US4378999A - Pulverulent bitumen concentrate and its use - Google Patents
Pulverulent bitumen concentrate and its use Download PDFInfo
- Publication number
- US4378999A US4378999A US06/175,742 US17574280A US4378999A US 4378999 A US4378999 A US 4378999A US 17574280 A US17574280 A US 17574280A US 4378999 A US4378999 A US 4378999A
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- Prior art keywords
- bitumen
- sup
- silica
- asphalt
- concentrate
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Definitions
- bitumens are a dark colored, semisolid to brittle, meltable, high molecular weight hydrocarbon mixtures which are obtained in the careful refining of petroleums and the portion of the natural asphalts as well as mineral wax and montan wax soluble in carbon disulfide (see Rompp Lexikon der Chemie, 7th Edition, page 377).
- Natural asphalt can be employed in admixture with bituminous binders according to DIN 1995 for the production of mortar rich coating layers (e.g., cast asphalt, asphalt concrete, sand asphalt and asphalt mastic).
- a natural asphalt of this type is, e.g., Trinidad-Epure (Trinidad-refined) which has the following composition:
- Trinidad-Epure as well as the other known natural asphalts have the disadvantage that in spite of the very high filler content they are solid and must be melted before use.
- a powder (or pulverulent) bitumen concentrate containing 10 to 85 weight %, preferably 40 to 80 weight %, of synthetic silica.
- synthetic silicas there can be used precipitated silica as well as pyrogenically produced silica.
- the precipitated silica can have a BET-surface area of 120 to 500 m 2 /g. In a given case it can be ground by a steam jet, spray dried or spray dried and ground.
- the pyrogenically produced silica can have a BET-surface area of 100 to 400 m 2 /g.
- bitumen concentrate of the invention can be produced by simply mixing the liquid bitumen with the synthetic silica or spraying the liquid bitumen on the synthetic silica.
- bitumen concentrate of the invention has the advantage that in spite of the high proportion of bitumen it is powdery, temperature stable and flowable.
- the use of the powdery bitumen concentrate in asphalt mixture for building roads results in a surprisingly high stiffening effect.
- the process can comprise, consist essentially of or consist of the steps set forth with the stated materials.
- the bulk density of the powders in each case was determined (g/cm 3 ).
- the recording was according to the school annotation system.
- the results are compiled in Table 1.
- the silica FK 320 used is a precipitated silica with the following physical chemical properties:
- a silica 320 DS is a precipitated and steam jet ground silica having the following physical chemical properties:
- the silica Sipernat 22 is a precipitated and spray dried silica having the following physical-chemical properties:
- the additives were added in the laboratory to the mixtures of an asphalt concrete 0/11 mm suited for use in the classified road construction. In this connection in consideration of the amounts of crushed rock and binders contained in the additives the remaining composition of the mixtures are the same.
- Filler 0/0.09 mm limestone powder, basalt true filler+additive
- the binder content of all mixtures was 5.9 weight %.
- Table 3 gives a summary of the composition of the mixtures.
- Asphalt mixtures were mixed in batches of 6,300 grams or 4,000 grams in the laboratory mixture while maintaining a homegeneous discharge.
- the powdery additives were brought into the hot mixture according to the proportion of bitumen but before the limestone powder.
- the uniaxial compressive strength was 0.1 MN/m 2 .
- the formation of the uniaxial strength state was promoted by arrangement of a sliding layer.
- the specimens produced under the same compression conditions at 135° C. show differences in the space densities between the zero mixtures on the one hand and the mixtures with additives on the other. Therewith they give an indication of the relations in mixed goods structures.
- Creep tests at 40° C. give information in regard to the resistance to deformation of the mixed goods. They refer in this connection to the ratios in service with elevated outside temperatures.
- German priority application No. P 29 33 339.9-44 is hereby incorporated by reference.
- road is intended to include streets, bike paths, sidewalks, and other surfaces for vehicle or pedestrian use.
Abstract
Powdery bitumen concentrates are prepared containing 10 to 85 weight %, preferably 40 to 80 weight %, of synthetic silica. The concentrate is used in asphalt mixtures for building roads to give high stiffening value thereto.
Description
According to DIN 55946 (German Industrial Standard 55946) bitumens are a dark colored, semisolid to brittle, meltable, high molecular weight hydrocarbon mixtures which are obtained in the careful refining of petroleums and the portion of the natural asphalts as well as mineral wax and montan wax soluble in carbon disulfide (see Rompp Lexikon der Chemie, 7th Edition, page 377).
These kinds of materials which in the Anglo-Saxon region (above all the U.S.A.) are designated as asphalt are employed admixed with limestone powder, granite powder, basalt powder, greenstone powder and gabbro powder in the building of streets.
In this connection of especial significance is the use of natural asphalt.
Natural asphalt can be employed in admixture with bituminous binders according to DIN 1995 for the production of mortar rich coating layers (e.g., cast asphalt, asphalt concrete, sand asphalt and asphalt mastic). A natural asphalt of this type is, e.g., Trinidad-Epure (Trinidad-refined) which has the following composition:
______________________________________
Soluble bitumen 53 to 55 weight %
Mineral portion 36 to 37 weight %
Residual constituents
9 to 10 weight %
______________________________________
(compare Handbuch fur Strassenwesen Planung-Bau-Verkehr-Betrieb 1979, Otto Elsner Verlagsgesellschaft, Darmstadt).
Trinidad-Epure as well as the other known natural asphalts have the disadvantage that in spite of the very high filler content they are solid and must be melted before use.
According to the invention there is prepared a powder (or pulverulent) bitumen concentrate containing 10 to 85 weight %, preferably 40 to 80 weight %, of synthetic silica.
As synthetic silicas there can be used precipitated silica as well as pyrogenically produced silica.
The precipitated silica can have a BET-surface area of 120 to 500 m2 /g. In a given case it can be ground by a steam jet, spray dried or spray dried and ground.
The pyrogenically produced silica can have a BET-surface area of 100 to 400 m2 /g.
The bitumen concentrate of the invention can be produced by simply mixing the liquid bitumen with the synthetic silica or spraying the liquid bitumen on the synthetic silica.
The bitumen concentrate of the invention has the advantage that in spite of the high proportion of bitumen it is powdery, temperature stable and flowable.
Furthermore according to another aspect of the invention, the use of the powdery bitumen concentrate in asphalt mixture for building roads, results in a surprisingly high stiffening effect.
The powdery bitumen concentrate of the invention is described in more detail in the following examples.
The process can comprise, consist essentially of or consist of the steps set forth with the stated materials.
Unless otherwise indicated all parts and percentages are by weight.
For the production of powdery bitumen concentrate there was carried out the following operation:
1. Heat the particular silica and the bitumen to 140° C. in the drying oven. 2. There is present in the mixing vessel the weighed out amount of silica. Add the bitumen in portions with stirring (by hand or with a wing stirrer according to the amount), powerful subsequent mixing until visible homogenization. 3. Bringing out the still hot composition into a sheet, spreading until cooling to room temperature. 4. The cold, friable to granulate type composition is disintegrated and ground in the Braun mixer. 5. The powder is placed on a 0.75 mm sieve, sieved, homogenized in the glass container in a Turbula mixer.
The bulk density of the powders in each case was determined (g/cm3). In order to find an indication of the storage stability there were carried out pressure testings over 36 hours in pressure cylinders (diameter 49 mm, impressions 3.2 kp=1.7 N/cm2 and 11.2 kp=5.95 N/cm2) at normal temperature. The recording was according to the school annotation system. The results are compiled in Table 1.
In order to check the temperature stability of the individual bitumen powders, in each case the samples were tempered at increasing temperature in the drying oven (increasing in each case around 10° C. to 20° C.). The results are compiled in Table 2.
TABLE 1
______________________________________
Bulk Pressure Testing
Density 1.7
Sample Designation
g/cm.sup.3
N/cm.sup.2
5.95 N/cm.sup.2
Notes
______________________________________
50% B 80 (bitumen) dry
50% SIPERNAT 22
0.349 3 3-4 powder
60% B 80 (bitumen) dry
40% SIPERNAT 22
0.373 4 4-5 powder
66.7% B 80 (bitumen) dry
33.3% SIPERNAT 22
0.437 4 5 powder
70% B 80 (bitumen) dry
30% SIPERNAT 22
0.440 4 5 powder
80% B 80 (bitumen) dry
20% SIPERMAN 22
0.459 5 6 powder
60% B 80 (bitumen) dry
40% FK 320 0.450 4 5 powder
66.7% B 80 (bitumen) dry
33.3% FK 320 DS
0.578 5 6 powder
______________________________________
The determination of the bulk density was according to DIN 53 194.
3=satisfactory--loosely shaped, with slight finger pressure substantially powdery disintegration
4=adequate--loosely adhered together, still most finely disintegrated with finger pressure
5=imperfect--semisolidly adhered together, no longer most finely disintegrated with finger pressure
6=insufficient--solidly adhered together.
A detailed description of this procedure for evaluation is found in Seifen-Ole-Fette-Wachse 8900 Augsburg, Year 94/1968, Part 12, pages 849-858.
A special printing of this literature appears as No. 31 in the series of pigment publications of the firm Degussa.
TABLE 2
__________________________________________________________________________
1 hour
1 hour 1 hour
14 hours
1 hour
1 hour
1 hour
Sample Designation
Start 80° C.
90° C.
100° C.
120° C.
140° C.
160° C.
1880° C.
__________________________________________________________________________
50% B 80 gray-brown
gray-brown
gray-brown
gray-
light
light
light
light
brown
beige
beige
beige
brown
50% SIPERNAT 22
loose loose loose loose
loose
loose
loose
loose
60% B 80 gray gray gray gray beige
beige
medium
brown
brown
40% SIPERNAT 22
loose loose loose loose
loose
loose
loose
loose
66.7% B 80 gray gray light brown
medium
dark dark dark black
brown
brown
brown
brown
33.3% SIPERNAT 22
loose loose loose loose
loose
lightly
adhered
adhered
adhered
together
together
together
70% B 80 gray gray light brown
medium
dark dark dark black
brown
brown
brown
brown
30% SIPERNAT 22
loose loose loose loose
loose
lightly
adhered
adhered
adhered
together
adhered
together
80% B 80 gray brown dark brown
dark black
black
black
black
brown
20% SIPERNAT 22
loose loose lightly adhered
adhered
adhered
adhered
adhered
adhered
together
together
together
together
together
together
60% B 80 gray gray light brown
brown
light
brown
brown
dark
brown brown
40% FK 320 loose loose loose loose
lightly
lightly
adhered
adhered
adhered
adhered
together
together
together
together
66.7% B 80 gray-brown
gray-brown
medium brown
brown
brown
dark dark black
brown
brown
33.3% FK 320 DS
loose loose loose loose
lightly
adhered
adhered
adhered
adhered
together
together
together
together
__________________________________________________________________________
The silica FK 320 used is a precipitated silica with the following physical chemical properties:
______________________________________
Apperance loose, white powder
X-ray structure amorphous
Surface area 170 m.sup.2 /g (according to BET)
Average size of the
primary particles
18 nanometer
Specific gravity
2.05 g/ml
Degree of purity
SiO.sub.2.sup.(6) 98%
Na.sub.2 O.sup.(6) 1%
Al.sub.2 O.sub.3.sup.(6) 0.2%
SO.sub.3.sup.(6) 0.8
Loss on drying.sup.(1)
6%
Loss on ignition.sup.(2)(3)
5%
pH.sup.(4) 6.3%
Solubility practically insoluble in water
Characteristics precipitated silica
Tamped density.sup.(5)
200 g/l
Sieve residue according
to Mocker (DIN 53 580)
0.2%
______________________________________
.sup.(1) DIN 53 198, Method A
.sup.(2) Based on the material dried for 2 hours at 105° C. DIN 55
921
.sup.(3) DIN 52 911
.sup.(4) DIN 53 200
.sup.(5) DIN 53 194
.sup.(6) Based on the material ignited for 2 hours at 1000° C.
A silica 320 DS is a precipitated and steam jet ground silica having the following physical chemical properties:
______________________________________
Appearance loose, white powder
X-ray structure amorphous
Surface area 170 m.sup.2 /g (according to BET)
Average size of the
primary particles
18 nanometer
Specific gravity
2.05 g/ml
Degree of purity
SiO.sub.2.sup.(6) 98%
Na.sub.2 O.sup.(6) 1%
Al.sub.2 O.sub.3.sup.(6) 0.2%
SO.sub.2.sup.(6) 0.8
Loss on drying.sup.(1)
6%
Loss on ignition.sup.(2)(3)
5%
pH.sup.(4) 6.3%
Solubility practically insoluble in water
Characteristics precipitated silica having a
high fineness of grinding
Tamped density.sup.(5)
70 g/l
Sieve residue according
to Mocker (DIN 53 580)
0%
______________________________________
.sup.(1) DIN 53 198, Method A
.sup.(2) Based on the material dried for 2 hours at 105° C.
.sup.(3) DIN 52 911
.sup.(4) DIN 53 200
.sup.(5) DIN 53 194
.sup.(6) Based on the material calcined at 1000° C. for 2 hours
The silica Sipernat 22 is a precipitated and spray dried silica having the following physical-chemical properties:
______________________________________
Surface area according to BET
m.sup.2 /g
190
Average size of the primary particles
nanometer 18
Average size of the secondary particles
micrometer
80
Tamped density (DIN 53 194)
g/l 220
Loss on drying (DIN 55 921)
(2 hours at 105° C.)
% 6
Loss on ignition.sup.(1) (DIN 55 921)
(2 hours at 1000° C.)
% 5
pH (DIN 53 200) 6.3
SiO.sub.2 (DIN 55 921)
% 98
Al.sub.2 O.sub.3 % 0.2
Fe.sub.2 O.sub.3 % 0.03
Na.sub.2 O % 1
So.sub.3 % 0.8
Sieve residue according to Mocker
(DIN 53 580) % 0.5
Oil number (according to DIN 53 199)
g/100 g
______________________________________
.sup.(1) Based on the material dried for 2 hours at 105° C.
.sup.(2) In water: acetone or methanol 1:1
.sup.(3) Based on the material ignited for 2 hours at 1000° C.
.sup.(4) Contains about 2% chemically bound carbon
In connection therewith there are concerned the following materials and combinations of materials:
Sipernat 22
B 80 to Sipernat 22 (50/50), powder
Natural asphalt-Trinidad Epure, non-comminuted
The additives were added in the laboratory to the mixtures of an asphalt concrete 0/11 mm suited for use in the classified road construction. In this connection in consideration of the amounts of crushed rock and binders contained in the additives the remaining composition of the mixtures are the same.
As binder for a comparison mixture and the mixture with additives road construction bitumen B 80 there is provided for a second comparison mixture road construction bitumen B 65.
The following tests were undertaken:
1. Production of specimens according to Marshall from the various asphalt mixtures.
2. Determination of space density, hollow space content, as well as stability and flow value according to Marshall on the specimens according to 1.
3. Carrying out creep tests on every three specimens produced according to 1.
There were used for the mineral mixture for the production of an asphaltic concrete 0/11 mm according to TV bit 3/72 full of chips of basalt rich chips, basalt rich broken sand, a natural sand and a commercial limestone powder. The mineral materials with the exception of the limestone powder were sieved in particle classes and the mineral mixtures again combined according to a provided recipe.
Portion above 2.0 mm: basalt rich chips 2/5, 5/8 and 8/11
Sand 0.09/2.0 mm: basalt rich broken sand and natural sand (in the ratio 3:1)
Filler 0/0.09 mm: limestone powder, basalt true filler+additive
Therewith for all mixtures there was reached the following particle size distribution of the mineral mixture:
______________________________________ Sieve Passage: ______________________________________ 0.09 0.25 0.71 2.0 5.0 8.0 11.2 mm 8.6 15.0 25.0 40.0 67.0 84.0 100.0 weight % ______________________________________
The binder content of all mixtures was 5.9 weight %.
Table 3 gives a summary of the composition of the mixtures.
Asphalt mixtures were mixed in batches of 6,300 grams or 4,000 grams in the laboratory mixture while maintaining a homegeneous discharge.
The powdery additives were brought into the hot mixture according to the proportion of bitumen but before the limestone powder.
The corresponding amount of Trinidad-Epure was melted and added in advance to the bitumen portion.
No peculiarities were observed in the asphalt mixtures. In all cases there resulted a homogeneously encased, normal appearing mixed goods.
There were produced from each mixture variant 5+3=8 specimens according to Marshall.
TABLE 3
__________________________________________________________________________
Binder
Additive From
Amount additive
Original
Total
(parts by
Type (parts by
(parts by
(parts by
Mixture
Type of Additive
weight)
(original)
weight)
weight)
weight %)
__________________________________________________________________________
1 -- -- B 65 -- 6.27 5.9
2 -- -- B 80 -- 6.27 5.9
3 SIPERNAT 22 0.5 B 80 -- 6.27 5.9
8 TRINIDAD-EPURE
2.0 B 80 1.1 5.17 5.9
9 SIPERNAT with B 80
2.0 B 80 1.0 5.27 5.9
(Powder 50/50)
__________________________________________________________________________
Mineral
From From True
Additive
Granulation
Limestone
Filler
Sand Chips
(parts by
(parts by
(parts by
(parts by
(parts by
(parts by
Mixture
weight)
weight)
weight)
weight)
weight)
weight)
__________________________________________________________________________
1 -- 100 6.0 2.6 31.4 60
2 -- 100 6.0 2.6 31.4 60
3 0.5 99.5 5.5 2.6 31.4 60
8 0.9 99.1 5.1 2.6 31.4 60
9 1.0 99.0 5.0 2.6 31.4 60
__________________________________________________________________________
Of the eight specimens three were used for determination of stability and flow value, and three for the creep test.
Space density and hollow space content were ascertained on all specimens.
The results are collected in Table 4.
There were carried out at 3 specimens of each mixture creep tests with static load. Thereby the bases of the specimens were evened up through a compensating layer.
In the test there was applied to the specimen at a testing temperature of 40° C. a uniform surface load.
The uniaxial compressive strength was 0.1 MN/m2. The formation of the uniaxial strength state was promoted by arrangement of a sliding layer. The resulting compressions Σ=Δh/h×1,000 in .permill. were plotted in the double logarithmic scale, so that the function of the tensions could be recognized from the time after 1 to 5 hours of an asymptotic end value.
From the transition t→∞ there can be derived a final tension and a strain modulus Smix as material index of the logarithm.
The final tension and the strain modulus are compiled in Table 5.
TABLE 4
__________________________________________________________________________
Test Results on Specimens According to Marshall
Hollow Space
Content
In the
Space
Raw In the
Mineral
Degree of Flow
Density
Density
Asphalt
Framework
Packing
Stability
Value
Mixture
g/cm.sup.3
g/cm.sup.3
Vol. %
Vol. %
% kN mm
__________________________________________________________________________
1 2,569
2,635
2.50 17.3 85.5 7.6 6.0
2 2,570
2,635
2.47 17.3 85.7 6.9 5.3
3 2,561
2,635
2.81 17.6 84.0 7.5 5.9
8 2,561
2,635
2.81 17.6 84.0 7.0 6.0
9 2,556
2,635
3.00 17.7 83.1 7.7 5.9
__________________________________________________________________________
TABLE 5
______________________________________
Results of Creep Tests
Strain Modulus
Mixture .permill.Final Tension
##STR1##
______________________________________
1 5.8 17.2
2 6.2 16.2
3 5.6 17.9
8 6.1 16.5
9 5.6 17.8
______________________________________
The mixtures with additives (3, 8, 9) do not differ in behavior and appearance with the mixes without additives (1, 2)
Peculiarities were not established compared to normally mixed goods.
The specimens produced under the same compression conditions at 135° C. show differences in the space densities between the zero mixtures on the one hand and the mixtures with additives on the other. Therewith they give an indication of the relations in mixed goods structures.
In the laboratory tests the compression resistance of the mixed goods characterized by the hollow space proportion increased at 135° C. both with addition of SIPERNAT 22 and also Trinidad-Epure, i.e., both additives cause stiffening.
The greatest effect was produced by the addition of Sipernat/bitumen powder (Mixture 9), in which case it should be observed that the Sipernat portion in the total mixture is once again increased compared to Mixture 3. An interesting comparison is offered by Mixture 9 and Mixture 8 (Trinidad-Epure), since in both cases there are added mineral material/binder combinations with quantitatively about the same ratios. Based on the results it can be established that the stiffening produced by Trinidad-Epure is exceeded by the synthetically produced products.
Creep tests at 40° C. give information in regard to the resistance to deformation of the mixed goods. They refer in this connection to the ratios in service with elevated outside temperatures.
The results of the laboratory tests clearly show increases of the decisive strain modulus (Deformation Modulus) of the mixtures with SIPERNAT 22. (Mixtures 3 and 9) compared to the comparison mixture with B 80 (Mixture 2), with simultaneous reduction of the corresponding final tensions.
The results of the creep tests at 40° C. show that an equal increase of the resistance to deformation of the mixture with Trinidad-Epure.
The entire disclosure of German priority application No. P 29 33 339.9-44 is hereby incorporated by reference.
As used in the claims the term road is intended to include streets, bike paths, sidewalks, and other surfaces for vehicle or pedestrian use.
Claims (11)
1. A powdery bitumen concentrate having 40 to 80% of synthetic silica wherein the synthetic silica is precipitated silica having a BET surface area of 120 to 500 m2 /g or pyrogenically produced silica having a BET surface area of 100 to 400 m2 /g.
2. A powdery bitumen concentrate according to claim 1 wherein the synthetic silica has an average primary particle size of about 18 nanometers.
3. A powdery bitumen concentrate according to claim 1 containing 40 to 50% of synthetic silica.
4. A powdery bitumen concentrate according to claim 1 wherein the synthetic silica is precipitated silica having a BET surface area of 120 to 500 m2 /g.
5. A powdery bitumen concentrate according to claim 1 wherein the synthetic silica is pyrogenically produced silica having a BET surface area of 100 to 400 m2 /g.
6. An asphalt composition suitable for constructing a street comprising the bitumen concentrate of claim 1 and asphalt.
7. An asphalt composition suitable for constructing a street comprising the bitumen concentrate of claim 4 and asphalt.
8. An asphalt composition suitable for constructing a street comprising the bitumen concentrate of claim 5 and asphalt.
9. In a bitumen concentrate and asphalt containing road the improvement comprising having present as the bitumen concentrate the bitumen-silica composition of claim 1.
10. In a bitumen concentrate and asphalt containing road the improvement comprising having present as the bitumen concentrate the bitumen-silica composition of claim 4.
11. In a bitumen concentrate and asphalt containing road the improvement comprising having present as the bitumen concentrate the bitumen-silica composition of claim 5.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2933339A DE2933339C2 (en) | 1979-08-17 | 1979-08-17 | Bitumen concentrate in powder form and its uses |
| DE2933339 | 1979-08-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4378999A true US4378999A (en) | 1983-04-05 |
Family
ID=6078673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/175,742 Expired - Lifetime US4378999A (en) | 1979-08-17 | 1980-08-06 | Pulverulent bitumen concentrate and its use |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4378999A (en) |
| EP (1) | EP0024513B1 (en) |
| JP (1) | JPS5636547A (en) |
| AT (1) | ATE8404T1 (en) |
| CA (1) | CA1147102A (en) |
| DE (2) | DE2933339C2 (en) |
| DK (1) | DK175780A (en) |
| FI (1) | FI71945C (en) |
| NO (1) | NO154922C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU585012B2 (en) * | 1985-05-09 | 1989-06-08 | Degussa A.G. | A powder-form binder concentrate |
| US5053279A (en) * | 1988-08-04 | 1991-10-01 | Degussa Aktiengesellschaft | Granular bitumen coated with carbon black or silica |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1983000700A1 (en) * | 1981-08-25 | 1983-03-03 | Karl Gunnar Ohlson | Method and apparatus for the production of asphalt concrete |
| DE3505051A1 (en) * | 1985-02-14 | 1986-08-21 | Degussa Ag, 6000 Frankfurt | POWDERED BITUMEN CONCENTRATE AND ITS USE |
| DE3535581A1 (en) * | 1985-10-05 | 1987-04-16 | Degussa | BITUMEN RAILWAYS, PREFERRED ELASTICALLY MODIFIED BITUMEN RAILWAYS AND POLYMER BITUMEN RAILWAYS |
| DE3736215A1 (en) * | 1987-10-26 | 1989-05-03 | Juergen Dipl Chem Dr Kuether | Pourable, loose bitumen mixture, process for the preparation thereof, and the use thereof |
| JPH01281566A (en) * | 1988-05-09 | 1989-11-13 | Sanyo Electric Co Ltd | Automatic sales system for automatic food processing and cooking |
| JPH01281567A (en) * | 1988-05-09 | 1989-11-13 | Sanyo Electric Co Ltd | Automatic vending machine for automatic food processing and cooking |
| JPH01281568A (en) * | 1988-05-09 | 1989-11-13 | Sanyo Electric Co Ltd | Automatic vending machine for automatic food processing and cooking |
| DE3942215A1 (en) * | 1989-12-21 | 1991-06-27 | Degussa | BITUMEN GRANULATE AND METHOD FOR THE PRODUCTION THEREOF |
| US6197852B1 (en) | 2000-02-28 | 2001-03-06 | Equistar Chemicals, Lp | Polyolefin concentrates and composition having improved carbon black dispersion |
| EP3105291B1 (en) * | 2014-02-12 | 2017-12-27 | Rubbertec Technologie Engineering AG | Method for producing a rubber modified bitumen |
| CH719365A1 (en) * | 2022-01-18 | 2023-07-31 | NewRoad AG | Use of a fuel to operate a heating device. |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2949378A (en) * | 1953-12-08 | 1960-08-16 | Nynaes Petroleum Ab | Asphalt compositions |
| US3766074A (en) * | 1972-09-15 | 1973-10-16 | Us Navy | Magnetically pigmented paint |
| US3920470A (en) * | 1972-05-05 | 1975-11-18 | Cimescaut | Composition based on bitumen and a filler |
| US4100059A (en) * | 1975-12-11 | 1978-07-11 | Michio Jinno | Asphalt recycle system |
| US4189238A (en) * | 1975-08-11 | 1980-02-19 | Mendenhall Robert Lamar | Recycled asphalt-aggregate process and apparatus |
| GB2009758B (en) | 1977-12-13 | 1982-09-22 | Degussa | Process for mineral asphaltic surfacings for road and highway construction |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2438330C2 (en) * | 1974-08-09 | 1982-11-11 | Trinidad Lake Asphalt, Handelsgesellschaft Wilh. Asche & Co, 2800 Bremen | Free-flowing asphaltite and process for its production |
| DE2848583C2 (en) * | 1978-11-09 | 1982-09-16 | Degussa Ag, 6000 Frankfurt | Mastic asphalt mix |
| DE2919444C2 (en) * | 1979-05-15 | 1983-03-03 | Wibau Industrie und Verwaltung GmbH, 6466 Gründau | Process for the preparation of pourable and / or compactable asphalt concrete masses for the production of flat ceiling coverings and flat screed coverings in buildings |
-
1979
- 1979-08-17 DE DE2933339A patent/DE2933339C2/en not_active Expired
-
1980
- 1980-04-18 FI FI801246A patent/FI71945C/en not_active IP Right Cessation
- 1980-04-24 DK DK175780A patent/DK175780A/en not_active Application Discontinuation
- 1980-04-25 NO NO801212A patent/NO154922C/en unknown
- 1980-07-08 DE DE8080103875T patent/DE3068513D1/en not_active Expired
- 1980-07-08 AT AT80103875T patent/ATE8404T1/en not_active IP Right Cessation
- 1980-07-08 EP EP80103875A patent/EP0024513B1/en not_active Expired
- 1980-07-15 CA CA000356174A patent/CA1147102A/en not_active Expired
- 1980-08-06 US US06/175,742 patent/US4378999A/en not_active Expired - Lifetime
- 1980-08-18 JP JP11276980A patent/JPS5636547A/en active Granted
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2949378A (en) * | 1953-12-08 | 1960-08-16 | Nynaes Petroleum Ab | Asphalt compositions |
| US3920470A (en) * | 1972-05-05 | 1975-11-18 | Cimescaut | Composition based on bitumen and a filler |
| US3766074A (en) * | 1972-09-15 | 1973-10-16 | Us Navy | Magnetically pigmented paint |
| US4189238A (en) * | 1975-08-11 | 1980-02-19 | Mendenhall Robert Lamar | Recycled asphalt-aggregate process and apparatus |
| US4100059A (en) * | 1975-12-11 | 1978-07-11 | Michio Jinno | Asphalt recycle system |
| GB2009758B (en) | 1977-12-13 | 1982-09-22 | Degussa | Process for mineral asphaltic surfacings for road and highway construction |
Non-Patent Citations (1)
| Title |
|---|
| The Chemistry of Silica, by Ralph K. Oler, p. 25. * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU585012B2 (en) * | 1985-05-09 | 1989-06-08 | Degussa A.G. | A powder-form binder concentrate |
| US5053279A (en) * | 1988-08-04 | 1991-10-01 | Degussa Aktiengesellschaft | Granular bitumen coated with carbon black or silica |
Also Published As
| Publication number | Publication date |
|---|---|
| NO801212L (en) | 1981-02-18 |
| JPS5714778B2 (en) | 1982-03-26 |
| JPS5636547A (en) | 1981-04-09 |
| DK175780A (en) | 1981-02-18 |
| NO154922C (en) | 1987-01-14 |
| DE3068513D1 (en) | 1984-08-16 |
| FI71945C (en) | 1987-03-09 |
| FI71945B (en) | 1986-11-28 |
| FI801246A (en) | 1981-02-18 |
| NO154922B (en) | 1986-10-06 |
| ATE8404T1 (en) | 1984-07-15 |
| EP0024513A1 (en) | 1981-03-11 |
| CA1147102A (en) | 1983-05-31 |
| DE2933339A1 (en) | 1981-02-26 |
| EP0024513B1 (en) | 1984-07-11 |
| DE2933339C2 (en) | 1982-04-22 |
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