US1982179A - Inorganic insulation for electrical sheets - Google Patents

Inorganic insulation for electrical sheets Download PDF

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Publication number
US1982179A
US1982179A US543003A US54300331A US1982179A US 1982179 A US1982179 A US 1982179A US 543003 A US543003 A US 543003A US 54300331 A US54300331 A US 54300331A US 1982179 A US1982179 A US 1982179A
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US
United States
Prior art keywords
sheets
electrical
enamel
enamels
inorganic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US543003A
Inventor
Charles A Scharschu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Allegheny Ludlum Corp
Original Assignee
Allegheny Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Allegheny Steel Corp filed Critical Allegheny Steel Corp
Priority to US543003A priority Critical patent/US1982179A/en
Priority to US588226A priority patent/US1951039A/en
Application granted granted Critical
Publication of US1982179A publication Critical patent/US1982179A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/16Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
    • H01F1/18Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets with insulating coating
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials

Definitions

  • This invention relates to inorganic enamels for electrical sheets and to a method of applying the same to such sheets.
  • silicates are generally used, but these enamels, on account of the properties desired, are more complex than is preferred in an enamel for electrical sheets and these enamels are, moreover, of such a composition and fired at such temperatures as to cause the enamel to melt and flow. Enamels of this nature consequently are not suitable for electrical sheets as such enamels would cause the individual sheets to stick together when annealed in stacks. Again, these enamels are much heavier and more continuous than is necessary for the insulation of electrical sheets.-
  • Inorganic enamels when properly made and applied have excellent electrical resistance and. may be used to coat electrical sheets.
  • the electrical sheet may be enameled before it is punched or cut into parts for electrical apparatus and these punchings may be subsequently annealed to produce better electrical qualities without destroying the enamel.
  • One of the objects of this invention is the provision of an inorganic insulation which will adhere to electrical sheets and which can be uniformly deposited thereupon.
  • Another object is to provide an inorganic insulation which can be subjected to an anneal without detriment to the enamel.
  • a further object is the production of an inorganic enamel of certain composition which not only has the desired electrical properties but which acts as a protective coating for the sheets to prevent rusting of the same.
  • a still further object is the provision of a meth- -od of applying an inorganic insulating material so as to produce an even adherent coating having the desired characteristics.
  • the sheets of material destined for electrical uses are passed singly through a bath of the liquid enamel, then through a set of rolls and through a drying oven to drive off the water.
  • the rolls cause an even distribution of the liquid enamel on the surfaces of the sheets and remove excess enamel and may be of any suitable type. If desired, or found necessary glue or. an excess of water glass'may be added to the bath to make the enamel adhere more tightly to the sheet before the sheets are heated.
  • the drying oven is kept at a suitable temperature, for example, about 600 Fahrenheit, and the coated sheets are passed therethrough at a suitable rate such that the coating is subjected to the heat for about two minutes.
  • the coating is iinally baked on in the anneal which is carried out at about 1450 Fahrenheit.
  • the temperature of the drying oven may vary considerably but in such cases the time of exposure thereto is suitably varied in inverse relationship thereto; that is, the hotter the oven the less the time of exposure and the cooler the oven the greater the time of exposure.
  • I may vary the constituents over wide limits to produce enamels having different properties, which when baked at the proper temperature form an insulating enamel suitable for electrical sheets.
  • This enamel especially when applied to pickled sheets, also acts as a protective coating preventing the sheets from rusting.

Description

Patented Nov. 27, 1934 1,982,179 INORGANIC INSULATION FOR ELECTRICAL SHEETS Charles A. Scharschu, Brackenridge, Pa., assignor to Allegheny Steel Company, a corporation of Pennsylvania No Drawing. Application June 8, 1931, Serial No. 543,003
3 Claims. (01. 15443) This invention relates to inorganic enamels for electrical sheets and to a method of applying the same to such sheets.
Hitherto organic enamels or varnishes have been used to coat electrical sheets for the purpose of insulating one sheet from another in electrical apparatus, thus cutting down the eddy loss. There are, however, many applications for which this type of coating is objectionable, such as in those cases where it is desired to anneal the punching after the enamel has been applied.
For producing porcelainic enamels, silicates are generally used, but these enamels, on account of the properties desired, are more complex than is preferred in an enamel for electrical sheets and these enamels are, moreover, of such a composition and fired at such temperatures as to cause the enamel to melt and flow. Enamels of this nature consequently are not suitable for electrical sheets as such enamels would cause the individual sheets to stick together when annealed in stacks. Again, these enamels are much heavier and more continuous than is necessary for the insulation of electrical sheets.-
Inorganic enamels when properly made and applied have excellent electrical resistance and. may be used to coat electrical sheets. When inorganic enamels are used the electrical sheet may be enameled before it is punched or cut into parts for electrical apparatus and these punchings may be subsequently annealed to produce better electrical qualities without destroying the enamel.
One of the objects of this invention is the provision of an inorganic insulation which will adhere to electrical sheets and which can be uniformly deposited thereupon.
Another object is to provide an inorganic insulation which can be subjected to an anneal without detriment to the enamel.
A further object is the production of an inorganic enamel of certain composition which not only has the desired electrical properties but which acts as a protective coating for the sheets to prevent rusting of the same.
A still further object is the provision of a meth- -od of applying an inorganic insulating material so as to produce an even adherent coating having the desired characteristics.
Other and further objects and advantages will be understood by those skilled in this art or will be pointed out hereinafter.
I have found that very simple enamelsare satisfactory for coating electrical sheets. For instance, water glass may be used as the source of 59 silicate although finely ground silica may also be used. To either of these there is added lime and another metallic oxide such as iron oxide, the proportions depending upon the properties desired in the enamel.
For example, these three constituents are used in the following proportions for certain applications:---
Water 200 cc.
Lime 15 grams Iron oxide 28 grams Water glass '70 grams It is understood that magnesium oxide may be substituted for the lime or both may be used and that silica, preferably in a finely ground condition, may be substituted for the water glass and the iron oxide may or may not be used depending upon the properties desired in the enamel.
The sheets of material destined for electrical uses are passed singly through a bath of the liquid enamel, then through a set of rolls and through a drying oven to drive off the water. The rolls cause an even distribution of the liquid enamel on the surfaces of the sheets and remove excess enamel and may be of any suitable type. If desired, or found necessary glue or. an excess of water glass'may be added to the bath to make the enamel adhere more tightly to the sheet before the sheets are heated.
The drying oven is kept at a suitable temperature, for example, about 600 Fahrenheit, and the coated sheets are passed therethrough at a suitable rate such that the coating is subjected to the heat for about two minutes. The coating is iinally baked on in the anneal which is carried out at about 1450 Fahrenheit. The temperature of the drying oven may vary considerably but in such cases the time of exposure thereto is suitably varied in inverse relationship thereto; that is, the hotter the oven the less the time of exposure and the cooler the oven the greater the time of exposure.
I may vary the constituents over wide limits to produce enamels having different properties, which when baked at the proper temperature form an insulating enamel suitable for electrical sheets. This enamel, especially when applied to pickled sheets, also acts as a protective coating preventing the sheets from rusting.
What I claim as new and desire to secure by Letters Patent is:
1. Steel elements for electrical apparatus coated with an inorganic electrical insulating enamel consisting substantially entirely of an insoluble complex silicate unaffected by conditions encountered in annealing such sheets according to commercial practice.
2. Steel elements for electrical apparatus coated with an inorganic electrical insulation consisting chiefly of silica, iron oxide and an oxide of the alkaline earth metals converted by heat, prior to annealing the elements, into a complex silicate which is un'afiected by moisture and by conditions of annealing encountered in the processing of such elements.
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US543003A 1931-06-08 1931-06-08 Inorganic insulation for electrical sheets Expired - Lifetime US1982179A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US543003A US1982179A (en) 1931-06-08 1931-06-08 Inorganic insulation for electrical sheets
US588226A US1951039A (en) 1931-06-08 1932-01-22 Method of applying inorganic insulation to electrical sheets

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US543003A US1982179A (en) 1931-06-08 1931-06-08 Inorganic insulation for electrical sheets

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US1982179A true US1982179A (en) 1934-11-27

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2542043A (en) * 1947-09-06 1951-02-20 Glenn H Mcintyre Method of producing a corrosion resistant coating on steel
US2694020A (en) * 1950-10-20 1954-11-09 Westinghouse Canada Ltd Metal members provided with stabilized alkali metal silicate insulation and process for producing the same
US2745437A (en) * 1951-09-12 1956-05-15 Norton Co Reinforced ceramic body of revolution
US3523881A (en) * 1966-09-01 1970-08-11 Gen Electric Insulating coating and method of making the same
US4661171A (en) * 1984-08-29 1987-04-28 Shinko-Pfaudler Company, Ltd. Method for treating the surface of stainless steel by high temperature oxidation
US4762753A (en) * 1987-03-31 1988-08-09 Usx Corporation Insulative coating composition
US20090215655A1 (en) * 2006-03-14 2009-08-27 Sumitmo Metal Industrial, Ltd. Lubricant for a Hot Plastic Working

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2542043A (en) * 1947-09-06 1951-02-20 Glenn H Mcintyre Method of producing a corrosion resistant coating on steel
US2694020A (en) * 1950-10-20 1954-11-09 Westinghouse Canada Ltd Metal members provided with stabilized alkali metal silicate insulation and process for producing the same
US2745437A (en) * 1951-09-12 1956-05-15 Norton Co Reinforced ceramic body of revolution
US3523881A (en) * 1966-09-01 1970-08-11 Gen Electric Insulating coating and method of making the same
US4661171A (en) * 1984-08-29 1987-04-28 Shinko-Pfaudler Company, Ltd. Method for treating the surface of stainless steel by high temperature oxidation
US4762753A (en) * 1987-03-31 1988-08-09 Usx Corporation Insulative coating composition
US20090215655A1 (en) * 2006-03-14 2009-08-27 Sumitmo Metal Industrial, Ltd. Lubricant for a Hot Plastic Working
US7956019B2 (en) * 2006-03-14 2011-06-07 Sumitomo Metal Industries, Ltd. Lubricant for a hot plastic working

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