US620307A - William s - Google Patents
William s Download PDFInfo
- Publication number
- US620307A US620307A US620307DA US620307A US 620307 A US620307 A US 620307A US 620307D A US620307D A US 620307DA US 620307 A US620307 A US 620307A
- Authority
- US
- United States
- Prior art keywords
- wire
- magnesium
- magnesia
- coating
- insulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 64
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 38
- 229910052749 magnesium Inorganic materials 0.000 description 38
- 239000011777 magnesium Substances 0.000 description 38
- 239000000395 magnesium oxide Substances 0.000 description 32
- 239000011248 coating agent Substances 0.000 description 28
- 238000000576 coating method Methods 0.000 description 28
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical compound [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 26
- 238000009413 insulation Methods 0.000 description 24
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 22
- 229910052760 oxygen Inorganic materials 0.000 description 22
- 239000001301 oxygen Substances 0.000 description 22
- 238000000034 method Methods 0.000 description 14
- 239000000126 substance Substances 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 230000004075 alteration Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
- 229910052748 manganese Inorganic materials 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 206010022114 Injury Diseases 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000012212 insulator Substances 0.000 description 4
- 229910052573 porcelain Inorganic materials 0.000 description 4
- 229910001369 Brass Inorganic materials 0.000 description 2
- 101710028361 MARVELD2 Proteins 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000001464 adherent Effects 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000000615 nonconductor Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003223 protective agent Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/06—Insulating conductors or cables
- H01B13/065—Insulating conductors with lacquers or enamels
Definitions
- the present invention relates to a means for producing an insulating-coating of great efficiency and durability upon the wires which are used for electric heating; and the inven- I 5 tion consists in a process for coating heatingwires with magnesia and in the combination of the same withaheater-body.
- the wire is first coated with metallic magnesium and the magnesium then 2 0 oxidized to form an insulating envelop or environment of magnesia.
- Such process' is practiced by disposing the magnesium-coated wire 'm situ for use with an environment of an oxygen-bearing element, as manganese oxid, and
- the invention also includes the combination, with the body to be heated and the elec- 3o tric heatin g-wir'e having a coating of magnesia,
- a protecting agent preferably of a heatconducting character
- Such heating-wires are employed in electric ally-heated tools, furnaces, and appliances for warming air and are in all cases exposed to great alterations of heat and cold.
- the temperature to which such wires are exposed requires the use of a highly-refractory insula- 40 tion, and such insulation when firmly adherent to the wire or of, a rigid character, like porcelain, is liable to be cracked and displaced by the extreme alterations of temperature.
- the metallic magnesium is ap plied to-the wire by drawing it through abath of melted megnesium in a suitable furnace, and the wire is then coated with anadhesive paste of manganese oxid. The wire is then disposed in its permanent position and the manganese heated to free the oxygen. Such heating may be elfected by the electric cur rent or .by pouring melted soapstone, metal, or other suitable material over the wires in their permanent situation.
- magnesia-coated wire disposed within its body and surrounded by the metal poured thereon in a fluid condition.
- A is the body of the sad-iron, provided with a recess A to contain the coils contiguous to the lower surface, which is used for hot-pressing.
- the recess also serves to contain the material H, which is poured in a melted state around the coils to oxidize the same.
- B is the cover, secured upon the body and having the handle 0 attached thereto, as well ina'semiflnid paste of manganese'oxid to form a covering over the magnesium.
- magnesia occupies a larger space than-the'rnetal from which it is pro- IOD **d, and the wire is thus secured firmly in its permanent situation, while the yielding character of the magnesia permits each of the coils to expand and contract separatelyin the insulation and without such expansion affecting the adjacent coils.
- the magnesium and its coating of manganese oxid are heated by an electric current, it is desirable to use a current of low voltage, as the manganese oxid is a very imperfect insulator; but a comparatively low temperature suffices to generate the oxygen where the electric current is employed, asthe current assists by electrolysis to transfer the oxygen from'the manganese to the magnesium.
- the combination of the oxygen with the magnesium also operates to generate a very considerable degree of heat, which serves to not only liberate the oxygen, but to maintain the wire and its environment at an elevated temperature during the entire conversion of the magnesium, so that the environment and the wire are able to shrink by cooling in substantially the same ratio when the conversion is completed.
- magnesia has very little coherence, it requires some permanent protection, which, if a heatconducting environmentbe required, may be formed of a metallic filling, as iron, steel, or brass particles. 7 In practice melted soapstone may be used, which requires such a temperature to fuse it that it forms crystals upon cooling, which possess a good degree of heatconducting quality. Where the environment of the wire does not require heat-conducting properties, it may be covered before the magnesium is coverted with any suitable powder or plastic material, as asbestos, plaster-ofparis, and similar substances. By any of these substances it is permanently protected and is thus preserved from derangement or from any such agitation as might displace the magnesia coating. H
- a melted substance obviously performs the double function of, first, furnishing the heat to decompose the manganese oxid, and, second, of furnishing when cooled the permanent protection for the coating:
- magnesia is highly refractory and is thus able to endure without injury the highest temperature to which the wire may'beheat-ed by an electric current.
- the magnesia is also" an excellent non-conductor of electricity, and it is thus adapted to maintain the insulation of the. coils and prevent any short-circuiting of the current.
- the magnesia is thus formed in a relatively soft condition, it is incapable of injury by jars and by the expansion-and contraction of the wire, which would operate to crack and loosen a hard or scaly insulation, like porcelain, and the magnesia is thus in every way adapted to form a most effective and durable insulation for the electric wire in a heating device. 7.
- Any agent adapted to furnish the required oxygen may be used as a covering for the coating of magnesium metal upon the heating-wire, provided such agent may be readily decomposed to furnish the necessary oxygen for conversion of the magnesium into an insulator.
- the invention is not therefore limited to the combination of such wire with any special appliance.
Description
No. 620,307. Patenfed Feb. 28, I899. w. s. HADAWAY, In.
PROCESS OF FOBIING IAGNESIA INSULATION UPON CONDUCTORS.
(Application filed Jan. 28, 1898.)
(No Model.)
digdl w zycnfaz' M/adw n,
V UNITED STATES PATENT OFFICE.
WILLIAM S. I-IADAWAY, JR., OF NEW YORK, N. Y.
PROCESS OF FORMING MAGNESIA INSULATION UPON CONDUCTORS.
SPECIFICATION forming part of Letters Patent No. 620,307, dated February 28, 1899. Application filed January 26,1898- Serial No. 667,970. iNo specimens.)
To all whom it may concern:
Be it known that I,WILLIAM S. HADAWAY,
J r., a citizen of the United States, residing at New York, county of NewYork, State of New York, have invented certain new and useful Improvements in Processes of Forming Magnesia Insulation Upon Conductors, fully described and represented in the followingspecification and the accompanying drawing, formro ing a part of thesame.
The present invention relates to a means for producing an insulating-coating of great efficiency and durability upon the wires which are used for electric heating; and the inven- I 5 tion consists in a process for coating heatingwires with magnesia and in the combination of the same withaheater-body. In the present invention the wire is first coated with metallic magnesium and the magnesium then 2 0 oxidized to form an insulating envelop or environment of magnesia. Such process'is practiced by disposing the magnesium-coated wire 'm situ for use with an environment of an oxygen-bearing element, as manganese oxid, and
as applying heat or a heated fluid adapted to liberate the oxygen from the manganese oxid to oxidize the magnesium.
The invention also includes the combination, with the body to be heated and the elec- 3o tric heatin g-wir'e having a coating of magnesia,
of a protecting agent (preferably of a heatconducting character) packed permanently about the wire to retain the same in situ.
Such heating-wires are employed in electric ally-heated tools, furnaces, and appliances for warming air and are in all cases exposed to great alterations of heat and cold. The temperature to which such wires are exposed requires the use of a highly-refractory insula- 40 tion, and such insulation when firmly adherent to the wire or of, a rigid character, like porcelain, is liable to be cracked and displaced by the extreme alterations of temperature.
The expansion and contraction consequent 5 upon such alterations sooner or later impair 5o nesia about the heating-wire when arranged in situation for use, such coatin g permitting by its character the necessary expansion and contraction of the wire, and thus preserving the insulation indefinitely.
In practice the metallic magnesium is ap plied to-the wire by drawing it through abath of melted megnesium in a suitable furnace, and the wire is then coated with anadhesive paste of manganese oxid. The wire is then disposed in its permanent position and the manganese heated to free the oxygen. Such heating may be elfected by the electric cur rent or .by pouring melted soapstone, metal, or other suitable material over the wires in their permanent situation.
The invention will be understood by refer ence to the annexed drawing, in which the figure is a longitudinal section of a sad-iron,
showing the magnesia-coated wire disposed within its body and surrounded by the metal poured thereon in a fluid condition.
A is the body of the sad-iron, provided with a recess A to contain the coils contiguous to the lower surface, which is used for hot-pressing. The recess also serves to contain the material H, which is poured in a melted state around the coils to oxidize the same.
B is the cover, secured upon the body and having the handle 0 attached thereto, as well ina'semiflnid paste of manganese'oxid to form a covering over the magnesium. The
coil is shown arranged within the heater-body in the recess A and a suitable melted substance H poured over such coil to heat the manganese oxid and inclose the coils. The
high temperature to which the manganese oxid is raised serves to free the oxygen and transform the magnesium into magnesia, as desired. The magnesia occupies a larger space than-the'rnetal from which it is pro- IOD duced, and the wire is thus secured firmly in its permanent situation, while the yielding character of the magnesia permits each of the coils to expand and contract separatelyin the insulation and without such expansion affecting the adjacent coils. When the magnesium and its coating of manganese oxid are heated by an electric current, it is desirable to use a current of low voltage, as the manganese oxid is a very imperfect insulator; but a comparatively low temperature suffices to generate the oxygen where the electric current is employed, asthe current assists by electrolysis to transfer the oxygen from'the manganese to the magnesium. The combination of the oxygen with the magnesium also operates to generate a very considerable degree of heat, which serves to not only liberate the oxygen, but to maintain the wire and its environment at an elevated temperature during the entire conversion of the magnesium, so that the environment and the wire are able to shrink by cooling in substantially the same ratio when the conversion is completed. Such mutual shrinkage of the wire and its environment prevents the surroundiug mass from crowding the coating of magnesia upon the cooling of such mass. As the magnesia has very little coherence, it requires some permanent protection, which, if a heatconducting environmentbe required, may be formed of a metallic filling, as iron, steel, or brass particles. 7 In practice melted soapstone may be used, which requires such a temperature to fuse it that it forms crystals upon cooling, which possess a good degree of heatconducting quality. Where the environment of the wire does not require heat-conducting properties, it may be covered before the magnesium is coverted with any suitable powder or plastic material, as asbestos, plaster-ofparis, and similar substances. By any of these substances it is permanently protected and is thus preserved from derangement or from any such agitation as might displace the magnesia coating. H
A melted substance obviously performs the double function of, first, furnishing the heat to decompose the manganese oxid, and, second, of furnishing when cooled the permanent protection for the coating:
It is well known that magnesia is highly refractory and is thus able to endure without injury the highest temperature to which the wire may'beheat-ed by an electric current. The magnesiais also" an excellent non-conductor of electricity, and it is thus adapted to maintain the insulation of the. coils and prevent any short-circuiting of the current. .As the magnesia is thus formed in a relatively soft condition, it is incapable of injury by jars and by the expansion-and contraction of the wire, which would operate to crack and loosen a hard or scaly insulation, like porcelain, and the magnesia is thus in every way adapted to form a most effective and durable insulation for the electric wire in a heating device. 7.
Any agent adapted to furnish the required oxygen may be used as a covering for the coating of magnesium metal upon the heating-wire, provided such agent may be readily decomposed to furnish the necessary oxygen for conversion of the magnesium into an insulator.
Although the insulation described is by reason of its highly-refractory character especially useful upon a wire to be used for heating, it is obvious that it may be formed upon wires to be used for other purposes, and
the invention is not therefore limited to the combination of such wire with any special appliance.
Having thus set forth the nature of my invention, what I claim herein is-- 1. The process of coating electric wire with an insulation ofmagnesia for use in electric heaters, which consists in'first coating the wire with metallic magnesium, and second, applying an oxygen-bearing substance, as manganese oxid, to the coating of magnesium,
and heating the whole to decompose the manganese oxid and oxidize the magnesiumupon.
the wire, substantially as herein set forth.
2. The process of coating electric wire with an insulation of magnesia for use in electric heaters, which consists in first coating the wire with'metallic magnesium, second, ap-
plying manganese oxid in a paste to such coating of magnesium, and third, placing a IOO heated mass about'the said wire to decompose the manganeseoxid and. thus oxidize the magnesium upon the wire, substantially the manganese oxid, substantially as hereinset forth." I
In testimony'whereof I have hereunto set inyhand in the presence of two subscribing witnesses. .7
WILLIAM s.- HADAWAY, JR.
Witnesses:
.THOMAS S. CRANE,
EDWARD F. Kinsma-
Publications (1)
Publication Number | Publication Date |
---|---|
US620307A true US620307A (en) | 1899-02-28 |
Family
ID=2688916
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US620307D Expired - Lifetime US620307A (en) | William s |
Country Status (1)
Country | Link |
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US (1) | US620307A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3065436A (en) * | 1960-07-12 | 1962-11-20 | Mc Graw Edison Co | Sheathed heating element |
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0
- US US620307D patent/US620307A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3065436A (en) * | 1960-07-12 | 1962-11-20 | Mc Graw Edison Co | Sheathed heating element |
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