US604206A - edward john bevan - Google Patents
edward john bevan Download PDFInfo
- Publication number
- US604206A US604206A US604206DA US604206A US 604206 A US604206 A US 604206A US 604206D A US604206D A US 604206DA US 604206 A US604206 A US 604206A
- Authority
- US
- United States
- Prior art keywords
- cellulose
- plastic
- bevan
- compound
- decomposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002678 cellulose Polymers 0.000 description 50
- 239000001913 cellulose Substances 0.000 description 50
- 239000004033 plastic Substances 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 28
- 238000000354 decomposition reaction Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 18
- 239000000047 product Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000004048 modification Effects 0.000 description 10
- 238000006011 modification reaction Methods 0.000 description 10
- 229920002160 Celluloid Polymers 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 229920002301 Cellulose acetate Polymers 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N carbon bisulphide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 4
- 239000003518 caustics Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 239000002360 explosive Substances 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- DSSYKIVIOFKYAU-UHFFFAOYSA-N Camphor Chemical compound C1CC2(C)C(=O)CC1C2(C)C DSSYKIVIOFKYAU-UHFFFAOYSA-N 0.000 description 2
- 229960000846 Camphor Drugs 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 229920001875 Ebonite Polymers 0.000 description 2
- 210000003284 Horns Anatomy 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229930007890 camphor Natural products 0.000 description 2
- 229950008597 drug INN Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 230000004301 light adaptation Effects 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000002035 prolonged Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- -1 whalebone Polymers 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
Definitions
- This decomposition of 0 the plastic compound may be easily effected by many means-as, for example, by w ak acids, or by a moderate de *eeoiiheat, or by exposure to steam attlTe gidinary temperature0r the decomposition may even occur s ontaneousl on standin and the inorganic products of the decomposition, together with the by-products of the interaction of the original reagents, may be removed by washing or in other suitable manner in the adaptation of the structureless cellulose to various uses in practice.
- the plastic material which we have discovered is non-explosive, soluble in water, and less combustible than the cellulose from which it was derived, and it may be made to yield by its decomposition the original or slightly-modified cellulose in a structureless form possessing among others the desirable physical properties of celluloid, zylonite, 850., althoughentirelyfreefromtheirobjectionable chemical properties, and it is this structureless modification thus derived which forms the subject of the present application.
- the original cellulose may be taken in either its natural or purified form and treated as set forth in our Patent No. 520,770, above referred to, for the production of the plastic soluble compound of cellulose which forms the subject of that patent.
- This plastic compound may then either be rolled out into sheets or otherwise brought to the desired shape. It is then,by preference, dried, and if the degree of heat has not been sufficient to decompose the compound with separation of the cellulose in the insoluble form the compound may then be decomposed in any suitable manneras, for examble, by exposure to a heat of about 212 or by exposure to steam at the same temperature, the length of time in either case being determined by the thickness of the material; but it should in any case be prolonged until the decomposition is effected, as is shown by the cellulose becoming insoluble.
- the structureless cellulose thus obtained may be freed from the inorganic products of the decomposition, together with the by-products of the interaction of the original reagents, by washing with water or in other suitable manner, as may be desirable in View of the use to which the material is to be put.
- the material thus prepared shrinks somewhat on drying and may, unless treated, become brittle when dried.
- sheets which shall retain their flexibility we soak the material in glycerin or glycerin and water after it has been washed. Sheets thus prepared and suitably colored may be made to closely imitate leather.
- the stiffness of the product may be increased by using less glycerin or none at all, and by manipulating and coloringin suitable ways products maybe obtained which resemble closely celluloid, whalebone, hard rubber, horn, tortoise-shell, and the like.
- a structureless insoluble modified cellulose obtained by first treating cellulose, with caustic alkali and carbon disulfid, and then decomposing the soluble mass thus obtained to obtain the modified cellulose.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
NIED ST TES ArEN'r Erica.
CHARLEs FREDERICK oRoss, EDWARD JOHN BEVAN, AND CLAYTON BEADLE, OE LONDON, ENGLAND.
MODIFICATION OF CELLULOSE AND METHOD OF PREPARING'SAME.
A SPECIFICATION forming partef Letters Patent No. 604,206, dated May'17, 1898.
Application filed August 16, 1893. Serial No. 483,279. (N specimens.)
To all whom it may concern.-
Be it known that we, CHARLEs FREDERICK ORoss, EDWARD JOHN BEVAN, and CLAYTON BEADLE, subjects of the Queen of Great Britain, residing at No. 4 New Court, Lincolns Inn, in the city of London, England, have discovered a new and useful modification of cellulose having peculiar properties which render it of great value in the industrial arts and method of preparing the same, as set forth in the following specification.
In our Patent No. 520,770, granted June 5, 1894, we have already described a plastic viscid compound of cellulose which is soluble in water and have therein set forth the method cellulose which forms the subject of the previous patent. WVe have discovered that the novel product described in this previous patent and consisting of a plastic or viscid compound of cellulose and which is soluble in water may, by subsequent treatment in various manners, as by heat, be decomposed with recovery of the cellulose in a structureless insoluble modification which permits of many useful applications. This decomposition of 0 the plastic compound may be easily effected by many means-as, for example, by w ak acids, or by a moderate de *eeoiiheat, or by exposure to steam attlTe gidinary temperature0r the decomposition may even occur s ontaneousl on standin and the inorganic products of the decomposition, together with the by-products of the interaction of the original reagents, may be removed by washing or in other suitable manner in the adaptation of the structureless cellulose to various uses in practice.
We have already stated in our patent above referred to that the novel product therein described and claimed is plastic and may be rolled into sheets or otherwise worked or molded, or that it may be distended or dissolved in water. By Virtue of these properties it thus becomes possible to work the material into sheets and other desirable forms after the manner which will readily occur to those skilled in the art of Working such plastic materials as celluloid or rubber, but the softness, solubility, and odor of the material un fit it for many uses. By means of our present invention we are enabled, after having brought the material into the desired form, to recover from it the original or slightly-modified insoluble cellulose in a structureless condition, which may be applged to many additional and verynsefjul purposesifTtEBrt's and whichis entirely free from the ObjRti'on able features of the plastic and soluble compound of cellulose.
We are aware that for a long time prior to our discovery it has been known that the compound of cellulose known as nitrocellulose and possessing dangerous and explosive properties may be rendered plastic by manipulation with camphor or suitable solvents, so that it may be rolled or otherwise worked for the production of celluloid, zylonite, &c. The plastic material which we have discovered is non-explosive, soluble in water, and less combustible than the cellulose from which it was derived, and it may be made to yield by its decomposition the original or slightly-modified cellulose in a structureless form possessing among others the desirable physical properties of celluloid, zylonite, 850., althoughentirelyfreefromtheirobjectionable chemical properties, and it is this structureless modification thus derived which forms the subject of the present application. In order to obtain the cellulose in this new and desirable form, the original cellulose may be taken in either its natural or purified form and treated as set forth in our Patent No. 520,770, above referred to, for the production of the plastic soluble compound of cellulose which forms the subject of that patent. This plastic compound may then either be rolled out into sheets or otherwise brought to the desired shape. It is then,by preference, dried, and if the degree of heat has not been sufficient to decompose the compound with separation of the cellulose in the insoluble form the compound may then be decomposed in any suitable manneras, for examble, by exposure to a heat of about 212 or by exposure to steam at the same temperature, the length of time in either case being determined by the thickness of the material; but it should in any case be prolonged until the decomposition is effected, as is shown by the cellulose becoming insoluble. The structureless cellulose thus obtained may be freed from the inorganic products of the decomposition, together with the by-products of the interaction of the original reagents, by washing with water or in other suitable manner, as may be desirable in View of the use to which the material is to be put. The material thus prepared shrinks somewhat on drying and may, unless treated, become brittle when dried. In order, therefore, to prepare sheets which shall retain their flexibility, we soak the material in glycerin or glycerin and water after it has been washed. Sheets thus prepared and suitably colored may be made to closely imitate leather. The stiffness of the product may be increased by using less glycerin or none at all, and by manipulating and coloringin suitable ways products maybe obtained which resemble closely celluloid, whalebone, hard rubber, horn, tortoise-shell, and the like.
In order to recover the cellulose, it is only necessary to effect the decomposition of the plastic compound, and this may be easily accomplished, either after the manner previously set forth in this specification or in any other suitable way, as Will readily occur to chemists, and we do not intend by anything herein to limit ourselves as to the manner of effecting such decomposition.
What we claim isi 1. The structureless insoluble modification of cellulose recovered through the decomposition of thesoluble plastic compound hereinbefore described.
2. The process herein described consisting in first treating cellulose to form the soluble plastic compound described hereinbefore, and then decomposing the plastic compound thus obtained, substantially as set forth.
3. The process herein described consisting in first treating cellulose with caustic alkali and carbon disulfid, and then decomposing the plastic compound thus obtained, substantially as set forth.
4:. A structureless insoluble modified cellulose obtained by first treating cellulose, with caustic alkali and carbon disulfid, and then decomposing the soluble mass thus obtained to obtain the modified cellulose.
In testimony whereof we affix our signatures in presence of two witnesses.
CHARLES FREDERICK CROSS. EDWARD JOHN BEVAN. CLAYTON BEADLE.
Witnesses:
WILMER M. HARRIS, THOMAS LAKE.
Publications (1)
Publication Number | Publication Date |
---|---|
US604206A true US604206A (en) | 1898-05-17 |
Family
ID=2672837
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US604206D Expired - Lifetime US604206A (en) | edward john bevan |
Country Status (1)
Country | Link |
---|---|
US (1) | US604206A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2744292A (en) * | 1953-02-10 | 1956-05-08 | Rayonier Inc | Regenerated cellulose sheets and process of producing the sheets |
US5736087A (en) * | 1996-10-30 | 1998-04-07 | Alfacel S.A. | Method for finishing of sausage casings |
US5776398A (en) * | 1997-01-15 | 1998-07-07 | Alfacel S.A. | Method of regenerating sausage casing |
US5782683A (en) * | 1996-08-27 | 1998-07-21 | Alfacel S.A. | Cold temperature shirring |
US5783131A (en) * | 1996-08-27 | 1998-07-21 | Alfacel S.A. | Method to slowly regenerate cellulosic sausage casing |
US5795523A (en) * | 1996-10-30 | 1998-08-18 | Alfacel S.A. | Method for treatment of CS2 and H2 S emissions during viscose regeneration |
US5897432A (en) * | 1996-10-15 | 1999-04-27 | Alfacel S.A. | Shirred food casing end system |
US5914141A (en) * | 1997-03-11 | 1999-06-22 | Alfacel S.A. | Easy peeling wiener casings via use of enzymes |
-
0
- US US604206D patent/US604206A/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2744292A (en) * | 1953-02-10 | 1956-05-08 | Rayonier Inc | Regenerated cellulose sheets and process of producing the sheets |
US5782683A (en) * | 1996-08-27 | 1998-07-21 | Alfacel S.A. | Cold temperature shirring |
US5783131A (en) * | 1996-08-27 | 1998-07-21 | Alfacel S.A. | Method to slowly regenerate cellulosic sausage casing |
US5897432A (en) * | 1996-10-15 | 1999-04-27 | Alfacel S.A. | Shirred food casing end system |
US5736087A (en) * | 1996-10-30 | 1998-04-07 | Alfacel S.A. | Method for finishing of sausage casings |
US5795523A (en) * | 1996-10-30 | 1998-08-18 | Alfacel S.A. | Method for treatment of CS2 and H2 S emissions during viscose regeneration |
US5776398A (en) * | 1997-01-15 | 1998-07-07 | Alfacel S.A. | Method of regenerating sausage casing |
US5914141A (en) * | 1997-03-11 | 1999-06-22 | Alfacel S.A. | Easy peeling wiener casings via use of enzymes |
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