US533643A - hawkins - Google Patents

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US533643A
US533643A US533643DA US533643A US 533643 A US533643 A US 533643A US 533643D A US533643D A US 533643DA US 533643 A US533643 A US 533643A
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gas
acid
chambers
generating
pipes
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/08Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of inorganic compounds with metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00Apparatus for generating gases
    • B01J7/02Apparatus for generating gases by wet methods
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells

Definitions

  • the object of our invention is to devise certain improvements in generators to be used in the production of hydrogen gas and more particularlyto that class of apparatus adapted to be employed in the evolution of the said gas by the action of diluted sulphuric or muriatic acid upon metals such as zinc or iron, and our invention consists in the details and combination'of parts hereinafter described and set forth.
  • Figure l is a side elevation of a generator constructed in accordance with our said invention.
  • Fig. 2 is a front elevation of the same.
  • Fig. 3 is a transverse section taken on the line y y in Fig. l.
  • Our improved generator consists of a vessel A, of copper (which ⁇ we find will resist the action of the acid sufficiently for our purpose) or of iron lined with lead or any suitable acid resisting material preferably rectangular in shape, the said vessel A being divided by a ⁇ vertical partition or diaphragm B, the said vessel being further divided into upper and lower compartments C, D, E and F respectively upon each side of the said diaphragm B.
  • the upper compartments O, D are intended for use, as receptacles or tanks for acidulated water, the lower compartments E, F forming the generating chambers in which are placed the metal or metals employed.
  • a pipe G leads from the acid tank O tothe generating chamber E for the passage of the acidulated water and H is a similar pipe communicating with the acid tank D and generating chamber F.
  • a pipe I leads from the upper portion of the generating chamber E for the passage of the gas while a similar pipe .T provides for the passage of the gas from the chamber F, the said pipes I and J being connected to a common or mai'n pipe from which it is delivered to the apparatus in which it is collected or used.
  • Suitable pipes L are also provided in the lower p0rtion of each compartment for drawing off the liquid when required.
  • a perforated shelf N is placed in the lower part of each of the generating chambers for supporting the metals which are placed therein.
  • the Vessel is also provided with suitable manholes for the insertion and the removal of the metal.
  • the method of using the apparatus is as follows:-The lower or generating chambers E, F are charged with a suitable quantity ot' met-al, the said metal being placed upon the perforated shelves N within the said chambers.
  • the upper chambers C, D forming the acid tanks are charged with a suitable volume of acidulated water as before mentioned.
  • the apparatus is then ready for use. Vv'hen it is required to produce the gas the acidolated Water in the acid tank C, is allowed to dow through the pipe G leading to the generating chamber E by opening a valve or cock g in the said acid pipe.
  • the gas evolved by the contact of the acidulated water and the metal within the generating chamber will pass out of the said chamber through the pipe I before referred to, the said pipe being also controlled by means of a suitable valve c'.
  • the acidulated water in contact with the metal within the chamber ⁇ will bythe pressure of the gas be driven back through the pipes G and the pipes O into the acid tank.
  • the pipes O remain permanently open and are mainly intended for the purpose of forming additional and adequate relieving channels in the event of a sudden evolution of a large volume of gas in the generating chambers for the relief of which the pipes G would not be suiiicient.
  • Said pipes O serve the purpose of permitting the unirnpeded escape of the excess gas from the generating chambers to the upper part of the acid chambers and thence to the atmosphere by means of Vents d without the necessity of said gas having to pass through the acidulated water in the acid chambers and thence to the atmosphere which it must do if forced through ⁇ the supply pipe G; and in the event of valves g being closed, said pipes O will act as relief pipes should the pressure in the generators become excessive.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)

Description

iNo Mode.) 2 Sheets-Sheet 1.
W. & T. HAWKINS. HYDROGEN GBNERATING APPARATUS.
No. 533,643. Patented Feb. 5, i895.
(No Model.) 2 Sheets-Sheet 2, W. 8a T. HAWKNS. HYDROGEN GBNERATING APPARATUS.
No. 533,643. Patented Feb. 5, 1895.
Fl c5.
Unirse dramas armer erica.
WILLIAM IIAVKINS AND THOMAS HAlVKINS, OF PORTSMOUTH, ENGLAND.
HYDROGEN-GENERATING APPARATUS.
SPECIFICATION forming part of Letters Patent No. 533,643, dated February 5, 1895.
Application filed September 21, 1893. Serial No. 486,149. (No model.) Patented in England July 21, 1892, No. 13,379.
'b M whom zit may concern.-
Be it known that we, YVILLrAM HAWKINS and THOMAS Hnwnnvs, subjects of the Queen of England, residing at 38 Queens Road, Buckland, Portsmouth, England, have invented certain new and useful Improvements in Generators to be Used in the Production of Hydrogen Gas, of which the following is a specification.
British Patent No. 13,379, dated July 2l, 1892, has been granted for this invention.
'The object of our invention is to devise certain improvements in generators to be used in the production of hydrogen gas and more particularlyto that class of apparatus adapted to be employed in the evolution of the said gas by the action of diluted sulphuric or muriatic acid upon metals such as zinc or iron, and our invention consists in the details and combination'of parts hereinafter described and set forth.
Referring to the accompanying drawings, wherein like letters indicate corresponding parts thoughout the several views, Figure l is a side elevation of a generator constructed in accordance with our said invention. Fig. 2 is a front elevation of the same. Fig. 3 is a transverse section taken on the line y y in Fig. l.
Our improved generator consists of a vessel A, of copper (which `we find will resist the action of the acid sufficiently for our purpose) or of iron lined with lead or any suitable acid resisting material preferably rectangular in shape, the said vessel A being divided by a `vertical partition or diaphragm B, the said vessel being further divided into upper and lower compartments C, D, E and F respectively upon each side of the said diaphragm B. The upper compartments O, D are intended for use, as receptacles or tanks for acidulated water, the lower compartments E, F forming the generating chambers in which are placed the metal or metals employed.
A pipe G leads from the acid tank O tothe generating chamber E for the passage of the acidulated water and H is a similar pipe communicating with the acid tank D and generating chamber F. A pipe I leads from the upper portion of the generating chamber E for the passage of the gas while a similar pipe .T provides for the passage of the gas from the chamber F, the said pipes I and J being connected to a common or mai'n pipe from which it is delivered to the apparatus in which it is collected or used. Suitable pipes L are also provided in the lower p0rtion of each compartment for drawing off the liquid when required.
A perforated shelf N is placed in the lower part of each of the generating chambers for supporting the metals which are placed therein. The Vessel is also provided with suitable manholes for the insertion and the removal of the metal. There are also provided upon the upper face of the vessel one or more ap ertures for the charging of the acid tanks.
The method of using the apparatus is as follows:-The lower or generating chambers E, F are charged with a suitable quantity ot' met-al, the said metal being placed upon the perforated shelves N within the said chambers. The upper chambers C, D forming the acid tanks are charged with a suitable volume of acidulated water as before mentioned. The apparatus is then ready for use. Vv'hen it is required to produce the gas the acidolated Water in the acid tank C, is allowed to dow through the pipe G leading to the generating chamber E by opening a valve or cock g in the said acid pipe. The gas evolved by the contact of the acidulated water and the metal within the generating chamber, will pass out of the said chamber through the pipe I before referred to, the said pipe being also controlled by means of a suitable valve c'. Should the gas be produced in a greater volume within either of the generating chambers than can escape through the gas outlet pipes leading therefrom, the acidulated water in contact with the metal within the chamber `will bythe pressure of the gas be driven back through the pipes G and the pipes O into the acid tank. The pipes O remain permanently open and are mainly intended for the purpose of forming additional and adequate relieving channels in the event of a sudden evolution of a large volume of gas in the generating chambers for the relief of which the pipes G would not be suiiicient. In practice it is found impossible to drive back the whole of the acidulated water from the metal in the acid chamber to the generating chamber in consequence of a certain portion of the acid- IOO ulated water adhering to the numerous interstices of the metal thus cont-inning the evolution of gas in small quantity and it is not till the metal is perfectly dry that the evolution of gas absolutely ceases. Said pipes O serve the purpose of permitting the unirnpeded escape of the excess gas from the generating chambers to the upper part of the acid chambers and thence to the atmosphere by means of Vents d without the necessity of said gas having to pass through the acidulated water in the acid chambers and thence to the atmosphere which it must do if forced through` the supply pipe G; and in the event of valves g being closed, said pipes O will act as relief pipes should the pressure in the generators become excessive.
Vhen the production of the gas in the generating chamber E becomes slow, the valve i' in the gas pipe I is closed which causes the acidulated water to be driven on. the metal in the said generating chamberin the manner described. At the same time the production of gas `may be continued in the other generating chamber F, in a similar manner to that already described, and thus, by working the generating chambers alternately a continuous supply of gas may be maintained.
Having now described our invention, what we claim as new, and desire to secure by Letters Patent, is-
The combination in a hydrogen generating apparatus of acid chambers C D in communication at will, respectively with generating chambers E F by means of pipes G IAI and valves said acid chambers and generating chambers being also respectively situated in the upper and lower portions of a vessel A having in its upper portion vents d, open to the atmosphere, and pipes O communicating between the lower portion of said generating chambers and the upper portion of said acid chambers, all for ythe purposes and substantially in the manner liereinbefore described.
In Witness whereof we have hereunto set our hands in presence of two witnesses.
WILLIAM I-IAWKINS. THOMAS HAWKINS.
Witnesses:
W. WILSON HORN, ARTHUR GARRICK.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2635948A (en) * 1948-11-06 1953-04-21 Eastman Kodak Co Manufacture of hydrogen

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2635948A (en) * 1948-11-06 1953-04-21 Eastman Kodak Co Manufacture of hydrogen

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