US543503A - oakley - Google Patents

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US543503A
US543503A US543503DA US543503A US 543503 A US543503 A US 543503A US 543503D A US543503D A US 543503DA US 543503 A US543503 A US 543503A
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sensitive
emulsion
coloring
sensitive emulsion
oakley
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Description

UNIT D STATES PAT NT OFFICE.
CHARLES F. OAKLEY, OF LONDON, ENGLAND.
SENSITIVE NO N-HALATION PLATE.
SPECIFICATION formingpart of Letters Patent No. 543,503, dated July 30, 1895.
Application filed April 9, 1895. Serial No. 545,090. (No specimens.) A
To all whom it may concern:
Be it known that I, CHARLES FREDERICK OAKLEY, of Thornton Heath, London, Surrey, England, have invented certain new and useful Improvements in the Man ufacture of Photographic Plates and Films, of which the following is a specification.
My invention has reference to the manufacture of photographic plates and films and its object is the prevention of the effects generally known as halation. For the purpose of preventing halation it has been proposed at various times during the last six or eight years to coat the glass plate, film, or other support for the sensitive emulsion with a layer or substratum below the sensitive emulsion, this layer or substratum containing a coloring-matter which renders it non-actinic, the said coloring-matter subsequently disappearing during the development or fixing; but these colored substrata have failed to answer in practice because the coloringmatters which they-contain are of such a nature that they become to a great extent taken up by the superposed coating of emulsion the sensitiveness of which is consequently seriously impaired and sometimes practically destroyed. It has also been proposed, with the object of preventinghalation, to coat the glass plates or other supports with two or more coats of emulsion of graduated degrees of sensitiveness; but these plates, besides being expensive, have not been found altogether satisfactory.
Now the object of my invention is to cover the glass plate or other support with a layer or substratum colored with such a material and in such a manner that the coloring-matter will not be subsequently taken up by the sensitive emulsion applied to the plate over the substratum, the sensitiveness of the emulsion therefore not being affected.
My invention consists in the manufacture of photographic plates and films by first coating the glass plate or other support with a solution of gelatin or other suitable nonsensitive material, then immersing the plate, preferably when dry, for a sufficient'length of time-say from two to five minutes, more or lessin a coloring and hardening solution,
has the effect of oxidizing and hardening the V gelatinand rendering it practically insoluble. Consequently the coloring matter is prevented from being taken up by the sen sitive emulsion subsequently applied. The solution preferably employed for the purpose is potassium permanganate and a suitable strength is obtained by adding about one ounce of the permanganate to one gallon of water.
The color in the non-sensitive substratum disappears during the development, when developers such as hydroquinone are employed or in the fixing-bath, when this contains sulphite of soda and acid.
What I claim, and desire to secure by Letters Patent, is-
1. The mode hereinbefore described of manufacturing photographic plates and films which consists in first coating the support for the sensitive emulsion with a non-sensitive material, then immersing it in a coloring and hardening solution whereby it is colored, rendered non-actinic and practically insoluble and therefore prevented from giving up its coloring matter to the sensitive emulsion, and then coating the colored non-sensitive material with a sensitive emulsion, substantially as and for the purpose set forth.
2. The mode hereinbefore described of manufacturing photographic plates and films which consists in first coating the support for the sensitive emulsion with a non-sensitive material, then immersing it in a solution of permanganate of potass whereby itis colored, rendered non-actinic and practically insoluble and therefore prevented from giving up its coloring matter to the sensitive emulsion and then coating the colored nonsensitive material with a sensitive emulsion 3. As a new article of manufacture a pho- Ico tographie plate or film consisting of a sup- In witness whereof I have hereunto signed port having two coats the first coat being a my name in the presence of two subscribing 1o non-sensitive material which has been 001- ored and rendered non-actinic and practically insoluble by immersion in a solution of permanganate of potass after its application to said support, and the second coat being a sensitive emulsion, substantially as set forth.
witnesses.
CHARLES F. OAKLEY.
Witnesses:
JOHN C. MEWBURN, THOMAS L. WHITEHEAD.
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