US502791A - Apparatus for the manufacture of gas - Google Patents

Apparatus for the manufacture of gas Download PDF

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US502791A
US502791A US502791DA US502791A US 502791 A US502791 A US 502791A US 502791D A US502791D A US 502791DA US 502791 A US502791 A US 502791A
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steam
pipe
oil
generator
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/46Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using discontinuously preheated non-moving solid materials, e.g. blast and run
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils

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  • My invention relates to certain new and useful improvements in apparatus for the manufacture of gas for illuminating and heating purposes; and more particularly to the manufacture of gas from oil and steam.
  • the practice of my invention involves an alternating process, such as'that described in the United States Patent No. 454,531, of June 23, 1891, granted to me as the assignee of Charles Stilwell, and wherein the interior of the gas-generating chamber and its contents of refractory material are first brought to a high degree' of incandescence by the active combustion therein of a steam-injected oil blast, and the heat thus absorbed or stored up within the furnace is employed, in the ⁇ second stage of the operation, after combustion has ceased, in generating gas from a like steam -injected blast; the heating up stageand the gas-generating stage of the operation alternating during the furnace run.
  • My present invention involves v improvements in the apparatus employed for carrying out this alternating process.
  • Figure l represents a cross-section al view of a gas-generating furnace, embodying my invention, to- ⁇ gether withits'accessory scrubberand exhauster,so1ne of' the parts being shown in elevation.
  • Fig. 2 represents a front elevation of the :gas-generating furnace.
  • Fig. 3 represents a longitudinal section and partial elevation of the same; and
  • Fig. 4 represents, in longitudinal section, and on a larger scale, the construction i of the preferred form of burner or injector usedin connection with my invention..
  • 5 indicates the brick lining or masonry work of a gas generchamber formed by the arch 8,-and accessible by means of the closing plate 9.
  • a body of refractory checker-Work fire-brick 10 piled up as shown so as to present alarge heating surface.
  • VAt its extreme end the basal chamber commu ⁇ nicates with the proximate ends of a set of horicommunicates with the ends of a similar set of horizontal multiple flues, discharging into a like cross-nue 12.
  • Additional superposed sets of horizontal multiple nues having connecting cross-flues 13, 14, are likewise arranged within the generator, the several superposed sets of multiple nues being thus connected in zig-zag order back and forth across the generator.
  • the ooring or horizontal partitions between the sets of dues are made up of single courses of ⁇ ire-brick, laid upon their at faces, and that the dividing walls between the members of each sets of iues are made up of single courses of fire-brick set'edge-wise and spaced apart so as to form the nues.
  • These iues 15 are surmounted by an arch 16, and the partitions between the said flues present a largely increased extent of heating surface to that of any one of the sets of horizontal multiple lines 17 below them. They are located at lthepoint where the products of combustion leave the generator, and, by reason of the large extent of heating surface referred to,theyabso ⁇ rb and retain a very large amount of heat,while at the same time not materially interfering i ator, mounted upon a suitable foundation 6, and provided with a gas-tight metallic casing 17.
  • the casing 7 is provided with a removable plate 18, upon whose removal, the fines may be made accessible for repairs, by breaking down and removing a part of the masonry at the front of the generator.
  • the flues 15 discharge into a cross-due 19 from which projects a stack 20, for discharging the products of combustion into the atmosphere, said stack being provided with a weighted valve 2l having a pivoted lever 22 and operating rod 23, whereby7 the stack may be closed gas-tight during the gas-making stage of the operation.
  • a gas exit pipe 24 also communicates with the said cross-flue 19.
  • the gas-exit pipe 24 enters a suitable scrubber, as 27 and dips below the water-level therein as shown, said water level being kept constant by a seal 28.
  • the gas on its way to the pipe 29 leading to the holder is broken up by the grid-like structure 30, made up of wooden bars laid in alternate courses opposite in direction and spaced apart as shown.
  • a perforated spray pipe 31 distributes a shower or spray of water upon the structure 30 and the gases rising through it, and eifects the condensation and removal of condensible and sooty particles from the gas.
  • the injector consists of a steam jet 34 supplied from a steam pipe 35, said steam jet having its discharge orifice located above an oil supply pipe 36 so as to draw oil up from said pipe and project it into the oil and steam mixing pipe 37.
  • the pipe 37 is surrounded by a concentric pipe 40 supplied with air, preferably preheated by means of the pipe 4l. Vith a given steam pressure, this injector burner can be set to supply a flame of the desired caloritic power.
  • the steam supply may be derived from any suitable generator and is supplied through a pipe 42 which is provided with a continuation 43 embedded in the masonry of the generator above the arch of the basal chamber 33; so that the steam in passing through the pipe extension 43 Will be heated to a high temperature, but without 43 being brought'into contact with the products of combustion so as to be oxidized thereby.
  • a branch pipe 44 from the steam supply pipe connects with the depending pipes 35 leading to theinjector burners, and a pipe 45 supplies crude petroleum or other liquid hydrocarbon of a like character to the oil inlet pipe of theinjectorburner.
  • suitable valves are provided for controlling, regulating or entirely cutting off the fiow ot' steam or oil through the several pipes, according to the necessities of the case.
  • the operation of the invention is as follows: The stack valve being opened, a small fire 1s started in the combustion chamber 33 by means ot ⁇ Waste or other material, Steam is then admitted through the inlet pipe 42, su per-heater 43, branch 44 and depending pipes 35, into the injector burners. The steam draws in oil from the oil supply pipes of the injector burners, and together with said oil issues through the opening in front of the jet nozzle, and finally issues into the combustion chamber, drawing in with ita quantity of air through the surrounding air pipe. . The mingled jet of steam, oil and air becomes ignited and produces a ame of intense heat. T he supply of air, may, if desired, be further 1ncreased by opening the door of the combustion chamber to a greateror less extent.
  • the flame from the injector burners strikes the mass of checker-work fire-brick within the combustion chamber and rapidly brings it to a high state of incandescence, generally ap- IOO proximatiuga cherry-red heat, and sometimes exceeding that degree, according to the particular character of the hydrocarbon employed.
  • the products of combustion pass from the combustion chamber in azig-zag direction through the super-posed sets of multiple lues 17 and in their passage through said zig-zag sets of multiple lues, they give up to the walls thereof a great quantity of heat; the products of combustion then pass through the single set of super-heater lues 15 imparting to the more extended surface of the latter practically all of their remaining available heat, and finally passing out through the stack into the atmosphere.
  • the apparatus' is heated upas before, preliminary to a succeeding gas-making run.
  • the apparatus is thus used alternately 1n preparing for the making of gas, and in the actual making and storing of the gas.
  • a gas generator provided at its base with a combustion chamber, having a filling of refractory material; a series of superposed sets of multiple horizontal fines the flooring between each setbeing made up of single courses of fire-brick, and the side walls of the fines being made up of single courses of fire-brick arranged between the floorings and spaced apart to form the iiues; cross-fines at alternately opposite ends of the multiple horizontal flues thereby connecting the sets in zigzag order; a super-heater composed of a set of multiple iiues separated from each other by fire-brick walls of varying heights, surmounted by an arch; and oil and steam supply pipes entering the combustion chamber; substantially as described.
  • steam pipe having a portion of its length embedded'in the generator above said arch, so as to be subjected to heat therefrom but protected from the products of combustion, and having a branch extending along in front of the generator and depending pipesfrom said branch; oil injector burners entering the combustion chamber and supplied with steam by the depending pipes; an oil pipe for supplying oil to said injector burners; superposed sets of multiple iues communicating with the combustion 'chamber and connected in zig-zag order; and a superheater composed of a set of multiple fines having fine-walls of varying height, surmounted by an arch; substantially as described.
  • a gas generator comprising a basal combustion chamber surmounted by an arch and containing refractory material; a superposed series of sets of multiple iiues said setsbeing connected in zig-zag order above said arch; a superheater composed of multiple iiues of varyingheights surmounted by an arch, and a metallic casing surrounding and inclosing the generator body, substantially as described.
  • a xing chamber con sisting of sets of multiple horizontal iues arranged above each other in zig-zag order, and a superposed set of iiues of varying heights supported by the lower tlues, and surmounted by an arch; substantially as described.
  • a fixing chamber consisting of sets of multiple horizontal iiues arranged above each other in zig-zag order andy communicating by means of single cross-fines, and a superposed set of tlues of varying heights supported by the lower fines, and surmounted. by an arch; substantially as described. .Y

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Incineration Of Waste (AREA)

Description

(No. Model.) 2 Sheets-Sheet ,1.
S. W. VAN SYCKEL.
y APPARATUS PoR THE MANUPAGTURB 0F GAS.
(No Moden.) 2 sheetsfsheef 2.
s. W. VAN 'SYGKEL APPARATUS FOR- THB MANUFAGTURE 0F GAS.
'UNITED STATES PATENT OFFICE.
STEPHEN W. VAN SYOKEL, OF HOPEWELL, vNEW JERSEY.
APPARATUS FOR THE MANUFACTURE OF GAS.
SPECIFICATION forming part of LettersPatent No.V 52,'791, dated August 8, 1893.
Application iiled February 11, 1892. Renewed January 11. 1893. Serial No. 458,024. (No model.)
To a/ZZ whom it may concern:
Be it known that I, STEPHEN W. VAN SYCKEL, a citizen of the United States, residing at Hopewell, in the county of` Mercer and State of New Jersey, have invented certain new and useful Improvements in Apparatus for theManufacture of Gas; and I do hereby declare the .following to be' a full, clear, and exact description of the invention, such as will enable others skilledl in the art to which V zontal multiple flues located side by side, and discharging into a cross-flue 11 which in turnV it appertains to make and use the same.
My invention relates to certain new and useful improvements in apparatus for the manufacture of gas for illuminating and heating purposes; and more particularly to the manufacture of gas from oil and steam.
The practice of my invention involves an alternating process, such as'that described in the United States Patent No. 454,531, of June 23, 1891, granted to me as the assignee of Charles Stilwell, and wherein the interior of the gas-generating chamber and its contents of refractory material are first brought to a high degree' of incandescence by the active combustion therein of a steam-injected oil blast, and the heat thus absorbed or stored up within the furnace is employed, in the` second stage of the operation, after combustion has ceased, in generating gas from a like steam -injected blast; the heating up stageand the gas-generating stage of the operation alternating during the furnace run.
My present invention involves v improvements in the apparatus employed for carrying out this alternating process.
In the accompanying drawings, Figure l represents a cross-section al view of a gas-generating furnace, embodying my invention, to-` gether withits'accessory scrubberand exhauster,so1ne of' the parts being shown in elevation. Fig. 2 represents a front elevation of the :gas-generating furnace.l Fig. 3 represents a longitudinal section and partial elevation of the same; and Fig. 4 represents, in longitudinal section, and on a larger scale, the construction i of the preferred form of burner or injector usedin connection with my invention..
Similar numerals of reference indicate similar parts throughout the several views.
' Referring to the drawings, 5 indicates the brick lining or masonry work of a gas generchamber formed by the arch 8,-and accessible by means of the closing plate 9. Within this basal chamber is contained a body of refractory checker-Work fire-brick 10, piled up as shown so as to present alarge heating surface. VAt its extreme end the basal chamber commu` nicates with the proximate ends of a set of horicommunicates with the ends of a similar set of horizontal multiple flues, discharging into a like cross-nue 12. Additional superposed sets of horizontal multiple nues having connecting cross-flues 13, 14, are likewise arranged within the generator, the several superposed sets of multiple nues being thus connected in zig-zag order back and forth across the generator. It- Will be noted that the ooring or horizontal partitions between the sets of dues are made up of single courses of {ire-brick, laid upon their at faces, and that the dividing walls between the members of each sets of iues are made up of single courses of fire-brick set'edge-wise and spaced apart so as to form the nues. In" this manner,I am enabled to provide iues of the desired uniformity and regularity, the work of construction ybeing of great simplicity, and .involving a minimum amount of skill and labor on the part of the workmen employed to build up or repair the flues. At the same time, the multiple lines expose a large heating surface to the passage of .the gases and products of combustion passingthrough them in the operation of the invention.
At the upper part f the furnace, I conistruct a super-heater consisting of a series of flues connected with the cross-'flue 14, and of varying heights. These iues 15 are surmounted by an arch 16, and the partitions between the said flues present a largely increased extent of heating surface to that of any one of the sets of horizontal multiple lines 17 below them. They are located at lthepoint where the products of combustion leave the generator, and, by reason of the large extent of heating surface referred to,theyabso`rb and retain a very large amount of heat,while at the same time not materially interfering i ator, mounted upon a suitable foundation 6, and provided with a gas-tight metallic casing 17. At the bottom of the generator, is abasal IOO with the draft of the generator, as would be the case if the smaller dues below were continued in zig-zag order to the full height of the generator. The dividing walls, moreover, serve as an additional means of support to the arch 16, and thereby add strength and stability to the general structure.
The casing 7 is provided with a removable plate 18, upon whose removal, the fines may be made accessible for repairs, by breaking down and removing a part of the masonry at the front of the generator. The flues 15 discharge into a cross-due 19 from which projects a stack 20, for discharging the products of combustion into the atmosphere, said stack being provided with a weighted valve 2l having a pivoted lever 22 and operating rod 23, whereby7 the stack may be closed gas-tight during the gas-making stage of the operation. A gas exit pipe 24 also communicates with the said cross-flue 19. The gas-exit pipe 24 enters a suitable scrubber, as 27 and dips below the water-level therein as shown, said water level being kept constant by a seal 28. In the form of scrubber illustrated in the drawings the gas on its way to the pipe 29 leading to the holder, is broken up by the grid-like structure 30, made up of wooden bars laid in alternate courses opposite in direction and spaced apart as shown. A perforated spray pipe 31 distributes a shower or spray of water upon the structure 30 and the gases rising through it, and eifects the condensation and removal of condensible and sooty particles from the gas. To establish and maintain a proper exhaust during the gas making stage of the operation, I employ a steam jet 32 within the pipe 29 and located in front of a contraction in said pipe.
l/Vithin the basal chamber or combustion chamber 33, I insert the discharge ends of two injector burners, preferably of the type illustrated in Fig. 4. I do not confine myself to the specific form of injector burner shown, as I may employ a different arrangement of oil and steam injector than that illustrated. I prefer, however, the employment of the particular injector referred to, as I have secured the best results when employing the same. The injector consists of a steam jet 34 supplied from a steam pipe 35, said steam jet having its discharge orifice located above an oil supply pipe 36 so as to draw oil up from said pipe and project it into the oil and steam mixing pipe 37. The pipe 37 is surrounded by a concentric pipe 40 supplied with air, preferably preheated by means of the pipe 4l. Vith a given steam pressure, this injector burner can be set to supply a flame of the desired caloritic power.
The steam supply may be derived from any suitable generator and is supplied through a pipe 42 which is provided with a continuation 43 embedded in the masonry of the generator above the arch of the basal chamber 33; so that the steam in passing through the pipe extension 43 Will be heated to a high temperature, but without 43 being brought'into contact with the products of combustion so as to be oxidized thereby. A branch pipe 44 from the steam supply pipe connects with the depending pipes 35 leading to theinjector burners, and a pipe 45 supplies crude petroleum or other liquid hydrocarbon of a like character to the oil inlet pipe of theinjectorburner. It will be noted that suitable valves are provided for controlling, regulating or entirely cutting off the fiow ot' steam or oil through the several pipes, according to the necessities of the case.
The operation of the invention is as follows: The stack valve being opened, a small fire 1s started in the combustion chamber 33 by means ot` Waste or other material, Steam is then admitted through the inlet pipe 42, su per-heater 43, branch 44 and depending pipes 35, into the injector burners. The steam draws in oil from the oil supply pipes of the injector burners, and together with said oil issues through the opening in front of the jet nozzle, and finally issues into the combustion chamber, drawing in with ita quantity of air through the surrounding air pipe. .The mingled jet of steam, oil and air becomes ignited and produces a ame of intense heat. T he supply of air, may, if desired, be further 1ncreased by opening the door of the combustion chamber to a greateror less extent. The flame from the injector burners strikes the mass of checker-work lire-brick within the combustion chamber and rapidly brings it to a high state of incandescence, generally ap- IOO proximatiuga cherry-red heat, and sometimes exceeding that degree, according to the particular character of the hydrocarbon employed. The products of combustion pass from the combustion chamber in azig-zag direction through the super-posed sets of multiple lues 17 and in their passage through said zig-zag sets of multiple lues, they give up to the walls thereof a great quantity of heat; the products of combustion then pass through the single set of super-heater lues 15 imparting to the more extended surface of the latter practically all of their remaining available heat, and finally passing out through the stack into the atmosphere. When the apparatus is brought to the requisite degree of heat for decomposing steam and oil and recombining their constituent elements into permanent fixed gases, the supply of steam, oil and air is temporarily cut ed from the combustion chamber, thereby extinguishing the tire therein. The door to the combustion chamber and the stack-valve are also closed, and thereupon steam and oil, but not air, is admitted through the injectors into the combustion chamber. The jets of steam and oil thus admitted strike the highly heated refractory material in the combustion chambers and are decomposed thereby into gases which pass through the iues 17 and l5, and the exhauster is put in operation. The gas thereupon passes to the scrubber and thence into the gas holder. The gas on its passage through the iiues 15 and 17, becomes fixed and combined into permanent gas of high candle power. At the conclusion of the gasmaking run, which generally lasts from about twenty to twenty-five minutes, under normal conditions, the apparatus'is heated upas before, preliminary to a succeeding gas-making run. The apparatus is thus used alternately 1n preparing for the making of gas, and in the actual making and storing of the gas.
Having thus described my invention, what I claim is- 1. A gas generator, provided at its base with a combustion chamber having a filling of refractory material; a series of superposed sets of horizontal multiple iues communicating with the combustion chambers, the members of each set being arranged side by side, and opening at their ends into a cross iiue which in turn communicates with the proximate ends of the next succeeding set; a superheater composed of a set of multiple fines having line-walls of varying heights, surmounted by an arch; and oil and steam supply pipes entering thecombustion chamber; substantially as described.
2. A gas generator, provided at its base with a combustion chamber, having a filling of refractory material; a series of superposed sets of multiple horizontal fines the flooring between each setbeing made up of single courses of fire-brick, and the side walls of the fines being made up of single courses of fire-brick arranged between the floorings and spaced apart to form the iiues; cross-fines at alternately opposite ends of the multiple horizontal flues thereby connecting the sets in zigzag order; a super-heater composed of a set of multiple iiues separated from each other by fire-brick walls of varying heights, surmounted by an arch; and oil and steam supply pipes entering the combustion chamber; substantially as described.
3. A gas generator, provided at its base with a combustion chamber surmounted by an arch and having a filling of refractory material; a
steam pipe, having a portion of its length embedded'in the generator above said arch, so as to be subjected to heat therefrom but protected from the products of combustion, and having a branch extending along in front of the generator and depending pipesfrom said branch; oil injector burners entering the combustion chamber and supplied with steam by the depending pipes; an oil pipe for supplying oil to said injector burners; superposed sets of multiple iues communicating with the combustion 'chamber and connected in zig-zag order; and a superheater composed of a set of multiple fines having fine-walls of varying height, surmounted by an arch; substantially as described.
4. A gas generator comprising a basal combustion chamber surmounted by an arch and containing refractory material; a superposed series of sets of multiple iiues said setsbeing connected in zig-zag order above said arch; a superheater composed of multiple iiues of varyingheights surmounted by an arch, and a metallic casing surrounding and inclosing the generator body, substantially as described.
5. In a gas generator, a xing chamber con sisting of sets of multiple horizontal iues arranged above each other in zig-zag order, and a superposed set of iiues of varying heights supported by the lower tlues, and surmounted by an arch; substantially as described.
6. In a gas generator, a fixing chamber consisting of sets of multiple horizontal iiues arranged above each other in zig-zag order andy communicating by means of single cross-fines, and a superposed set of tlues of varying heights supported by the lower fines, and surmounted. by an arch; substantially as described. .Y
In testimony whereof I affix my signature in presence of two witnesses.
' STEPHEN W. VAN SYCKEL.
Witnesses:
F. O. LowTHoRP, SAMUEL D. OLIPHANT, Jr.
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