US4407676A - Fiber-reinforced cement and process - Google Patents
Fiber-reinforced cement and process Download PDFInfo
- Publication number
- US4407676A US4407676A US06/394,785 US39478582A US4407676A US 4407676 A US4407676 A US 4407676A US 39478582 A US39478582 A US 39478582A US 4407676 A US4407676 A US 4407676A
- Authority
- US
- United States
- Prior art keywords
- cement mortar
- filaments
- gas bubbles
- microfibrillated
- cement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000004568 cement Substances 0.000 title claims description 50
- 239000004033 plastic Substances 0.000 claims abstract description 63
- 229920003023 plastic Polymers 0.000 claims abstract description 63
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 20
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims description 53
- 239000011159 matrix material Substances 0.000 claims description 33
- 239000007789 gas Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 27
- 239000011083 cement mortar Substances 0.000 claims description 26
- 230000001413 cellular effect Effects 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 22
- -1 polypropylene Polymers 0.000 claims description 22
- 229920000098 polyolefin Polymers 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000004743 Polypropylene Substances 0.000 claims description 17
- 229920001155 polypropylene Polymers 0.000 claims description 17
- 239000004088 foaming agent Substances 0.000 claims description 10
- 210000001724 microfibril Anatomy 0.000 claims description 10
- 239000012779 reinforcing material Substances 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- 239000004794 expanded polystyrene Substances 0.000 claims description 8
- 159000000011 group IA salts Chemical class 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 claims description 4
- 239000002657 fibrous material Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 238000003892 spreading Methods 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 2
- 229930195729 fatty acid Natural products 0.000 claims 2
- 239000000194 fatty acid Substances 0.000 claims 2
- 150000004665 fatty acids Chemical class 0.000 claims 2
- 238000009775 high-speed stirring Methods 0.000 claims 2
- 238000003756 stirring Methods 0.000 claims 2
- 238000005520 cutting process Methods 0.000 claims 1
- 239000011236 particulate material Substances 0.000 claims 1
- 239000011369 resultant mixture Substances 0.000 claims 1
- 238000011068 loading method Methods 0.000 abstract description 4
- 239000011396 hydraulic cement Substances 0.000 abstract description 3
- 239000004567 concrete Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 8
- 239000011398 Portland cement Substances 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 206010061592 cardiac fibrillation Diseases 0.000 description 5
- 230000002600 fibrillogenic effect Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000004873 anchoring Methods 0.000 description 4
- 238000005336 cracking Methods 0.000 description 3
- 239000012783 reinforcing fiber Substances 0.000 description 3
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000011381 foam concrete Substances 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 241001009766 Argyrodendron trifoliolatum Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920006329 Styropor Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000003823 mortar mixing Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000011208 reinforced composite material Substances 0.000 description 1
- 239000003829 resin cement Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C5/00—Reinforcing elements, e.g. for concrete; Auxiliary elements therefor
- E04C5/07—Reinforcing elements of material other than metal, e.g. of glass, of plastics, or not exclusively made of metal
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/04—Macromolecular compounds
- C04B16/06—Macromolecular compounds fibrous
- C04B16/0608—Fibrilles, e.g. fibrillated films
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
Definitions
- liquid polymeric-resin systems have been formulated to be embodied into mortars and concretes, developing thereby in their end products improved tensile strength and compressive strength, as well as characteristics of chemical and abrassion-resistance.
- a polymer mortar is prepared by partially replacing cement with polymer in the respective cementitious mix. This process requires to use on the one hand, specific liquid polymer systems (resins, accelerators and catalysts) and, on the other, apparatus specially designed for proportioning and blending the appropriate amounts of materials.
- plastic filamentary reinforcing means has been proposed.
- Plastic fibers have proved to be unsuitable in some respects as reinforcing materials.
- a main drawback is the one arising in great measure from the plastic fibers' hydrophobic nature, which comes to impair their frictional adhesion with the cementitious matrix whereby the stressed plastic filaments become debonded.
- the problem brought about by the poor physic-chemical adherence with their matrix is also involved to deter further the use of the so far commercially available plastic fiber as reinforcing means for cement products.
- the plastic reinforced sheets manufactured by the method of the patent are necessarily layered structures, having the fibers as a single-direction reinforcement, as a direct consequence of their manufacturing process.
- the sheets have been proposed as suitable substitutes for asbestos-reinforced cement articles.
- certain conditions, particularly under high temperature bring about spallation and delamination of the aforecited layered structures.
- fibrillated plastic films as the reinforcing means for cement-based parts, they are coated with cement mortar and the excess mortar removed from the coated films; the so coated layers are laid in sequence each coextensively arranged into the other until piling up the required number of layers to make up the desired sheet thickness.
- the so prepared sheet while still in its fresh condition may be handled to be molded into the shape of the particular mold used, suited to the end product.
- the articles manufactured in that way because of prevailing orientation of the fibrils in their reinforcing films in one direction only, have values for its mechanical properties greatly differing according to the directions in which they are oriented; that is, the articles are said to be remarkably anisotropic.
- the anisotropic nature is controlled then, in accordance to the orientation in which the plastic mesh is placed and according as the mesh opening.
- the reinforcing plastic films are mechanically slit into a predetermined degree of fibrillation which will be preserved throughout the manufacturing process and it will be the same amount of fibrillation that will be present in the hardened cement product. Since the fibrillated film is embedded into a previously prepared mortar paste, and inasmuch as the plastic material is chosen from polyolefines, particularly polypropylene, which are hardly wettable materials, the process therefore does not provide for means to help promote the desirable humidification to develop appropriate adherence between the fibrous material and the matrix encapsulating it. Poor adhesion impairs the tensile strength of the cement mortar elements obtained by this process, as well as its ability to develop closely spaced multicracking with desirable small cracks. The development of thin cracks in a closely arranged pattern is a phenomenon normally occuring in hardened cement elements which have been reinforced by means of aligned polypropylene fibers.
- Another well-known means of obtaining lightweight concrete is by introducing gas bubbles into the plastic cement mix in order to produce a material with a cellular structure, somewhat similar to sponge rubber. For this reason the resulting concrete is known as cellular or aerated concrete.
- gas bubbles into the plastic cement mix in order to produce a material with a cellular structure, somewhat similar to sponge rubber.
- the resulting concrete is known as cellular or aerated concrete.
- Gas concrete is obtained by a chemical reaction generating a gas in fresh mortar, so that when it sets it contains a large number of gas bubbles.
- Finely divided aluminium powder is most commonly used, its proportion being of the order of 0.2 percent of the weight of cement.
- the reaction of the active powder with a hydroxide of calcium or alkali liberates hydrogen, which forms the bubbles.
- Powdered zinc can also be used. Sometimes hydrogen peroxide is used; this generates oxygen.
- Foamed concrete is produced by adding to the mix a foaming agent (usually some form of hydrolyzed protein or resin soap) which introduces and stabilizes air bubbles during mixing at high speed.
- a foaming agent usually some form of hydrolyzed protein or resin soap
- a stable pre-formed foam is added to the mortar during mixing in an ordinary mixer.
- Cellular concrete is mostly used for partitions for heat insulation purposes because of its low thermal conductivity, and for fireproofing as it offers better fire resistance than ordinary concrete.
- Portland cement with aerating agent is that which contains some substance which incorporates many very small gas bubbles to the concrete made with such cement. Before setting, this concrete has more plasticity and is more homogeneous than common concrete, because the bubbles delay sedimentation of greater particles.
- the first Portland cement with aerating agent was manufactured in the United States in 1938, and in 1942 the American Society of Testing Materials (ASTM) adopted a specification for it.
- Manufacture of Portland cement with aerating agent is similar to that of common Portland cement, except that the aerating agent is ground with the clinker in the final grinding operation.
- the quantity of aerating agent is 0.01-0.02% in weight of cement, and the quantity which must be added for a particular cement is fixed by the required quantity for obtaining an air content of 19 ⁇ 3% in a normal mortar, as described in the ASTM method to determine the air content of hydraulic cement mortar.
- the ASTM specifies the following: (1) natural woods' resins, such as that from silver tree; (2) animal or vegetal greases and resins, such as fish oil, or tallow, and their fat acids; (3) various humectant agents, such as alkaline salts of sulphonated organic compounds; (4) water-soluble soaps; (5) others, such as hydrogen peroxide and aluminum powder.
- Aerated concrete may be made adding these materials directly to the mixer.
- the present invention relates to the preparation of lightweight cement mortar materials comprising reinforcing plastic fibers and chunks of a cellular plastic (crushed in the mixing process, or before it, and/or gas bubbles, wherein the above set forth drawbacks are overcome.
- a main object of this invention is to provide products from plastic-fibers reinforced mortar wherein the effect of mechanical anchoring of the fiber into the cementitious matrix is improved and, thus, more efficient use of the reinforcing material is achieved, whereby the end products are obtained in a less expensive manner, providing at the same time gas bubbles (or chunks of a cellular plastic) which cause the mortar to be lightweight.
- Another object of the present invention is to provide a lightweight fiber-cement material which is reinforced by means of individual, refibrillated plastic fibers, made from fibrillated untwisted ribbons. Said material is very well suited to be molded into variously-shaped products by means of a wide variety of molding processes.
- an additional object of this invention is to provide lightweight fiber-cement products possessing identical mechanical properties when measured to any directions thereto and, accordingly, the end elements are as wholly isotropic as possible.
- Yet another object of the invention is to provide lightweight plastic fiber-reinforced products having increased resistance to withstand tensile loads and impact loading after the hardened cementitious matrix has developed minute cracking therein, compared with the respective properties of the same cement matrix free from said reinforcing material.
- the invention provides for a fibrous cement material comprised of a hydraulically setting binder as typified by Portland cement mortar, and randomly oriented separate plastic fibers uniformly dispersed therein, so as to bring the end-product anisotropy down to a minimum, and wherein said plastic fibers are given a microfibrillated structure, as it will be set forth herein-below.
- the fiber present within the matrix is a branched monofilament fiber derived from an untwisted fibrillated ribbon of fibrillate polyolefin film.
- the polyolefin film is cut into rather long narrow ribbons or strips of about 15 mm wide, and the non-twisted ribbons are fibrillated into fibers by conventional fibrillating means.
- the so fibrillated ribbons are cut into lengths going up to about 50 mm long.
- the mechanical shredding action which takes place in the mixing operation causes the ribbon fibrils to become further fibrillated or refibrillated and the ribbon fibrils are broken apart into individual filaments having a branched structure provided with microfibrils or fibrets outwardly projecting along their length.
- the projected microfibrils are somewhat curled in shape, and for their anchorage purposes they perform as anchoring elements or "hooks" within the cement hardened matrix.
- the filaments cross-sectional area and their length as well as their length in one same direction--differ from one another.
- the chunks do not need a humidifier because the structural cohesion of the mix relies on the action of the fiber and not on the binding of the cellular plastic chunks with the matrix.
- the foaming agent is added, and the high speed mixing generates the air bubbles from the foaming agent. Otherwise an aerating agent is added to incorporate the air bubbles.
- the chunks of cellular plastic are selected from expanded polystyrene, expanded polyurethane, both of which are crushed before the mixing, or any other expanded plastic.
- a composite material comprising an intimate and homogeneous mixture of microfibrillated polyolefin filaments which are oriented in all of the spatial directions and kept evenly distributed throughout the mass of hydraulically setting binder, like Portland cement. Because of both the polydirectional orientation of the fibers in the mass, and their particularly fibrillated structure suitable to achieve a hook-like anchoranging reinforcement, the so reinforced composite material gives rise to elements having identical mechanical properties when measured at any directions thereof, that is, they physically behave as isotropic bodies. Of course, mechanical isotropy is a largely desirable behavior in elements.
- the invention takes into consideration the observation that fabrillated sections cut from polyolefin ribbons, when subjected to the combined effect of a shear mixer and shredding action of the mortar components, basically cement and sand besides breaking apart into monofilamentary fibers, these monofilaments become microfibrillated branched structures with laterally extending microfibrils or fibrets having varying length and cross-sectional area. Also, the microfibrillated polyolefin fibers are thoroughly wetted in the mortar components' mixing operation.
- the present process provides elastic behavior of the reinforcing filaments to take place, while at the same time allowing that the elongation brought about thereon by the crack opening will not be taken up only by the filament extension spanning or bridging the crack width, but instead of that, the elongation stress is brought to bear throughout the filament length, it follows therefore that the tensile stress is kept thereby below the ultimate elongation of the reinforcing filaments; if the tensile stress were to be concentrated upon the filament section intersecting or spanning the crack width, filament breaking would occur.
- the fibrillated reinforcing material according to the present invention makes it possible for the tensile stress to be transmitted between adjacent blocks of the fractured matrix through the entire filament stretchable sections while they are kept anchored within the cracked matrix, and this without being substantially affected by the matrix cracks.
- the adherence is not bonding to the matrix, it is interlocking of the fibrils of the monofilaments and the matrix.
- the mortar components comprised of hydraulic cement, water inorganic fillers such as sand which may or may not be used having a particle size distribution such that no particle is greater than 1/10 the average length of the reinforced fibrillated filaments to be formed in the mixing operation, chunks of a cellular plastic, and/or foaming or aerating agent are blended together in a mixer machine equipped with a high-speed propeller.
- the final specific weight, with the gas bubbles chunks of cellular plastic is comprised within approximately 0.35 and 1.95.
- the chunks of cellular plastic are selected from expanded polystyrene, expanded polyurethane, or any other expanded plastic.
- the fibrous material fed into the mixing step is derived from polyolefin film which has been slit into ribbons of about 15 mm wide; the ribbons while kept untwisted are fibrillated into fibrils by conventional mechanical means and then cut into sections of about 50 mm long; and thereafter the ribbon fibrillated sections are spread out by air jet means.
- the plastic fiber's own resilence its effective length in one direction is a function of its diameter. Also, the amount of fibrillation caused in the plastic ribbons to form separate monofilaments, as well as the mixing time and of course the degree of branching so effect the fiber effective length. Further, the fiber's effective length and its diameter along with the amount of fiber are determining factors of the width and spacing of cracks to be developed in the fiber-cement hardened element once it undergoes its naturally occuring multiple cracking. This hardened element, however already cracked, continues still to effectively withstand tensile stresses.
- Performance specifications to be met by a particular fiber-cement element once cracked, will determine the permissible breadth of cracks and spacing therebetween. In the process in accordance with the present invention these characteristics can be controlled since it provides for means to exercise influence over the process parameters related to diameter and length of fiber and of course its amount used.
- the material obtained can either be shaped into sheets or it can also be molded into several other forms. Moreover, because of its mechanical isotropic properties this is a multipurpose material that can in an economic manner be used for application such as to replace asbestos-cement as well as for forming flexible coatings, and it is suitable also for varied specific application where high impact loading, elastic behavior and/or lightweight are required characteristics.
- Sections of untwisted polypropylene fibrillated ribbon are prepared.
- the ribbon section is conventionally fibrillated along lengthwise extending slits. In this slit condition the ribbon has the following features:
- the mixing compartment of the machine is chosen so as to be at least 20% greater than the volume of wet mixture.
- Said compartment is truncated-cone shaped and it is arranged with its smaller base downwardly directed.
- the mixing time was 14 min. with the propeller running at 1200 rpm.
- the fibrillated ribbon undergoes a strong frictional action by the cement particles whereby the ribbon is fully broken apart into separate monofilaments. These monofilaments are at the same time given the further fibrillated structure, by opening them up into a number of microfibrils or generally crimped fibrets varying in cross-sectional area and length.
- the adherence of the reinforcing fiber with the reinforced cement matrix is other than a friction pehnomenon, inasmuch as in the polypropylene fiber, and the like plastic fibers, under tensile stress the Poisson's ratio does not allow for contact between the hardened matrix and the reinforcing fiber outer surface. Adherence is therefore the result of anchoring effect.
- the specific weight of the fiber-cement as it finally sets is about 0.80; the gas or cellular plastic content is approximately 60% of the total volume.
- the general condition for all of the physical properties of the fiber-cement material prepared according to the present invention lies in its isotropy which is accomplished as a result from the process of its manufacture.
- the mortar prepared in accordance with the present invention can easily be molded. Its molding may be carried out by means of extrusion, injection molding, casting, centrifugal molding or by means of a combination of the above molding methods. Parts of that material while in their fresh condition are easily joined to each other as a result of the intercrossing of filaments of the different masses to be joined together.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
______________________________________ specific weight 0.91 denier 6000 width 15 mm thickness 50 microns length of section 47 mm ______________________________________
Claims (20)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/394,785 US4407676A (en) | 1981-11-25 | 1982-07-02 | Fiber-reinforced cement and process |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/325,035 US4414030A (en) | 1981-11-25 | 1981-11-25 | Fiber-reinforced cement, and process |
| US06/394,785 US4407676A (en) | 1981-11-25 | 1982-07-02 | Fiber-reinforced cement and process |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/325,035 Continuation-In-Part US4414030A (en) | 1981-11-25 | 1981-11-25 | Fiber-reinforced cement, and process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4407676A true US4407676A (en) | 1983-10-04 |
Family
ID=26984740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/394,785 Expired - Lifetime US4407676A (en) | 1981-11-25 | 1982-07-02 | Fiber-reinforced cement and process |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US4407676A (en) |
Cited By (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0152490A1 (en) * | 1983-11-08 | 1985-08-28 | Jose Manuel Restrepo | Improved fibre-reinforced cement and process |
| US5298071A (en) * | 1990-03-23 | 1994-03-29 | Vontech International Corporation | Interground fiber cement |
| US5338357A (en) * | 1991-10-01 | 1994-08-16 | Polyfibre S.A. | Fibre reinforced shaped solid articles |
| US5803964A (en) * | 1992-07-13 | 1998-09-08 | Sequoyah Exo Systems, Inc. | Composite building material and system for creating structures from such building material |
| US5849818A (en) * | 1993-06-03 | 1998-12-15 | Walles; Wilhelm E. | Skin sulfonated particles in matrices |
| US5904763A (en) * | 1995-03-24 | 1999-05-18 | Blocken; Wilfried | Insulating mortar |
| WO1999046214A1 (en) * | 1998-03-11 | 1999-09-16 | Dalhousie University | Fiber reinforced building materials |
| RU2150446C1 (en) * | 1998-12-01 | 2000-06-10 | АООТ Всероссийский федеральный головной технологический институт ВНИИжелезобетон | Composition for preparing polystyrene concrete mix |
| US6187409B1 (en) | 1997-09-12 | 2001-02-13 | National Gypsum Company | Cementitious panel with reinforced edges |
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| US6694690B2 (en) | 2000-07-10 | 2004-02-24 | The Regents Of The University Of Michigan | Concrete constructions employing the use of a ductile strip |
| US20040099982A1 (en) * | 2002-08-19 | 2004-05-27 | Sirola D. Brien | Conductive concrete compositions and methods of manufacturing same |
| US20040149170A1 (en) * | 2003-02-04 | 2004-08-05 | Osvaldo Moran | Cellular concrete having normal compressive strength |
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| US6809131B2 (en) | 2000-07-10 | 2004-10-26 | The Regents Of The University Of Michigan | Self-compacting engineered cementitious composite |
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| US20060005967A1 (en) * | 2002-08-19 | 2006-01-12 | Sirola D B | Deep well anodes for electrical grounding |
| US20060185560A1 (en) * | 2005-02-24 | 2006-08-24 | Wisconsin Electric Power Company | Carbon dioxide sequestration in foamed controlled low strength materials |
| US20060201393A1 (en) * | 2005-03-11 | 2006-09-14 | Pkl Corporation | Shrinkage compensating concrete |
| US20060276088A1 (en) * | 2005-06-01 | 2006-12-07 | Polymer Group, Inc. | Profiled Structural Concrete Fiber Material And Building Products Including Same, And Methods |
| US7229492B2 (en) * | 2004-03-17 | 2007-06-12 | Halliburton Energy Services, Inc. | Cement compositions comprising improved lost circulation materials and methods of use in subterranean formations |
| US20070187854A1 (en) * | 2002-08-19 | 2007-08-16 | Sirola D B | Deep well anodes for electrical grounding |
| KR100784978B1 (en) * | 2006-05-03 | 2007-12-11 | 신순옥 | Concrete motor with foam urethane pole and waste synthetic resin as main components and its manufacturing method |
| US20080245274A1 (en) * | 2005-02-24 | 2008-10-09 | Ramme Bruce W | Carbon Dioxide Sequestration in Foamed Controlled Low Strength Materials |
| WO2009061016A1 (en) * | 2007-11-09 | 2009-05-14 | Soon-Ok Shin | A mortar for concrete having polyurethane foam and method of thereof |
| US20100307091A1 (en) * | 2009-06-08 | 2010-12-09 | NEHEMIAH ELITE WALL SYSTEMS, INC., an Arizona Corporation | Plaster panel and method of using same |
| US20100307657A1 (en) * | 2009-06-08 | 2010-12-09 | NEHEMIAH ELITE WALL SYSTEMS, INC., an Arizona Corporation | System and method of making plaster panels |
| US20110139037A1 (en) * | 2003-04-03 | 2011-06-16 | Construction Research & Technology Gmbh | Powdery Building Compound |
| US20110189456A1 (en) * | 2010-02-02 | 2011-08-04 | Nicholas Reck | Pavement overlay material and method |
| ES2683082A1 (en) * | 2017-03-16 | 2018-09-24 | Universidad De La Laguna | Non-structural concrete made from polyurethane pellet residues from the refrigerator recycling process. |
| EP2935145B1 (en) * | 2012-12-20 | 2020-05-13 | Qim Projekt & Consult GmbH | Building material composition for producing a lightweight concrete |
| US10654751B2 (en) * | 2016-05-25 | 2020-05-19 | W. Robert Wilson | Polymer modified cement adhesive for providing high friction surfacing |
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| US11349228B2 (en) | 2017-08-14 | 2022-05-31 | Shore Acres Enterprises Inc. | Corrosion-protective jacket for electrode |
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| EP0152490A1 (en) * | 1983-11-08 | 1985-08-28 | Jose Manuel Restrepo | Improved fibre-reinforced cement and process |
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| US5338357A (en) * | 1991-10-01 | 1994-08-16 | Polyfibre S.A. | Fibre reinforced shaped solid articles |
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