US4001034A - High temperature coatings based on poly (zinc phosphinates) - Google Patents

High temperature coatings based on poly (zinc phosphinates) Download PDF

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US4001034A
US4001034A US05/627,808 US62780875A US4001034A US 4001034 A US4001034 A US 4001034A US 62780875 A US62780875 A US 62780875A US 4001034 A US4001034 A US 4001034A
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coating
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Joseph Simkin
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United States Department of the Air Force
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/14—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing two or more elements other than carbon, oxygen, nitrogen, sulfur and silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints

Definitions

  • This invention relates to thermally resistant coating materials.
  • this invention concerns itself with high temperature coating materials based on poly (zinc phosphinates) and to a method for preparing such coatings.
  • poly(zinc phosphinates) possess the high thermal stability required for use with supersonic vehicles.
  • Poly(metal phosphinates) are a family of polymers based on an inorganic backbone formed by metal atoms connected by --OPO-- bridges. Because the metal centers in the poly(metal phosphinates) are surrounded by oxygen atoms, the polymer backbone is particularly resistant to oxidative degradation, and, as a rule, the polymers are very stable thermally.
  • the metal phosphinates found to be most stable and useful as a coating material are the metal phosphinates in which zinc is the central atom. They possess an inherent thermal stability that makes them especially useful for high temperature applications in many areas of technology.
  • Zn[OP(Me)(Ph)O] 2 is one of the few zinc phosphinates that are appreciably soluble in organic solvents and melt at a reasonable temperature, but the coatings obtainable to date have been unsatisfactory because of pinhole formation. Moreover, this composition is less thermally stable than others of the same type. The zinc phosphinates which show the greatest thermal stability are practically insoluble or poorly soluble in common solvents and do not melt at a reasonable point below their decomposition temperatures.
  • Zn[OPh 2 O] 2 is insoluble in common solvents and as a result cannot be utilized as a binder for high temperature coatings.
  • Zn[OP(C 6 H 4 SO 2 Ph) (Ph)O] 2 is practically insoluble in common solvents and required a proportionally large amount of strong coordinating solvents such as dimethyl formanide for disolution.
  • coating materials based on poly(zinc phosphinates) can be used effectively as high temperature coatings on supersonic vehicles. Previous attempts at using these materials as coatings were not fruitful because of a lack of suitable solvents for the phosphinates. This problem was circumvented, however, by the present invention which involves an in-situ reaction between starting materials soluble in a non-aqueous solvent system.
  • Zn[OPPh 2 O] 2 is insoluble in a mixture of MeOH and benzene, but a mixture of ZnCl 2 and Ph 2 P(O)OH was found to be soluble in such a solvent system.
  • this solution is sprayed onto a surface, the resultant residue, after evaporation of solvent, is essentially Zn[OPPh 2 O] 2 , and none of the byproduct is present after curing.
  • a blend consisting of TiO 2 and containing ZnCl 2 , Ph(PhSO 2 C 6 H 4 )P(O)OH, and Me(Ph)P(O)OH was dispersed in a solvent mixture.
  • a formulation containing 20 percent solids gave coatings with satisfactory hardness, integrity, and appearance.
  • the coating thickness was approximately 1-1.5 mil, and the weight of the coating per panel averaged 0.35 g.
  • the coating properties were independent of the cure temperatures, which ranged from ambient to 150° C. Analysis of scrapings from the coating indicates that no chloride is present in the "cured" product. During exposure to 1000° F (538° C) in air for 2 hours the coating apparently undergoes a partial oxidation. It first turns dark and then gradually becomes white again. The resulting coating is ceramic-like in appearance, possesses excellent hardness, and shows no visible mudcracking or loss of coating integrity.
  • the primary object of this invention is to develop a technique for utilizing thermally stable poly(zinc phosphinates) as high temperature coatings.
  • Another object of this invention is to provide a method for fabricating coating materials that can be cured at low temperatures and possess thermal stability up to 1000° F.
  • Zn(OPPh 2 O) 2 for example, first decomposes at 475° C when heated in air in a thermal balance.
  • Zn[OP(Me)(Ph)O] 2 is one of the few zinc phosphinates that are appreciably soluble in organic solvents and melt at a reasonable temperature, but the coatings obtainable to date have been unsatisfactory because of pinhole formation. Moreover, this composition is less thermally stable than others of the same type (Table 1). The zinc phosphinates which show the greatest thermal stability are insoluble or poorly soluble in common solvents and do not melt at a reasonable point below their decomposition temperature.
  • Zn[OPPh 2 O] 2 is insoluble in common solvents and as a result, cannot be utilized as a binder for high temperature coatings.
  • Zn[OP(C 6 H 4 SO 2 Ph)(Ph)O] 2 for example, is practically insoluble in common solvents and requires a proportionally large amount of strong coordinating solvents such as dimethyl formide for dissolution.
  • Preparations attempted from a solution of Zn[OP(C 6 H 4 SO 2 Ph)PhO] 2 in 15 parts DMF and 35 parts C 6 H 6 result in coatings with poor integrity and pinholes.
  • This invention provides a novel procedure for the preparation of coatings utilizing zinc phosphinates which were heretofore impossible to use because of poor solubility.
  • the use of zinc phosphinates has been made possible by an in-situ preparation with ingredients soluble in common solvents.
  • Such formulations are surprisingly stable in solution and do not show any supersaturation or tendency to precipitate even though the reaction products would be expected to be insoluble.
  • Zn[OPPh 2 O] 2 is insoluble in a mixture of MeOH and benzene, but a mixture of ZnCl 2 and Ph 2 P(O)OH was found to be soluble in such a solvent system.
  • this solution is sprayed onto a surface, the resultant residue, after evaporation of solvent, is essentially Zn[OPPh 2 O] 2 , and none of the byproduct is present after curing.
  • the chemical reaction is shown by equation (1) as follows:
  • the example details the preparation of a coating on titanium alloy that is essentially Zn[OP(C 6 H 4 SO 2 P 6 H 5 ) (Ph)O] 2 and that is of satisfactory physical appearance.
  • the ZnCl 2 (95% assay), (PhSO 2 C 6 H 4 )(Ph) -- P(O)OH, and Me(Ph)P(O)OH were dispersed in a solvent mixture of dimethyl formamide, MeOH, and benzene. Warming the dispersion on a hot plate (35° to 40° C) for several minutes gave a clear pale yellow solution.
  • the titanium dioxide pigment was then added to the solution together with an appropriate amount of ceramic grinding stones.
  • the dispersion was then ground by rolling on a rolling mill for 6 hours, decanted from the grinding stones, and sprayed onto a titanium alloy sheet.
  • the coating which resulted after evaporation at room temperature set to touch in an hour. An additional 15 hours at ambient temperature gave a coating which is hard and shows good integrity and adhesion. Hardness may be enhanced even further by curing at 150° to 200° C for 2 hours.
  • R and R' are alkyl or aryl substituents.
  • the titanium alloy Ti-6Al-4v is accepted in the industry and is known for its poor coating adhesion, it was selected as the standard metal to be used in evaluating the coating materials of this invention.
  • the formulation of the above example was used to spray eleven 3 in. by 2 in. panels and eight 2 in. by 1 in. panels of the titanium alloy.
  • the amount of dry coating found (2 hours at 150° C) averaged 0.16 g per panel or 2.8 g/ft 2 .
  • the panels were first cleaned in accordance with conventional techniques.
  • Duplicate panels for each formulation were placed in a furnace held at 350° C (662° F). The panels were removed after 23 hours and permitted to cool at ambient room temperature for one hour. Observations and physical measurements were made on the heated panels after they reached room temperature (usually within 35 to 45 minutes after removal from furnace). This cycle was repeated three more times, and the panels were then heated for 71 hours to terminate the run at a total heating time of 163 hours.

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  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
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  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

A high temperature coating composition composed of a solvent mixture of zinc chloride, titanium dioxide, and an organo-substituted phosphinic acid.

Description

STATEMENT OF GOVERNMENT INTEREST
The invention described herein may be manufactured and used by and for the Government for governmental purposes without the payment of any royalty thereon.
BACKGROUND OF THE INVENTION
This invention relates to thermally resistant coating materials. In a more particular aspect, this invention concerns itself with high temperature coating materials based on poly (zinc phosphinates) and to a method for preparing such coatings.
The recent advent of supersonic vehicles has created a need for coating materials resistant to the high skin temperatures that are generated within the operational environment of such vehicles. Conventional protective coatings, based upon drying oils and resins such as linseed oil and alkyds, are useful only at moderately elevated temperatures. Progress has been made on extending the thermal tolerance of coatings by the development of systems utilizing organic polymers based upon condensed units with highly conjugated double bonds. Additional improvements have been made with organosilicone-based coatings. However, current temperature requirements are even higher, and coatings resistant to thermal and oxidative degradation up to 1000° F in air are needed.
An attempt to provide a solution to the need for high temperature coatings indicated that coating compositions based on poly(zinc phosphinates) possess the high thermal stability required for use with supersonic vehicles. Poly(metal phosphinates) are a family of polymers based on an inorganic backbone formed by metal atoms connected by --OPO-- bridges. Because the metal centers in the poly(metal phosphinates) are surrounded by oxygen atoms, the polymer backbone is particularly resistant to oxidative degradation, and, as a rule, the polymers are very stable thermally. Among the polymer compositions found to be most stable and useful as a coating material are the metal phosphinates in which zinc is the central atom. They possess an inherent thermal stability that makes them especially useful for high temperature applications in many areas of technology.
At the present time, however, few of these materials are capable of facile conversion into coatings by standard preparative methods such as from a melt or by deposition from a solvent. Zn[OP(Me)(Ph)O]2 is one of the few zinc phosphinates that are appreciably soluble in organic solvents and melt at a reasonable temperature, but the coatings obtainable to date have been unsatisfactory because of pinhole formation. Moreover, this composition is less thermally stable than others of the same type. The zinc phosphinates which show the greatest thermal stability are practically insoluble or poorly soluble in common solvents and do not melt at a reasonable point below their decomposition temperatures. Zn[OPh2 O]2 is insoluble in common solvents and as a result cannot be utilized as a binder for high temperature coatings. Zn[OP(C6 H4 SO2 Ph) (Ph)O]2 is practically insoluble in common solvents and required a proportionally large amount of strong coordinating solvents such as dimethyl formanide for disolution. Preparations attempted from a solution of Zn[OP(C6 H4 SO2 Ph)PhO]2 in 15 parts DMF and 35 parts C6 H6 result in coatings with poor integrity and pinholes.
An attempt to overcome these problems led to the discovery that the preparation of coatings utilizing zinc phosphinates that were heretofore impossible to use because of poor solubility or intractability can be accomplished by an in-situ preparation with ingredients soluble in common solvents. Such formulations are surprisingly stable in solution and do not show any supersaturation or tendency to precipitate even though the reaction products would be expected to be insoluble.
SUMMARY OF THE INVENTION
In accordance with this invention, it has been found that coating materials based on poly(zinc phosphinates) can be used effectively as high temperature coatings on supersonic vehicles. Previous attempts at using these materials as coatings were not fruitful because of a lack of suitable solvents for the phosphinates. This problem was circumvented, however, by the present invention which involves an in-situ reaction between starting materials soluble in a non-aqueous solvent system.
For example, Zn[OPPh2 O]2 is insoluble in a mixture of MeOH and benzene, but a mixture of ZnCl2 and Ph2 P(O)OH was found to be soluble in such a solvent system. When this solution is sprayed onto a surface, the resultant residue, after evaporation of solvent, is essentially Zn[OPPh2 O]2, and none of the byproduct is present after curing.
In still another example, a blend consisting of TiO2 and containing ZnCl2, Ph(PhSO2 C6 H4)P(O)OH, and Me(Ph)P(O)OH was dispersed in a solvent mixture. A formulation containing 20 percent solids gave coatings with satisfactory hardness, integrity, and appearance. The coating thickness was approximately 1-1.5 mil, and the weight of the coating per panel averaged 0.35 g. The coating properties were independent of the cure temperatures, which ranged from ambient to 150° C. Analysis of scrapings from the coating indicates that no chloride is present in the "cured" product. During exposure to 1000° F (538° C) in air for 2 hours the coating apparently undergoes a partial oxidation. It first turns dark and then gradually becomes white again. The resulting coating is ceramic-like in appearance, possesses excellent hardness, and shows no visible mudcracking or loss of coating integrity.
Accordingly, the primary object of this invention is to develop a technique for utilizing thermally stable poly(zinc phosphinates) as high temperature coatings.
Another object of this invention is to provide a method for fabricating coating materials that can be cured at low temperatures and possess thermal stability up to 1000° F.
The above and still other objects and advantages of the present invention will become more readily apparent upon consideration of the following detailed description thereof.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Poly(zinc phosphinates) possess a relatively high degree of thermal stability by virtue of inorganic backbones in which metal atoms are connected by "--OPO--" bridges. Zn(OPPh2 O)2, for example, first decomposes at 475° C when heated in air in a thermal balance. Thermogravimetric data on this and other phosphinates are given in Table 1.
                                  Table 1.                                
__________________________________________________________________________
TGA                                                                       
                    Temperature ° C wt. loss                       
Composition   Atmosphere                                                  
                    Initial                                               
                         5%  10% 20%                                      
__________________________________________________________________________
Zn(OPP.sub.2 O).sub.2                                                     
              air   475  510 520 330                                      
Zn[OP(Me)(Ph)O].sub.2                                                     
              air   380  440 460 470                                      
Zn[OP(C.sub.6 H.sub.4 SO.sub.2 Ph)(Ph)O].sub.2                            
              air   450  499 500 520                                      
__________________________________________________________________________
However, at the present state of the art, few of these materials are capable of facile conversion into coatings by standard preparative methods such as from a melt or by deposition from a solvent. Zn[OP(Me)(Ph)O]2 is one of the few zinc phosphinates that are appreciably soluble in organic solvents and melt at a reasonable temperature, but the coatings obtainable to date have been unsatisfactory because of pinhole formation. Moreover, this composition is less thermally stable than others of the same type (Table 1). The zinc phosphinates which show the greatest thermal stability are insoluble or poorly soluble in common solvents and do not melt at a reasonable point below their decomposition temperature. Zn[OPPh2 O]2 is insoluble in common solvents and as a result, cannot be utilized as a binder for high temperature coatings. Zn[OP(C6 H4 SO2 Ph)(Ph)O]2, for example, is practically insoluble in common solvents and requires a proportionally large amount of strong coordinating solvents such as dimethyl formide for dissolution. Preparations attempted from a solution of Zn[OP(C6 H4 SO2 Ph)PhO]2 in 15 parts DMF and 35 parts C6 H6 result in coatings with poor integrity and pinholes.
This invention, however, provides a novel procedure for the preparation of coatings utilizing zinc phosphinates which were heretofore impossible to use because of poor solubility. The use of zinc phosphinates has been made possible by an in-situ preparation with ingredients soluble in common solvents. Such formulations are surprisingly stable in solution and do not show any supersaturation or tendency to precipitate even though the reaction products would be expected to be insoluble. For example, Zn[OPPh2 O]2 is insoluble in a mixture of MeOH and benzene, but a mixture of ZnCl2 and Ph2 P(O)OH was found to be soluble in such a solvent system. When this solution is sprayed onto a surface, the resultant residue, after evaporation of solvent, is essentially Zn[OPPh2 O]2, and none of the byproduct is present after curing. The chemical reaction is shown by equation (1) as follows:
ZnCl.sub.2 + 2 Ph.sub.2 P(O)H→Zn[OPPh.sub.2 O].sub.2 + 2HCl 1.
For the purpose of further illustrating the invention, the following example is presented. The example details the preparation of a coating on titanium alloy that is essentially Zn[OP(C6 H4 SO2 P6 H5) (Ph)O]2 and that is of satisfactory physical appearance.
EXAMPLE 1 
______________________________________                                    
ZnCl.sub.2 (95% assay)                                                    
                  0.71    grams                                           
Ph(PhSO.sub.2 C.sub.6 H.sub.4)P(O)OH                                      
                  3.58    grams                                           
Me(Ph)P(O)OH      0.78    grams                                           
TiO.sub.2 (DuPont R900)                                                   
                  7.00    grams                                           
DMF               5       grams                                           
MeOH              15      grams                                           
Benzene           30      grams                                           
______________________________________
In this example, the ZnCl2 (95% assay), (PhSO2 C6 H4)(Ph) -- P(O)OH, and Me(Ph)P(O)OH were dispersed in a solvent mixture of dimethyl formamide, MeOH, and benzene. Warming the dispersion on a hot plate (35° to 40° C) for several minutes gave a clear pale yellow solution. The titanium dioxide pigment was then added to the solution together with an appropriate amount of ceramic grinding stones. The dispersion was then ground by rolling on a rolling mill for 6 hours, decanted from the grinding stones, and sprayed onto a titanium alloy sheet. The coating which resulted after evaporation at room temperature set to touch in an hour. An additional 15 hours at ambient temperature gave a coating which is hard and shows good integrity and adhesion. Hardness may be enhanced even further by curing at 150° to 200° C for 2 hours.
An obvious advantage of the procedure of this invention is that any zinc phosphinate type coating can be tailored by selection of the appropriate substituted phosphinic acid as is represented by the following general equation:
ZnCl.sub.2 + 2R (R')P(O)OH→Zn[OP (R)(R')O].sub.2 +2HCl
where R and R' are alkyl or aryl substituents.
Because the titanium alloy Ti-6Al-4v is accepted in the industry and is known for its poor coating adhesion, it was selected as the standard metal to be used in evaluating the coating materials of this invention. The formulation of the above example was used to spray eleven 3 in. by 2 in. panels and eight 2 in. by 1 in. panels of the titanium alloy. The amount of dry coating found (2 hours at 150° C) averaged 0.16 g per panel or 2.8 g/ft2. The panels were first cleaned in accordance with conventional techniques.
All panels were dried at room temperature for 16 hours and then heated at 150° C for 2 hours to remove trace solvents.
Duplicate panels for each formulation were placed in a furnace held at 350° C (662° F). The panels were removed after 23 hours and permitted to cool at ambient room temperature for one hour. Observations and physical measurements were made on the heated panels after they reached room temperature (usually within 35 to 45 minutes after removal from furnace). This cycle was repeated three more times, and the panels were then heated for 71 hours to terminate the run at a total heating time of 163 hours.
A separate run was made under identical conditions except that the furnace temperature was maintained at 540° C
The panels were examined after each heating cycle for the following properties: color, weight, coating integrity (microscope), and adhesion (tape test without scoring of coating). Results of the tests are given in Tables II and III. The data indicate that these coatings show excellent thermal-shock resistance and reasonably good adhesion and retain sufficient integrity so that protection is maintained even after 163 hours heating at 540° C (1000° F).
                                  TABLE II                                
__________________________________________________________________________
Cyclic Thermal Tests at 350° C - Physical Properties of Coatings   
from the Example                                                          
Start        23 hours 46 hours                                            
                             69 hours                                     
                                    92 hours                              
                                           163 hours                      
__________________________________________________________________________
Color A light gray                                                        
              slight yellowing                                            
                       off-white,                                         
                              gray   gray   gray                          
                       gray cast                                          
      B   "   "        "      "      "      "                             
Weight                                                                    
      A 17.151                                                            
              17.144   17.140 --     --     17.118                        
grams B 16.656                                                            
              16.648   16.635 16.624 16.620 16.618                        
Tape  A pass  --       good, 10%                                          
                              --     --     pass                          
                       removal                                            
      B pass  --       --     pass   --     pass                          
Integrity                                                                 
      A good, not                                                         
              good, not                                                   
                       good, smooth                                       
                              good, smooth                                
                                     good, smooth                         
                                            good, smooth                  
        smooth                                                            
              smooth                                                      
__________________________________________________________________________

                                  TABLE III                               
__________________________________________________________________________
Cyclic Thermal Tests at 540° C (1000° F) - Physical         
Properties of Coatings from the Example                                   
Start         23 hours                                                    
                    46 hours                                              
                          69 hours                                        
                                92 hours                                  
                                      163 hours                           
__________________________________________________________________________
Color A light gray                                                        
              white white white white white                               
      B   "   "     "     "     "     "                                   
Weight                                                                    
      A 16.064                                                            
              16.030                                                      
                    16.030                                                
                          16.031                                          
                                16.031                                    
                                      16.034                              
grams B 15.932                                                            
              15.897                                                      
                    15.898                                                
                          15,899                                          
                                15,900                                    
                                      15.900                              
Tape  A pass  --    pass  pass  --    pass                                
      B   "   --    --    "     --    "                                   
Micro A good, not                                                         
              good, not                                                   
                    good, not                                             
                          good, not                                       
                                good  good                                
integrity                                                                 
        smooth                                                            
              smooth                                                      
                    smooth                                                
                          smooth                                          
      B   "   "     "     "     "     "                                   
__________________________________________________________________________
Although the principle of this invention has been described with particularity, it should be understood that various alterations and modifications can be made without departing from the spirit of the invention which is defined by the appended claims.

Claims (1)

What is claimed is:
1. A coating composition composed of a solvent mixture of about 1.0 percent by weight ZnCl2 ; about 5.7 percent by weight Ph(PhSO2 C6 H4)P(O)OH; about 1.2 percent by weight Me(Ph)P(O)OH; about 11.2 percent by weight TiO2 ; and the balance substantially all solvent.
US05/627,808 1975-10-31 1975-10-31 High temperature coatings based on poly (zinc phosphinates) Expired - Lifetime US4001034A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4357170A (en) * 1981-07-30 1982-11-02 The New Jersey Zinc Company Titanium dioxide pigment treated to suppress yellowing in polymers
US4377417A (en) * 1981-07-30 1983-03-22 Gulf & Western Industries, Inc. Titanium dioxide pigment treated to suppress yellowing in polymers
US20040051087A1 (en) * 2002-09-17 2004-03-18 Clariant Gmbh Fire-protection coating

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3505088A (en) * 1965-08-05 1970-04-07 Titan Gmbh Process for the manufacture of a titanium dioxide pigment for the delustering of polyamide fibers
US3556828A (en) * 1968-01-22 1971-01-19 Laporte Titanium Ltd Process for treating titanium dioxide pigments
US3560234A (en) * 1969-03-03 1971-02-02 Thann & Mulhouse Process for the manufacture of pigments of titanium dioxide in the rutile form
US3756841A (en) * 1971-06-30 1973-09-04 Du Pont Chloride tio2 pigments suited for high solids low viscosity slurries

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3505088A (en) * 1965-08-05 1970-04-07 Titan Gmbh Process for the manufacture of a titanium dioxide pigment for the delustering of polyamide fibers
US3556828A (en) * 1968-01-22 1971-01-19 Laporte Titanium Ltd Process for treating titanium dioxide pigments
US3560234A (en) * 1969-03-03 1971-02-02 Thann & Mulhouse Process for the manufacture of pigments of titanium dioxide in the rutile form
US3756841A (en) * 1971-06-30 1973-09-04 Du Pont Chloride tio2 pigments suited for high solids low viscosity slurries

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4357170A (en) * 1981-07-30 1982-11-02 The New Jersey Zinc Company Titanium dioxide pigment treated to suppress yellowing in polymers
US4377417A (en) * 1981-07-30 1983-03-22 Gulf & Western Industries, Inc. Titanium dioxide pigment treated to suppress yellowing in polymers
US20040051087A1 (en) * 2002-09-17 2004-03-18 Clariant Gmbh Fire-protection coating
EP1400573A1 (en) * 2002-09-17 2004-03-24 Clariant GmbH Fireproof coating
US7144527B2 (en) 2002-09-17 2006-12-05 Clariant Gmbh Fire-protection coating

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