US4794163A - Process for producing a polyarylene sulfide with alkali metal salt of pyridine carboxylic acid catalyst - Google Patents
Process for producing a polyarylene sulfide with alkali metal salt of pyridine carboxylic acid catalyst Download PDFInfo
- Publication number
- US4794163A US4794163A US07/136,593 US13659387A US4794163A US 4794163 A US4794163 A US 4794163A US 13659387 A US13659387 A US 13659387A US 4794163 A US4794163 A US 4794163A
- Authority
- US
- United States
- Prior art keywords
- sodium
- alkali metal
- carboxylic acid
- metal salt
- polyarylene sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/025—Preparatory processes
- C08G75/0254—Preparatory processes using metal sulfides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Pyridine Compounds (AREA)
Abstract
Description
TABLE 1 ______________________________________ Example 1 Example 2 Comp. Ex. 1 ______________________________________ Color tone Light-white Light-white Light-gray of polymer η.sub.i * (Pa.s) 115 85 75 η.sub.c ** (Pa.s) 277 203 610 ______________________________________ *η.sub.i : viscosity of the polymer before heattreating **η.sub.c : viscosity of the polymer after heattreating
TABLE 2 ______________________________________ Heavy metal content (ppm) Fe Cr Ni ______________________________________ Example 5 87 51 22 Comp. Ex. 2 420 140 86 Comp. Ex. 3 390 110 74 ______________________________________
Claims (3)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61-303655 | 1986-12-22 | ||
JP61303655A JPS63156829A (en) | 1986-12-22 | 1986-12-22 | Production of polyarylene sulfide |
Publications (1)
Publication Number | Publication Date |
---|---|
US4794163A true US4794163A (en) | 1988-12-27 |
Family
ID=17923624
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/136,593 Expired - Fee Related US4794163A (en) | 1986-12-22 | 1987-12-22 | Process for producing a polyarylene sulfide with alkali metal salt of pyridine carboxylic acid catalyst |
Country Status (6)
Country | Link |
---|---|
US (1) | US4794163A (en) |
EP (1) | EP0272903B1 (en) |
JP (1) | JPS63156829A (en) |
KR (1) | KR920006367B1 (en) |
CA (1) | CA1281487C (en) |
DE (1) | DE3786653T2 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5015702A (en) * | 1989-10-06 | 1991-05-14 | Phillips Petroleum Company | Treatment of poly(arylene sulfide/sulfone) polymers |
US5037953A (en) * | 1987-12-24 | 1991-08-06 | Tosoh Corporation | Process for producing poly (para-phenylene-sulfide) |
US5235034A (en) * | 1989-11-06 | 1993-08-10 | Phillips Petroleum Company | Treatment of polyarylene sulfide/sulfone polymers with zinc compound and acidic solution |
US5324796A (en) * | 1992-12-02 | 1994-06-28 | General Electric Company | Polyarylene sulfide and epoxy-functionalized siloxane blends |
US5350834A (en) * | 1989-11-06 | 1994-09-27 | Phillips Petroleum Company | Treatment of polyarylene sulfide/sulfone polymers |
US5380821A (en) * | 1992-07-14 | 1995-01-10 | Solvay (Societe Anonyme) | Process for the manufacture of poly(arylene sulphide) |
US5777069A (en) * | 1994-02-07 | 1998-07-07 | Tonen Chemical Corporation | Method of maufacturing a tubular extrusion molding product comprising a high molecular weight polyarylene sulfide |
US5856433A (en) * | 1996-04-16 | 1999-01-05 | Idemitsu Petrochemical Co., Ltd. | Apparatus for manufacturing polyarylene sulfide and process for manufacturing polyarlene sulfide using the apparatus |
EP3868820A1 (en) | 2020-02-20 | 2021-08-25 | SHPP Global Technologies B.V. | Articles and structures with laser breakable and platable compounds |
EP4141058A1 (en) | 2021-08-31 | 2023-03-01 | SHPP Global Technologies B.V. | High dielectric thermoplastic composition with ceramic titanate and the shaped article thereof |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2790217B2 (en) * | 1989-02-09 | 1998-08-27 | ダイセル化学工業株式会社 | Method for producing aromatic polythioether sulfone |
EP0456349A3 (en) * | 1990-04-09 | 1992-12-30 | Tosoh Corporation | Corrosion-resistant material for sulfur-containing alkali metal salts and equipment for producing polyarylene sulfide using the same, and polyarylene sulfide and process for producing the same |
US5280104A (en) * | 1992-06-30 | 1994-01-18 | Phillips Petroleum Company | Process for the preparation of poly(arylene sulfide) with low metal contamination and polymer produced |
JPH11504315A (en) * | 1995-02-21 | 1999-04-20 | ヘ,ジジャン・アレックス | Imidazolidinone derivatives as corrosion inhibitors |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3354129A (en) * | 1963-11-27 | 1967-11-21 | Phillips Petroleum Co | Production of polymers from aromatic compounds |
US3867356A (en) * | 1973-11-19 | 1975-02-18 | Phillips Petroleum Co | Arylene sulfide polymers |
US3919177A (en) * | 1973-11-19 | 1975-11-11 | Phillips Petroleum Co | P-phenylene sulfide polymers |
US4038262A (en) * | 1975-05-27 | 1977-07-26 | Phillips Petroleum Company | Production of arylene sulfide polymers |
US4038261A (en) * | 1975-05-27 | 1977-07-26 | Phillips Petroleum Company | Production of branched arylene sulfide polymers |
US4064114A (en) * | 1975-05-27 | 1977-12-20 | Phillips Petroleum Company | Production of arylene sulfide polymers |
US4116947A (en) * | 1977-04-29 | 1978-09-26 | Phillips Petroleum Company | Branched arylene sulfide polymer production |
US4282347A (en) * | 1979-08-14 | 1981-08-04 | Phillips Petroleum Company | Preparation of branched polymers of arylene sulfide |
US4661584A (en) * | 1984-08-07 | 1987-04-28 | Bayer Aktiengesellschaft | Preparation of polyarylene sulphide in presence of amino carboxylic acid |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4368321A (en) * | 1981-09-01 | 1983-01-11 | Phillips Petroleum Company | Elevated, declining pressure dehydration of poly(arylene sulfide) prepolymerization mixture |
US4393197A (en) * | 1982-02-16 | 1983-07-12 | Phillips Petroleum Company | Arylene sulfide polymer preparation |
-
1986
- 1986-12-22 JP JP61303655A patent/JPS63156829A/en active Pending
-
1987
- 1987-12-21 DE DE87311243T patent/DE3786653T2/en not_active Expired - Fee Related
- 1987-12-21 EP EP87311243A patent/EP0272903B1/en not_active Expired - Lifetime
- 1987-12-21 CA CA000555001A patent/CA1281487C/en not_active Expired - Fee Related
- 1987-12-22 US US07/136,593 patent/US4794163A/en not_active Expired - Fee Related
- 1987-12-22 KR KR1019870014577A patent/KR920006367B1/en not_active IP Right Cessation
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3354129A (en) * | 1963-11-27 | 1967-11-21 | Phillips Petroleum Co | Production of polymers from aromatic compounds |
US3867356A (en) * | 1973-11-19 | 1975-02-18 | Phillips Petroleum Co | Arylene sulfide polymers |
US3919177A (en) * | 1973-11-19 | 1975-11-11 | Phillips Petroleum Co | P-phenylene sulfide polymers |
US4038262A (en) * | 1975-05-27 | 1977-07-26 | Phillips Petroleum Company | Production of arylene sulfide polymers |
US4038261A (en) * | 1975-05-27 | 1977-07-26 | Phillips Petroleum Company | Production of branched arylene sulfide polymers |
US4064114A (en) * | 1975-05-27 | 1977-12-20 | Phillips Petroleum Company | Production of arylene sulfide polymers |
US4116947A (en) * | 1977-04-29 | 1978-09-26 | Phillips Petroleum Company | Branched arylene sulfide polymer production |
US4282347A (en) * | 1979-08-14 | 1981-08-04 | Phillips Petroleum Company | Preparation of branched polymers of arylene sulfide |
US4661584A (en) * | 1984-08-07 | 1987-04-28 | Bayer Aktiengesellschaft | Preparation of polyarylene sulphide in presence of amino carboxylic acid |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5037953A (en) * | 1987-12-24 | 1991-08-06 | Tosoh Corporation | Process for producing poly (para-phenylene-sulfide) |
US5015702A (en) * | 1989-10-06 | 1991-05-14 | Phillips Petroleum Company | Treatment of poly(arylene sulfide/sulfone) polymers |
US5235034A (en) * | 1989-11-06 | 1993-08-10 | Phillips Petroleum Company | Treatment of polyarylene sulfide/sulfone polymers with zinc compound and acidic solution |
US5350834A (en) * | 1989-11-06 | 1994-09-27 | Phillips Petroleum Company | Treatment of polyarylene sulfide/sulfone polymers |
US5380821A (en) * | 1992-07-14 | 1995-01-10 | Solvay (Societe Anonyme) | Process for the manufacture of poly(arylene sulphide) |
US5324796A (en) * | 1992-12-02 | 1994-06-28 | General Electric Company | Polyarylene sulfide and epoxy-functionalized siloxane blends |
US5777069A (en) * | 1994-02-07 | 1998-07-07 | Tonen Chemical Corporation | Method of maufacturing a tubular extrusion molding product comprising a high molecular weight polyarylene sulfide |
US5856433A (en) * | 1996-04-16 | 1999-01-05 | Idemitsu Petrochemical Co., Ltd. | Apparatus for manufacturing polyarylene sulfide and process for manufacturing polyarlene sulfide using the apparatus |
EP3868820A1 (en) | 2020-02-20 | 2021-08-25 | SHPP Global Technologies B.V. | Articles and structures with laser breakable and platable compounds |
WO2021165832A1 (en) | 2020-02-20 | 2021-08-26 | Shpp Global Technologies B.V. | Articles and structures with laser breakable and platable compounds |
EP4141058A1 (en) | 2021-08-31 | 2023-03-01 | SHPP Global Technologies B.V. | High dielectric thermoplastic composition with ceramic titanate and the shaped article thereof |
WO2023031832A1 (en) | 2021-08-31 | 2023-03-09 | Shpp Global Technologies B.V. | High dielectric thermoplastic composition with ceramic titanate and the shaped article thereof |
Also Published As
Publication number | Publication date |
---|---|
EP0272903A2 (en) | 1988-06-29 |
DE3786653T2 (en) | 1993-11-04 |
EP0272903A3 (en) | 1989-04-26 |
EP0272903B1 (en) | 1993-07-21 |
CA1281487C (en) | 1991-03-12 |
KR880007579A (en) | 1988-08-27 |
JPS63156829A (en) | 1988-06-29 |
DE3786653D1 (en) | 1993-08-26 |
KR920006367B1 (en) | 1992-08-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: TOSOH CORPORATION, 4560, OAZA TONDA, SHINNANYO-SHI Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:INOUE, HIROSHI;KATO, TOSHIKAZU;EMURA, NORIAKI;REEL/FRAME:004958/0967 Effective date: 19871127 Owner name: TOSO SUSTEEL CO., LTD., 7-7, AKASAKA 1-CHOME, MINA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:INOUE, HIROSHI;KATO, TOSHIKAZU;EMURA, NORIAKI;REEL/FRAME:004958/0967 Effective date: 19871127 Owner name: TOSOH CORPORATION, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:INOUE, HIROSHI;KATO, TOSHIKAZU;EMURA, NORIAKI;REEL/FRAME:004958/0967 Effective date: 19871127 Owner name: TOSO SUSTEEL CO., LTD., JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:INOUE, HIROSHI;KATO, TOSHIKAZU;EMURA, NORIAKI;REEL/FRAME:004958/0967 Effective date: 19871127 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
REMI | Maintenance fee reminder mailed | ||
LAPS | Lapse for failure to pay maintenance fees | ||
FP | Lapsed due to failure to pay maintenance fee |
Effective date: 19970101 |
|
STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |