US5159490A - Mirror - Google Patents
Mirror Download PDFInfo
- Publication number
- US5159490A US5159490A US07/709,603 US70960391A US5159490A US 5159490 A US5159490 A US 5159490A US 70960391 A US70960391 A US 70960391A US 5159490 A US5159490 A US 5159490A
- Authority
- US
- United States
- Prior art keywords
- layer
- metal
- mirror
- thickness
- directly formed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910052751 metal Inorganic materials 0.000 claims abstract description 22
- 239000002184 metal Substances 0.000 claims abstract description 22
- 239000010409 thin film Substances 0.000 claims abstract description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 239000002994 raw material Substances 0.000 description 9
- 229910004446 Ta2 O5 Inorganic materials 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910003327 LiNbO3 Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 238000007733 ion plating Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
- B60R1/02—Rear-view mirror arrangements
- B60R1/08—Rear-view mirror arrangements involving special optical features, e.g. avoiding blind spots, e.g. convex mirrors; Side-by-side associations of rear-view and other mirrors
- B60R1/083—Anti-glare mirrors, e.g. "day-night" mirrors
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0816—Multilayer mirrors, i.e. having two or more reflecting layers
- G02B5/0825—Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only
- G02B5/0833—Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only comprising inorganic materials only
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0816—Multilayer mirrors, i.e. having two or more reflecting layers
- G02B5/085—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal
- G02B5/0875—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal the reflecting layers comprising two or more metallic layers
Definitions
- the present invention relates to a mirror and in particular to a mirror used as a rear view mirror of a motor vehicle.
- a mirror according to the present invention comprises a first layer being of a transparency, a second layer mounted on the first layer and being in the form of a translucent metal thin film with a thickness of less than 350 A, a third layer mounted on the second layer and being in the form of a transparent oxide or fluoride of a metal, and a fourth layer mounted on the third layer and being in the form of a thin metal to be used as a reflecting member.
- FIG. 1 is a cross-sectional view of a portion of a mirror according to the present invention.
- FIG. 2 is a graph showing the relationship between the reflectance and the wave length of the light.
- the mirror which is formed into a built-up configuration, includes a first layer 1, a second layer 2, a third layer 3 and a fourth layer 4. These layers 1-4 are carried in a casing or frame (not shown).
- a transparent material such as a glass is used.
- transparent paint which is applied on the second layer 2 can be used.
- the second layer 2 is in the form of a translucent metal thin film having a thickness of less than 350 A.
- As the metal Al, Cr, Ag, Au, Pt and alloys of each of the foregoing materials.
- the second layer 2 is at one of the transparent function and reflection function.
- the third layer 3 is in the form of a transparent oxide or fluoride of a metal such as Ta 2 O 5 , TiO 2 , ZrO 2 , SiO 2 , MgF, Y 2 O 3 , LiNbO 3 , and ZnO.
- the refractive index of each material of the third layer 3 is not restricted or limited.
- the fourth layer 4 is in the form of metal thin film and is used as a reflecting film.
- a raw material and the thickness of the fourth layer 4 depend on the desired reflectance.
- the brightness and color tone of the reflected light mainly depend on the thickness of the second layer 2 and the third layer 3, respectively.
- the conventional example fails to have a layer corresponding to the second layer of the present invention.
- the evaluation is classified into three grades - "excellent", “good” and “bad” when the reflectance is 45-55%, less than 45% and above 55% respectively. This criteria is determined in light of the fact that the mirror should not be highly bright when it is used as a rear-view mirror of a motor vehicle.
- the foregoing "45-55%” is regarded as a best mode.
- the relationship between the reflectance and the wave length in regard to each example in the Table is illustrated in a graph as shown in FIG. 2.
- the colors of the above examples (A), (B) and (C) are somewhat dark brown, dark brown and light brown, respectively.
- the second layer is made of Al (Cr) with a thickness of 35 (40) ⁇
- the third layer is made of Ta 2 O 5 (Ta 2 O 5 ) with a thickness of 2000 (500) ⁇
- the fourth layer Cr (Cr) with a thickness of 0.1 (0.1) ⁇ m.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Multimedia (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Optical Elements Other Than Lenses (AREA)
- Optical Filters (AREA)
Abstract
A mirror comprises a first layer being of a transparency, a second layer mounted on the first layer and being in the form of a translucent metal thin film with a thickness of less than 350Å, a third layer mounted on the second layer and being in the form of a transparent oxide or fluoride of a metal and a fourth layer mounted on the third layer and being in the form of a thin metal to be used as a reflecting member.
Description
1. Field of Invention
The present invention relates to a mirror and in particular to a mirror used as a rear view mirror of a motor vehicle.
2. Discussion of Related Art
It is well known that a rear view mirror should be glare-proof from the view point of safety in driving a motor vehicle. In order to comply with the foregoing requirement, various mirror have been provided or proposed as shown in, for example, Japanese Utility Model Registration Laid-open Pring No.64(1989)-34603, Japanese Patent Laid-Open Print No.60(1985)-212704 and Japanese Patent Laid-Open Print No.63(1988)-163402.
However, in each of the foregoing conventional mirrors, it is difficult to adjust easily the reflectance, lightness, brightness, hue and other characteristics.
It is, therefore, a primary object of the present invention to provide a mirror without the foregoing drawback.
It is another object of the present invention to provide a mirror having adjustable characteristics, such as reflectance, lightness, brightness and hue.
In order to accomplish the foregoing objects, a mirror according to the present invention comprises a first layer being of a transparency, a second layer mounted on the first layer and being in the form of a translucent metal thin film with a thickness of less than 350 A, a third layer mounted on the second layer and being in the form of a transparent oxide or fluoride of a metal, and a fourth layer mounted on the third layer and being in the form of a thin metal to be used as a reflecting member.
The above and other objects, features and advantages of the present invention will be become more apparent and more readily appreciated from the following detailed description of preferred exemplary embodiments of the present invention, taken in connection with the accompanying drawings, in which:
FIG. 1 is a cross-sectional view of a portion of a mirror according to the present invention; and
FIG. 2 is a graph showing the relationship between the reflectance and the wave length of the light.
Referring now to FIG. 1 showing a partial portion of a mirror according to one embodiment of the present invention, the mirror, which is formed into a built-up configuration, includes a first layer 1, a second layer 2, a third layer 3 and a fourth layer 4. These layers 1-4 are carried in a casing or frame (not shown).
As the first layer 1, a transparent material such as a glass is used. Instead of the glass, transparent paint which is applied on the second layer 2 can be used.
The second layer 2 is in the form of a translucent metal thin film having a thickness of less than 350 A. As the metal, Al, Cr, Ag, Au, Pt and alloys of each of the foregoing materials. The second layer 2 is at one of the transparent function and reflection function.
The third layer 3 is in the form of a transparent oxide or fluoride of a metal such as Ta2 O5, TiO2, ZrO2, SiO2, MgF, Y2 O3, LiNbO3, and ZnO. The refractive index of each material of the third layer 3 is not restricted or limited.
The fourth layer 4 is in the form of metal thin film and is used as a reflecting film. A raw material and the thickness of the fourth layer 4 depend on the desired reflectance.
In the foregoing embodiment, the brightness and color tone of the reflected light mainly depend on the thickness of the second layer 2 and the third layer 3, respectively.
A single Table attached to this specification as an appendix, two embodiments of the present invention, which are indicated by characters (A) and (B), respectively are compared with a conventional example indicated by character (C). The conventional example fails to have a layer corresponding to the second layer of the present invention. In the Table, the evaluation is classified into three grades - "excellent", "good" and "bad" when the reflectance is 45-55%, less than 45% and above 55% respectively. This criteria is determined in light of the fact that the mirror should not be highly bright when it is used as a rear-view mirror of a motor vehicle. The foregoing "45-55%" is regarded as a best mode. The relationship between the reflectance and the wave length in regard to each example in the Table is illustrated in a graph as shown in FIG. 2. The colors of the above examples (A), (B) and (C) are somewhat dark brown, dark brown and light brown, respectively.
Royal purple (dark blue) reflected light is obtained when the second layer is made of Al (Cr) with a thickness of 35 (40)Å, the third layer is made of Ta2 O5 (Ta2 O5) with a thickness of 2000 (500)Å, and the fourth layer Cr (Cr) with a thickness of 0.1 (0.1)μm.
As apparent from the foregoing description, alternation of the materials of the layers and the thickness of each layer, a wide range of colors can be obtained in addition to the foregoing colors such as pink, green, yellow and gold.
In order to obtain the foregoing structure in layers, sputtering method, ion-plating method and so on are available.
Obviously, numerous modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practised otherwise than as specifically described herein.
TABLE
__________________________________________________________________________
Evalu-
2nd Layer
3rd Layer 4th Layer
ation
__________________________________________________________________________
Embodiment
raw material: Al
raw material: Ta.sub.2 O.sub.5
raw material: Al
⊚
(A) thickness: 35 Å
thickness: 500 Å
thickness: 0.15 μm
Embodiment
raw material: Al
raw material: Ta.sub.2 O.sub.5
raw material: Al
◯
(B) thickness: 70 Å
thickness: 500 Å
thickness: 0.15 μm
Conventional
-- raw material: Ta.sub.2 O.sub.5
raw material: Al
X
Example thickness: 500 Å
thickness: 0.15 μm
__________________________________________________________________________
Claims (7)
1. A rear-view mirror for a motor vehicle comprising
a first transparent layer;
a second layer directly formed on the first layer and being in the form of a translucent metal thin film having a thickness of less than 100 Angstroms;
a third layer directly formed on the second layer and being in the form of transparent oxide or fluoride of metal; and
a fourth layer directly formed on the third layer and being in the form of a thin metal layer to be used substantially as a reflecting member.
2. A mirror according to claim 1 wherein the metal thin film of the second layer is a metal or an alloy from the group consisting of Al, Cr, Ag, Au, and Pt.
3. A mirror according to claim 1 wherein the metal of the fourth layer is the same as the metal of the second layer.
4. A rear-view mirror for a motor vehicle comprising
a first transparent layer;
a second layer directly formed on the first layer and being in the form of a translucent aluminum thin film having a thickness in the range of about 35 to 70 Angstroms;
a third layer directly formed on the second layer and being in the form of transparent oxide or fluoride metal; and
a fourth layer directly formed on the third layer and being in the form of a thin aluminum layer to be used as a reflecting member for reflecting substantially all of incident light.
5. A mirror according to claim 4 wherein the reflectance of the mirror is in the range of approximately 45-55 percent.
6. A mirror according to claim 4 wherein the metal thin film of the second layer is a metal or an alloy from the group consisting of Al, Cr, Ag, Au, and Pt.
7. A mirror according to claim 4 wherein the metal of the fourth layer is the same as the metal of the second layer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2145845A JPH0437805A (en) | 1990-06-04 | 1990-06-04 | Reflecting mirror consisting of laminated thin film |
| JP2-145845 | 1990-06-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US5159490A true US5159490A (en) | 1992-10-27 |
Family
ID=15394432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US07/709,603 Expired - Fee Related US5159490A (en) | 1990-06-04 | 1991-06-03 | Mirror |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US5159490A (en) |
| JP (1) | JPH0437805A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2317021A (en) * | 1996-08-28 | 1998-03-11 | Seos Displays Ltd | An optical device |
| US5838505A (en) * | 1996-03-08 | 1998-11-17 | Palathingal; Jose C. | Divided-reflection method of wide-angle observation and wide-angle view automobile mirror |
| US6266193B1 (en) | 1997-07-24 | 2001-07-24 | Cpfilms Inc. | Anti-reflective composite |
| US6583935B1 (en) | 1998-05-28 | 2003-06-24 | Cpfilms Inc. | Low reflection, high transmission, touch-panel membrane |
| WO2005111672A1 (en) * | 2004-05-12 | 2005-11-24 | Flabeg Gmbh & Co. Kg | Low glare rear-view mirror for vehicles |
| WO2006048940A1 (en) * | 2004-11-05 | 2006-05-11 | Murakami Corporation | Anti-dazzle/anti-fog device and mirror for automobile |
| US20090080076A1 (en) * | 2007-09-26 | 2009-03-26 | Toyoda Gosei Co., Ltd. | Apparatus housing and apparatus decoration with interference color film |
| WO2015054724A1 (en) * | 2013-10-15 | 2015-04-23 | University Of South Australia | Anti-glare mirrors |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4552733B2 (en) * | 2005-03-31 | 2010-09-29 | ソニー株式会社 | Screen and manufacturing method thereof |
| FR2930996B1 (en) * | 2008-05-07 | 2010-08-27 | Christian Dalloz Sunoptics | NEW TYPE OF GLASS FOR EYEWEAR AND METHOD OF OBTAINING SAME |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4214818A (en) * | 1978-11-08 | 1980-07-29 | Westinghouse Electric Corp. | Hot pressed SiC-high power laser mirror |
| JPS60212704A (en) * | 1984-04-06 | 1985-10-25 | Murakami Kaimeidou:Kk | Reflection mirror |
| US4669074A (en) * | 1982-05-19 | 1987-05-26 | Burroughs Corporation | Focusing control circuitry for an optical memory system |
| JPS63163402A (en) * | 1986-12-26 | 1988-07-06 | Ichikoh Ind Ltd | Glare preventing mirror for vehicle |
| US4773717A (en) * | 1986-11-03 | 1988-09-27 | Ovonic Synthetic Materials Co. | Transparency having a second surface multilayer decorative coating |
| US4838648A (en) * | 1988-05-03 | 1989-06-13 | Optical Coating Laboratory, Inc. | Thin film structure having magnetic and color shifting properties |
| US4888759A (en) * | 1982-09-09 | 1989-12-19 | Burroughs Corporation | Laser optical memory system having beam combining and separating apparatus for combining and separating reading and writing laser beams |
| US4930866A (en) * | 1986-11-21 | 1990-06-05 | Flex Products, Inc. | Thin film optical variable article and method having gold to green color shift for currency authentication |
| US5055358A (en) * | 1989-09-29 | 1991-10-08 | Libbey-Owens-Ford Co. | Low reflectance films for transparent substrates |
| US5080455A (en) * | 1988-05-17 | 1992-01-14 | William James King | Ion beam sputter processing |
-
1990
- 1990-06-04 JP JP2145845A patent/JPH0437805A/en active Pending
-
1991
- 1991-06-03 US US07/709,603 patent/US5159490A/en not_active Expired - Fee Related
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4214818A (en) * | 1978-11-08 | 1980-07-29 | Westinghouse Electric Corp. | Hot pressed SiC-high power laser mirror |
| US4669074A (en) * | 1982-05-19 | 1987-05-26 | Burroughs Corporation | Focusing control circuitry for an optical memory system |
| US4888759A (en) * | 1982-09-09 | 1989-12-19 | Burroughs Corporation | Laser optical memory system having beam combining and separating apparatus for combining and separating reading and writing laser beams |
| JPS60212704A (en) * | 1984-04-06 | 1985-10-25 | Murakami Kaimeidou:Kk | Reflection mirror |
| US4773717A (en) * | 1986-11-03 | 1988-09-27 | Ovonic Synthetic Materials Co. | Transparency having a second surface multilayer decorative coating |
| US4930866A (en) * | 1986-11-21 | 1990-06-05 | Flex Products, Inc. | Thin film optical variable article and method having gold to green color shift for currency authentication |
| JPS63163402A (en) * | 1986-12-26 | 1988-07-06 | Ichikoh Ind Ltd | Glare preventing mirror for vehicle |
| US4838648A (en) * | 1988-05-03 | 1989-06-13 | Optical Coating Laboratory, Inc. | Thin film structure having magnetic and color shifting properties |
| US5080455A (en) * | 1988-05-17 | 1992-01-14 | William James King | Ion beam sputter processing |
| US5055358A (en) * | 1989-09-29 | 1991-10-08 | Libbey-Owens-Ford Co. | Low reflectance films for transparent substrates |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5838505A (en) * | 1996-03-08 | 1998-11-17 | Palathingal; Jose C. | Divided-reflection method of wide-angle observation and wide-angle view automobile mirror |
| GB2317021A (en) * | 1996-08-28 | 1998-03-11 | Seos Displays Ltd | An optical device |
| US6266193B1 (en) | 1997-07-24 | 2001-07-24 | Cpfilms Inc. | Anti-reflective composite |
| US6583935B1 (en) | 1998-05-28 | 2003-06-24 | Cpfilms Inc. | Low reflection, high transmission, touch-panel membrane |
| US20080019006A1 (en) * | 2004-05-12 | 2008-01-24 | Flabeg Gmbh & Co. Kg | Low-Glare Rear-View Mirror For Vehicles |
| WO2005111672A1 (en) * | 2004-05-12 | 2005-11-24 | Flabeg Gmbh & Co. Kg | Low glare rear-view mirror for vehicles |
| US20080212188A1 (en) * | 2004-05-12 | 2008-09-04 | Flabeg Gmbh & Co. Kg | Low Glare Rear-View Mirror for Vehicles |
| CN100514090C (en) * | 2004-05-12 | 2009-07-15 | 福勒柏格两合公司 | Low glare rear-view mirror for vehicles |
| US7762678B2 (en) * | 2004-05-12 | 2010-07-27 | Flabeg Gmbh & Co. Kg | Low-glare rear-view mirror for vehicles |
| US7887201B2 (en) | 2004-05-12 | 2011-02-15 | Flabeg Gmbh & Co. Kg | Low glare rear-view mirror for vehicles |
| WO2006048940A1 (en) * | 2004-11-05 | 2006-05-11 | Murakami Corporation | Anti-dazzle/anti-fog device and mirror for automobile |
| US20090080076A1 (en) * | 2007-09-26 | 2009-03-26 | Toyoda Gosei Co., Ltd. | Apparatus housing and apparatus decoration with interference color film |
| WO2015054724A1 (en) * | 2013-10-15 | 2015-04-23 | University Of South Australia | Anti-glare mirrors |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0437805A (en) | 1992-02-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: AISIN SEIKI KABUSHIKI KAISHA, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:AMANO, TAKASHI;OKA, TETSUO;MITA, JUNICHI;AND OTHERS;REEL/FRAME:005779/0724 Effective date: 19910717 |
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Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
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| FPAY | Fee payment |
Year of fee payment: 4 |
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| REMI | Maintenance fee reminder mailed | ||
| LAPS | Lapse for failure to pay maintenance fees | ||
| FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20001101 |
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| STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |