US4997881A - Poly(alkyl vinyl ether)polyolefin copolymers - Google Patents

Poly(alkyl vinyl ether)polyolefin copolymers Download PDF

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Publication number
US4997881A
US4997881A US07/418,366 US41836689A US4997881A US 4997881 A US4997881 A US 4997881A US 41836689 A US41836689 A US 41836689A US 4997881 A US4997881 A US 4997881A
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poly
vinyl ether
alkyl vinyl
polyolefin
blend
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US07/418,366
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Niranjan Patel
Judy S. Riffle
James E. McGrath
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Virginia Tech Intellectual Properties Inc
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Assigned to VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY reassignment VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: RIFFLE, JUDY S., VERMA, AKHILKUMAR
Assigned to VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY reassignment VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: MC GRATH, JAMES E., PATEL, NIRANJAN, RIFFLE, JUDY S.
Assigned to VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY reassignment VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: GUNGOR, ATTILA, MC GRATH, JAMES E.
Assigned to VIRGINIA TECH INTELLECTUAL PROPERTIES, INC., A NONPROFIT CORP. OF VA reassignment VIRGINIA TECH INTELLECTUAL PROPERTIES, INC., A NONPROFIT CORP. OF VA ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene

Definitions

  • polyolefins e.g., polypropylene, polyethylene
  • the instant invention relates to novel poly(alkyl vinyl ether)/polyolefin copolymers and reactive processing of blends of a poly(alkyl vinyl ether) and polyolefin to form them.
  • FIG. 1a and 1b are melting point depression plots of polypropylene and blends of polypropylene and poly(methyl vinyl ether);
  • FIG. 2 is another melting point depression plot analogous to those of FIG. 1a and FIG. 1b and
  • FIG. 3 is a plot of the isothermal crystallization rates for polypropylene and certain polypropylene/poly(ethyl vinyl ether) blends processed under differing conditions.
  • a blend of a poly(alkyl vinyl ether) and a polyolefin e.g., polypropylene
  • a polyolefin e.g., polypropylene
  • a minor amount e.g., from about 0.5% to about 49%, by weight of the entire blend
  • a polypropylene for example, in this manner, the resulting blend becomes compatible.
  • Such a blend can find a variety of uses as will be described in greater detail below.
  • the poly(alkyl vinyl ether) component to which the instant invention pertains includes those having the repeating unit ##STR1## where R is lower straight or branched chain alkyl, such as methyl, ethyl, propyl, butyl, and the like or branched structures thereof (isopropyl, isobutyl, and the like).
  • Polyolefins which can be used herein include polypropylene.
  • the reactive processing involves heat blending the two aforesaid polymers at a sufficiently high temperature (e.g., about 210° C. or greater) with or without a free radical catalyst below their thermal decomposition point for a sufficient length of time (e.g., about fifteen minutes or greater) to achieve copolymerization between the poly(alkyl vinyl ether) and polyolefin.
  • a sufficiently high temperature e.g., about 210° C. or greater
  • a free radical catalyst below their thermal decomposition point for a sufficient length of time (e.g., about fifteen minutes or greater) to achieve copolymerization between the poly(alkyl vinyl ether) and polyolefin.
  • Isotactic polypropylene (90 parts by weight) was blended with 10 weight percent poly(methyl vinyl ether) in a an air atmosphere at 200° C. for fifteen minutes. Differential scanning calorimetry showed that the melting point of the resulting blend was substantially identical (within experimental error) to the melting point of the isotactic polypropylene homopolymer indicating that the blend was immiscible.
  • the blend prepared in an air atmosphere at 200° C. for fifteen minutes showed a faster crystallization rate than polypropylene homopolymer indicating that a second immiscible phase existed at the crystallization temperature (130° C.).
  • the polymer blend prepared in air atmosphere at 210° C. for thirty minutes showed a slower crystallization rate (upper portion of FIG.
  • the hydrophilic/lipophilic balance of the resulting material can be controlled by adjustment of the relative proportions of each which are combined and treated.
  • Enhanced adhesive properties of the polyolefin to hydrophilic substrates can be imparted in this manner.
  • the blend in accordance with the instant invention also functions as a compatibilizer so that other hydrophilic components or particles (e.g., dye molecules or hydrophilic filler materials) can be well dispersed in the otherwise hydrophobic polyolefin matrix.
  • hydrophilic components or particles e.g., dye molecules or hydrophilic filler materials
  • Water vapor permeability can also be controlled for the blend. This can allow for control of water vapor permeability through various materials and can have importance for applications such as disposable outer layers for diapers where water permeability for a non-porous polyolefin is highly desirable.
  • An alternative embodiment of the invention involves preparation of block or graft copolymers comprised of the poly(alkyl vinyl ether) with another polymer structure in the copolymer.
  • a poly(alkyl vinyl ether)/polyoxazoline block or graft copolymer or a poly(alkyl vinyl ether)/poly(alkyl methacrylate) block or graft copolymer might be formed initially with the subsequent grafting of this onto the polyolefin through the poly(alkyl vinyl ether) component and the reactive processing step described herein.
  • This composition can then be blended with other homopolymers compatible with the polyoxazoline or poly(alkyl methacrylate) components, for example.
  • this method provides a route to compatibilization of a wider range of polymeric materials with polyolefins.
  • Another important feature of the present grafting reaction of the poly(alkyl vinyl ether) onto the polyolefin (e.g., polypropylene) is that a significant level of ketone groups are formed in the reaction processing step which render the resulting modified polyolefin composition photodegradable.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A blend of a polyolefin and a poly(alkyl vinyl ether) can be blended at elevated temperature to form a copolymer of the polyolefin and poly(alkyl vinyl ether). The resulting composition is useful as a compatibilizer, as a more water permeable substrate than the polyolefin, and as a photo-degradable material.

Description

BACKGROUND OF THE INVENTION
Blends of poly(alkyl vinyl ethers) with various polymers, e.g., polystyrene, have been reported J. Hu et al., for example, in Polymer Preprints 29(1), June 1988, pp. 321-322 reported that poly(methyl vinyl ether) was miscible with such polymers as polystyrene, poly(vinyl phenol), phenoxy polymers, and poly(ethylene-co-methacrylic acid) but was immiscible with amorphous polyurethane. Apparently blends of poly(alkyl vinyl ethers) with polyolefins (e.g., polypropylene, polyethylene) have not been reported nor has reactive processing of such blends been performed.
SUMMARY OF THE INVENTION
The instant invention relates to novel poly(alkyl vinyl ether)/polyolefin copolymers and reactive processing of blends of a poly(alkyl vinyl ether) and polyolefin to form them.
DESCRIPTION OF THE DRAWING
The Drawings form a portion of the instant application wherein:
FIG. 1a and 1b are melting point depression plots of polypropylene and blends of polypropylene and poly(methyl vinyl ether);
FIG. 2 is another melting point depression plot analogous to those of FIG. 1a and FIG. 1b and
FIG. 3 is a plot of the isothermal crystallization rates for polypropylene and certain polypropylene/poly(ethyl vinyl ether) blends processed under differing conditions.
DESCRIPTION OF THE INVENTION
It has been found that a blend of a poly(alkyl vinyl ether) and a polyolefin (e.g., polypropylene), which is normally immiscible, can be reactively processed at elevated temperature to form copolymers of the poly(alkyl vinyl ether) and the polyolefin. When a minor amount (e.g., from about 0.5% to about 49%, by weight of the entire blend) of the poly(alkyl vinyl ether) is reacted with a polypropylene, for example, in this manner, the resulting blend becomes compatible. Such a blend can find a variety of uses as will be described in greater detail below.
The poly(alkyl vinyl ether) component to which the instant invention pertains includes those having the repeating unit ##STR1## where R is lower straight or branched chain alkyl, such as methyl, ethyl, propyl, butyl, and the like or branched structures thereof (isopropyl, isobutyl, and the like).
Polyolefins which can be used herein include polypropylene.
The reactive processing involves heat blending the two aforesaid polymers at a sufficiently high temperature (e.g., about 210° C. or greater) with or without a free radical catalyst below their thermal decomposition point for a sufficient length of time (e.g., about fifteen minutes or greater) to achieve copolymerization between the poly(alkyl vinyl ether) and polyolefin.
The invention is further understood by reference to the Examples which follow.
COMPARATIVE EXAMPLE 1
Isotactic polypropylene (90 parts by weight) was blended with 10 weight percent poly(methyl vinyl ether) in a an air atmosphere at 200° C. for fifteen minutes. Differential scanning calorimetry showed that the melting point of the resulting blend was substantially identical (within experimental error) to the melting point of the isotactic polypropylene homopolymer indicating that the blend was immiscible.
EXAMPLE 2
This Example repeated the blending procedure of Comparative Example 1 at a temperature of 210° C. for a period of thirty minutes. Differential scanning calorimetry indicated that the melting point of the blend was depressed approximately 5° C. thereby indicating that the two polymers had reacted under the blending conditions to form a graft copolymer.
The results of Comparative Example 1 and Example 2 are shown in FIGS. 1aand 1b.
EXAMPLE 3
The immiscible blend produced in Comparative Example 1 was heat treated at 210° C. for fifteen minutes. Differential scanning calorimetry showed a melting point depression of approximately 6° C. from the original melting point of the polypropylene. FIG. 2 shows these results along with a second run in accordance with Example 2.
EXAMPLE 4
The isothermal crystallization rates of polypropylene homopolymer as compared to the ungrafted, immiscible blend of Comparative Example 1 and the grafted, at least partially miscible blend of Example 2, was monitored at several temperatures as shown in FIG. 3. The blend prepared in an air atmosphere at 200° C. for fifteen minutes (the lower portion of FIG. 3) showed a faster crystallization rate than polypropylene homopolymer indicating that a second immiscible phase existed at the crystallization temperature (130° C.). By contrast, the polymer blend prepared in air atmosphere at 210° C. for thirty minutes showed a slower crystallization rate (upper portion of FIG. 3) indicating that nucleation by a second phase was not significant in such a blend and that the growth rate is slowed by the necessity for exclusion of the miscible polypropylene/poly(methyl vinyl ether) component from the blend as the polypropylene crystallizes which is also evidence of some degree of miscibility in this system.
Since the poly(methyl vinyl ether), for example, is hydroscopic and the polypropylene is hydrophobic, the hydrophilic/lipophilic balance of the resulting material can be controlled by adjustment of the relative proportions of each which are combined and treated. Enhanced adhesive properties of the polyolefin to hydrophilic substrates can be imparted in this manner.
The blend in accordance with the instant invention also functions as a compatibilizer so that other hydrophilic components or particles (e.g., dye molecules or hydrophilic filler materials) can be well dispersed in the otherwise hydrophobic polyolefin matrix.
Water vapor permeability can also be controlled for the blend. This can allow for control of water vapor permeability through various materials and can have importance for applications such as disposable outer layers for diapers where water permeability for a non-porous polyolefin is highly desirable.
An alternative embodiment of the invention involves preparation of block or graft copolymers comprised of the poly(alkyl vinyl ether) with another polymer structure in the copolymer. For example, a poly(alkyl vinyl ether)/polyoxazoline block or graft copolymer or a poly(alkyl vinyl ether)/poly(alkyl methacrylate) block or graft copolymer might be formed initially with the subsequent grafting of this onto the polyolefin through the poly(alkyl vinyl ether) component and the reactive processing step described herein. This composition can then be blended with other homopolymers compatible with the polyoxazoline or poly(alkyl methacrylate) components, for example. By varying the structure of the second component in the poly(alkyl vinyl ether) copolymer, this method provides a route to compatibilization of a wider range of polymeric materials with polyolefins.
Another important feature of the present grafting reaction of the poly(alkyl vinyl ether) onto the polyolefin (e.g., polypropylene) is that a significant level of ketone groups are formed in the reaction processing step which render the resulting modified polyolefin composition photodegradable.
The foregoing illustrate certain embodiments of the present invention but should not be considered in a limiting sense. The scope of protection sought is set forth in the claims which follow.

Claims (6)

We claim:
1. A reacted polymer blend of a polyolefin and a poly(alkyl vinyl ether) component which is a block or graft copolymer comprising poly(alkyl vinyl ether and polyoxazoline, said reacted blend being prepared by mixing the polymers at an elevated temperature.
2. A reacted polymer blend as claimed in claim 1 wherein the poly(alkyl vinyl ether) component comprises a minor amount of the copolymer.
3. A reacted polymer blend as claimed in claim 2 wherein the minor amount comprises up to about 49% by weight).
4. A reacted polymer blend as claimed in claim 1 wherein the polyolefin is polypropylene.
5. A reacted polymer blend as claimed in claim 1 wherein the poly(alkyl vinyl ether) is poly(methyl vinyl ether).
6. A process of forming the reacted polymer blend of claim 1 which comprises heat blending the polyolefin and the poly(alkyl vinyl ether).
US07/418,366 1989-10-06 1989-10-06 Poly(alkyl vinyl ether)polyolefin copolymers Expired - Fee Related US4997881A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5250626A (en) * 1990-11-08 1993-10-05 Eastman Kodak Company Miscible blends of polyphosphazenes and acidic functional polymers
US5359006A (en) * 1988-12-30 1994-10-25 Amoco Corporation Poly(vinylalkylether)-containing hot melt adhesives for polyethllene and polypropylene

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3121070A (en) * 1960-05-03 1964-02-11 Eastman Kodak Co Thermally modified polymers of polypropylene and other polymers and process for preparing the same
US3144430A (en) * 1961-10-09 1964-08-11 Minnesota Mining & Mfg Polypropylene film and method of making
US3153680A (en) * 1959-08-03 1964-10-20 Montedison Spa Poly-alpha-olefin compositions having improved dye affinity
US3497574A (en) * 1961-04-04 1970-02-24 Jack J Press Adhesive compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3153680A (en) * 1959-08-03 1964-10-20 Montedison Spa Poly-alpha-olefin compositions having improved dye affinity
US3121070A (en) * 1960-05-03 1964-02-11 Eastman Kodak Co Thermally modified polymers of polypropylene and other polymers and process for preparing the same
US3497574A (en) * 1961-04-04 1970-02-24 Jack J Press Adhesive compositions
US3144430A (en) * 1961-10-09 1964-08-11 Minnesota Mining & Mfg Polypropylene film and method of making

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5359006A (en) * 1988-12-30 1994-10-25 Amoco Corporation Poly(vinylalkylether)-containing hot melt adhesives for polyethllene and polypropylene
US5250626A (en) * 1990-11-08 1993-10-05 Eastman Kodak Company Miscible blends of polyphosphazenes and acidic functional polymers

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