US59888A - Improvement in the manufacture of gun-cotton - Google Patents
Improvement in the manufacture of gun-cotton Download PDFInfo
- Publication number
- US59888A US59888A US59888DA US59888A US 59888 A US59888 A US 59888A US 59888D A US59888D A US 59888DA US 59888 A US59888 A US 59888A
- Authority
- US
- United States
- Prior art keywords
- cotton
- gun
- pulp
- manufacture
- improvement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000020 Nitrocellulose Substances 0.000 title description 22
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 title description 22
- 229920001220 nitrocellulos Polymers 0.000 title description 22
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000203 mixture Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003721 gunpowder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
Definitions
- gun-cotton Such compound has heretofore been employed either in a loose fibrous or woolly state; or of late it has been spun into the form of rovings, yarn,
- my invention has for its object to, as-
- I first convert cotton-wool, by the processes now well known, into gun-cotton.
- the gun-cotton has been purified from acid, by washing in running water and in very dilute alkali, I transfer it to a beating-engine of the description commonly used in the manufacture of paper, where it is reduced to a pulp, which is then converted 'into'solid masses, such as sheets, disks, cylindots, and other forms, either perforated or not, by any of the processes ordinarily em ployed for producing sheets, disks, cylinders, and other forms from paper-pulp.
- a small quantity of gum or other binding material soluble in water may be mixed with pulp.
- ether or mixtures of those liquids, with or without some binding material soluble in the 1 liquid, may be employed.
- aportion of the same may beleft in the original state, and be mixed with the pulp in such proportions that, when subjected to the requisite pressure, such combination will become a solid conglomerate mass of the requisite density.
- Such solid gun cotton whether formed of pulp only or of pulp mixed with fiber, may also be coated or mixed with soluble gun-cotton,known as collodion, applied in the form of solution.
- the solidified guncotton may also be formed of mixtures of guncotton ofdifl'erent composition, the properties of which are well known-that is to say, of gun-cotton which is soluble in mixtures of spirit of wine and ether, and in wood-spirit, alone or mixed with spirit of wine, and of guncotton which is insoluble in those liquids and the mixtures may be produced either by reducing both or only one of the varieties of guncotton to pulp, leaving the other in a fibrous state, or by combining them when both are in the fibrous state.
- Such mixtures may be converted into solid masses, either by the aid of pressure alone (that is, whenone or both varieties is or are in the form of pulp) or by making the soluble gun-cotton present 1n the mixtures serve as a binding material by their treatment with the liquids above named,
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
UNITED STATES PATENT QFFIGE.
FREDERIGK AUGUSTUS ABEL, OF WOOLWICH, GREAT BRITAIN IMPROVEMENT IN; THE MANUFACTURE OF GUN-COTTQN.
I Specification forming of Letters Patent No. 59,888, dated November 20, 1866.
compound known as gun-cotton. Such compound has heretofore been employed either in a loose fibrous or woolly state; or of late it has been spun into the form of rovings, yarn,
or thread, and has then been formed into cartridges, either by winding, braiding, or weaving Now, my invention has for its object to, as-
similate the physical condition of gun-cotton as nearly as possible to that of gunpowder, bymechanically converting it into a solid conglomerate state, and imparting to it either a granular or other suitable form that will present the exact amount of surface and compactness required for obtaining a certain rapidity or intensity of combustion.
The methodof treating the gun-cotton which I prefer to employ in carrying my invention into practice is as follows:
I first convert cotton-wool, by the processes now well known, into gun-cotton. For this purpose I prefer to use the cotton in the form of a loose roving. When the gun-cotton has been purified from acid, by washing in running water and in very dilute alkali, I transfer it to a beating-engine of the description commonly used in the manufacture of paper, where it is reduced to a pulp, which is then converted 'into'solid masses, such as sheets, disks, cylindots, and other forms, either perforated or not, by any of the processes ordinarily em ployed for producing sheets, disks, cylinders, and other forms from paper-pulp. A small quantity of gum or other binding material soluble in water may be mixed with pulp.
To obtain any required degree of density of the solid gun-cotton, I subject the mass, while in a moist state, to the action of hydraulic or other presses, or of any other known arrangement of machinery for exerting the requisite pressure on the material. To produce a granular structure, I either' cut the sheets,
disks, and other solid forms into small pieces of the required size, or I introduce the pulp containing water and a small quantity of the binding material into a vessel, to which a vibrating motion is imparted, wherebythe pulp is at once formed into granules of difierent sizes, which are subsequently sorted, if necessary.
ether, or mixtures of those liquids, with or without some binding material soluble in the 1 liquid, may be employed. Instead of forming the whole mass of the gun-cotton into pulp, as described, aportion of the same may beleft in the original state, and be mixed with the pulp in such proportions that, when subjected to the requisite pressure, such combination will become a solid conglomerate mass of the requisite density. Such solid gun cotton, whether formed of pulp only or of pulp mixed with fiber, may also be coated or mixed with soluble gun-cotton,known as collodion, applied in the form of solution. The solidified guncotton may also be formed of mixtures of guncotton ofdifl'erent composition, the properties of which are well known-that is to say, of gun-cotton which is soluble in mixtures of spirit of wine and ether, and in wood-spirit, alone or mixed with spirit of wine, and of guncotton which is insoluble in those liquids and the mixtures may be produced either by reducing both or only one of the varieties of guncotton to pulp, leaving the other in a fibrous state, or by combining them when both are in the fibrous state. Such mixtures may be converted into solid masses, either by the aid of pressure alone (that is, whenone or both varieties is or are in the form of pulp) or by making the soluble gun-cotton present 1n the mixtures serve as a binding material by their treatment with the liquids above named,
which act as solvents, in which case the mixtures may be consolidated with or without the In the above processes, in place of water, other fluids, such as wood-spirit, spirit of wine,
2 i eases rials, after conversion by wel-Lknown process es, being in all cases wholly orpartly reduced to pulp, and treated as hereinbefore described.
Having now described the nature of my invention, and in what manner the same is to be performed, I wish it to be understood that what I claim is 1. Reducing gun-cotton to a pulp, and consolidating such pulp, with or without the aid of pressure, into the'form of sheets, disks, granules, cylinders, or other solid forms, either with or without the admixture of binding materials.
2. Combining with gun-cotton reduced to a pulp, gun-cotton in a fibrous state, and consolidating such mixture into sheets, disks,
granules, cylinders, or othersolid forms, either with or Without the admixture of binding materials.
3. Gombining-solubleand insoluble gun-cotton,;eith er when both are in a state of pulp, or when one is in a state of pulp and the other in a fibrous condition, and consolidating such mixtures into cylinders, sheets, disks, granules,
either alone "or with the employment of pressure, so 'as to effect the consolidation of the same.
5. The application to the surface of the consolidated gun-cotton of a solution of the solulole forms of gun-cotton, or of shellac or other suitable gums or resins.
In testimony whereof I have signed my name to this specification in the presence of two sub scribing" witnesses this 26th day of September, 1866.
F. A. ABEL.
Witnesses:
G. D. ABEL, Enos. TAYLOR.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US59888A true US59888A (en) | 1866-11-20 |
Family
ID=2129427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US59888D Expired - Lifetime US59888A (en) | Improvement in the manufacture of gun-cotton |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US59888A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2999743A (en) * | 1960-08-17 | 1961-09-12 | Du Pont | Deformable self-supporting explosive composition |
-
0
- US US59888D patent/US59888A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2999743A (en) * | 1960-08-17 | 1961-09-12 | Du Pont | Deformable self-supporting explosive composition |
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