US572676A - Treatment of petroleum for removing sulfur compounds - Google Patents
Treatment of petroleum for removing sulfur compounds Download PDFInfo
- Publication number
- US572676A US572676A US572676DA US572676A US 572676 A US572676 A US 572676A US 572676D A US572676D A US 572676DA US 572676 A US572676 A US 572676A
- Authority
- US
- United States
- Prior art keywords
- petroleum
- treatment
- sulfur compounds
- removing sulfur
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000003464 sulfur compounds Chemical class 0.000 title description 10
- 239000003208 petroleum Substances 0.000 title description 6
- 239000003921 oil Substances 0.000 description 22
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 18
- 229910052802 copper Inorganic materials 0.000 description 18
- 239000010949 copper Substances 0.000 description 18
- 241000266847 Mephitidae Species 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000002085 persistent Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000010405 reoxidation reaction Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
Definitions
- My improvement is designed for the treatment of that class of oils found at Lima,0hio, and some other places, which contain sulfur compounds, the presence of which gives to said oils the peculiarly offensive and persistent odor known as skunk, and also the physical characteristic of being a solvent of lead oxid and other metals and metallic compounds.
- This treatment eifects the destruction of the skunk by the breaking up of the peculiar sulfur compounds present in this class of oils by means of, or at any rate resulting in, the formation of a sulfid of the metal or metallic base of the oxid employed, such sulfid being readily separable and being capable of revivification by reoxidation and burning out of the sulfur.
- My improvement consists in the preparation and use of a metallic oxid especially adapted for the purpose before mentioned.
- I take copper matte, or partially-reduced native sulfid of copper, containing about sixty per centum of copper and fortyper centum of iron and sulfur, and after grinding it to a powder I place the powdered matte in a furnace and roast it until the sulfur is eliminated as much as is possible by such treatment.
- the roasted powder is again reduced to a pulverulent condition by grinding, and is then bolted, so as to remove the The resulting powder is then in a condition for use as a purificator of petroleum-oils containing skunk,
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
larger particles and lumps.
UNITED STATES PATENT OFFICE.-
HERMAN FRASOH, OF CLEVELAND, OI-IIO, ASSIGNOR TO THE SOLAR REFINING COMPANY, OF OHIO.
SPECIFICATION forming part of Letters Patent No. 572,676, dated December 8, 1896. Application filed July 14, 1890. Serial No. 358,712. (No specimens.)
To all whom it may concern:
Be it known that I, HERMAN. FRASCH, of Cleveland, in the county of Ouyahoga and State of Ohio, have invented a new and useful Improvement in the Treatment of Petroleum for the Removal of Sulfur Oompounds,of which the following is a full, clear, and exact description.
My improvement is designed for the treatment of that class of oils found at Lima,0hio, and some other places, which contain sulfur compounds, the presence of which gives to said oils the peculiarly offensive and persistent odor known as skunk, and also the physical characteristic of being a solvent of lead oxid and other metals and metallic compounds. This treatment eifects the destruction of the skunk by the breaking up of the peculiar sulfur compounds present in this class of oils by means of, or at any rate resulting in, the formation of a sulfid of the metal or metallic base of the oxid employed, such sulfid being readily separable and being capable of revivification by reoxidation and burning out of the sulfur.
My improvement consists in the preparation and use of a metallic oxid especially adapted for the purpose before mentioned. For this purpose I take copper matte, or partially-reduced native sulfid of copper, containing about sixty per centum of copper and fortyper centum of iron and sulfur, and after grinding it to a powder I place the powdered matte in a furnace and roast it until the sulfur is eliminated as much as is possible by such treatment. The roasted powder is again reduced to a pulverulent condition by grinding, and is then bolted, so as to remove the The resulting powder is then in a condition for use as a purificator of petroleum-oils containing skunk,
in contact with the purificator in any convenwith the copper, acts as a carrier for the copper and thus practically exposes a larger surface of copper to the sulfur compounds or skunk in the oil and furnishes a Very energetic purificator of the oil.
I do not herein claim, broadly, the method of treating petroleum containing skunk either in a liquid or vaporous condition with metals or metallic oxids or compounds, as these methods form the subject-matter of other applications for patents; but i What I do claim as my invention, and desire to secure by Letters Patent, is
1. In the art of distilling petroleum-oils containing sulfur compounds of the character specified, the improvement which consists in eliminating the sulfur by subjecting the oil during the process of distillation either in a liquid or vaporous condition to roasted and pulverized copper matte, substantially as described.
2. The process of treating oil of the Lima class, for removal of. the skunk, by subjecting the skunk-bearing oil during a distillation thereof to a pulverulent purifying material of metallic oxid having a basis of iron and copper in the intimate union resulting from a melting together oftheir compounds and admixture in the molten state and consisting of roasted and pulverized copper matte; the purifying material being used in the body of oil in distillation or brought into contact with the vapors after they have been given off from said body; substantially asdescribed.
In testimony whereof I have hereunto set my hand this 14th day of June, A. D. 1890.
HERMAN FRASOH. Witnesses:
F. W. LOTHMAN, A. O. TILDEN.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US572676A true US572676A (en) | 1896-12-08 |
Family
ID=2641373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US572676D Expired - Lifetime US572676A (en) | Treatment of petroleum for removing sulfur compounds |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US572676A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3420910A (en) * | 1967-01-16 | 1969-01-07 | Scm Corp | Copper sweetening pretreating before isomerizing alpha-pinene |
-
0
- US US572676D patent/US572676A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3420910A (en) * | 1967-01-16 | 1969-01-07 | Scm Corp | Copper sweetening pretreating before isomerizing alpha-pinene |
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