US511891A - Process of making vegetable-parchment fabrics - Google Patents
Process of making vegetable-parchment fabrics Download PDFInfo
- Publication number
- US511891A US511891A US511891DA US511891A US 511891 A US511891 A US 511891A US 511891D A US511891D A US 511891DA US 511891 A US511891 A US 511891A
- Authority
- US
- United States
- Prior art keywords
- sheets
- parchment
- solution
- vegetable
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 28
- 239000004744 fabric Substances 0.000 title description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 48
- 239000000463 material Substances 0.000 description 36
- 235000013311 vegetables Nutrition 0.000 description 28
- 239000000835 fiber Substances 0.000 description 26
- 239000003795 chemical substances by application Substances 0.000 description 22
- QPLDLSVMHZLSFG-UHFFFAOYSA-N copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 20
- 239000002904 solvent Substances 0.000 description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 16
- 239000001117 sulphuric acid Substances 0.000 description 16
- 235000011149 sulphuric acid Nutrition 0.000 description 16
- 238000001035 drying Methods 0.000 description 12
- 229960004643 Cupric oxide Drugs 0.000 description 10
- 239000003517 fume Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 229920002678 cellulose Polymers 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000003825 pressing Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 230000000266 injurious Effects 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000001788 irregular Effects 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 240000002027 Ficus elastica Species 0.000 description 2
- 206010022114 Injury Diseases 0.000 description 2
- 210000001503 Joints Anatomy 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive Effects 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- BESJRHHIPGWPTC-UHFFFAOYSA-N azane;copper Chemical compound N.[Cu] BESJRHHIPGWPTC-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000881 depressing Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000001264 neutralization Effects 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N p-acetaminophenol Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000011088 parchment paper Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/08—Vegetable parchment
Definitions
- the object of this invention is to manufacture sheets, tubes, and other fabrics, of vegetable parchment, by cementing separate sheets of the parchment together to form a thick material.
- Such material from one quarter of an inch and upward in thickness, is of great use in various manufactures; but can only be produced by cementing numer ous sheets together, and certain difficulties have been heretofore experienced in its production, for the reason that some solvents of cellulose cannot be properly washed out of the thick material, and others are much more expensive and require a very slow process to expel the solvent.
- Sulphuric acid is the cheapest agent in use for parchmentizing sheets of vegetable matter, and operates rapidly upon the cellulose; but is liable to convert the same into pulp if it acts too long upon the cellulose, and it cannot be removed by evaporation, and cannot be washed wholly from a thick mass of the material without great difficulty.
- Ghloride'of zinc although more expensive, is therefore commonly used in forming thick masses of parchmentized material, which are generally known as vulcanized fiber, but this agent as well as sulphuric acid injures the fiber if it remains permanently in contact therewith, and must therefore be removed or neutralized. Such removal, which may be done by a bath of suitable reagent, is relatively slow in its operation, and the use of chloride of zinc there fore involves a slow and relatively expensive process.
- My process therefore consists essentially in first parchmentizing the vegetable fiber by a suitable agent, as sulphuric acid, washing such agent from the fiber and drying the same and then cementing a mass of such parchmentized fiber together by the means of a suitable ammoniacal solution.
- a suitable agent as sulphuric acid
- washing such agent from the fiber and drying the same and then cementing a mass of such parchmentized fiber together by the means of a suitable ammoniacal solution.
- the sheets require drying before the application of the copper solution, as the water if left in the sheets, would dilute the solution and prevent its action in the de sired degree as a solvent.
- Sheets of the vegetable parchment, in suitable number to form a mass of the required thickness are then treated with the ammoniaeal solution of cupric oxide for a suitable length of time to dissolve their surfaces, say half a minute, and are then pressed together with a very moderate pressure, sufficient to bring the surfaces uniformly into contact.
- the surfaces of the separate sheets are rendered so adhesive by this solution that the mass becomes completely consolidated in. four or five minutes, and the product may then be dried in the atmosphere, which for sheets under half an inch in thickness can be accomplish ed in from one to three days.
- I employ parchment paper or the waste pieces of the sheets made as above reduced to small grains, and immerse them in the ammoniacal solution for a suitable length of time, and then press the same into a mold of the required form.
- the greater part of the solution is expressed from the mass of parchmentized material, and may be preserved and used over and over if its strength he maintained by the addition of ammonia as. g It will be understood that it is essential to dry the material, whatever its form, after it is parchmentized, before it is subjected to the solution for cementing the material together.
- Figurel is a of the apparatus with the exhaust hood removed
- Fig. 2 is an elevation of the same with the parts in section, where hatched, on line m, w, in Fig. 1.
- Fig. 3 showsinasectional View like Fig. 2, the apparatus for producing molded objects; and
- Fig. 4 is a plan of the receptacle and lower die.
- a is an india-rubber tank or receptacle adapted to receive the sheets when ready for pressure, the opposite sides of the tank being fitted to a bed I) and a platen c actuated by handscrew 01.
- Such a tank forms a yielding receptacle, whose Walls may be pressed upon the parchmentized material, and also serves to prevent the loss of the solution.
- the bottom of the tank is connected by a tube cwith the bottom of an iron receiver f, which is provided with a vertical plunger 9.
- the receiver and its plunger are made sufficiently tight to prevent the escape of the ammonia, and a pipe h with .cock h is also connected with the bottom of the receiver to supply ammonia gas, to strengthen the solution when desired.
- a pipe is may be used to fill the receiver when the plunger is raised, and the solution is forced into the tank by depressing theplunger.
- the parchmentized sheets are then immersed in the tank and when their surfaces are suitably softened the plunger is raised to withdraw the solution; and the opposite sides then pressed'together by rotatingthe screw 01.
- the pressure which is only intended to bring the surfaces of the sheets into uniform contact, is sufficient to expel the greater part of the ammoniacal solution, which passes from the tube e into the receiver.
- the cock h in the pipe his closed, and a cock 6 in the tube e is opened,and the solution is drawn into the receiver by lifting the plunger g to a suitable degree. 15y closing the cock e and opening the cock in the pipe h, ammonia gas under pressure may be admitted to the receiver beneath the plunger, which operates to maintain the strength of the so lution in the receiver until the same is required for subsequent use.
- a pipe is with cock Z is provided to supply or draw off the solution when required
- the hood j is provided over the tank a to collect the ammonia fumes, and an exhaust pipe m is connected with the hood to draw off the fumes and thus prevent the fumes from affecting the operator after the parchment is placed in the tank.
- suitable dies In making objects or masses of irregular form, suitable dies would be used,- and surrounded by a suitable receptacle to collect the solution and discharge it to a receiver as already described.
- the receptacle a is made rigid and dies m, n are shown within the same to form a spherical object, as a billiard ball.
- the lower die 72 may be filled with a suitable volume of the softened vegetable parchment, and the upper die m would be pressed upon the same in any ordinary press; which is not shown in the drawings, as the operation of such presses is already well known.
- the vegetable parchment may be softened by admitting a supply of the cupric ammonia to the receptacle, as described in connection with Fig. 2, or the parchment may be suitably softened by the solvent before it is applied to the dies within the receptacle. In either case, the solution expressed from the material within the dies would overflow within the receptacle and may be discharged through the tube e into any suitable receiver.
- the apparatus like that shown in Fig. 2, is provided with an exhaust hood j, to draw the fumes away from the operator.
- an exhaust hood j to draw the fumes away from the operator.
- single sheets may be first made into layers one quarter of an inch in thickness and then dried and when the water and ammonia are thoroughly evaporated from such layers, several of the layers may be cemented together by softening their surfaces with the ammonia copper solution.
- the layers when pressed together adhere with the same readiness as single sheets, and the solvent is absorbed in the whole mass in such a manner that it is easily evaporated, being very small in amount, owing to the small number of joints.
- My process is distinguished from others by its performance in three distinct steps, and by the use of two distinct agents, the material being first treated with a cheap solvent to parchmentize the fiber; second, washed and dried, and third, cemented together by the use of an ammoniacal solution.
- the division of the process into three steps greatly facilitates the complete removal of the sulphuric acid or other parchmentizing agent by which the fiber is primarily treated.
- the use of an ammoniacal solution in the final step of the process greatly facilitates the final drying of the product,,and secures the entire absence of all injurious ingredients within the mass.
Description
, (No Modl.) 2 Sheets-Sheet 1. E J. W. HYATT.
- PROCESS OF MAKING VEGETABLE PARGHMENT FABRIC.
No. 511,891. Patented Jan. 2, 1894.
I Y[III/[IIIIII/I/Il/I/IIIIIIIII 2 Sheets-Sheet 2.
(No Model.)
J. .W. HYATT. PROGESS OF MAKING VEGETABLE PARGHMENT FABRIC.
110. 511,891. Patented Jan, 2, 1894.
amar aim.
JOHN IV. HYATT, OF NEWVARII, NEW .IERQEY.
PROCESS OF MAKING VEGETABLE-PARQHMENT FABRICS.
SPECIFICATION forming part of Letters Patent No. 511,891, dated January 2, 1894.
Application filed July 23,1892. Serial No. 440,988. (No specimens.) g
To aZZ whom it may concern.-
Be it known that I, JOHN IV. HYATT, a citizen of the United States, residing'at Newark, Essex county, New Jersey, have invented certain new and useful Improvements in Processes of Making Vegetable-Parchment Fabrics, fully described and represented in the following specification and the accompanying drawings, forming a part of the same.
The object of this invention is to manufacture sheets, tubes, and other fabrics, of vegetable parchment, by cementing separate sheets of the parchment together to form a thick material. Such material, from one quarter of an inch and upward in thickness, is of great use in various manufactures; but can only be produced by cementing numer ous sheets together, and certain difficulties have been heretofore experienced in its production, for the reason that some solvents of cellulose cannot be properly washed out of the thick material, and others are much more expensive and require a very slow process to expel the solvent. Sulphuric acid is the cheapest agent in use for parchmentizing sheets of vegetable matter, and operates rapidly upon the cellulose; but is liable to convert the same into pulp if it acts too long upon the cellulose, and it cannot be removed by evaporation, and cannot be washed wholly from a thick mass of the material without great difficulty. Ghloride'of zinc, although more expensive, is therefore commonly used in forming thick masses of parchmentized material, which are generally known as vulcanized fiber, but this agent as well as sulphuric acid injures the fiber if it remains permanently in contact therewith, and must therefore be removed or neutralized. Such removal, which may be done by a bath of suitable reagent, is relatively slow in its operation, and the use of chloride of zinc there fore involves a slow and relatively expensive process.
I have discovered a means'of utilizing the rapid action of sulphuric acid in parchmentizing the vegetable matter, and of avoiding the expense and slow operation of the chloride of zinc in the formation of thick bodiesof the material. In the use of chloride of zinc, the parchmentizing of the vegetable sheets and the cementing of them together is performed simultaneously; but in my process I employ two steps, first, parchmentizing the sheets separately by the use of sulphuric acid, and second, softening their surfaces and cementing them firmly together by the use of a solvent which contains no injurious agent, and the liquid in which evaporates readily from the mass. An ammoniacal solution of cupric oxide is such a solvent, and other ammoniacal solutions which perform the same functions may also be used. The evaporation of aqua-ammonia leaves the cupric oxide in the mass of parchmentized material, but such agent is entirely neutral in relation to the parchment, except when associated with the ammonia, and its presence causes no injury to the product. By the use of such a solvent, I find that a mass of parchmentized material may be built up of any d'esired thickness, and the solvent wholly expelled with comparative rapidity; as the ammonia and the water combined with the same are wholly volatile, and are easily discharged from the product by mere exposure to the atmosphere.
My process therefore consists essentially in first parchmentizing the vegetable fiber by a suitable agent, as sulphuric acid, washing such agent from the fiber and drying the same and then cementing a mass of such parchmentized fiber together by the means of a suitable ammoniacal solution. By the use of such agents, the process is performed with great cheapness and rapidity, and objects of any desired shape and dimensions may be produced; as the product is somewhat pervious to water, and the water and ammonia may thus be perfectly discharged from the same.
In forming layers or fiat masses, I parchmentize single sheets of paper of suitable quality with sulphuric acid, and thoroughly wash and dry the same, which wholly removes the acid. The sheets require drying before the application of the copper solution, as the water if left in the sheets, would dilute the solution and prevent its action in the de sired degree as a solvent. Sheets of the vegetable parchment, in suitable number to form a mass of the required thickness, are then treated with the ammoniaeal solution of cupric oxide for a suitable length of time to dissolve their surfaces, say half a minute, and are then pressed together with a very moderate pressure, sufficient to bring the surfaces uniformly into contact. The surfaces of the separate sheets are rendered so adhesive by this solution that the mass becomes completely consolidated in. four or five minutes, and the product may then be dried in the atmosphere, which for sheets under half an inch in thickness can be accomplish ed in from one to three days.
To form objects of irregular shape, I employ parchment paper or the waste pieces of the sheets made as above reduced to small grains, and immerse them in the ammoniacal solution for a suitable length of time, and then press the same into a mold of the required form. In any case, the greater part of the solution is expressed from the mass of parchmentized material, and may be preserved and used over and over if its strength he maintained by the addition of ammonia as. g It will be understood that it is essential to dry the material, whatever its form, after it is parchmentized, before it is subjected to the solution for cementing the material together.
In the annexed drawings, I have illustrated the means for pressing fiat sheets together to form a thick layer, and have shown the'means for preserving the ammoniacal solution, for preventing the dissipation of the ammonia from such solution, and for protecting the operator from the ammonia vapor.
Inthe annexed drawings, Figurel is a of the apparatus with the exhaust hood removed, and Fig. 2 is an elevation of the same with the parts in section, where hatched, on line m, w, in Fig. 1. Fig. 3 showsinasectional View like Fig. 2, the apparatus for producing molded objects; and Fig. 4 is a plan of the receptacle and lower die.
I will refer first to Figs. 1 and 2, showing the apparatus for forming thick layers of parchmentized material. In these figures a is an india-rubber tank or receptacle adapted to receive the sheets when ready for pressure, the opposite sides of the tank being fitted to a bed I) and a platen c actuated by handscrew 01. Such a tank forms a yielding receptacle, whose Walls may be pressed upon the parchmentized material, and also serves to prevent the loss of the solution. The bottom of the tank is connected by a tube cwith the bottom of an iron receiver f, which is provided with a vertical plunger 9. The receiver and its plunger are made sufficiently tight to prevent the escape of the ammonia, and a pipe h with .cock h is also connected with the bottom of the receiver to supply ammonia gas, to strengthen the solution when desired. A pipe is may be used to fill the receiver when the plunger is raised, and the solution is forced into the tank by depressing theplunger. The parchmentized sheets are then immersed in the tank and when their surfaces are suitably softened the plunger is raised to withdraw the solution; and the opposite sides then pressed'together by rotatingthe screw 01. The pressure, which is only intended to bring the surfaces of the sheets into uniform contact, is sufficient to expel the greater part of the ammoniacal solution, which passes from the tube e into the receiver In removing the solution from the tank a, the cock h in the pipe his closed, and a cock 6 in the tube e is opened,and the solution is drawn into the receiver by lifting the plunger g to a suitable degree. 15y closing the cock e and opening the cock in the pipe h, ammonia gas under pressure may be admitted to the receiver beneath the plunger, which operates to maintain the strength of the so lution in the receiver until the same is required for subsequent use. A pipe is with cock Z is provided to supply or draw off the solution when required The hood j is provided over the tank a to collect the ammonia fumes, and an exhaust pipe m is connected with the hood to draw off the fumes and thus prevent the fumes from affecting the operator after the parchment is placed in the tank.
In making objects or masses of irregular form, suitable dies would be used,- and surrounded by a suitable receptacle to collect the solution and discharge it to a receiver as already described. y
In Fig. 3, the receptacle a is made rigid and dies m, n are shown within the same to form a spherical object, as a billiard ball. The lower die 72 may be filled with a suitable volume of the softened vegetable parchment, and the upper die m would be pressed upon the same in any ordinary press; which is not shown in the drawings, as the operation of such presses is already well known. In such an apparatus the vegetable parchment may be softened by admitting a supply of the cupric ammonia to the receptacle, as described in connection with Fig. 2, or the parchment may be suitably softened by the solvent before it is applied to the dies within the receptacle. In either case, the solution expressed from the material within the dies would overflow within the receptacle and may be discharged through the tube e into any suitable receiver.
The apparatus, like that shown in Fig. 2, is provided with an exhaust hood j, to draw the fumes away from the operator. With the use of such apparatus, the operator is protected from the ammonia fumes, and the ammoniacal solution is collected and its strength maintained, so that it can be repeatedly used.
To facilitate the formation of thick masses and the rapid drying of the same, single sheets may be first made into layers one quarter of an inch in thickness and then dried and when the water and ammonia are thoroughly evaporated from such layers, several of the layers may be cemented together by softening their surfaces with the ammonia copper solution.
The layers when pressed together adhere with the same readiness as single sheets, and the solvent is absorbed in the whole mass in such a manner that it is easily evaporated, being very small in amount, owing to the small number of joints.
My process is distinguished from others by its performance in three distinct steps, and by the use of two distinct agents, the material being first treated with a cheap solvent to parchmentize the fiber; second, washed and dried, and third, cemented together by the use of an ammoniacal solution. The division of the process into three steps greatly facilitates the complete removal of the sulphuric acid or other parchmentizing agent by which the fiber is primarily treated. The use of an ammoniacal solution in the final step of the process greatly facilitates the final drying of the product,,and secures the entire absence of all injurious ingredients within the mass.
Mechanical means are already well known for forming tubes and sheets of thick material of parchmentized fiber, and I do not therefore claim any such means but only the means described herein for collecting and preserving the ammoniacal solution when pressing the fiber together.
No process has been heretofore known for forming a plastic mass or compound which could be molded into objects of homogeneous vegetable parchment,and no means has therefore been known of utilizing the scraps of vegetable parchment which are formed by cutting sheets of such material into various articles. By my process, such scraps when reduced into small particles may be exter-. nally softened and reunited by pressure into ahomogeneous mass, and many articles which are nowmade by cutting up sheets with great waste may thus be molded directly into form. The scraps which are unavoidably produced in making certain articles can also be utilized in the production of other articles. vention, both in the operation of the successive steps, and by the nature of the product, is therefore clearly distinguished from the means heretofore known, which merely produce alayer of material in a single step or operation.
Having thus set forth the nature of my invention, what I claim herein is 1. The process for making a mass of vegetable parchment, which consists in first parchmentizing the vegetable fiber by a suitable agent, second, washing such agent from the vvegetable fiber and drying the same, and
third, cementing the parch mentized fiber into a mass by means of an ammoniacalsolution of cupric oxide or its equivalent, as set forth.
2. The process for making vegetable parchment fabric, which consists in first parchmentizing sheets of vegetable fiber with sulphuric acid, washing the acid from such sheets, drying the same, dissolving the surfaces of the sheets by an ammoniacal solution of cupric oxide and pressing the sheets together, substantially as set forth.
In testimony whereof I have hereunto set my hand in the presence of two subscribing witnesses.
JOHN W. HYATT.
Witnesses:
THOMAS S. CRANE, HENRY J. MILLER.
My inv
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US511891A true US511891A (en) | 1894-01-02 |
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US511891D Expired - Lifetime US511891A (en) | Process of making vegetable-parchment fabrics |
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