US4781985A - Ink jet transparency with improved ability to maintain edge acuity - Google Patents
Ink jet transparency with improved ability to maintain edge acuity Download PDFInfo
- Publication number
- US4781985A US4781985A US07/146,087 US14608788A US4781985A US 4781985 A US4781985 A US 4781985A US 14608788 A US14608788 A US 14608788A US 4781985 A US4781985 A US 4781985A
- Authority
- US
- United States
- Prior art keywords
- sub
- transparency
- ink jet
- resin
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31797—Next to addition polymer from unsaturated monomers
Definitions
- the present invention relates to a recording sheet for use in an ink jet recording process. More specifically, the present invention relates to an improved transparency recording sheet.
- Ink jet printing refers to a method of forming type characters on a substrate, e.g., paper, by ejecting ink droplets from a printhead having one or more nozzles.
- a substrate e.g., paper
- Several schemes are utilized to control the deposition of the ink droplets on the printing substrate or recording sheet to form the desired characters.
- one method comprises deflecting electrically-charged droplets by electrostatic means.
- Another method comprises the ejection of single droplets under the control of a piezoelectric device.
- ink employed is the so-called non-drying type which functions by quickly penetrating the substrate, e.g., paper fibers, thus giving the appearance of being dry to the touch even though still possessing a quantity of relatively low vapor pressure solvent.
- aqueous ink that is, an ink which is composed of a relatively large quantity of water which functions as the solvent and carrier for the dyes therein.
- the image generated by an ink jet printing device may be either in the form of a reflective print wherein the image is deposited on a substantially opaque reflective substrate, e.g., paper, or may comprise a transparency, that is, when the image is formed on a substantially transparent recording substrate and is viewed by illuminating the side of the substrate opposite the image side and viewing from the image side.
- a substantially opaque reflective substrate e.g., paper
- Such material is, of course, particularly advantageous for use in viewing by projection.
- an object of the present invention to provide an ink jet recording transparency which exhibits excellent edge acuity for patterns and blocks of ink on the transparency.
- Yet another object of the present invention is to provide an ink jet recording transparency exhibiting improved prevention of the ink from trailing.
- Still another object of the present invention is to provide an ink jet recording transparency comprising a novel coating layer on a transparent substrate.
- Another object of the present invention is to provide an ink jet recording transparency comprising a novel coating layer on a transparent substrate which exhibits improved ink dry times.
- an ink jet recording transparency exhibiting an improved ability to maintain the edge acuity of ink blocks on the transparency, which transparency comprises
- R f F(CF 2 CF 2 ) 3-8 in each instance;
- R is hydrogen; alkyl, preferably having from 1-6 carbon atoms; aralkyl, preferably having from 7-15 carbon atoms; alkenyl, preferably having from 1-6 carbon atoms; or alkoxy, preferably having from 1-6 carbon atoms; and
- X is halogen, methylsulfate (CH 3 SO 4 - ) or ethylsulfate (CH 3 CH 2 SO 4 - ).
- the most preferred fluorosurfactants are of the general formula
- R f F (CF 2 CF 2 ) 3-8 in each instance.
- a mixture of anionic and cationic fluorosurfactants are employed in order to control edge acuity.
- ink dry times are significantly improved upon utilizing an emulsion of a water insoluble polymer and a hydrophilic polymer as the coating of the transparency.
- the fluorosurfactants of the present invention can also be used successfully to control edge acuity in such a coating for the ink transparency.
- the ink jet recording transparency of the invention includes a transparent resin base, which is generally a thermoplastic film, such as a polyester, e.g., polyethylene terephthalate, as marketed under the trademark Mylar 40PB by DuPont, polystyrene, polyvinyl chloride, polymethylmethacrylate, cellulose acetate and the like.
- a polyester film base is preferred because of its excellent permanency and dimensional stability.
- the thickness of the resin film base is not restricted to any special range although usually it has a thickness of about 2 to 10 mils.
- Polyethylene terephthalate base sheets are relatively hydrophobic, and it can be difficult to apply a water based coating to them. This problem can be overcome in a number of ways.
- the polyester film itself may be surface treated, e.g., by means of corona discharge, to better accept the coating.
- a second method is the use of an intermediate coating which has good affinity for both the base film and the surface coating. Gelatin is an example of such a material.
- Another method is to use a solvent system for the coating that wets the base sheet better than water alone. Alcohol can be included in an aqueous solvent system to achieve the necessary good wetting required to obtain uniform coatings. Either ethanol or methanol is satisfactory. Where a gelatin film is applied from an alcoholic solution, it is necessary to make the solution slightly acidic in order to achieve adequate solubility. A small amount of acetic acid added to the solution can accomplish this purpose.
- the coating formulation useful in obtaining a clear coating over the transparent resin base can comprise any conventional resin based coating formulation used in ink-jet transparencies, with the addition of a fluorosurfactant in accordance with the present invention.
- a formulation comprised of a polymer component which is a carboxylated, high molecular weight polymer or copolymer, or salts thereof.
- Suitable polymers include carboxylated acrylic or methacrylic acid, and esters thereof; carboxylated vinyl acetates; and carboxylated styrenated acrylics.
- the molecular weight of the polymer or copolymer ranges from about 50,000 to 1 million.
- Such polymers provide a clear coating, while being receptive to the ink so as to provide useful recorded images thereon.
- the polymer may contain other substituents in addition to carboxyl groups, such as hydroxyl, ester or amino groups, as long as the wettability property of the polymer is retained, and its ionic nature is sufficient to absorb the dye component of the ink.
- the carboxyl group of the polymer also may be reacted wholly or partially with a base, such as a high boiling organic amine or an inorganic hydroxide, if necessary, to increase its water solubility.
- Typical organic amines which may be used for this purpose include methanolamine, ethanolamine and di- and trimethyl and ethanolamine.
- Inorganic hydroxides include sodium hydroxide, potassium hydroxide and the like.
- the foregoing polymer component coating formulation may also contain a polyalkylene glycol component which is generally polyethylene glycol, although other alkylene glycols may be used as well.
- a polyalkylene glycol component which is generally polyethylene glycol, although other alkylene glycols may be used as well.
- polyethylene glycols have an average molecular weight of about 5,000 to about 25,000.
- the polyethylene glycol compound is made up of two moles of polyethylene glycol of average molecular weight of 8,000 each, which are joined by an epoxide to form a glycol compound with an average molecular weight of 17,500.
- This glycol is available commercially, for example, as "20M" from Union Carbide Corp.
- compositional amounts of polymer and glycol in the coating formulation which will provide desirable results.
- This range suitably includes about 5% to 70% of the glycol by weight of the polymer, preferably about 10% to 25%, and optimally, about 20% of glycol by weight of polymer. Best results are achieved when the foregoing compositional ranges are observed.
- a conventional coating formulation is a formulation comprising a coalesced block copolymer latex of polyvinyl alcohol and polyvinyl (benzyl ammonium chloride), alone or with up to 95% by weight of a water-soluble polymer, e.g., polyvinyl alcohol, gelatin or polyethylene oxide.
- the coating formulation may also comprise a highly hydrophilic, highly water soluble polymer such as polyvinylpyrolidone, which is available as a commercial chemical from a number of suppliers. It is preferred that the polyvinylpyrrolidone have a molecular weight of 90,000 or greater, and should not be crosslinked or be only slightly crosslinked so as to not adversely affect its room temperature solubility in water.
- the polyvinylpyrrolidone can also be used in combination with another matrix polymer such as either gelatin or polyvinyl alcohol.
- the fluorosurfactant is of the formula
- R f F (CF 2 CF 2 ) 3-8 in each instance;
- R is hydrogen; alkyl, preferably having from 1-6 carbon atoms; aralkyl, preferably having from 7-15 carbon atoms; alkenyl, preferably having from 1-6 carbon atoms; or alkoxy, preferably having from 1-6 carbon atoms; and
- X is halogen, methosulfate (CH 3 SO 4 - ) or ethosulfate (CH 3 CH 2 SO 4 - ).
- the most preferred fluorosurfactants are of the general formula
- R f F (CF 2 CF 2 ) 3-8 in each instance.
- fluorosurfactants can be purchased commercially, e.g., as they are available from DuPont under the trademarks Zonyl FSP, Zonyl FSJ, Zonyl FSE and Zonyl FSC.
- Other surfactants, and in particular other fluorosurfactants, have been found to be ineffective in achieving the advantages and benefits of the present invention.
- the foregoing fluorosurfactants can be employed when desired.
- the foregoing fluorosurfactants can be used advantageously in combination with other fluorosurfactants.
- the mixture comprises at least one anionic fluorosurfactant and at least one cationic surfactant, with at least one of the fluorosurfactants being within the defined fluorosurfactants of the present invention.
- an anionic surfactant of the present invention e.g., Zonyl FSJ
- a cationic fluorosurfactant e.g., such as a fluorosurfactant available under the trademark Lodyne S106B.
- the fluorosurfactant of the present invention is generally employed in an amount ranging from about 1 weight percent to about 10 weight percent based upon the weight of solid resin in the clear coating formulation. More preferably, the amount of fluorosurfactant employed ranges from about 3 weight percent to about 5 weight percent. Normal industry use of such surfactants is only from 0.001 to about 0.1 weight percent. Any conventional technique can be employed to effect the coating operation of the coating formulation containing the fluorosurfactant of the present invention.
- the clear coating on the transparent support can also include such additives as ultraviolet absorbers, antioxidants, humectants, bacteriostats and/or cross-linking agents, if desired.
- the thickness of the coatings used herein generally range from about 2-15 microns. Such thicknesses will accommodate dyes of varying concentrations which can be delivered to the transparency at high rates of delivery and with accompanying high dye absorbtivity into the coating.
- the presence of the fluorosurfactant in the coating of the present invention results in excellent maintenance of edge acuity.
- ink-jet ink is prevented from trailing from one pattern or solid block of ink into another.
- the ability to maintain edge acuity is particularly important when different colors of ink are used.
- the use of the fluorosurfactant of the present invention also results in much larger dot sizes and an improved apparent projected density.
- the drying time of the ink dot is also found to be improved, and a slippery surface is imparted to the transparency which helps prevent fingerprinting and film blocking. As a result, there is obtained a much sharper transparency, which is also more easily handled.
- the polymer composition of an ink jet transparency is important to obtaining large dot sizes and rapid ink drying times.
- the polymer composition should be water receptive and possess sufficient surface energy to spread the ink drops rapidly to obtain large dots. If the polymer composition is too water receptive, the ink droplets will not spread sufficiently and the film will feel tacky during routine handling.
- a mixture of a water soluble polymer and a water insoluble polymer there is used in the coating formulation a mixture of a water soluble polymer and a water insoluble polymer.
- a water insoluble polymer prevents film tackiness during handling, and by reducing water receptivity slightly, allows the ink droplets to spread before ink solvent vehicle absorbtion takes place.
- an ink jet film is obtained which is free from tackiness or fingerprinting during handling, exhibits large dot sizes and permits the inks to dry quickly.
- a suitable "water soluble” polymer examples include polyvinyl pyrrolidone, polyvinyl pyrrolidine/polyvinyl acetate copolymer, polyacrylamides, hydroxyethylcellulose and carboxymethylcellulose.
- a preferred water soluble polymers is polyvinyl pyrrolidine of a molecular weight of 360,000 to about 1,000,000, e.g. that are available from GAF under the trademark PVP K-90.
- Suitable "water insoluble” polymers are the highly styrenated acrylics available from Johnson Wax under the Joncryl trademark, the styrene/allyl alcohol co-polymers available from Monsanto Corp. under the trademarks Monsanto RJ100, RJ101 and RF4506, the nitrocellulose polymer available from Hercules, a carboxylated resin available from B.F. Goodrich under the trademark CARBOSET 525, the polyester resin and polyketone resin available from Khrumbhar Resin under the PRINCE 5130 trademark and KHRUMBAR K1717 trademark respectively, and the polyvinyl butyral resin available from Monsanto Corp. under the trademark BUTVAR B90.
- the Joncryl polymers are among the most preferred for the purposes of the present invention.
- an emulsion of a hydrophilic polymer and water insoluble polymer is employed in the clear resin coating.
- the water insoluble polymer employed in the emulsion of this preferred embodiment is a polymer having carboxyl groups, preferably such that the polymer exhibits an acid number of around 200 or more.
- the hydrophilic polymer contains some free amine groups such that it exhibits a basic character. It is believed that the microemulsion is formed due to the acid/base interaction.
- a coagulate forms.
- the coagulate breaks down to form a viscous suspension.
- a solvent solution of a carboxylated styrene-acrylic acid copolymer e.g., such as available under the trademark Joncryl 678
- an aqueous solution of N-vinyl pyrrolidone/N,N-dimethyl amino ethyl methacrylate copolymer e.g., such as available under the trademark GAF copolymer 937
- the coagulate breaks down to a viscous milk-like suspension.
- the microemulsion results in a milky coating which surprisingly dries to a completely transparent film.
- the film exhibits vastly improved ink dry times, e.g., only a few minutes.
- the advantages of this clear coating can be realized with or without the fluorosurfactants of the present invention. However, it is most preferred to also employ the fluorosurfactants of the present invention in order to achieve a transparency coating which exhibits improved edge acuity as well.
- Example 1A with no surfactant showed small dots and trailing of ink between a black solid fill area and a yellow solid fill area. In addition, trailing was readily apparent between magenta and yellow and between purple and green. Because the ink dots had not spread, they took a longer time to dry. Very poor solid area fill was obtained because of the small dots.
- Example 1B containing Zonyl FSO, also exhibited trailing of inks between colors.
- Example 1C containing Zonyl FSC, showed practically no ink trailing between colors in adjacent solid fill areas and gave the largest dot size. In addition, the solid fill areas exhibited a very uniform ink coverage.
- Example II The solutions were coated as in Example I and dried. They were then processed (printed) in a Tektronix 4695 Color Graphics Copier.
- Example IIA with no surfactant had a stickier feeling, smaller dot size, longer drying time. Of more importance, there was trailing of black dots into the yellow block of color. IIB did not exhibit this effect.
- the mixes were coated onto a ICI 505 polyester base with a wire wound Meyer rod, and dried 5 minutes at 220° F. in a Blue M convection oven. The dried coating thickness was approximately 0.25 mils (0.00025 inches).
- the films were then printed on a Tektronix 4695 Color Graphics Ink-Jet Copier using the Test Mode Pattern. The amount of trailing of black ink from a solid color square into an adjacent yellow solid square was observed. In addition, the amount of trailing from a Magenta solid color square to an adjacent yellow solid color square was observed. The observations are recorded in the Table above.
- Example 1 and Example 6 of U.S. Pat. No. 4,528,242 were repeated with the inclusion of 4% by wt of Zonyl FSC fluorosurfactant, in accordance with the present invention.
- the films were printed on a Tektronix 4695, the ink trailing between one solid block of color to another was practically eliminated.
- the dot size was increased substantially, resulting in a more dense projected image.
- a coating formulation in accordance with Example 4 of U.S. Pat. No. 4,503,111 was coated onto ICI 505 base. The film was dried in a convection oven, then printed on a Tektronix 4695 color graphics copier. Severe trailing of a solid block of black ink into an adjacent solid yellow block of color was observed.
- the solution was coated with a #48 wire wound Meyer rod onto ICI 505 polyester film, then dried in a precision scientific convection oven for 5 minutes at 225° F. A dry coating thickness of 0.32 mils was obtained.
- the film was then printed in a Xerox 4020 drop-on-demand color ink-jet printer using the NLQ (near letter quality) mode, and a computer generated color square test pattern containing black, cyan, magenta, yellow, red, blue and green colors. The printed transparency was then observed.
- NLQ near letter quality
- DuPont Zonyl FSJ is an anionic surfactant of the structure:
- DuPont Zonyl FSJ additionally contains a non-fluorinated surfactant (an aliphatic quaternary methosulfate).
- Ciba-Geigy Lodyne S106B is a cationic fluorosurfactant of the fluoro alkyl ammonium chloride type.
- Syloid 620 is an amorphous silica available from W.R. Grace.
- the Zonyl FSJ may be replaced with an amine salt of Zonyl UR
- Suitable amines would be ethanolamine, triethanolamine, morpholine, imidazole, and the like.
- the master mix was divided into 10 equal parts of 23.3 gms each.
- the amounts of surfactant indicated in the table below were added to each mix with the mix then being coated on the polyester film of Example V.
- the Xerox 4020 ink-jet printer was employed for printing onto the film.
- a microemulsion was formed between Joncryl 678 (a carboxylated styrene acrylic polymer) and GAF copolymer 937 (a N-vinyl pyrrolidone/N,N-dimethyl amino ethyl methacrylate copolymer) as follows:
- the emulsion was coated onto ICI 505 polyester film with a #24 wire wound rod and then dried 5 minutes at 220° F. in a convection oven. Surprisingly, the dry coating of 0.32 mils. thickness had excellent clarity.
- the film was then printed in a Tektronix 4696 color graphics copier using a computer generated color square test pattern containing black, cyan, magenta, yellow, red, blue and green colors. Excellent edge acuity was obtained between color squares, as no color bled into another in any combination.
- the inks used in this test were Textronix inks with the following part numbers.
- the emulsion is stable for months with no settling.
- the emulsion also blocks a beam of light.
- Addition of acidic or basic materials breaks the emulsion to form solutions.
- the emulsion cannot be formed in water only, but only in solvents or solvents with the presence of some water (e.g., from the GAF copolymer 937).
- Joncryl resins such as Joncryl 67, 680 and the like are useful in the formation of such an emulsion.
- GAF polymers which are preferably used in forming the solvent emulsion are GAFQUAT 755N, 755, 734 and copolymers 845, 937 and 958. Of these, GAF copolymer 937 is most preferred.
- anionic fluorosurfactants available from Atochem such as Forafac 1176 and 1185, resulted in small ink dot sizes and trailing.
- cationic fluorosurfactants available from Atochem, such as Forafac 1098 and 1179, resulted in large dot sizes, but the edge acuity between adjacent colors was poor (ink trailing). In addition, Forafac 1098 coatings showed many repellencies.
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
Description
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (R).sub.3 X.sup.-
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONR.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.3 CH.sub.3 SO.sub.4.sup.-1
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (R).sub.3 X.sup.-
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONR.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.3 CH.sub.3 SO.sup.-.sub.4
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
______________________________________ Gm. ______________________________________ Joncryl 680 9 Ethanol 100 Dowanol PM 100 PVP K90 21 ______________________________________ Joncryl 680 is a styrenated acrylic of Johnson Wax Co. Dowanol PM is a product of Dow Chemical Polyvinyl Pyrrolidone is GAF PVP K90
______________________________________ A B C ______________________________________ Additive none Zonyl FSO Zonyl FSC .16 Gm. .16 Gm. ______________________________________
______________________________________ A B ______________________________________ Ethanol 10 Gm. 10 Gm. Dowanol PM 10 10 Joncryl 678 .9 .9 PVP K90 2.1 2.1 Zonyl FSC -- .16 ______________________________________
______________________________________ Joncryl 678 14.0 Gms. Dowanol PM 200.0 Gms. Ethanol 200.0 Gms. GAF PVP K90 46.0 Gms. TOTAL 460.0 Gms. ______________________________________
TABLE __________________________________________________________________________ % Solids Fluorosurfactant Amt. (Gms.) Solids Type Comments __________________________________________________________________________ 50% (1) Zonyl FSC - .16 .08 Cationic No trailing large dots 40% (2) Zonyl FSJ - .20 .08 Anionic Slight trailing 50% (3) Zonyl FSA - .16 .08 Anionic Trailing 50% (4) 3MFC135 - .16 .08 Cationic Trailing Paste (5) 3MFC430 - .18 .18 Nonionic Slight trailing, hazy film, small dots 50% (6) 3MFC431 - .16 .08 Nonionic Trailing, hazy film, small dots 25% (7) 3MFC99 - .32 .08 Anionic Trailing 25% (8) 3MFC100 - .32 .08 Amphoteric Difficulty drying film, trailing 50% (9) 3MFC740 - .16 .08 Nonionic Trailing, surfactant insoluble 100% (10) 3MFC134 - .08 .08 Unknown Trailing 100% (11) 3MFC124 - .08 .08 Anionic Trailing 50% (12) 3MFC129 - .16 .08 Anionic Trailing Unknown (13) 3MFC170C - .16 .08 Nonionic Trailing 30% (14) Lodyne S106 - .27 .08 Cationic Trailing 35% (15) Lodyne S110 - .23 .08 Amphoteric Trailing 35% (16) Lodyne S112 - .23 .08 Anionic Trailing 45% (17) Lodyne S107 - .20 .08 Nonionic Trailing 100% (18) 3MFC433 - .08 .08 Unknown Trailing -- (19) No surfactant - -- -- -- Trailing __________________________________________________________________________ 3M FC fluorosurfactants are a trademark of Minnesota, Mining and Manufacturing Lodyne is a trademark of CibaGeigy Chemical
______________________________________ Type Type Comments ______________________________________ Zonyl FSP Anionic No trailing, but many repellency spots Zonyl FSN Nonionic Trailing Zonyl FSO Nonionic Trailing Lodyne S100 Amphoteric Trailing Lodyne S103 Anionic Trailing Non-fluorinated Surfactants Union Carbide Trailing Ucar Super Wetter FP Rohm & Haas Trailing Triton X405 Union Carbide "Carbowax" Nonionic Trailing 400 Polyethylene Glycol M.W. 400 American Cyanamide Trailing Aerosol OTS ______________________________________
______________________________________ Component Amt. (Gms) Designed Function ______________________________________ Dowanol PM 10 solvent Ethanol 10 solvent Syloid 620 Silica 0.010 anti-blocking 45% DuPont Zonyl FSJ 0.20 anionic fluorosurfactant 30% Lodyne S106B 0.20 cationic fluorosurfactant Joncryl 678 0.84 hydrophobic polymer GAF PVPK90 2.04 hydrophilic polymer 67% Glycolic Acid 0.30 improves surface energy ______________________________________
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
______________________________________ Xerox Color Part No. ______________________________________ Magenta 8R2305 Cyan 8R2304 Yellow 8R2303 Black 8R2302 ______________________________________
______________________________________ GMS ______________________________________ Dowanol PM 100 Ethanol 100 Joncryl 678 10 Syloid 620 0.10 PVPK 90 20 67% Glycolic acid 3 TOTAL 233.1 ______________________________________
__________________________________________________________________________ Type of Surfactant Amt (gms) Amt (solids) Xerox 4020 Print __________________________________________________________________________ (1) Cationic Forafac 1179 (40%) .20 .08 much bleeding (2) Cationic Forafac 1098 (50%) .16 .08 moderate bleeding (3) Anionic Forafac 1176 (100%) .08 .08 severe bleeding (4) Anionic Forafac 1185 (100%) .08 .08 much bleeding (5) Cationic Forafac 1179 (40%) .10 .04 much bleeding, Anionic Forafac 1176 (100%) .04 .04 especially black (6) Cationic Forafac 1179 (40%) .10 .04 moderate bleeding Anionic Forafac 1185 (100%) .04 .04 (7) Cationic Forafac 1098 (50%) .08 .04 moderate bleeding Anionic Forafac 1176 .04 .04 (8) Cationic Forafac 1098 (50%) .08 .04 moderate bleeding Anionic Forafac 1185 .04 .04 (9) Cationic Lodyne S106B (30%) .10 .03 no bleeding Anionic Zonyl FSJ (45%) .10 .045 excellent edge acuity __________________________________________________________________________ Forafac 1179 is an ammonium polyfluoroalkyl salt. Forafac 1098 is a polyfluoroalkyl pyridinium salt. Forafac 1176 is a polyfluoro sulfonic acid salt. Forafac 1185 is a perfluoro sulfonic acid salt.
______________________________________ Component Amt. (Gms) Function ______________________________________ Ethanol 15.6 solvent Dowanol PM 7.0 solvent Syloid 620 0.010 anti-blocking Joncryl 678 0.84 hydrophobic polymer ______________________________________
______________________________________ Color Part No. ______________________________________ Black PN-016-0839-01 Cyan PN-016-0840-01 Magenta PN-016-0841-01 Yellow PN-016-0842-01 ______________________________________
______________________________________ Color Part No. ______________________________________ Black PN-016-0839-00 Cyan PN-016-0840-00 Magenta PN-016-0841-00 Yellow PN-016-0842-00 ______________________________________
Claims (28)
R.sub.f CH2CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (R).sub.3 X.sup.-
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONR.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.3 CH.sub.3 SO.sup.-.sub.4
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N(CH.sub.3).sub.3 CH.sub.3 SO.sub.4.sup.-
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.3 CH.sub.3 SO.sub.4.sup.-
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.3 CH.sub.3 SO.sup.-.sub.4
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.3 CH.sub.3 SO.sup.-.sub.4
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONH.sub.4).sub.2,1
R.sub.f CH.sub.2 SCH.sub.2 CH.sub.2 N.sup.+ (R).sub.3 X.sup.-
(R.sub.f CH.sub.2 CH.sub.2 O).sub.1,2 P(O)(ONR.sub.4).sub.2,1
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/146,087 US4781985A (en) | 1986-06-20 | 1988-01-20 | Ink jet transparency with improved ability to maintain edge acuity |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US87644886A | 1986-06-20 | 1986-06-20 | |
US07/146,087 US4781985A (en) | 1986-06-20 | 1988-01-20 | Ink jet transparency with improved ability to maintain edge acuity |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US87644886A Continuation-In-Part | 1986-06-20 | 1986-06-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
US4781985A true US4781985A (en) | 1988-11-01 |
Family
ID=26843561
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/146,087 Expired - Lifetime US4781985A (en) | 1986-06-20 | 1988-01-20 | Ink jet transparency with improved ability to maintain edge acuity |
Country Status (1)
Country | Link |
---|---|
US (1) | US4781985A (en) |
Cited By (79)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5047084A (en) * | 1990-01-23 | 1991-09-10 | Hewlett-Packard Company | Microemulsion ink jet ink composition |
WO1992009439A1 (en) * | 1990-12-03 | 1992-06-11 | Eastman Kodak Company | Ink-receiving transparent recording elements |
WO1992009440A1 (en) * | 1990-12-03 | 1992-06-11 | Eastman Kodak Company | Transparent image-recording elements containing ink-receptive layers |
US5139903A (en) * | 1989-06-23 | 1992-08-18 | Xerox Corporation | Transparencies |
US5182571A (en) * | 1990-02-26 | 1993-01-26 | Spectra, Inc. | Hot melt ink jet transparency |
US5198306A (en) * | 1987-02-24 | 1993-03-30 | Xaar Limited | Recording transparency and method |
US5212008A (en) * | 1992-04-01 | 1993-05-18 | Xerox Corporation | Coated recording sheets |
US5277965A (en) * | 1990-08-01 | 1994-01-11 | Xerox Corporation | Recording sheets |
US5320902A (en) * | 1992-04-01 | 1994-06-14 | Xerox Corporation | Recording sheets containing monoammonium compounds |
US5354368A (en) * | 1993-05-04 | 1994-10-11 | Markem Corporation | Hot melt jet ink composition |
US5441795A (en) * | 1993-03-19 | 1995-08-15 | Xerox Corporation | Recording sheets containing pyridinium compounds |
US5500668A (en) * | 1994-02-15 | 1996-03-19 | Xerox Corporation | Recording sheets for printing processes using microwave drying |
US5521002A (en) * | 1994-01-18 | 1996-05-28 | Kimoto Tech Inc. | Matte type ink jet film |
EP0742109A1 (en) * | 1995-05-12 | 1996-11-13 | Konica Corporation | Ink-jet recording method |
US5589277A (en) * | 1994-02-15 | 1996-12-31 | Xerox Corporation | Recording sheets containing amino acids, hydroxy acids, and polycarboxyl compounds |
WO1997015455A1 (en) * | 1995-10-26 | 1997-05-01 | Minnesota Mining And Manufacturing Company | Ink-jet recording sheet |
US5657064A (en) * | 1993-03-19 | 1997-08-12 | Xerox Corporation | Recording sheets containing pyrrole, pyrrolidine, pyridine, piperidine, homopiperidine, quinoline, isoquinoline, quinuclidine, indole, and indazole compounds |
US5659348A (en) * | 1993-03-19 | 1997-08-19 | Xerox Corporation | Recording sheets containing purine, pyrimidine, benzimidazole, imidazolidine, urazole, pyrazole, triazole, benzotriazole, tetrazole, and pyrazine compounds |
US5688603A (en) * | 1995-10-26 | 1997-11-18 | Minnesota Mining And Manufacturing Company | Ink-jet recording sheet |
US5702804A (en) * | 1996-03-07 | 1997-12-30 | Xerox Corporation | Recording sheets |
US5729266A (en) * | 1993-03-19 | 1998-03-17 | Xerox Corporation | Recording sheets containing oxazole, isooxazole, oxazolidinone, oxazoline salt, morpholine, thiazole, thiazolidine, thiadiazole and phenothiazine compounds |
US5759701A (en) * | 1994-02-15 | 1998-06-02 | Xerox Corporation | Recording sheets containing amine salts and quaternary choline halides |
US5912280A (en) * | 1996-12-27 | 1999-06-15 | E. I. Du Pont De Nemours And Company | Ink jet inks containing emulsion-polymer additives to improve water-fastness |
US5914211A (en) * | 1995-12-01 | 1999-06-22 | Toyo Boseki Kabushiki Kaisha | Photosensitive lithographic printing plate and image-adding type lithographic printing plate using the same |
US5980011A (en) * | 1997-05-16 | 1999-11-09 | Fargo Electronics, Inc. | Identification card printer |
US6114022A (en) * | 1997-08-11 | 2000-09-05 | 3M Innovative Properties Company | Coated microporous inkjet receptive media and method for controlling dot diameter |
US6153288A (en) * | 1997-07-24 | 2000-11-28 | Avery Dennison Corporation | Ink-receptive compositions and coated products |
WO2000076779A1 (en) * | 1999-06-11 | 2000-12-21 | Kodak Polychrome Graphics Co. Ltd. | Surfactant-pretreated printing plate substrate, lithographic printing plate and method for production thereof |
US6245421B1 (en) | 1999-02-04 | 2001-06-12 | Kodak Polychrome Graphics Llc | Printable media for lithographic printing having a porous, hydrophilic layer and a method for the production thereof |
US6264296B1 (en) | 1997-05-06 | 2001-07-24 | Fargo Electronics, Inc. | Ink jet identification card printer with lamination station |
US6383612B1 (en) | 1998-06-19 | 2002-05-07 | 3M Innovative Properties Company | Ink-drying agents for inkjet receptor media |
US6387473B1 (en) | 1999-09-03 | 2002-05-14 | Ferrania S.P.A. | Receiving sheet for ink-jet printing comprising a surfactant combination |
US6451413B1 (en) | 1999-02-04 | 2002-09-17 | Kodak Polychrome Graphics Llc | Method of preparing a printing plate and printing plate |
WO2003002353A1 (en) | 2001-06-29 | 2003-01-09 | 3M Innovative Properties Company | Imaged articles comprising a substrate having a primed surface |
US6506478B1 (en) | 2000-06-09 | 2003-01-14 | 3M Innovative Properties Company | Inkjet printable media |
US6514599B1 (en) | 1999-04-16 | 2003-02-04 | 3M Innovative Properties Company | Inkjet receptor medium having a multi-staged ink migration inhibitor and method of making and using same |
US6537650B1 (en) | 1998-06-19 | 2003-03-25 | 3M Innovative Properties Company | Inkjet receptor medium having ink migration inhibitor and method of making and using same |
US6555213B1 (en) | 2000-06-09 | 2003-04-29 | 3M Innovative Properties Company | Polypropylene card construction |
US20030090712A1 (en) * | 1999-07-14 | 2003-05-15 | Lenz Gary A. | Identification card printer with client/server |
US20030159607A1 (en) * | 2000-01-06 | 2003-08-28 | Boaz Nitzan | Method for the preparation of lithographic printing plates |
US20030164982A1 (en) * | 2002-03-01 | 2003-09-04 | Lien Brent D. | Card cleaner roller assembly |
US6632510B1 (en) | 1997-07-14 | 2003-10-14 | 3M Innovative Properties Company | Microporous inkjet receptors containing both a pigment management system and a fluid management system |
US20030197056A1 (en) * | 2002-04-19 | 2003-10-23 | Dunham Matthew K. | Identification card printer data encoder module |
US6677007B1 (en) | 1999-02-12 | 2004-01-13 | 3M Innovative Properties Company | Image receptor medium and method of making and using same |
US6685312B2 (en) | 1997-10-24 | 2004-02-03 | Fargo Electronics, Inc. | Ink jet card printer |
US6692799B2 (en) | 2000-06-09 | 2004-02-17 | 3M Innovative Properties Co | Materials and methods for creating waterproof, durable aqueous inkjet receptive media |
US6694884B2 (en) | 1999-01-25 | 2004-02-24 | Fargo Electronics, Inc. | Method and apparatus for communicating between printer and card supply |
US6702282B2 (en) | 1997-10-24 | 2004-03-09 | Fargo Electronics, Inc. | Card transport mechanism roller support |
US6703112B1 (en) | 1998-06-19 | 2004-03-09 | 3M Innovative Properties Company | Organometallic salts for inkjet receptor media |
US6729719B2 (en) | 2002-04-19 | 2004-05-04 | Fargo Electronics, Inc. | Identification card printer formed from a sheet feed printer |
US20040114981A1 (en) * | 1999-01-25 | 2004-06-17 | Fargo Electronics, Inc. | Identification card printer ribbon cartridge |
US6758616B2 (en) | 2000-01-21 | 2004-07-06 | Fargo Electronics, Inc. | Identification card printer |
US20040136768A1 (en) * | 1999-01-25 | 2004-07-15 | Klinefelter Gary M. | Printer or laminator supply |
WO2004060687A1 (en) | 2002-12-23 | 2004-07-22 | 3M Innovative Properties Company | Ink jet receptive coating |
US20040202838A1 (en) * | 2002-10-24 | 2004-10-14 | Eastman Kodak Company | Overcoat composition for image recording materials |
US6932527B2 (en) | 1999-01-25 | 2005-08-23 | Fargo Electronics, Inc. | Card cartridge |
US6945524B2 (en) | 2002-09-05 | 2005-09-20 | Fargo Electronics, Inc. | Card singularization gate |
US20050208234A1 (en) * | 2004-03-19 | 2005-09-22 | Agfa-Gevaert | Ink-jet recording material |
US20050250869A1 (en) * | 2004-05-06 | 2005-11-10 | Agfa-Gevaert N.V. | Radiation-curable ink-jet printing |
US20050271439A1 (en) * | 1999-01-25 | 2005-12-08 | Fargo Electronics, Inc. | Printer and ribbon cartridge |
US6979480B1 (en) | 2000-06-09 | 2005-12-27 | 3M Innovative Properties Company | Porous inkjet receptor media |
WO2006011797A1 (en) | 2004-07-30 | 2006-02-02 | Fuji Photo Film B.V. | Recording media |
WO2006047030A1 (en) * | 2004-10-21 | 2006-05-04 | Hewlett-Packard Development Company, L.P. | Print media and methods for making the same |
EP1671805A2 (en) | 2004-12-16 | 2006-06-21 | Agfa-Gevaert | Radiation curable ink-jet printing process using dotsize control fluid |
US20060132566A1 (en) * | 2004-12-16 | 2006-06-22 | Agfa-Gevaert | Dotsize control fluid for radiation curable ink-jet printing process |
US20060147658A1 (en) * | 2003-06-18 | 2006-07-06 | Fuji Photo Film B.V. | Ink-jet recording medium |
US20060222787A1 (en) * | 2003-10-03 | 2006-10-05 | Fuji Photo Film B.V. | Recording medium |
US20070087138A1 (en) * | 2005-10-14 | 2007-04-19 | Koenig Michael F | Recording sheet with improved image dry time |
US7237485B2 (en) | 1999-01-25 | 2007-07-03 | Fargo Electronics, Inc. | Print supply monitoring |
US7290146B2 (en) | 2004-05-03 | 2007-10-30 | Fargo Electronics, Inc. | Managed credential issuance |
US7399131B2 (en) | 2001-03-05 | 2008-07-15 | Fargo Electronics, Inc. | Method and Device for forming an ink-receptive card substrate |
US7430762B2 (en) | 2002-03-01 | 2008-09-30 | Fargo Electronics, Inc. | Identification card manufacturing security |
US7490055B2 (en) | 2003-09-11 | 2009-02-10 | Fargo Electronics, Inc. | Identification card manufacturing system supply ordering and diagnostic report |
EP1417546B1 (en) * | 2001-08-08 | 2009-04-15 | Hewlett-Packard Indigo B.V. | Coating especially for liquid toner imaging system components |
EP2075140A1 (en) | 2007-12-04 | 2009-07-01 | FUJIFILM Manufacturing Europe B.V. | Printing process |
US7620815B2 (en) | 2003-02-21 | 2009-11-17 | Fargo Electronics, Inc. | Credential production using a secured consumable supply |
US7878505B2 (en) | 2003-08-19 | 2011-02-01 | Hid Global Corporation | Credential substrate rotator and processing module |
US8099187B2 (en) | 2005-08-18 | 2012-01-17 | Hid Global Corporation | Securely processing and tracking consumable supplies and consumable material |
US8646770B2 (en) | 2009-09-18 | 2014-02-11 | Hid Global Corporation | Card substrate rotator with lift mechanism |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4547405A (en) * | 1984-12-13 | 1985-10-15 | Polaroid Corporation | Ink jet transparency |
US4554181A (en) * | 1984-05-07 | 1985-11-19 | The Mead Corporation | Ink jet recording sheet having a bicomponent cationic recording surface |
US4555437A (en) * | 1984-07-16 | 1985-11-26 | Xidex Corporation | Transparent ink jet recording medium |
US4575465A (en) * | 1984-12-13 | 1986-03-11 | Polaroid Corporation | Ink jet transparency |
US4578285A (en) * | 1983-03-16 | 1986-03-25 | Polaroid Corporation | Ink jet printing substrate |
US4592951A (en) * | 1984-07-18 | 1986-06-03 | Polaroid Corporation | Ink jet recording sheet |
-
1988
- 1988-01-20 US US07/146,087 patent/US4781985A/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4578285A (en) * | 1983-03-16 | 1986-03-25 | Polaroid Corporation | Ink jet printing substrate |
US4554181A (en) * | 1984-05-07 | 1985-11-19 | The Mead Corporation | Ink jet recording sheet having a bicomponent cationic recording surface |
US4555437A (en) * | 1984-07-16 | 1985-11-26 | Xidex Corporation | Transparent ink jet recording medium |
US4592951A (en) * | 1984-07-18 | 1986-06-03 | Polaroid Corporation | Ink jet recording sheet |
US4547405A (en) * | 1984-12-13 | 1985-10-15 | Polaroid Corporation | Ink jet transparency |
US4575465A (en) * | 1984-12-13 | 1986-03-11 | Polaroid Corporation | Ink jet transparency |
Cited By (110)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5198306A (en) * | 1987-02-24 | 1993-03-30 | Xaar Limited | Recording transparency and method |
US5139903A (en) * | 1989-06-23 | 1992-08-18 | Xerox Corporation | Transparencies |
US5047084A (en) * | 1990-01-23 | 1991-09-10 | Hewlett-Packard Company | Microemulsion ink jet ink composition |
US5182571A (en) * | 1990-02-26 | 1993-01-26 | Spectra, Inc. | Hot melt ink jet transparency |
US5277965A (en) * | 1990-08-01 | 1994-01-11 | Xerox Corporation | Recording sheets |
WO1992009439A1 (en) * | 1990-12-03 | 1992-06-11 | Eastman Kodak Company | Ink-receiving transparent recording elements |
WO1992009440A1 (en) * | 1990-12-03 | 1992-06-11 | Eastman Kodak Company | Transparent image-recording elements containing ink-receptive layers |
US5212008A (en) * | 1992-04-01 | 1993-05-18 | Xerox Corporation | Coated recording sheets |
US5320902A (en) * | 1992-04-01 | 1994-06-14 | Xerox Corporation | Recording sheets containing monoammonium compounds |
US5657064A (en) * | 1993-03-19 | 1997-08-12 | Xerox Corporation | Recording sheets containing pyrrole, pyrrolidine, pyridine, piperidine, homopiperidine, quinoline, isoquinoline, quinuclidine, indole, and indazole compounds |
US6846525B2 (en) | 1993-03-19 | 2005-01-25 | Xerox Corporation | Recording sheets containing purine, pyrimidine, benzimidazole, imidazolidine, urazole, pyrazole, triazole, benzotriazole, tetrazole, and pyrazine compounds |
US5729266A (en) * | 1993-03-19 | 1998-03-17 | Xerox Corporation | Recording sheets containing oxazole, isooxazole, oxazolidinone, oxazoline salt, morpholine, thiazole, thiazolidine, thiadiazole and phenothiazine compounds |
US5441795A (en) * | 1993-03-19 | 1995-08-15 | Xerox Corporation | Recording sheets containing pyridinium compounds |
US7105214B2 (en) | 1993-03-19 | 2006-09-12 | Xerox Corporation | Recording sheets containing pyrrole, pyrrolidine, pyridine, piperidine, homopiperidine, quinoline, isoquinoline, quinuclidine, indole, and indazole compounds |
US5659348A (en) * | 1993-03-19 | 1997-08-19 | Xerox Corporation | Recording sheets containing purine, pyrimidine, benzimidazole, imidazolidine, urazole, pyrazole, triazole, benzotriazole, tetrazole, and pyrazine compounds |
US6482503B1 (en) | 1993-03-19 | 2002-11-19 | Xerox Corporation | Recording sheets containing pyrrole, pyrrolidine, pyridine, piperidine, homopiperidine, quinoline, isoquinoline, quinuclidine, indole, and indazole compounds |
US6180238B1 (en) | 1993-03-19 | 2001-01-30 | Xerox Corporation | Recording sheets containing oxazole, isooxazole, oxazolidinone, oxazoline salt, morpholine, thiazole, thiazolidine, thiadiazole, and phenothiazine compounds |
US5354368A (en) * | 1993-05-04 | 1994-10-11 | Markem Corporation | Hot melt jet ink composition |
US5521002A (en) * | 1994-01-18 | 1996-05-28 | Kimoto Tech Inc. | Matte type ink jet film |
US5589277A (en) * | 1994-02-15 | 1996-12-31 | Xerox Corporation | Recording sheets containing amino acids, hydroxy acids, and polycarboxyl compounds |
US5500668A (en) * | 1994-02-15 | 1996-03-19 | Xerox Corporation | Recording sheets for printing processes using microwave drying |
US5757408A (en) * | 1994-02-15 | 1998-05-26 | Xerox Corporation | Recording sheets containing amino acids, hydroxy acids, and polycarboxyl compounds |
US5759701A (en) * | 1994-02-15 | 1998-06-02 | Xerox Corporation | Recording sheets containing amine salts and quaternary choline halides |
EP0742109A1 (en) * | 1995-05-12 | 1996-11-13 | Konica Corporation | Ink-jet recording method |
US5877796A (en) * | 1995-05-12 | 1999-03-02 | Konica Corporation | Recording sheet for ink-jet recording and recording method employing the same |
US5707722A (en) * | 1995-10-26 | 1998-01-13 | Minnesota Mining And Manufacturing Company | Ink jet recording sheet |
US5688603A (en) * | 1995-10-26 | 1997-11-18 | Minnesota Mining And Manufacturing Company | Ink-jet recording sheet |
WO1997015455A1 (en) * | 1995-10-26 | 1997-05-01 | Minnesota Mining And Manufacturing Company | Ink-jet recording sheet |
US5914211A (en) * | 1995-12-01 | 1999-06-22 | Toyo Boseki Kabushiki Kaisha | Photosensitive lithographic printing plate and image-adding type lithographic printing plate using the same |
US5702804A (en) * | 1996-03-07 | 1997-12-30 | Xerox Corporation | Recording sheets |
US5912280A (en) * | 1996-12-27 | 1999-06-15 | E. I. Du Pont De Nemours And Company | Ink jet inks containing emulsion-polymer additives to improve water-fastness |
US6264296B1 (en) | 1997-05-06 | 2001-07-24 | Fargo Electronics, Inc. | Ink jet identification card printer with lamination station |
EP0984862A1 (en) * | 1997-05-16 | 2000-03-15 | Fargo Electronics, Inc. | Identification card printer |
US6241332B1 (en) | 1997-05-16 | 2001-06-05 | Fargo Electronics, Inc. | Identification card printer |
US5980011A (en) * | 1997-05-16 | 1999-11-09 | Fargo Electronics, Inc. | Identification card printer |
EP0984862A4 (en) * | 1997-05-16 | 2000-10-11 | Fargo Electronics Inc | Identification card printer |
US6632510B1 (en) | 1997-07-14 | 2003-10-14 | 3M Innovative Properties Company | Microporous inkjet receptors containing both a pigment management system and a fluid management system |
US6153288A (en) * | 1997-07-24 | 2000-11-28 | Avery Dennison Corporation | Ink-receptive compositions and coated products |
US6114022A (en) * | 1997-08-11 | 2000-09-05 | 3M Innovative Properties Company | Coated microporous inkjet receptive media and method for controlling dot diameter |
US6685312B2 (en) | 1997-10-24 | 2004-02-03 | Fargo Electronics, Inc. | Ink jet card printer |
US6702282B2 (en) | 1997-10-24 | 2004-03-09 | Fargo Electronics, Inc. | Card transport mechanism roller support |
US6703112B1 (en) | 1998-06-19 | 2004-03-09 | 3M Innovative Properties Company | Organometallic salts for inkjet receptor media |
US6383612B1 (en) | 1998-06-19 | 2002-05-07 | 3M Innovative Properties Company | Ink-drying agents for inkjet receptor media |
US6537650B1 (en) | 1998-06-19 | 2003-03-25 | 3M Innovative Properties Company | Inkjet receptor medium having ink migration inhibitor and method of making and using same |
US7018117B2 (en) | 1999-01-25 | 2006-03-28 | Fargo Electronics, Inc. | Identification card printer ribbon cartridge |
US20040114981A1 (en) * | 1999-01-25 | 2004-06-17 | Fargo Electronics, Inc. | Identification card printer ribbon cartridge |
US20050271439A1 (en) * | 1999-01-25 | 2005-12-08 | Fargo Electronics, Inc. | Printer and ribbon cartridge |
US6694884B2 (en) | 1999-01-25 | 2004-02-24 | Fargo Electronics, Inc. | Method and apparatus for communicating between printer and card supply |
US7237485B2 (en) | 1999-01-25 | 2007-07-03 | Fargo Electronics, Inc. | Print supply monitoring |
US6932527B2 (en) | 1999-01-25 | 2005-08-23 | Fargo Electronics, Inc. | Card cartridge |
US7154519B2 (en) | 1999-01-25 | 2006-12-26 | Fargo Electronics, Inc. | Printer and ribbon cartridge |
US6832866B2 (en) | 1999-01-25 | 2004-12-21 | Fargo Electronics, Inc. | Printer or laminator supply |
US20040136768A1 (en) * | 1999-01-25 | 2004-07-15 | Klinefelter Gary M. | Printer or laminator supply |
US7344325B2 (en) | 1999-01-25 | 2008-03-18 | Fargo Electronics, Inc. | Identification card printer having ribbon cartridge with cleaner roller |
US6451413B1 (en) | 1999-02-04 | 2002-09-17 | Kodak Polychrome Graphics Llc | Method of preparing a printing plate and printing plate |
US6455132B1 (en) | 1999-02-04 | 2002-09-24 | Kodak Polychrome Graphics Llc | Lithographic printing printable media and process for the production thereof |
US6555205B2 (en) | 1999-02-04 | 2003-04-29 | Kodak Polychrome Graphics Llc | Printing plate and method to prepare a printing plate |
US6245421B1 (en) | 1999-02-04 | 2001-06-12 | Kodak Polychrome Graphics Llc | Printable media for lithographic printing having a porous, hydrophilic layer and a method for the production thereof |
US6472054B1 (en) | 1999-02-04 | 2002-10-29 | Kodak Polychrome Graphics Llc | Method of preparing a printing plate and printing plate |
US6677007B1 (en) | 1999-02-12 | 2004-01-13 | 3M Innovative Properties Company | Image receptor medium and method of making and using same |
US6514599B1 (en) | 1999-04-16 | 2003-02-04 | 3M Innovative Properties Company | Inkjet receptor medium having a multi-staged ink migration inhibitor and method of making and using same |
US6276273B1 (en) | 1999-06-11 | 2001-08-21 | Kodak Polychrome Graphics Llc | Surfactant-pretreated printing plate substrate, lithographic printing plate and method for production thereof |
WO2000076779A1 (en) * | 1999-06-11 | 2000-12-21 | Kodak Polychrome Graphics Co. Ltd. | Surfactant-pretreated printing plate substrate, lithographic printing plate and method for production thereof |
US7339690B2 (en) | 1999-07-14 | 2008-03-04 | Fargo Electronics, Inc. | Identification card printer with client/server |
US20030090712A1 (en) * | 1999-07-14 | 2003-05-15 | Lenz Gary A. | Identification card printer with client/server |
US6387473B1 (en) | 1999-09-03 | 2002-05-14 | Ferrania S.P.A. | Receiving sheet for ink-jet printing comprising a surfactant combination |
US20030159607A1 (en) * | 2000-01-06 | 2003-08-28 | Boaz Nitzan | Method for the preparation of lithographic printing plates |
US6758616B2 (en) | 2000-01-21 | 2004-07-06 | Fargo Electronics, Inc. | Identification card printer |
US6905742B2 (en) | 2000-06-09 | 2005-06-14 | 3M Innovative Properties Company | Polypropylene card construction |
US6979480B1 (en) | 2000-06-09 | 2005-12-27 | 3M Innovative Properties Company | Porous inkjet receptor media |
US6555213B1 (en) | 2000-06-09 | 2003-04-29 | 3M Innovative Properties Company | Polypropylene card construction |
US6692799B2 (en) | 2000-06-09 | 2004-02-17 | 3M Innovative Properties Co | Materials and methods for creating waterproof, durable aqueous inkjet receptive media |
US6506478B1 (en) | 2000-06-09 | 2003-01-14 | 3M Innovative Properties Company | Inkjet printable media |
US6825279B2 (en) | 2000-06-09 | 2004-11-30 | 3M Innovative Properties Company | Inkjet printable media |
US7399131B2 (en) | 2001-03-05 | 2008-07-15 | Fargo Electronics, Inc. | Method and Device for forming an ink-receptive card substrate |
WO2003002353A1 (en) | 2001-06-29 | 2003-01-09 | 3M Innovative Properties Company | Imaged articles comprising a substrate having a primed surface |
EP1417546B1 (en) * | 2001-08-08 | 2009-04-15 | Hewlett-Packard Indigo B.V. | Coating especially for liquid toner imaging system components |
US6985167B2 (en) | 2002-03-01 | 2006-01-10 | Fargo Electronics, Inc. | Card cleaner roller assembly |
US7793353B2 (en) | 2002-03-01 | 2010-09-07 | Hid Global Corporation | Identification card manufacturing security |
US20030164982A1 (en) * | 2002-03-01 | 2003-09-04 | Lien Brent D. | Card cleaner roller assembly |
US7430762B2 (en) | 2002-03-01 | 2008-09-30 | Fargo Electronics, Inc. | Identification card manufacturing security |
US20030197056A1 (en) * | 2002-04-19 | 2003-10-23 | Dunham Matthew K. | Identification card printer data encoder module |
US6729719B2 (en) | 2002-04-19 | 2004-05-04 | Fargo Electronics, Inc. | Identification card printer formed from a sheet feed printer |
US6945524B2 (en) | 2002-09-05 | 2005-09-20 | Fargo Electronics, Inc. | Card singularization gate |
US7219989B2 (en) * | 2002-10-24 | 2007-05-22 | Eastman Kodak Company | Overcoat composition for image recording materials |
US7718235B2 (en) | 2002-10-24 | 2010-05-18 | Eastman Kodak Company | Overcoat composition for image recording materials |
US20040202838A1 (en) * | 2002-10-24 | 2004-10-14 | Eastman Kodak Company | Overcoat composition for image recording materials |
EP1413453A3 (en) * | 2002-10-24 | 2006-03-15 | Eastman Kodak Company | Imaged recording materials having a transparent overcoat composition |
WO2004060687A1 (en) | 2002-12-23 | 2004-07-22 | 3M Innovative Properties Company | Ink jet receptive coating |
US7620815B2 (en) | 2003-02-21 | 2009-11-17 | Fargo Electronics, Inc. | Credential production using a secured consumable supply |
US20060159872A1 (en) * | 2003-06-18 | 2006-07-20 | Fuji Photo Film B.V. | Ink-jet recording medium |
US20060147658A1 (en) * | 2003-06-18 | 2006-07-06 | Fuji Photo Film B.V. | Ink-jet recording medium |
US7878505B2 (en) | 2003-08-19 | 2011-02-01 | Hid Global Corporation | Credential substrate rotator and processing module |
US7490055B2 (en) | 2003-09-11 | 2009-02-10 | Fargo Electronics, Inc. | Identification card manufacturing system supply ordering and diagnostic report |
US20060222787A1 (en) * | 2003-10-03 | 2006-10-05 | Fuji Photo Film B.V. | Recording medium |
US20090169455A1 (en) * | 2004-03-19 | 2009-07-02 | Agfa-Gevaert, N.V. | Ink-jet recording material |
US20050208234A1 (en) * | 2004-03-19 | 2005-09-22 | Agfa-Gevaert | Ink-jet recording material |
US7290146B2 (en) | 2004-05-03 | 2007-10-30 | Fargo Electronics, Inc. | Managed credential issuance |
US20050250869A1 (en) * | 2004-05-06 | 2005-11-10 | Agfa-Gevaert N.V. | Radiation-curable ink-jet printing |
US8083338B2 (en) | 2004-05-06 | 2011-12-27 | Agfa Graphics N.V. | Radiation-curable ink-jet printing |
WO2006011797A1 (en) | 2004-07-30 | 2006-02-02 | Fuji Photo Film B.V. | Recording media |
WO2006047030A1 (en) * | 2004-10-21 | 2006-05-04 | Hewlett-Packard Development Company, L.P. | Print media and methods for making the same |
EP1671805A2 (en) | 2004-12-16 | 2006-06-21 | Agfa-Gevaert | Radiation curable ink-jet printing process using dotsize control fluid |
US20060132566A1 (en) * | 2004-12-16 | 2006-06-22 | Agfa-Gevaert | Dotsize control fluid for radiation curable ink-jet printing process |
US7575314B2 (en) | 2004-12-16 | 2009-08-18 | Agfa Graphics, N.V. | Dotsize control fluid for radiation curable ink-jet printing process |
US8099187B2 (en) | 2005-08-18 | 2012-01-17 | Hid Global Corporation | Securely processing and tracking consumable supplies and consumable material |
US20070087138A1 (en) * | 2005-10-14 | 2007-04-19 | Koenig Michael F | Recording sheet with improved image dry time |
US8758886B2 (en) * | 2005-10-14 | 2014-06-24 | International Paper Company | Recording sheet with improved image dry time |
EP2075140A1 (en) | 2007-12-04 | 2009-07-01 | FUJIFILM Manufacturing Europe B.V. | Printing process |
US8646770B2 (en) | 2009-09-18 | 2014-02-11 | Hid Global Corporation | Card substrate rotator with lift mechanism |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4781985A (en) | Ink jet transparency with improved ability to maintain edge acuity | |
US4775594A (en) | Ink jet transparency with improved wetting properties | |
US5942335A (en) | Ink jet recording sheet | |
US4547405A (en) | Ink jet transparency | |
US6010790A (en) | Ink jet recording sheet | |
EP0661168B1 (en) | Recording medium and image-forming method employing the same | |
US5567507A (en) | Ink-receptive sheet | |
US4528242A (en) | Ink jet recording transparency | |
EP0693385A1 (en) | Recording medium, image-forming method and printed article using the medium | |
JPH04263985A (en) | Transparent liquid absorbing material for ink receiving layer | |
US5139867A (en) | Ink jet recording transparency | |
US4904519A (en) | Ink-receptive sheet | |
US5919558A (en) | Inkjet recording sheet | |
US5126193A (en) | Ink jet recording sheet | |
US6003989A (en) | Ink jet recording sheet | |
JP3092948B2 (en) | Aqueous ink-receptive inkjet receptive media resulting in water-resistant inkjet prints | |
JP4410827B2 (en) | Inkjet recording sheet | |
JPH1148600A (en) | Ink jet recording film | |
EP0742109A1 (en) | Ink-jet recording method | |
JP3053231B2 (en) | Inkjet recording sheet | |
WO1995016561A1 (en) | Ink acceptor material | |
US5147717A (en) | Transparent image-recording elements | |
JPH0757553B2 (en) | Inkjet recording sheet with excellent water resistance | |
JP3094699B2 (en) | Method of manufacturing ink jet recording sheet | |
JPH079757A (en) | Ink jet recording sheet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: JAMES RIVER GRAPHICS, INC., SO. HADLEY, MASS A COR Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:DESJARLAIS, ROBERT C.;REEL/FRAME:004837/0650 Effective date: 19880112 Owner name: JAMES RIVER GRAPHICS, INC., A CORP. OF VA,MASSACH Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DESJARLAIS, ROBERT C.;REEL/FRAME:004837/0650 Effective date: 19880112 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
AS | Assignment |
Owner name: JAMES RIVER U.S. HOLDINGS, INC., A CORP. OF DE Free format text: MERGER;ASSIGNORS:JAMES RIVER-BERLIN/GORHAM, INC., A CORP. OF DE;JAMES RIVER-KVP, INC., A CORP. OF DE;JAMES RIVER-MASSACHUSETS, INC., A CORP. OF DE;AND OTHERS;REEL/FRAME:005659/0939 Effective date: 19850422 Owner name: JAMES RIVER U.S. HOLDINGS, INC., A CORP. OF DELAWA Free format text: MERGER;ASSIGNORS:JAMES RIVER - BERLIN/GORHAM, INC. (DELAWARE);JAMES RIVER - KVP, INC. (DELAWARE);JAMES RIVER - MASSACHUSETTS, INC. (DELAWARE);AND OTHERS;REEL/FRAME:005657/0862 Effective date: 19850422 |
|
AS | Assignment |
Owner name: GRAPHICS TECHNOLOGY INTERNATIONAL INC., A CORPORAT Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:JAMES RIVER PAPER COMPANY, INC., A CORPORATION OF VA;REEL/FRAME:005805/0089 Effective date: 19910430 |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
AS | Assignment |
Owner name: REXHAM GRAPHICS INC., MASSACHUSETTS Free format text: CHANGE OF NAME;ASSIGNOR:GRAPHICS TECHNOLOGY INTERNATIONAL, INC.;REEL/FRAME:006823/0517 Effective date: 19930628 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
FPAY | Fee payment |
Year of fee payment: 12 |
|
AS | Assignment |
Owner name: REXAM INDUSTRIES CORP., NORTH CAROLINA Free format text: MERGER;ASSIGNOR:REXAM GRAPHICS INC.;REEL/FRAME:012946/0548 Effective date: 20000713 Owner name: REXAM IMAGE PRODUCTS INC., NORTH CAROLINA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:REXAM INDUSTRIES CORP.;REEL/FRAME:012946/0558 Effective date: 20000713 Owner name: REXAM GRAPHICS INC., NORTH CAROLINA Free format text: CHANGE OF NAME;ASSIGNOR:REXHAM GRAPHICS INC.;REEL/FRAME:012973/0538 Effective date: 19950518 Owner name: JAMES RIVER PAPER COMPANY, INC., VIRGINIA Free format text: MERGER;ASSIGNOR:JAMES RIVER U.S. HOLDINGS, INC.;REEL/FRAME:012973/0556 Effective date: 19890427 |
|
AS | Assignment |
Owner name: IMAGE PRODUCTS GROUP LLC, MASSACHUSETTS Free format text: CONVERSION TO A DELAWARE LIMITED LIABILITY COMPANY;ASSIGNOR:REXAM IMAGE PRODUCTS INC.;REEL/FRAME:012958/0586 Effective date: 20020610 |
|
AS | Assignment |
Owner name: CONGRESS FINANCIAL CORPORATION, FLORIDA Free format text: SECURITY INTEREST;ASSIGNOR:IMAGE PRODUCTS GROUP LLC;REEL/FRAME:013036/0434 Effective date: 20020619 |
|
AS | Assignment |
Owner name: SUN INTELICOAT FINANCE, LLC, FLORIDA Free format text: PATENT AND TRADEMARK SECURITY AGREEMENT;ASSIGNORS:IMAGE PRODUCTS GROUP LLC;INTELICIOAT TECHNOLOGIES IMAGE PRODUCTS PORTLAND LLC;INTELICOAT TECHNOLOGIES IMAGE PRODUCTS S. HADLEY LLC;REEL/FRAME:024630/0329 Effective date: 20100701 |
|
AS | Assignment |
Owner name: FCC, LLC D/B/A FIRST CAPITAL, GEORGIA Free format text: SECURITY AGREEMENT;ASSIGNORS:IMAGE PRODUCTS GROUP LLC;INTELICOAT TECHNOLOGIES IMAGE PRODUCTS PORTLAND LLC;INTELICOAT TECHNOLOGIES IMAGE PRODUCTS S. HADLEY LLC;REEL/FRAME:024723/0134 Effective date: 20100701 |
|
AS | Assignment |
Owner name: IMAGE PRODUCTS GROUP LLC, MASSACHUSETTS Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:WELLS FARGO BANK, N.A.;REEL/FRAME:024933/0591 Effective date: 20100831 |
|
AS | Assignment |
Owner name: INTELICOAT TECHNOLOGIES IMAGE PRODUCTS PORTLAND LL Free format text: RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 024723/0134;ASSIGNOR:FCC, LLC D/B/A FIRST CAPITAL;REEL/FRAME:031105/0509 Effective date: 20130828 Owner name: INTELICOAT TECHNOLOGIES IMAGE PRODUCTS S. HADLEY L Free format text: RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 024723/0134;ASSIGNOR:FCC, LLC D/B/A FIRST CAPITAL;REEL/FRAME:031105/0509 Effective date: 20130828 Owner name: IMAGE PRODUCTS GROUP LLC, MASSACHUSETTS Free format text: RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME 024723/0134;ASSIGNOR:FCC, LLC D/B/A FIRST CAPITAL;REEL/FRAME:031105/0509 Effective date: 20130828 |