US5159019A - Sliding material composition - Google Patents

Sliding material composition Download PDF

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US5159019A
US5159019A US07/710,395 US71039591A US5159019A US 5159019 A US5159019 A US 5159019A US 71039591 A US71039591 A US 71039591A US 5159019 A US5159019 A US 5159019A
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weight
resin
tetrafluoroethylene
ptfe
parts
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Yoshihisa Yamamoto
Tuyoshi Miyamori
Kazuo Ishiwari
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Daikin Industries Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms

Definitions

  • the present invention relates to a sliding material composition.
  • the present invention relates to a sliding material composition comprising a polyphenylene sulfide resin, a melt processable fluorine-containing resin and polytetrafluoroethylene.
  • Such a composition provides a heat-resistant plastic sliding material which can be injection molded so as to improve productivity.
  • compositions comprising a heat-resistant base resin in which powdery polytetrafluoroethylene (hereinafter referred to as "PTFE") or an inorganic solid lubricant,(e.g. molybdenum disulfide or graphite) is used as a filler in order to impart abrasion resistance or a lubricating property to the resin.
  • PTFE powdery polytetrafluoroethylene
  • inorganic solid lubricant e.g. molybdenum disulfide or graphite
  • PTFE abrasion resistance and lubricating properties which are imparted by the addition of PTFE most effectively contribute to a decrease in the friction coefficient. Then, PTFE is used as an additive filler to many heat-resistant resins.
  • polyphenylene sulfide As the base resin of the sliding material composition, polyphenylene sulfide (hereinafter referred to as "PPS") is widely used because of its good heat resistance, stiffness, moldability, chemical resistance, etc.
  • PPS polyphenylene sulfide
  • a composition of PPS to which PTFE is added to impart abrasion resistance and the sliding property is widely used as a heat-resistant material (see Japanese Patent Kokai Publication No. 73275/1977).
  • the addition of only the solid lubricants including PTFE cannot sufficiently improve abrasion characteristics, and the PPS composition containing the solid composition can only be used at a low speed under low load. Further, since the addition of PTFE will decrease mechanical strength such as impact resistance, the composition finds limited applications.
  • a flexible polymer is blended with the resin.
  • an elastomer for example, is blended with the resin, abrasion characteristics and lubricating properties deteriorate and no desirable composition is achieved.
  • One object of the present invention is to provide a material which can prevent decrease of impact resistance of a PPS composition caused by the addition PTFE while preventing deterioration of the abrasion resistance and the sliding property imparted by PTFE.
  • a sliding material composition comprising
  • the amount of the mixture (b) is less than 5 parts by weight per 100 parts by weight of PPS, the abrasion resistance and the sliding property are not sufficiently improved. When this amount exceeds 100 parts by weight, inherent properties of PPS such as heat resistance and stiffness may deteriorate.
  • melt processable fluorine-containing resin examples include tetrafluoroethylene/perfluoroalkyl vinyl ether copolymers (hereinafter referred to as "PFA”), tetrafluoroethylene/hexafluoropropylene copolymers (hereinafter referred to as "FEP”), tetrafluoroethylene/hexafluoropropylene/perfluoroalkyl referred to as "EPE”), ethylene/tetrafluoroethylene copolymers (hereinafter referred to as "ETFE”), polyvinylidene fluoride (hereinafter referred to as "PVDF”), polychlorotrifluoroethylene (hereinafter referred to as "PCTFE”) and the like. Among them, PFA and ETFE are preferred.
  • R f is a fluoroalkyl group having 1 to 10 carbon atoms, preferably perfluoroalkyl group.
  • PFA comprises 99.5 to 92 % by weight of tetrafluoroethylene and 0.5 to 8% by weight of the fluoroalkyl vinyl ether.
  • the melt processable fluorine-containing resin may comprise at least one other monomer in such amount that the inherent properties of the resin are not deteriorated.
  • the other monomer are tetrafluoroethylene (in the case of the resins other than PFA and FEP), hexafluorovinyl propylene (in the case of the resins other than FEP), perfluoroalkyl vinyl ether (in the case of the resins other than PFA), perfluoro(C 1 -C 10 -alkylethylene), perfluoro(C 1 -C 10 alkylallyl ether), and a compound of the formula:
  • PPS to be used in the present invention may be uncured or partially cured polyphenylene sulfide resin or mixtures thereof as well as their modified products.
  • Examples of commercially available PPS are PPS sold by Polyplastics under the trade name “FORTRON”, and PPS sold by Phillips Petroleum Co., Ltd. under the trade name of "RYTON".
  • At least one additive such as an inorganic or organic reinforcing material or other solid lubricant may be added so long as the objects of the present invention are not impaired.
  • PTFE and the melt processable fluorine-containing resin may be first kneaded and pelletized, and then kneaded with PPS.
  • the pellets are molded to produce an article of a desired shape using a molding machine which is used for molding a thermoplastic resin such as an injection molding machine, a compression molding machine, an extruder and the like.
  • the abrasion and wearing test is carried out under the following conditions:
  • tensile strength at break is measured according to ASTM D638 at room temperature at a drawing rate of 5 mm/min.
  • the pellets and a polyphenylene sulfide resin (FORTRON 1140-A1 containing 66.7 parts by weight of glass fibers per 100 parts of the polyphenylene sulfide resin, manufactured by Polyplastics Co., Ltd.) were mixed in a tumbling mixer in a ratio shown in the Table. Thereafter, the mixture was melt mixed and pelletized by a different direction type twin screw extruder at 340° to 380° C. to produce molding pellets.
  • the same polyphenylene sulfide resin as used in Examples 1 to 5 was mixed with PTFE or PFA in a ratio shown in the Table and then pelletized by the twin screw extruder and injection molded in the same manner as in Examples 1 to 5 to produce a test piece.
  • the properties of the test piece were measured by the above methods. The results are shown in the Table.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Lubricants (AREA)

Abstract

A sliding material composition comprising (a) 100 parts by weight of polyphenylene sulfide and (b) 5 to 100 parts by weight of a resin mixture of 10 to 90% by weight of a melt processable fluorine-containing resin and 90 to 10% by weight of polytetrafluoroethylene, which has good abrasion resistance and lubricating properties without the deterioration of impact strength.

Description

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a sliding material composition. In particular, the present invention relates to a sliding material composition comprising a polyphenylene sulfide resin, a melt processable fluorine-containing resin and polytetrafluoroethylene.
Such a composition provides a heat-resistant plastic sliding material which can be injection molded so as to improve productivity.
2. Description of the Related Art
Recently, a large amount of heat-resistant plastic materials have been used as materials of sliding parts such as a bearing. Many of such materials are compositions comprising a heat-resistant base resin in which powdery polytetrafluoroethylene (hereinafter referred to as "PTFE") or an inorganic solid lubricant,(e.g. molybdenum disulfide or graphite) is used as a filler in order to impart abrasion resistance or a lubricating property to the resin.
The abrasion resistance and lubricating properties which are imparted by the addition of PTFE most effectively contribute to a decrease in the friction coefficient. Then, PTFE is used as an additive filler to many heat-resistant resins.
As the base resin of the sliding material composition, polyphenylene sulfide (hereinafter referred to as "PPS") is widely used because of its good heat resistance, stiffness, moldability, chemical resistance, etc. A composition of PPS to which PTFE is added to impart abrasion resistance and the sliding property is widely used as a heat-resistant material (see Japanese Patent Kokai Publication No. 73275/1977).
However, the addition of only the solid lubricants including PTFE cannot sufficiently improve abrasion characteristics, and the PPS composition containing the solid composition can only be used at a low speed under low load. Further, since the addition of PTFE will decrease mechanical strength such as impact resistance, the composition finds limited applications.
Accordingly, it is desirable to provide a sliding material composition comprising PPS with good abrasion resistance and also good mechanical strength including impact strength.
In general, to improve impact strength of a resin, a flexible polymer is blended with the resin. However, when an elastomer, for example, is blended with the resin, abrasion characteristics and lubricating properties deteriorate and no desirable composition is achieved.
SUMMARY OF THE INVENTION
One object of the present invention is to provide a material which can prevent decrease of impact resistance of a PPS composition caused by the addition PTFE while preventing deterioration of the abrasion resistance and the sliding property imparted by PTFE.
Another object of the present invention is to provide a sliding material composition comprising PPS and PTFE which has good impact resistance.
According to the present invention, there is provided a sliding material composition comprising
(a) 100 parts by weight of PPS,
(b) 5 to 100 parts by weight of a resin mixture of 10 to 90 % by weight of a melt processable fluorine-containing resin and 90 to 10 % by weight of PTFE.
DETAILED DESCRIPTION OF THE INVENTION
In the composition of the present invention, if an amount of the melt processable fluorine-containing resin or PTFE in the mixture (b) is less than 10% by weight or larger than 90% by weight, the mechanical properties such as impact strength greatly deteriorate.
When the amount of the mixture (b) is less than 5 parts by weight per 100 parts by weight of PPS, the abrasion resistance and the sliding property are not sufficiently improved. When this amount exceeds 100 parts by weight, inherent properties of PPS such as heat resistance and stiffness may deteriorate.
Specific examples of the melt processable fluorine-containing resin are tetrafluoroethylene/perfluoroalkyl vinyl ether copolymers (hereinafter referred to as "PFA"), tetrafluoroethylene/hexafluoropropylene copolymers (hereinafter referred to as "FEP"), tetrafluoroethylene/hexafluoropropylene/perfluoroalkyl referred to as "EPE"), ethylene/tetrafluoroethylene copolymers (hereinafter referred to as "ETFE"), polyvinylidene fluoride (hereinafter referred to as "PVDF"), polychlorotrifluoroethylene (hereinafter referred to as "PCTFE") and the like. Among them, PFA and ETFE are preferred.
In general, PFA is a copolymer of tetrafluoroethylene and at least one fluoroalkyl vinyl ether of the formula:
CF.sub.2 =CF--O--R.sub.f                                   (I)
wherein Rf is a fluoroalkyl group having 1 to 10 carbon atoms, preferably perfluoroalkyl group. Preferably, PFA comprises 99.5 to 92 % by weight of tetrafluoroethylene and 0.5 to 8% by weight of the fluoroalkyl vinyl ether.
Preferably, FEP comprises 96 to 87% by weight of tetrafluoroethylene and 4 to 13% by weight of hexafluoropropylene, and ETFE comprises 90 to 74% by weight of tetrafluoroethylene and 10 to 26% by weight of ethylene.
The melt processable fluorine-containing resin may comprise at least one other monomer in such amount that the inherent properties of the resin are not deteriorated. Examples of the other monomer are tetrafluoroethylene (in the case of the resins other than PFA and FEP), hexafluorovinyl propylene (in the case of the resins other than FEP), perfluoroalkyl vinyl ether (in the case of the resins other than PFA), perfluoro(C1 -C10 -alkylethylene), perfluoro(C1 -C10 alkylallyl ether), and a compound of the formula:
CF.sub.2 =CF--[OCF.sub.2 CFX(CF.sub.2).sub.m ].sub.n --OCF.sub.2 (CF.sub.2).sub.p --Y                                      (II)
wherein X is a fluorine atom or a trifluoromethyl group, Y is a halogen atom (e.g. fluorine, chlorine, bromine or iodine), m is 0 or 1 provided that when m is 1 (one), X is a fluorine atom, n is a number of 0 to 5, and p is a number of 0 to 2.
PTFE to be used in the present invention is in a powder form having an average particle size of 30 μm or less and may be PTFE powder which is usually used to impart the sliding property. In the present invention, PTFE includes not only homopolymer of tetrafluoroethylene but also a copolymer of tetrafluoroethylene and 1.0% by weight or less of at least one copolymerizable monomer.
PPS to be used in the present invention may be uncured or partially cured polyphenylene sulfide resin or mixtures thereof as well as their modified products. Examples of commercially available PPS are PPS sold by Polyplastics under the trade name "FORTRON", and PPS sold by Phillips Petroleum Co., Ltd. under the trade name of "RYTON".
To the composition of the present invention, at least one additive such as an inorganic or organic reinforcing material or other solid lubricant may be added so long as the objects of the present invention are not impaired.
In order to increase the mechanical properties of the composition of the present invention, various fillers can be added. Examples of the fillers which can be used in the present invention are glass fibers, asbestos fibers, silica fibers, silica-alumina fibers, alumina fibers, zirconia fibers, potassium titanate whiskers, polyamide fibers, phenol resin fibers, silica, talc, clay, mica, calcium carbonate, barium sulfate, titanium oxide, silicon nitride and the like.
The resin composition of the present invention may be prepared by a known mixing process.
For example, the components are mixed with a twin-cylinder mixer, a tumbling mixer, a Henschel mixer and the like and then further mixed and pelletized with a melt kneading apparatus such as a twin-screw extruder.
In the preparation, all the components are mixed simultaneously, though PTFE and the melt processable fluorine-containing resin may be first kneaded and pelletized, and then kneaded with PPS.
The pellets are molded to produce an article of a desired shape using a molding machine which is used for molding a thermoplastic resin such as an injection molding machine, a compression molding machine, an extruder and the like.
PREFERRED EMBODIMENTS OF THE INVENTION
The present invention will be illustrated by the following Examples.
The resin compositions prepared in Examples are evaluated by the following test methods:
(1) Abrasion and wearing test
By using a Suzuki-Matsubara type abrasion machine (manufactured by Orientec Co., Ltd.) and S45C having a surface roughness Ra of 0.1 to 0.3 μm as an opposite material, the abrasion and wearing test is carried out under the following conditions:
i) Coefficient of dynamic friction
Measured at a surface pressure of 10 kg/cm2 and a sliding speed of 0.3 m/sec.
ii) Wear factor
After carrying the test at a surface pressure of 10 kg/cm2 and a sliding speed of 0.3 m/sec., a decreased amount of the sample is measured and a wear factor is calculated according to the following equation: ##EQU1##
(2) Izod impact test
By using a U-F impact test machine (manufactured by Ueshima Manufacturing Co., Ltd.), notched Izod impact strength is measured according to ASTM D256.
(3) Tensile test
By using a Tensilon universal test machine (manufactured by Orientec Co., Ltd.), tensile strength at break is measured according to ASTM D638 at room temperature at a drawing rate of 5 mm/min.
EXAMPLES 1-5
In a Henschel mixer, tetrafluoroethylene/perfluoroalkyl vinyl ether) copolymer powder (Neoflon PFA, AP-210 manufactured by Daikin Industries, Ltd.) and PTFE powder (Lublon L-5F having an average particle size of 5 μm manufactured by Daikin Industries, Ltd.) were homogeneously mixed in amounts shown in the Table, and then melt mixed and pelletized by an extruder having a screw diameter of 50 mm at a cylinder temperature of 380° C.
Then, the pellets and a polyphenylene sulfide resin (FORTRON 1140-A1 containing 66.7 parts by weight of glass fibers per 100 parts of the polyphenylene sulfide resin, manufactured by Polyplastics Co., Ltd.) were mixed in a tumbling mixer in a ratio shown in the Table. Thereafter, the mixture was melt mixed and pelletized by a different direction type twin screw extruder at 340° to 380° C. to produce molding pellets.
The produced pellets were charged in an injection molding machine (cylinder temperature: 340° to 380° C., mold temperature: 140° C.) and each test piece was injection molded.
With the molded test piece, each property was measured by the above described method. The results are shown in the Table.
EXAMPLE 6
In the same manner as in Examples 1 to 5 but mixing the PFA powder and the PTFE powder with the polyphenylene sulfide resin in a ratio of the Table and mixing and pelletizing them simultaneously by the twin screw extruder at 340° to 380° C., a test piece was produced and its properties were measured. The results are shown in the Table.
EXAMPLE 7
In the same manner as in Examples 1 to 5 but using a tetrafluoroethylene/hexafluoropropylene copolymer powder (Neoflon FEP, NP-20 manufactured by Daikin Industries, Ltd.) in place of the PFA powder, a test piece was produced and its properties were measured. The results are shown in the Table.
EXAMPLE 8
In the same manner as in Examples 1 to 5 but using a tetrafluoroethylene/ethylene copolymer powder (Neoflon ETFE, EP-521 manufactured by Daikin Industries, Ltd.) in place of the PFA powder and changing an extrusion temperature to 320° C. and a cylinder temperature for molding to 280° to 290° C., a test piece was produced and its properties were measured. The results are shown in the Table.
EXAMPLE 9
In the same manner as in Examples 1 to 5 but using a polyvinylidene fluoride powder (Neoflon VDF, VP-850 manufactured by Daikin Industries, Ltd.) in place of the PFA powder and changing an extrusion temperature to 300° C. and a cylinder temperature for molding to 280° to 290° C., a test piece was produced and its properties were measured. The results are shown in the Table.
COMPARATIVE EXAMPLES 1, 2 and 3
The same polyphenylene sulfide resin as used in Examples 1 to 5 was mixed with PTFE or PFA in a ratio shown in the Table and then pelletized by the twin screw extruder and injection molded in the same manner as in Examples 1 to 5 to produce a test piece. The properties of the test piece were measured by the above methods. The results are shown in the Table.
As seen from the results of the Table, the composition of the present invention has a smaller coefficient of dynamic friction and a smaller wear factor which are required for the sliding material, while there is no great decrease of the Izod impact strength and tensile strength. In Examples 1, 4, 5 and 7 to 9, the Izod impact strength was increased.
As understood from the results of the Table for Comparative Examples, the addition of only PTFE (Comparative Example 1) or only PFA (Comparative Example 2) reduced the wear factor in comparison with the PPS resin containing neither PTFE nor PFA (Comparative Example 3), but the Izod impact strength was greatly decreased and the tensile strength was also decreased.
In the Table, "parts" and "%" are by weight.
                                  TABLE                                   
__________________________________________________________________________
            Example No.                                                   
            1     2     3     4     5     6                               
__________________________________________________________________________
PPS (parts) 100   100   100   100   100   100                             
Glass fiber (parts)                                                       
            66.7  66.7  66.7  66.7  66.7  66.7                            
PTFE/melt processable                                                     
            41.6  41.6  41.6  71.4  18.5  41.6                            
F-cont. resin (parts)                                                     
Kind of     PFA   PFA   PFA   PFA   PFA   PFA                             
melt processable                                                          
F-cont. resin                                                             
Ratio:                                                                    
PTFE (%)    50    30    70    50    50    50                              
Melt processable                                                          
            50    70    30    50    50    50                              
F-cont. resin (%)                                                         
Coefficient of                                                            
            0.40  0.34  0.50  0.33  0.41  0.39                            
dynamic friction                                                          
Wear factor 1.4 × 10.sup.-2                                         
                  1.6 × 10.sup.-2                                   
                        4.6 × 10.sup.-2                             
                              3.2 × 10.sup.-2                       
                                    1.6 × 10.sup.-2                 
                                          5.0 × 10.sup.-2           
(mm.sup.3 /kg · km)                                              
Notched Izod                                                              
            9.9   8.3   7.2   9.0   9.5   6.8                             
impact strength                                                           
(kg · cm/cm)                                                     
Tensile strength                                                          
            1320  1310  1280  1200  1590  1100                            
(kg/cm.sup.2)                                                             
__________________________________________________________________________
            Example No.                                                   
            7     8     9     Comp. 1                                     
                                    Comp. 2                               
                                          Comp. 3                         
__________________________________________________________________________
PPS (parts) 100   100   100   100   100   100                             
Glass fiber (parts)                                                       
            66.7  66.7  66.7  66.7  66.7  66.7                            
PTFE/melt processable                                                     
            41.6  41.6  41.6  41.6  41.6  0                               
F-cont. resin (parts)                                                     
Kind of     FEP   ETFE  PVDF  --    PFA   --                              
melt processable                                                          
F-cont. resin                                                             
Ratio:                                                                    
PTFE (%)    50    50    50    100   0     0                               
Melt processable                                                          
F-cont. resin (%)                                                         
            50    50    50    0     100   0                               
Coefficient of                                                            
            0.39  0.40  0.41  0.42  0.46  0.48                            
dynamic friction                                                          
Wear factor 1.8 × 10.sup.-2                                         
                  2.9 × 10.sup.-2                                   
                        4.3 × 10.sup.-2                             
                              5.9 × 10.sup.-2                       
                                    2.3 × 10.sup.-2                 
                                          54.5 × 10.sup.-2          
(mm.sup.3 /kg · km)                                              
Notched Izod                                                              
            9.5   9.4   9.7   5.9   6.0   8.8                             
impact strength                                                           
(kg · cm/cm)                                                     
Tensile strength                                                          
            1200  1360  1400  1130  1110  1890                            
(kg/cm.sup.2)                                                             
__________________________________________________________________________

Claims (3)

What is claimed is:
1. A sliding material composition comprising
(a) 100 parts by weight of polyphenylene sulfide
(b) 5 to 100 parts by weight of a resin mixture of 10 to 90% by weight of a melt processable fluorine-containing resin and 90 to 10% by weight of polytetrafluoroethylene.
2. The sliding material composition according to claim 1, wherein said melt processable fluorine-containing resin is selected from the group consisting of tetrafluoroethylene/perfluoroalkyl vinyl ether copolymers, tetrafluoroethylene/hexafluoropropylene copolymers, tetrafluoroethylene/hexafluoropropylene/perfluoroalkyl vinyl ether copolymers, ethylene/tetrafluoroethylene copolymers, polyvinylidene fluoride and polychlorotrifluoroethylene.
3. The sliding material composition according to claim 1, wherein polytetrafluoroethylene is a powder having an average particle size of not larger than 30 μm.
US07/710,395 1990-06-08 1991-06-05 Sliding material composition Expired - Lifetime US5159019A (en)

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JP2151357A JP3052338B2 (en) 1990-06-08 1990-06-08 Sliding material composition and method for producing the same

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GB2274844A (en) * 1993-02-09 1994-08-10 T & N Technology Ltd Plain bearing material
US5470901A (en) * 1989-11-30 1995-11-28 Daikin Industries, Ltd. Polyphenylene sulfide resin composition and process for preparing the same
US5635299A (en) * 1993-10-07 1997-06-03 Tsubakimoto Chain Co. Sliding member usable in dry and wet states and method of manufacturing the member
US5684088A (en) * 1992-11-05 1997-11-04 Daikin Industries, Ltd. Polyphenylene sulfide resin compositions and process for preparation of same
US5708089A (en) * 1993-07-10 1998-01-13 Hoecht Ag Mixtures of fluoropolymers and oxidized polyarylene sulfides
US5750221A (en) * 1993-07-10 1998-05-12 Hoechst Ag Abrasion-resistant fluoropolymer mixtures
US6057393A (en) * 1992-09-14 2000-05-02 Oiles Corporation Sulfide polymer composition for sliding member and sliding member therefrom
US6303686B1 (en) * 1996-09-25 2001-10-16 Daikin Industries Ltd. Resin composition having water and oil repellency
CN101865212A (en) * 2009-04-17 2010-10-20 爱尔铃克铃尔股份公司 Sliding bearing
US9441109B2 (en) 2013-01-23 2016-09-13 Toray Industries, Inc. Polyphenylene sulfide resin composition, production method of the same and molded product
US9970483B2 (en) * 2013-12-27 2018-05-15 Federal-Mogul Wiesbaden Gmbh Self-lubricating thermoplastic layers containing PTFE additive having a polymodal molecular weight
CN110799593A (en) * 2017-06-28 2020-02-14 大金工业株式会社 Resin composition and molded article
CN112410099A (en) * 2019-08-23 2021-02-26 佳能株式会社 Lubricant composition, sliding apparatus, fixing apparatus, and image forming apparatus

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JP3235223B2 (en) * 1992-11-05 2001-12-04 ダイキン工業株式会社 Method for producing polyphenylene sulfide resin composition
DE29605891U1 (en) * 1996-03-29 1996-06-20 Heuser, Holger, 41469 Neuss Guide hose
US6121353A (en) * 1996-11-14 2000-09-19 Asahi Glass Company Ltd. Polymer alloy of an ethylene-tetrafluoroethylene copolymer
JP4223089B2 (en) * 1998-03-19 2009-02-12 Ａｇｃマテックス株式会社 Resin composition
CN109689788B (en) * 2016-10-21 2021-04-06 东丽株式会社 Polyarylene sulfide resin powder/particle mixture and method for producing three-dimensional shaped article
JP6961467B2 (en) * 2017-11-14 2021-11-05 大塚化学株式会社 Resin composition, molded body, sliding member, and sliding method

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JP3052338B2 (en) 2000-06-12
EP0460689A1 (en) 1991-12-11
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EP0460689B1 (en) 1996-05-08
DE69119298T2 (en) 1996-10-02
DE69119298D1 (en) 1996-06-13

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