US594009A - Humphrey harrington - Google Patents

Humphrey harrington Download PDF

Info

Publication number
US594009A
US594009A US594009DA US594009A US 594009 A US594009 A US 594009A US 594009D A US594009D A US 594009DA US 594009 A US594009 A US 594009A
Authority
US
United States
Prior art keywords
rivets
steel
coating
carbonizing
chemical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Publication date
Application granted granted Critical
Publication of US594009A publication Critical patent/US594009A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/02Modifying the physical properties of iron or steel by deformation by cold working
    • C21D7/04Modifying the physical properties of iron or steel by deformation by cold working of the surface
    • C21D7/06Modifying the physical properties of iron or steel by deformation by cold working of the surface by shot-peening or the like
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/02Pretreatment of the material to be coated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S76/00Metal tools and implements, making
    • Y10S76/02Case hardening

Definitions

  • the invention relates to the process employed in the production of the rivets.
  • the wire from which I manufacture the rivets or studs is of soft iron or low steel. I treat it in a carbon-bath composed, preferably, of broken bone for such period as will induce a moderately high steel over the entire surface. This produces a peculiar condition,
  • My rivets are of the ordinary form and appearance when completed and may be worked in all respects in the ordinary way, except that the operation of riveting or heading the ends after the parts of the chain have been assembled requires to be conducted with more vigor in consequence of the hardness of a thin coating on thesurface of the necks and ends.
  • the chain when completed appears in all respects like the ordinary chain.
  • my rivets are first treated according to the early steps of the process set forth in the patent to William S. Wilson, dated July 3, 1894, No. 522,247.
  • My chain works the same as a chain made with the Wilson process, except that it will 5 5 better endure wear by reason of the peculiar steel coating on the body of the rivet having not only the coating of moderately high steel, which is due to the original surface carbonizing of the wire, but also having the extreme 6o outer portion of such coating still harder steel, due to the later treatment with chemicals.
  • FIG. 2 is longitudinal sectional views on a large scale, showing one of my rivets in three conditions after the successive steps taken in its production.
  • Fig. 4 is a corresponding section showing the rivet and the adjacent portions of the side plates and'of the Fig. 7 is a plan view of the evener used for the first carbonizing treatment.
  • Fig. Si s a central vertical section through the vessel used for effecting the second carbonizing after the rivets have been cut into shape.
  • A is the soft iron or low steel
  • FIG. 1 is a moderate thickness on the exterior thereof which has been raised to a moderately-steelified condition not quite up to that of tool-steel.
  • this coating extends the whole length. purchased in that condition from some manufacturers, being known in the arts, uniform low steel or soft iron along the center and uniform higher steel on the whole exterior surface.
  • Figs. 5 and 6 believing that it will produce a wire having a more certain and uni- This figure shows the 75
  • the wire may be 5 I prefer to use the apparatus shown 10o form coating of moderately high steel than can at present be purchased.
  • Fig. 2 shows the partially-manufactured rivet after its necks have been machined down and the wire cut off into proper lengths for rivets. The operation of machining leaves the necks with little or none of the first coating of steel.
  • a quantity of the rivets thus far advanced are next placed in a suitable vessel M (see Fig. 8) with cyanid of potassium or prussiate of potash and heated to a cherry-red, when they are withdrawn from "the fire and poured into a tank of water or oil. (Not shown.)
  • the useful effect of this treatment with the chemical is to raise the steelified condition on the surface of the body still higher.
  • the highly-carbonized condition thus induced does not extend inward to the same depth as the more moderately-carbonized coating A.
  • Fig. 3 shows the rivet after the thin coating of high steel has been induced over the whole surface and before the riveting.
  • Fig. 4 shows the same after the parts have been assembled and the heading has been effected.
  • the soft material in the interior is spread at the ends,
  • D is a cylindrical case of cast-iron, screw-threaded to receive a cap at each end.
  • One cap, D may be permanently set.
  • the other, D should be removable. Both are made to fit with tolerable tightness.
  • Soft-iron or low-steel wire of the proper size is cut into lengths a little less than that of the casing D and accurately straightened. To properly charge the case D, it is set upright and the upper cover D removed.
  • E is a frame of small wire having a long handle E, by which it may be raised and lowered in the interior of the case D, the lower end being branched and formed into rings which loosely inclose the several wires A, set upright, and hold them evenly spaced in the interior of the casing.
  • the proper number of wires being inserted in the rings in the evener-frame E are lowered into the case D, and a small stream of broken bone G being poured into the casing the light frame E is raised and lowered in small extents, allowing the broken bone to move down past it and packing the latter in the even spaces between the several wires.
  • the wires now steelified to a moderately high condition to a considerable depth over the whole surface, should be cooled slowly to facilitate the subsequent cutting operations.
  • the tightness with which this form of case may be closed makes it practicable to mingle asmall quantity of cyanid of potassium or prussiate of potash with the broken bone. I prefer to do this.
  • the carbonizing effect of the first treatment is increased, and the time necessary to attain the proper depth and c011- The dition of the first steelifying is shortened.
  • the wires are subsequently machined to properly reduce the ends and to cut the several rivets apart one from another.
  • a cover N is fitted on the vessel by a hinge N and secured by a swinging catch P, hinged to the cover at the point P and engaging under a lip or flange h on the vessel.
  • This cover allows the vessel to be shaken to facilitate the distribution of the chemical among the rivets and prevents the escape of the fumes, which would otherwise be annoying to the workmen and are some what poisonous.
  • this hinged cover and the fastening therefor thequantity of chemical supplied for a given quantity of rivets may be accurately determined beforehand, and the heat of the vessel after one treat ment is over may be utilized, putting a hand ful of cold rivets into the open vessel, throwing the chemical upon those cold rivets, and rapidly closing and securing the cover.
  • the vessel may be agitated to effect the thorough distribution of the chemical and the rivets, and they may be allowed to remain for a longer period, until practically the whole of the carbonizin g effect of the chemical is exhausted.
  • This contributes to insure a uniformity of thickness of the high-steel coating induced by the chemical.
  • the opening of the apparatus is easy, requiring simply a slight blow on the beveled under face of the locking-catch P to liberate it and allow the vessel to be inverted and emptied.
  • the treatment with the chemical in the vessel M has the objectionable effect to also coat the reduced necks and also the offsets or shoulders at the junctions of the bodies with the necks and also the circular ends of the necks. All are incased in a thin coating of high steel, which in the operation of sudden cooling to which it is subjected becomes hardened steel. The thickness of this veryhigh steel coating is so slight that the disadvantageis of little importance. Practice will determine for how longa period the operation should be conducted. It should be such as to add appreciably to the hardness of the surface of the body portion and yet not be continued so long as to make an impracticable thickness of hardened steel on the ends,which have to be subsequently distorted by riveting or heading.
  • the first surface carbonizing may be carried to a greater depth, so that all the steel will not be removed from the necks by the machining process but it is important not to have so thick a coating of steel on the necks andespecially on the ends thereof, eitherfrom the first or the second carbonizing, as will when the coating is hardened offer serious difficulty in the riveting operation.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Description

H. HARRINGTON.
Tq'f'f Patented Nov.
m: ncnms PEYERS co ruumuwa, WASHINGTON, o a
(N6 Model.)
MANUFACTURE OF BICYCLE CHAINS.
UNITED STATES PATENT OFFICE.
IIUMPHREY HARRINGTON, OF INDIANAPOLIS, INDIANA, ASSIGNOR TO THE INDIANAPOLIS CHAIN AND STAMPING COMPANY, OF SAME PLACE.
MANUFACTURE OF BICYCLE-CHAINS.
SPECIFICATION forming part of Letters Patent No. 594,009, dated November 23, 1897. Application filed January 14, 1897. Serial No. 619,152. (No Specimens.)
To all whom, it may concern:
Be it known that I, HUMPHREY HARRING- TON, a citizen of the United States, residing at Indianapolis, Mar-ion county, in the State of Indiana, have invented a certain new and useful Improvement in and Relating to the Manufacture of Bicycle-Chains, of which the following is a specification.
The invention relates to the process employed in the production of the rivets.
The wire from which I manufacture the rivets or studs is of soft iron or low steel. I treat it in a carbon-bath composed, preferably, of broken bone for such period as will induce a moderately high steel over the entire surface. This produces a peculiar condition,
having'an interior of low steel or soft iron and a considerable thickness at the surface of sufficiently high steel, which latter alone will assume a tolerably hardened condition when heated and suddenly cooled. I then treat such wire by machining in the same manner as soft-iron wire is machined to reduce the portions which are to serve as the necks and to cut off the rivets to the proper lengths. The machining removes the whole or the main portion of the steelified surface on the portions which become the necks. I
. then treat the entire surfaces of such nearlycompleted rivets by'heating with a highlycarbonizing chemical, as cyanid of potassium or prussiate of potash, and then suddenly cooling the rivets in water or oil.
My rivets are of the ordinary form and appearance when completed and may be worked in all respects in the ordinary way, except that the operation of riveting or heading the ends after the parts of the chain have been assembled requires to be conducted with more vigor in consequence of the hardness of a thin coating on thesurface of the necks and ends. The chain when completed appears in all respects like the ordinary chain. In short, my rivets are first treated according to the early steps of the process set forth in the patent to William S. Wilson, dated July 3, 1894, No. 522,247. In the last stage of the entire operation my rivets are subjected to the same treatment as in the said Wilson patent-that is to say, they are while red-hot plunged in water or oil but I subject the rivets to an intermediate treatment by heating with cyanid of potassium or prussiate of potash.
My chain works the same as a chain made with the Wilson process, except that it will 5 5 better endure wear by reason of the peculiar steel coating on the body of the rivet having not only the coating of moderately high steel, which is due to the original surface carbonizing of the wire, but also having the extreme 6o outer portion of such coating still harder steel, due to the later treatment with chemicals.
In the accompanying drawings, Figures 1,
2, and 3 are longitudinal sectional views on a large scale, showing one of my rivets in three conditions after the successive steps taken in its production. Fig. 4 is a corresponding section showing the rivet and the adjacent portions of the side plates and'of the Fig. 7 is a plan view of the evener used for the first carbonizing treatment. Fig. Sis a central vertical section through the vessel used for effecting the second carbonizing after the rivets have been cut into shape.
Similar letters of reference indicate corresponding parts in all the figures where they appear.
Referring to Figs. 1, 2, 3, and 4., all showing the same rivet at different stages in its manufacture, A is the soft iron or low steel, 0
and A is a moderate thickness on the exterior thereof which has been raised to a moderately-steelified condition not quite up to that of tool-steel. In Fig. 1 this coating extends the whole length. purchased in that condition from some manufacturers, being known in the arts, uniform low steel or soft iron along the center and uniform higher steel on the whole exterior surface. in Figs. 5 and 6, believing that it will produce a wire having a more certain and uni- This figure shows the 75 The wire may be 5 I prefer to use the apparatus shown 10o form coating of moderately high steel than can at present be purchased.
Fig. 2 shows the partially-manufactured rivet after its necks have been machined down and the wire cut off into proper lengths for rivets. The operation of machining leaves the necks with little or none of the first coating of steel. A quantity of the rivets thus far advanced are next placed in a suitable vessel M (see Fig. 8) with cyanid of potassium or prussiate of potash and heated to a cherry-red, when they are withdrawn from "the fire and poured into a tank of water or oil. (Not shown.) The useful effect of this treatment with the chemical is to raise the steelified condition on the surface of the body still higher. The highly-carbonized condition thus induced does not extend inward to the same depth as the more moderately-carbonized coating A. This thin high-steel coating over the whole surface is marked A (See Figs. 3 and 4:.) It will be understood that the entire rivet retains its original soft condition in the interior and its fairly-hardened condition on the exterior of the body to about the same depth as in the ordinary wellknown rivets which are produced by the VVilson process, with the further quality that a thin portion A 011 the exterior of the body is still more hard, because of the higher condition of the steel induced by the chemical, and will allow the rivet to wear longer.
Fig. 3 shows the rivet after the thin coating of high steel has been induced over the whole surface and before the riveting.
Fig. 4 shows the same after the parts have been assembled and the heading has been effected. In the heading operation the soft material in the interior is spread at the ends,
0 carrying with it the intensely hard, but very thin, surface coating.
I will now describe the apparatus for effecting the surface carbonizing. D is a cylindrical case of cast-iron, screw-threaded to receive a cap at each end. One cap, D, may be permanently set. The other, D should be removable. Both are made to fit with tolerable tightness. Soft-iron or low-steel wire of the proper size is cut into lengths a little less than that of the casing D and accurately straightened. To properly charge the case D, it is set upright and the upper cover D removed.
E is a frame of small wire having a long handle E, by which it may be raised and lowered in the interior of the case D, the lower end being branched and formed into rings which loosely inclose the several wires A, set upright, and hold them evenly spaced in the interior of the casing. The proper number of wires being inserted in the rings in the evener-frame E are lowered into the case D, and a small stream of broken bone G being poured into the casing the light frame E is raised and lowered in small extents, allowing the broken bone to move down past it and packing the latter in the even spaces between the several wires. This is continued, the evener-frame E reciprocating in higher and higher positions as the broken bone accumulates and always holding the wires evenly spaced at the proper level where the packing is being effected. The case may be shaken during the filling. The case is ultimately filled above the tops of the wires, and the cover D being applied attention may be given to the next case, and so on. These cases are put in the highly-heatcd oven or furnace and rolled a little from time to time during the one hour or longer which it is found expedient to subject them to this treatment. cases are then removed and preferably piled together and covered with ashes or other nonconductor, so that the cooling will be very slow; but if occasion arises for rapid work the cap D can be removed and the cases emptied and recharged while hot. The wires, now steelified to a moderately high condition to a considerable depth over the whole surface, should be cooled slowly to facilitate the subsequent cutting operations. The tightness with which this form of case may be closed makes it practicable to mingle asmall quantity of cyanid of potassium or prussiate of potash with the broken bone. I prefer to do this. Thereby the carbonizing effect of the first treatment is increased, and the time necessary to attain the proper depth and c011- The dition of the first steelifying is shortened. It
is important-not to use a large proportion of the chemical in this first treatment. The wires are subsequently machined to properly reduce the ends and to cut the several rivets apart one from another.
The vessel Mis used for the second carbonizing. A cover N is fitted on the vessel by a hinge N and secured by a swinging catch P, hinged to the cover at the point P and engaging under a lip or flange h on the vessel. This cover allows the vessel to be shaken to facilitate the distribution of the chemical among the rivets and prevents the escape of the fumes, which would otherwise be annoying to the workmen and are some what poisonous. IVith this hinged cover and the fastening therefor thequantity of chemical supplied for a given quantity of rivets may be accurately determined beforehand, and the heat of the vessel after one treat ment is over may be utilized, putting a hand ful of cold rivets into the open vessel, throwing the chemical upon those cold rivets, and rapidly closing and securing the cover. In such mode of operating the vessel may be agitated to effect the thorough distribution of the chemical and the rivets, and they may be allowed to remain for a longer period, until practically the whole of the carbonizin g effect of the chemical is exhausted. This contributes to insure a uniformity of thickness of the high-steel coating induced by the chemical. The opening of the apparatus is easy, requiring simply a slight blow on the beveled under face of the locking-catch P to liberate it and allow the vessel to be inverted and emptied.
The treatment with the chemical in the vessel M has the objectionable effect to also coat the reduced necks and also the offsets or shoulders at the junctions of the bodies with the necks and also the circular ends of the necks. All are incased in a thin coating of high steel, which in the operation of sudden cooling to which it is subjected becomes hardened steel. The thickness of this veryhigh steel coating is so slight that the disadvantageis of little importance. Practice will determine for how longa period the operation should be conducted. It should be such as to add appreciably to the hardness of the surface of the body portion and yet not be continued so long as to make an impracticable thickness of hardened steel on the ends,which have to be subsequently distorted by riveting or heading.
Modifications may be made without departing from the principle or sacrificing the advantages of the invention. The first surface carbonizing may be carried to a greater depth, so that all the steel will not be removed from the necks by the machining process but it is important not to have so thick a coating of steel on the necks andespecially on the ends thereof, eitherfrom the first or the second carbonizing, as will when the coating is hardened offer serious difficulty in the riveting operation.
Instead of the cylindrical cases with provisions for tightly closing I can use other forms with much less efficient closing. Cases of rectangular cross-section lying on the sides and being closed simply by resting one upon another may serve. I can omit the provisions shown for the equal distribution of the wires in the carbonizing material-G and'allow the distribution to be effected according to the judgment of the operator. I can omit the small quantityof chemical in the first carbonizing process and allow that treatment to be effected by the broken bone or other milder carbonizing material alone.
I do not in this patent claim the rivet, such being thesubject of a separate application for patent filed by me-March 8, 1897, Serial No. 626,433.
I claim as my invention- In the process of manufacturing rivets for pitch-chains, first carbonizing mildly a considerable depth on the whole surface of iron or low-steel Wire, next machining by turning down the reduced necks and cutting off the rivets, third carbonizin g highly a thin coating over the entire surfaces of the fully-shaped rivets, and fourth hardening by sudden cooling from a red heat, all substantially as herein specified.
In testimony that I claim the invention above set forth I affiX my signature in presence of two witnesses.
HUMPHREY HARRINGTON.
Witnesses:
RoBT. W. CATHOART, CHARLES J. DROEGE.
US594009D Humphrey harrington Expired - Lifetime US594009A (en)

Publications (1)

Publication Number Publication Date
US594009A true US594009A (en) 1897-11-23

Family

ID=2662659

Family Applications (1)

Application Number Title Priority Date Filing Date
US594009D Expired - Lifetime US594009A (en) Humphrey harrington

Country Status (1)

Country Link
US (1) US594009A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3265415A (en) * 1965-01-25 1966-08-09 Anderson Co Wiper arm pivot joint
US3830054A (en) * 1971-09-21 1974-08-20 Hitachi Ltd Link chains for motor blocks

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3265415A (en) * 1965-01-25 1966-08-09 Anderson Co Wiper arm pivot joint
US3830054A (en) * 1971-09-21 1974-08-20 Hitachi Ltd Link chains for motor blocks

Similar Documents

Publication Publication Date Title
US6231996B1 (en) Part or jig for gas carburizing furnace
US594009A (en) Humphrey harrington
DE3322957C2 (en) Process for hardening the surface of objects made of ferrous material
JPS6039149B2 (en) Nitriding surface hardening method
US594010A (en) harrington
US9540721B2 (en) Method of carburizing
JP5742959B2 (en) Rust prevention treatment method for molds
US432651A (en) Method of working metals by electricity
US2188226A (en) Method of casing ferrous articles
US4104063A (en) Formed part of sintered iron and method and sintering tile for making same
US660533A (en) Method of annealing and oxidizing metal sheets or plates.
US1065697A (en) Annealing process, &c.
US574668A (en) Process of making carbonized steel for armor-plates
US1478367A (en) Process for treating iron and its alloys
US881221A (en) Rust-proofing iron, steel, &c.
US1471563A (en) Carbonizing compound and process of making and using it
US1507845A (en) Carbonizing compound and process of making and using it
Watkins Nitriding solutions
DE886001C (en) Process and installation for cementing metal parts
GB191122778A (en) Improvements in Case Hardening Processes for Articles of Iron, Steel and Steel Alloys.
US234900A (en) Coating stock-bells with brass
US1546937A (en) Carbonizing compound and process of making and using it
US1737007A (en) Sintering apparatus
US379371A (en) Manufacture of sheet-iron
JPS62235463A (en) Gas nitriding method for high alloy member