner, glue or gelatin from the material thus treated.
In witness whereof I have hereunto signed my name in the presence of two subscribing witnesses.
CARL THEODOR SE'ITERBERG.
Witnesses:
CARL P. GERELL, LAURA HORMEL.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66292297A US659261A (en) | 1897-12-21 | 1897-12-21 | Process of producing glue or gelatin free from fat. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66292297A US659261A (en) | 1897-12-21 | 1897-12-21 | Process of producing glue or gelatin free from fat. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US659261A true US659261A (en) | 1900-10-09 |
Family
ID=2727826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US66292297A Expired - Lifetime US659261A (en) | 1897-12-21 | 1897-12-21 | Process of producing glue or gelatin free from fat. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US659261A (en) |
-
1897
- 1897-12-21 US US66292297A patent/US659261A/en not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2040879A (en) | Substantially undegraded deacetylated chitin and process for producing the same | |
| US659261A (en) | Process of producing glue or gelatin free from fat. | |
| US1438101A (en) | Process for purifying sludge sulphonic acids and product | |
| SU467522A3 (en) | The method of alkaline neutralization of vegetable and animal oils and pyroneta | |
| US2127641A (en) | Process for obtaining high grade sulphuric acid esters | |
| US1740012A (en) | Process of bleaching fatty acids | |
| US3232924A (en) | Technique for preparation of low-chromium gelatin | |
| US1080970A (en) | Tanning material and method of making same. | |
| US1138348A (en) | Production of soluble nitrogen compounds from organic substances of animal origin. | |
| US1340721A (en) | Process for detanning chrome-leather | |
| US820648A (en) | Process for puring hides and skins. | |
| US1285474A (en) | Glue-extracting process. | |
| US698209A (en) | Process of degreasing wool. | |
| US2339405A (en) | Recovery of glue from chrome tanned leather | |
| US465474A (en) | Treatment of spent soap-lye | |
| US1594547A (en) | Production of alpha-nitronaphthalene-beta-sulphonic acids | |
| US1221929A (en) | Process for manufacturing leather. | |
| US1749724A (en) | Process for tanning hides and skins | |
| US1298334A (en) | Method for the utilization of niter cake. | |
| SU72112A1 (en) | The method of producing glue | |
| US1681369A (en) | Purifying phenolaldehyde resins | |
| US3849452A (en) | Process for producing alpha-anthraquinone-sulfonates with low mercury content | |
| SU876710A1 (en) | Method of pressing cotton soap wastes for producing aliphatic acids | |
| US1219486A (en) | Process of bleaching fats, oils, and their derivatives. | |
| US431986A (en) | Ebenezer kennard mitting |