US452210A - Rene bohn - Google Patents
Rene bohn Download PDFInfo
- Publication number
- US452210A US452210A US452210DA US452210A US 452210 A US452210 A US 452210A US 452210D A US452210D A US 452210DA US 452210 A US452210 A US 452210A
- Authority
- US
- United States
- Prior art keywords
- gallacetophenone
- color
- brown
- parts
- rene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XIROXSOOOAZHLL-UHFFFAOYSA-N Gallacetophenone Chemical compound CC(=O)C1=CC=C(O)C(O)=C1O XIROXSOOOAZHLL-UHFFFAOYSA-N 0.000 description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 16
- 230000005484 gravity Effects 0.000 description 14
- 238000007639 printing Methods 0.000 description 14
- 239000000835 fiber Substances 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 239000003086 colorant Substances 0.000 description 10
- 238000004043 dyeing Methods 0.000 description 10
- 235000011167 hydrochloric acid Nutrition 0.000 description 10
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 235000011149 sulphuric acid Nutrition 0.000 description 8
- 235000013311 vegetables Nutrition 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- 239000001117 sulphuric acid Substances 0.000 description 6
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K Iron(III) chloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- 241000322338 Loeseliastrum Species 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000003518 caustics Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000010454 slate Substances 0.000 description 4
- VSGNNIFQASZAOI-UHFFFAOYSA-L Calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L Iron(II) chloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- QJLDTVCWUDCBME-UHFFFAOYSA-K aluminum;trithiocyanate Chemical compound [Al+3].[S-]C#N.[S-]C#N.[S-]C#N QJLDTVCWUDCBME-UHFFFAOYSA-K 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 235000011092 calcium acetate Nutrition 0.000 description 2
- YRTKBCIAQCXVCM-UHFFFAOYSA-K chromium(3+);trithiocyanate Chemical compound [Cr+3].[S-]C#N.[S-]C#N.[S-]C#N YRTKBCIAQCXVCM-UHFFFAOYSA-K 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 2
- 235000019233 fast yellow AB Nutrition 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
Definitions
- My invention relates to the production of new compounds or lakes of gallaoetophenone with certain metallic oxides or mordants within or upon animal or vegetable fiber and thus dyeing the material.
- Gallacetophenone Was discovered by M. V. Nencki, (Journal ft'tr Pralatt'sche Ohemc'e, XXIII, pp. 151, 537, et seq.;) but it is not a coloring-matter in its free or uncombined condition, and up to the date of my invention it was not known that itcould in any way be used for dyeing and printing. Now I have found that it can be made to impart fast and useful colors to both animal and vegetable fiber by causing it to combine with metallic oxides or mordants within or upon the said fibrous materials. All the known metallic mordants may be used.
- alumina with which fast yellow shades are obtained
- chrome which gives brown colors
- iron with which the shades vary from slate color to black.
- results obtained by the use of alumina mordants may in some cases be improved by the employment therewith of calcium, and superior results may be produced on cotton by previously impregnating it with the well-known Turkey-red oil mordant.
- the print-color is compounded from thirty-seven and one-half parts (the parts are by weight) of gallacetophenone-paste (containing about ten per cent. dry substance,) fifteen parts solution of aluminium thiocyanate (rhodanate) of 1.15 specific gravity, seven and one-half parts acetate-of-lime solution of 1.075 specifie gravity, seven and one-half parts of acetic acid of 1.045 specific gravity, and thirty-two and one-half parts of thickening.
- gallacetophenone-paste containing about ten per cent. dry substance
- the goods After printing with the above-described colors the goods are steamed (at ordinary or increased pressure) in a manner similar to that in use for the development of the colored compounds orlakes of the alizarine dyes. .
- the goods are afterward soaped, washed, and dried.
- Goods dyed or printed with gallacetophenone can be readily recognized by the following tests:
- the yellow color produced upon an alumina mordant (the nature of the mordant can be ascertained by the analysis of the ashes of the material) is destroyed by weak and strong hydrochloric acid, Weak and strong nitric acid, weak and strong sulphuric acid. It is turned reddish by caustic soda and greenish by ferric chloride, but does not change color with ammonia.
- the yellowish brown color produced with a chrome inordant shows no change with dilute hydrochloric, nitric, and sulphuric acid, but is turned greenish by strong hydrochloric and sulphuric acids and brown by strong nitric acid.
- a very striking test characteristic to goods dyed or printed with gallacetophenone is the following: By boiling such goods with diluted hydrochloric acid they are stripped of some of their color, and the solution so obtained yields a characteristic reaction with caustic alkalies. At first on addition of the caustic alkali a yellow color is produced, which on standing turns a dirty green. By this test goods dyed or printed with gallacetophenone can be readily distinguished from goods dyed or printed with other coloring-matters.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
. Empire of Germany, have invented new and UNITED STATES PATENT OFFICE.
RENE BOHN, OF LUDWIGSHAFEN-ON-THE-RHINE, ASSIGNOR TO THE BADISOHE ANILIN AND SODA FABRIK, OF MANN HEIM, GERMANY.
PROCESS OF DYEING WITH GALLACETOPHENONE.
SPECIFICATION forming part of Letters Patent No. 452,210, dated May 12, 1891.
Application filed June 5, 1890. Serial No. 354,376. (No specimens.) Patented in Germany May 28. 1889, no. 50,238; in England June 6,1889,N o. 9,429, and in France June 11, 1889, No. 198,866.
To aZZ whom it ntay concern:
Be it known that I, RENE BoHN, a citizen of Switzerland, residing at L'udwigshafen-onthe-Rhine, in the Kingdom of Bavaria and useful Improvements in Dyeing and Printing Animal and Vegetable Fiber with Gallacetophenone, (for which I have obtained Letters Patent in Germany, dated May 28, 1889, No. 50,238; in France, dated June 11, 1889, No. 198,866, and in Great Britain, dated June 6, 1889, No. 9,429,) of which the following is a specification.
My invention relates to the production of new compounds or lakes of gallaoetophenone with certain metallic oxides or mordants within or upon animal or vegetable fiber and thus dyeing the material.
Gallacetophenone Was discovered by M. V. Nencki, (Journal ft'tr Pralatt'sche Ohemc'e, XXIII, pp. 151, 537, et seq.;) but it is not a coloring-matter in its free or uncombined condition, and up to the date of my invention it was not known that itcould in any way be used for dyeing and printing. Now I have found that it can be made to impart fast and useful colors to both animal and vegetable fiber by causing it to combine with metallic oxides or mordants within or upon the said fibrous materials. All the known metallic mordants may be used. The following appear at present to be most important: alumina, with which fast yellow shades are obtained; chrome, which gives brown colors; and iron, with which the shades vary from slate color to black. The results obtained by the use of alumina mordants may in some cases be improved by the employment therewith of calcium, and superior results may be produced on cotton by previously impregnating it with the well-known Turkey-red oil mordant.
In the following examples I give an exact description of the preparation of print-colors for use in printing calico various shades of yellow, brown, and black, and I prefer to use gallacetophenone in a finely-divided condition-say in the form of a thin paste or pulp containing about ten per cent. of dry gallacetophenone and ninety per cent. of water.
I. For yellow the print-coloris compounded from thirty-seven and one-half parts (the parts are by weight) of gallacetophenone-paste (containing about ten per cent. dry substance,) fifteen parts solution of aluminium thiocyanate (rhodanate) of 1.15 specific gravity, seven and one-half parts acetate-of-lime solution of 1.075 specifie gravity, seven and one-half parts of acetic acid of 1.045 specific gravity, and thirty-two and one-half parts of thickening.
II. For yellowish-brown mix as print-color thirty-seven and one-half parts gallacetophenone-paste, (ten per cent. dry) fifteen parts solution of chromium thiocyanate (rhodanate) of 1.2 specific gravity, seven and one-half parts of acetic acid of 1.045 specific gravity, and forty parts of thickening.
III. To obtain a print-color for black, take thirty-seven and one-half parts gallacetophenone-paste, (ten per cent. dry,) fifteen parts acetate of iron solution of 1.116 specific gravity, seven and one-half parts of acetic acid of 1.045 specific gravity, and forty parts of thickening.
After printing with the above-described colors the goods are steamed (at ordinary or increased pressure) in a manner similar to that in use for the development of the colored compounds orlakes of the alizarine dyes. .The goods are afterward soaped, washed, and dried.
Now although I have only described in detail the preparation of print-colors of gallacetophenone more particularly suited for print ing calico, inasmuch as this appears likely to be its principal application, still it must not be considered that my invention is confined to this application; but since I have discovered that the metallic lakes can also readily be formed within or upon the animal fiber it is possible for every dyer skilled in the art to which this appertains, and with the information conveyed to him by this specification to readily produce upon wool and silk by dyeing or printing, with the aid of mordants, shades similar to those mentioned above.
Goods dyed or printed with gallacetophenone can be readily recognized by the following tests: The yellow color produced upon an alumina mordant (the nature of the mordant can be ascertained by the analysis of the ashes of the material) is destroyed by weak and strong hydrochloric acid, Weak and strong nitric acid, weak and strong sulphuric acid. It is turned reddish by caustic soda and greenish by ferric chloride, but does not change color with ammonia. The yellowish brown color produced with a chrome inordant shows no change with dilute hydrochloric, nitric, and sulphuric acid, but is turned greenish by strong hydrochloric and sulphuric acids and brown by strong nitric acid. Caustic soda and iron chloride turn it brown, but ammonia does not change the color. The black or slate shades produced on iron mordant turn yellowish with strong hydrochloric acid and. are decolorized by weak hydrochloric acid. Veak nitric acid and weak and strong sulphuric acid turn them brown and Weak nitric acid decolorizes them. Sodium hydrate turns them brown. Ferric chloride deeolorizes, and ammonia produces no change of color.
A very striking test characteristic to goods dyed or printed with gallacetophenone is the following: By boiling such goods with diluted hydrochloric acid they are stripped of some of their color, and the solution so obtained yields a characteristic reaction with caustic alkalies. At first on addition of the caustic alkali a yellow color is produced, which on standing turns a dirty green. By this test goods dyed or printed with gallacetophenone can be readily distinguished from goods dyed or printed with other coloring-matters.
What I claim as new, and desire to secure by Letters Patent, is-
The within-described process of dyeing or printing animal and vegetable fiber, which consists in exposing the fiber to the action of gallacetophenone in the presence of a suitable mordant.
In testimony whereof I have hereunto set my hand in the presence of two subscribing witnesses.
RENE BOII'N.
\Vitnesses:
ERNEST F. EHRHARDT, IIERMANN HANG.
Publications (1)
Publication Number | Publication Date |
---|---|
US452210A true US452210A (en) | 1891-05-12 |
Family
ID=2521091
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US452210D Expired - Lifetime US452210A (en) | Rene bohn |
Country Status (1)
Country | Link |
---|---|
US (1) | US452210A (en) |
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0
- US US452210D patent/US452210A/en not_active Expired - Lifetime
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