US517454A - John henneman - Google Patents

John henneman Download PDF

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US517454A
US517454A US517454DA US517454A US 517454 A US517454 A US 517454A US 517454D A US517454D A US 517454DA US 517454 A US517454 A US 517454A
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enamel
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metal
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form

Definitions

  • vitreous enamel such as is usually applied to metal
  • vitreous enamel is a substance similar to and .partakes of the known qualities of glass.
  • a preparatory coat of some kind such as by a coat of enamel composed of white-sand, mica, and borax, after which one or more coats of finishing enamel is added.
  • My improved process is substantially as follows: I use the following articles in substantially the following proportions, to-wit: Floor-spar, two and one-half pounds; saltpeter, one and one-half pounds; white-sand, five pounds; pulverized-borax, four pounds; mica, two pounds; red lead, three pounds; carbonate of potash, three pounds; kryolite, two
  • the above ingredients are mixed and milled in the usual manner, preferably being milled wet.
  • the mixture is applied to the metal by pouring or dipping and allowed to dry to prevent the formation of blisters or holes in the enamel.
  • the enameled article is then placed in an oven or furnace heated to from 1,000 to 1,500 Fahrenheit, and baked until the application of the enamel is complete.
  • the metal may be subjected to the usual preparatory coat, if preferred, but ordinarily the enameling coating above described is sufficient, and the expense of a preparatory heating and coating is thereby avoided.
  • Articles enameled by the above described process may be bent or flexed without cracking or scaling the enamel.
  • this process is particularly adapted to sheet-metal roofing and other flexible sheet-metal articles.
  • An enamel composed of a mixture of fluorspar, salt-peter, white-sand, borax, mica, redlead, carbonate of potash, and kryolite with 2.
  • sptiltable coloring oxide substantially as set JOHN W. HILL, W. M. HILL.

Description

UNITED STATES PATENT QFFICE.
JOHN HENNEMAN, OF CHICAGO, ILLINOIS, ASSIGNOR OF ONE-HALF TO RICHARD E. STUPE, OF SAME PLACE.
ENAMEL FOR COATING SHEET METAL, 800.
SPECIFICATION forming part of Letters Patent No. 517,454, dated April 3, 18941. Application filed April 1,1893. SerialN'o. 468,717. (No specimens.)
To all whom it may concern:
Be it known that I, JOHN I-IENNEMAN, a citizen of the United States of America, residing at Chicago, county of Cook, State of Illinois, have invented certain new and useful Improvements in Enamel for Coating Sheet Metal and other Metals, of which the following is a description.
It is well known that vitreous enamel, such as is usually applied to metal, is a substance similar to and .partakes of the known qualities of glass. Hence it has not been practicable to enamel other than stiff, inflexible articles, such as culinary utensils, and similar articles, as the bending of a flexible article results in cracking off the enamel. It has also been found necessary in practicing the known processes of enameling, to first prepare the metal by a preparatory coat of some kind, such, for example, as by a coat of enamel composed of white-sand, mica, and borax, after which one or more coats of finishing enamel is added.
I have discovered a process of enameling metal articles whereby the enamel produced upon said articles is flexible, and the articles enameled can be bent more or less without cracking or injuring its enameled surface; and whereby, in the manufacture of the enameled article, the preparatory coating, above referred to, may be dispensed with, and the entire work performed by one heat, thereby very largely reducing the cost of manufacture.
My improved process is substantially as follows: I use the following articles in substantially the following proportions, to-wit: Floor-spar, two and one-half pounds; saltpeter, one and one-half pounds; white-sand, five pounds; pulverized-borax, four pounds; mica, two pounds; red lead, three pounds; carbonate of potash, three pounds; kryolite, two
pounds, together with a small quantity of coloring oxide, for example, for a blue color onehalf ounce of oxide of cobalt.
The above ingredients are mixed and milled in the usual manner, preferably being milled wet. The mixture is applied to the metal by pouring or dipping and allowed to dry to prevent the formation of blisters or holes in the enamel. The enameled article is then placed in an oven or furnace heated to from 1,000 to 1,500 Fahrenheit, and baked until the application of the enamel is complete. In practice, after the enamel has fused, I prefer to cool the enameled metal slowly, and for this purpose to pass it from the fusing furnace through a series of chambers, each of which is of a lower temperature than the preceding one.
Of course the metal may be subjected to the usual preparatory coat, if preferred, but ordinarily the enameling coating above described is sufficient, and the expense of a preparatory heating and coating is thereby avoided.
Articles enameled by the above described process may be bent or flexed without cracking or scaling the enamel. Hence, this process is particularly adapted to sheet-metal roofing and other flexible sheet-metal articles.
Having thus described my improved process, what I claim as new, and desire to secure by Letters Patent, is-
An enamel composed of a mixture of fluorspar, salt-peter, white-sand, borax, mica, redlead, carbonate of potash, and kryolite with 2. sptiltable coloring oxide, substantially as set JOHN W. HILL, W. M. HILL.
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