US397373A - Manufacture of cement - Google Patents

Description

- UNITED STATES PATENT OFFI E.

ROBERT W. LESLEY, OFIPHILADELPHIA, PENNSYLVANIA.

MANUFACTURE OF CEMENT.

SPECIFICATION forming part of Letters Patent No. 397,373, dated February 5, 1889..

. Application an Jmso, 18881 Serial No. 278,699. on specimens.)

To all whom it may con cm-1 1:

Be it known'that I, ROBER'I. W. LESLEY, of Philadelphia, in. the State of Pennsylvania,

have invented certain new and useful- Im provements in the Manufacture of Cement, of

which the following isa specification.

;- My invention consists of a new process of making from slags a cement which shall be of the quality of Portland cement; This process may be stated as follows I.

take the slag in molten condition as it runs from the blast-furnace, (having first ascering blown through t-ubesfor example, as

tuyeres-into the mass by a \Vhitwell or other suitable hot blast .at a temperature of,-say, 1,200" Fahrenheit, moreor less. A good Portland cement should analyze from fifty-eight to sixty per cent of lime, from twenty to twenty-six per cent-of silica, from eight to twelve per cent. of alumina and iron, and varying proportions of soda, potash, &c.; and

slags are to be found which will analyze: silica, 36.2 per cent; alumina, 11.10 per cent; lime, fortyeight per cent; magnesia, 1.4 per cent, and the balance of ingredients not afiecting the use of the material fora cement. This lime is the principal ingredient required to bring the slag up to the proportion's of Portland cement, although in some cases an addi- .tion of silica or alumina may be requisite, and

in other cases a small addition of the alkalies, potash, and soda maybe of benefit. In order to introduce the additional lime into the fluid slag, I, as before said, blow it into the mass by means of a hot blast. For this purpose the lime can be supplied in regulated quantity through tubes, which shall enter the blast I tubes or tuyeres ata short distance from the point where they discharge into the cupola containing the slag I prefer to use slaked lime for the purpose, because it is in the condition of a'powder much finer than canbe produced by any mechanical process of grinding or reduction. This pulverulcnt lime is taken by the hot blast, and is blown into the body of the fluid slag a-tatemperature which prevents chillingof the slag, and is that at which the lime will unite with the slag chemically to form silicates of alumina and lime. There is thus an intimate mixture and chemical union of the slag and the added ingredients, the blast serving to blow these ingredients into and through the mass, and at the same time to maintain the charge at the temperature requisite toeifec-t the chemical union orcombination of the same. portion. of-lime to the charge of slag has been driven into the mass, the material thus formed is drawn off from the furnace in fluid form,

is granulated by. being run into cold water or by being sprinkled with water, and this product then is ground or otherwise mechanically reduced to powder.

way as the lime. slaked, can be in the form of caustic lime, if desired. 4

In lieu of lime powder I can use the lime or other added ingredients in the form of a paste, which is vaporized .by driving it with. steam (preferablysuperheated) into the hot-air blast. The hot-air blast at once dissipates the water-vapor and carries the impalpable lime 'or;other'solid residue into the molten slag. I

thus present to the fluid slag the lime or other materials at about the temperature of the slag itself, and this causes a prompt and thorough intermingling of theatoms under conditions most favorable for the desired chemical reaction. I have set forth the details of the process which I prefer to employ. It is feasible, how- .ever, to inject the material'into and through 1 the fluid slag by means of a non-heated blast. In this event the pulverulent ingredients thus added would really be brought to heated condition by the time they were driven throughout the slag; but it would be advisable in such case, in order to avoid possibility of chilling the charge, to have fire or fuel in. the furnace containing the same, or to provide some extraneous means for maintaining the charge at the desired tcmpe aturc. By the injecting operation the added ingredients are driven v 1f silica or alumina. .are to lie-added, they can be added in the same The lime, instead of being When the proper pro- ICO .intimate and chemical union.

I am aware that it is not new, broadly con- 5 sidercd, to add lime to molten slag for cement- "making purposes. This has before been suggested by others and is not claimed by me;

- but I am not aware that it has ever before been attempted or-suggested to'inject or blow the 10 lime into and throughout the mass of slag in the manner and under the conditions hereinbefore expressed. *The' advantages-"and the I improved result due to this mode of procedure, as well as to the process of manufacture 1 5 as awhole, have been already stated, and need not be repeated here.

Having described my improvement, what I elainras new and of my own invention is as follows:

1. In the manufacture of cement from slags, the method of incorporating with the slag lime or other ingredients in the proportions necessary to bring the slag to a composition of Portland cement, which consists in Heating into slag heated to fluid condition the lime or other ingredients in finely-divided condigiog and at a high heat, substantially as speci- 2. The described process of making Portland cement, which consists in taking the molten slag drawn off from, iron-furnaces, injecting into .the. slag while still fluid highlyheated and'finely-divided lime or other ingredients, the'mass being maintained at the temperature at which said heated ingredients will chemically combine or unite with the slag, then running this fluid product or mixture into water or sprinkling it with water, so

' as to bring it to granular condition, and finally reducing this granular material-to a powder, substantially as hereinbefore set forth.

In' testimony whereof-I have hereun tosigned my name this 30th day of June, A. D. 1888.

I R. W. LESLEY.

Witnesses:

' EWELL A. DICK,

.1. Ban Irv.