US3904122A - Rotary desalting device - Google Patents

Rotary desalting device Download PDF

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US3904122A
US3904122A US427793A US42779373A US3904122A US 3904122 A US3904122 A US 3904122A US 427793 A US427793 A US 427793A US 42779373 A US42779373 A US 42779373A US 3904122 A US3904122 A US 3904122A
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skirt
disc
annular wall
liquid
lip
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US427793A
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Emanuel Schnitzer
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H B ZACHRY Co
H B ZACHRY CO FRONTIER ENGR CORP
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H B ZACHRY CO FRONTIER ENGR CORP
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B3/00Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
    • B05B3/001Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements incorporating means for heating or cooling, e.g. the material to be sprayed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/22Evaporating by bringing a thin layer of the liquid into contact with a heated surface
    • B01D1/222In rotating vessels; vessels with movable parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/28Evaporating with vapour compression
    • B01D1/2887The compressor is integrated in the evaporation apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B3/00Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements
    • B05B3/02Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements
    • B05B3/10Spraying or sprinkling apparatus with moving outlet elements or moving deflecting elements with rotating elements discharging over substantially the whole periphery of the rotating member, i.e. the spraying being effected by centrifugal forces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S159/00Concentrating evaporators
    • Y10S159/42Seals

Definitions

  • the rotary desalting device relates to a machine for purifying or concentrating fluids containing dissolved materials.
  • the rotary desalting device of the present invention utilizes one or more high speed, thin rotating discs as heat transfer surfaces between a boiling and condensing fluid. The disc or discs are rotated at such high speed that the extreme centrifugal force of hundreds of times the force of gravity reduces the insulating water film to a micro-thin liquid film wherein greatly improved heat transfer coefficients are obtained.
  • the rotary desalting engine of the present invention also incorporates other unique and novel components such as an easily cleanable tri-liquid counter-flow spiral heat exchanger and degasser devices to prevent dissolved gas from accumulating in and blocking the purifying system.
  • the present invention is directed to a rotary desalting device for purifying and/or concentrating fluids containing dissolved materials which utilizes one or more high speed. thin rotating discs as a heat transfer surface between boiling and condensing fluids. More specifically. the present invention is directed to a rotary desalting device wherein thin rotating discs are attached to a rotating hub capable of being rotated at such high speeds that the centrifugal force is hundreds of times the force of gravity causing the liquid on the rotating discs to be reduced to a micro-thin liquid film. In its more specific aspects. the rotary desalting device of the present invention may be used to convert sea Water. brackish water. or polluted fresh water into potable water.
  • Latham. Jr. US. Pat. No. 2.469.122 employs a trifluid counter-flow heat exchanger formed of concentric tubing in a helical spiral. This physical embodiment, however. cannot be disassembled for cleaning of corrosion and salt deposits.
  • Hickman. US. Pat. No. 2.734.023 utilizes a conical disc design supported from a cantilevered shaft. Because of the conical disc design. this conical disc must be quite thick since the disc supports peripherally a second disc to form a condensing chamber between the discs and/or supports peripherally axial flow compressor blades. which limits the operating speed as dis closed in Hickman to about It) times the force of gravity. Further. because the disc is supported from a cantilevered shaft with varying amounts of water. salt depos its and corrosion produced cover the inner perhiphery of the rotating condensing chamber; further. the disc is difficult to balance both initially and after some extended operation. which limits the operating speed. so that as claimed.
  • disassembly for cleaning is difiicult for a precision balance high speed rotor
  • the lower centrifugal force because of the inclined slope near the rim causes longer angular rotational contact with the fluid which results in spinning up the fluid to the disc velocity and a resultant power penalty.
  • heat transfer is reduced with the thicker liquid film combined with the absence of relative shear velocity between the liquid film and the near periphery of the ellipsoid.
  • the deletion of a center bearing in order to accommodate the internal plumbing requires a thicker walled ellipsoid for structural support and/or intensifies the unbalance problem.
  • Tidball. Ll.S. Pat. No. 3.282.798. utilizes a rubbing mechanical seal which absorbs energy through the work of friction.
  • the present invention is directed to a rotary desalting engine which utilizes one or more thin. rapidly rotating discs.
  • the rotating disc or discs act as heat exchange surfaces which surfaces extend essentially perpendicular to the hub and axes of rotation. Further. the rotating discs form condensing and evaporation chambers within the rotating disc chamber housing.
  • the operating speed of the thin. rapidly rotating disc produces a centrifugal force of up to several hundred times the force of gravity and results in a high liquid sheer velocity
  • the film of liquid on the rotating disc is microthin.
  • the rotating disc is sealed at its peripheral extremities by the liquid which comes from each side of the rotating disc with the disc spinning partially immersed in the liquid.
  • the present invention has a design unique to the rotary dcsalting device to maximize the conservation of energy while producing a design of simple construction and maintenance.
  • FIG. 1 is one possible embodiment of the rotary desalting device of the present invention
  • FIG. 2 is one embodiment of the disc seal
  • FIG. 3 is a second embodiment of the disc seal
  • FIG. 4 is a degasser device specially adapted to handle the inlet fluid to be purified
  • FIG. 5 is a degasser device specially designed to bandle the purified fluid
  • FIG. 6 is a second embodiment of the rotary desalting device of the present invention.
  • FIG. 7 is an embodiment of the seal disc of the device of FIG. 6-.
  • FIG. 8 is a cross-section of the rotating disc of the device of FIG. 6;
  • FIG. 9 is a cross-section of a mid-disc distributor on the rotating disc of the device of FIG. 6.
  • the rotary desalting device or engine of the present invention is specifically designed for purifying or concentrating fluids containing dissolved materials.
  • rotary desalting device utilizes one or more high speed.
  • the device of the present invention may be used to purify liquids such as converting sea water. brackish water, or polluted fresh water. into potable water.
  • the device may further be used to purify for recycling. process chemicals, or process water in industrial plants.
  • the device may be used to concentrate fluids such as film developers. nuclear wastes, or other expensivcly separated material, which can be purified or concentrated such that they can be either reused or stored.
  • a rotary desalting device or engine I is comprised of one or more rotating discs 2 which are mounted on and driven by a hollow drum 3 which is the hub in the rotating disc chamber housing 4.
  • the hollow drum 3 which is sealed at one end is attached to an armature shaft 5 of a drive motor 6.
  • armature shaft 5 also drives a gear train 7 which in turn drives compressor fans of the compressor 8.
  • gear train 7 and compressor 8 are between the drive motor 6 and the rotating disc chamber housing 4.
  • FIG. 1 there are two rotating circular discs 2 mounted on and driven by a hollow drum 3, which forms two evaporation chambers 10 and II. respectively. with a single condensing chamber 12 between the two discs 2.
  • Hollow drum 3 passes through scaled bearings 13 and 14 which are positioned in the pressure tight rotating disc chamber housing 4.
  • the hollow drum 3 is connected and keyed integrally to the armature shaft 5 by means of a spider 15 at one end of the hollow drum 3.
  • the rotating shaft 5 is an armature shaft of an electrical induction motor.
  • An induction type of electric motor is preferred because of the capability of its field to operate at boiling water temperatures permitting its bar-wound armature to operate at very high temperatures without burning out. This is not possible with wire wound rotor types of motors.
  • brush type motors do not possess the required long life capability for dcsalinization that the induction motor possesses, especially at high temperatures. If ad ditional heat is required, it can be supplied by electricity. or by burning fuel. It is to be understood that the rotating shaft 5 may be driven by electrical motors, combustion motors. or in large design. even a jet engine.
  • the motor 6 drives the shaft 5 which rotates in the bearing members 16 and I7 mounted in the housing I8 of the motor 6.
  • the shaft 5 may pass through one or more other bearing members. but is supported at its other end and passes through bearing [9 located at the opposite (sealed) end of the hollow drum 3 from the spider 15.
  • Sea water is drawn into the rotary desalting engine 1 through the intake strainer 20 which may consist of a perforated chamber, screen, or particle bed filter. to remove any solid material carried in with the fluid.
  • the sea water passes through the tube 21 to the pre-treatment chemical filter 22.
  • the pretreatment chemical filter 22 may contain chemicals to prevent corrosion of the machine. remove objectionable taste or odor. or remove dissolved or suspended material that the process will not remove.
  • the sea water goes through the tube 23 to a liquid phase degasser 24. The details of the liquid phase degasser 24 will be set forth hereinafter.
  • the sea water is then passed through tube 25 into the inlet 26 of pump 27.
  • the shaft 5 passes through the bearing 19 and has keyed integrally thereto a water pump impeller 28.
  • the sea water is pumped by the water pump impeller 28 through the tube 29 to a vapor phase degasser 30. the details of which will be set forth hereinafter.
  • the sea water acquires a small temperature increase in the vapor phase degasser 30 and passes through tube 31 into a tri-fluid counter-flow heat exchanger 32.
  • the sea water is heated to near its boiling temperature in the heat exchanger 32 wherein it is then passed out of the heat exchanger by tube 33 into a liquid jacket 34 which surrounds the motor 6.
  • Waste heat from the motor 6 is conserved in this embodiment not only by the shaft energy of the drive motor. but also its waste heat, and the heated sea water is removed from the liquid jacket 34 by tube 35, providing maximum conservation of energy. This is one of several instances in the present invention where conservation of energy is achieved and the utilization of energy is made at the level at which it is available.
  • the heated sea water flows through the thermostatic valve 36 which maintains the operation temperature at design level. and may be used to reduce the initial water flow to promote start-up heating.
  • the valve 36 provides for automatic start-up and for stable operation at design temperatures in spite of raw feed fluid temperatures changing with changing seasons. purified fluid demand or otherwise.
  • the sea water flows through the tube 37 into the disc chamber housing 4 to a spray ring 38 in the evaporation chamber 10.
  • the spray ring 38 has a number of nozzles of injector plate arrangements to spray the sea water against one of the rotating discs 2 mounted on the drum 3.
  • the sea water may be flowed onto the discs 2.
  • the sea water is sprayed as a fine mist due to the size and number of the nozzles in the spray ring 38.
  • the temperature of the side of the disc 2 in the evaporation chamber is higher than the boiling point for sea water, at the pressure existing in the chamber 10. and accordingly, some of the sea water is converted to steam which passes through the openings 39 in the hollow drum 3.
  • the remaining sea water on the disc 2 becomes a more concentrated brine" solution. Because of the centrifugal force imparted to the brine solution, as it approaches the rotation velocity of the disc 2, the brine solution is slung toward the periphery of the disc 2. The brine solution slung off the disc 2 flows into and fills one of the annular brine channels 40 in the rotating disc chamber housing 4. The brine solution is removed from the brine channel 40 by a tangential orifice 41 and is taken by the tube 42 to a second spray ring 43. The brine solution which is under pressure from the rotational velocity imparted to it from the disc is sprayed on the evaporation side of the second of the discs 2 in evaporation chamber ll.
  • This second evaporation effect operates similarly to the first effect previously described.
  • the temperature of the side of the disc in the evaporation chamber ll being higher than the salt water boiling point at the pressure existing in chamber 11 results in some of the water being converted to steam which enters drum 3 through the openings 44.
  • a higher concen trated brine is slung off of the second disc 2 into a concentrated brine channel 45.
  • the highly concentrated brine is removed from the brine channel 45 by a tangcntal orifice 46 and passed through the tube 47 into the tri-fluid counter-flow heat exchanger 32.
  • the hot brine is cooled in the heat exchanger 32 and is removed from the heat exchanger 32 by tube 48 wherein it is passed through venturi 49 to a brine outlet 50.
  • the steam generated in evaporation chambers 10 and l 1. respectively. is sucked through openings 39 and 44 in the hollow drum 3.
  • the steam passes through the spider [5 which permits axial flow of vapor therethrough into a gas compressor 8.
  • the gas compressor 8 may either be a multistage fan, or other type ofsingle or multi-stage gas compressor.
  • the compressor 8 may be driven by a separate motor. or as shown in this cni (il l bodiment, driven by the main drive motor 6 through the gear train 7.
  • the gear train 7 which is merely illustrative has a drive gear Sl which is keyed to the shaft 5.
  • the drive gear 51 drives the gear 52 on the idler shaft 53.
  • the idler shaft 53 has keyed to it a gear 54 which drives the gear 55.
  • the gear 55 drives the high speed drum 56 which supports and drives multi-stage compressor fans 57 and 58.
  • gravity drain mesh, fiber strainer, or centrifugal louvered droplet slingers 59 and 60 may be used to prevent salt water particles from enter ing the hollow drum 3 and the compressor 8.
  • the slingcrs 59 and 60 the salt water particles are slung upon impacting the slingers inclined slats radially outwardly and back toward the rotating disc 2, while the steam passes between the slats of the slingcrs 59 and 60 into the hollow drum 3 and into the compressor 8.
  • the compressor 8 raises the pressure and temperature of the steam. as well as the condensation temperature, and in general, results in the steam becoming superheated.
  • This higher pressure steam at its higher temper ature is removed from the compressor 8 through the discharge duct 61 into condensing chamber 12.
  • This high pressure steam condenses on the surfaces of rotating discs 2 which form the condensation chamber 12.
  • the condensed fresh water is slung from the rotating discs 2 into annular fresh water channels 62 and 63.
  • the fresh water is removed from fresh water channels 62 and 63 by radial water outlet orifices 64 and 65, respectively.
  • the fresh water is collected in the tube 66 which is passed into tri-fluid counter-flow heat exchanger 32.
  • the hot fresh water is removed from the heat exchanger 32 as cooler water by the tube 67 where it is passed through a venturi 68 through outlet 69 to a pure water storage tank (not shown).
  • water may be sprayed into the compressor 8, in which the rotary action of the blades will further divide the water into fine particles for easier evaporation during the long path length through the compressor 8 and its discharge duct 61.
  • the addition of water to the compressor 8 serves both to de super-heat the steam and to remove some of the waste heat energy of the compressor 8 caused by friction. turbulence, or other energy losses. to increase the compressor efficiency. decrease compressor power requirements, and increase the mass flow of steam through the compressor 8.
  • the saturation temperature of the steam at the compressor outlet 61 is higher than the saturation temperature under the pressure conditions at the inlet of the compressor 8. Accordingly. the condensing sides of the disc 2 are hotter than the sides where evaporation takes place. This results in not heat flow from the steam in the condensing chamber I2 to the steam in evaporation chambers I and II.
  • the first aspect is directed to the rotating circular disc 2 which are mounted on and driven by the hollow drum 3.
  • the rotating circular disc 2 which are mounted on and driven by the hollow drum 3.
  • the disc 2 in FIG. 2 has a bifurcated terminating portion with one leg 73 extending into the channel 62.
  • the concentrated brine solution which is slung from the disc 2 into the channel 40 forms a set of counter-rotating helical vortices in the channel 40 until it is withdrawn out of tangential orifice 41.
  • the fluid as it begins to fill the channel 40 will be removed as it en ters the orifice 41 which controls the fluid level in the channel. In the same manner. the fresh condensed water will be slung off the disc 2 into the channel 62 and be removed from the tangental orifice 64.
  • the portion 75 is a rise between the channels 40 and 62 which prevents fluid from passing from one channel to the other.
  • FIG. 3 there is an alternative arrangement of a disc seal collector.
  • the disc is flat at its periphery.
  • the chambers and I2 are identical to that described in FIG. 2, as well as the channels and 62 and the orifices 41' and 64'. respectively.
  • the wiping seal is contained in the rotary disc housing structure and one por tion 73' extends from the limits of the channel 40' whereas a second portion of the seal 74' extends from the channel 62'.
  • the rotary disc extends into a depression 75 in this modification.
  • the fluid slung off the discs 2 flows into and fills the annular channels in rotary disc chamber housing 4.
  • the fluid which is under pressure due to its high centrifugal force. and which is rotating in the channels as a single clockwise vortex. or dual counter-rotating helical vorti ces caused by disc-induced rotation. acts in conjunction with the disc running in the channel as a pressure seal between chambers 10 and I2 and chambers 11 and I2.
  • the level of fluid in the channels is adjusted by the position of outlet orifices relative to the bottom of the channel.
  • the pressure of the rotating fluid is communicated to the fluid outlet so that the disc, in effect. also acts like a second pump of a centrifugal type. If this pressure is too high because of excessive fluid rotational velocity resulting in energy waste. backward curved grooves can be cut in the disc surface to reduce the fluid rotational speed.
  • FIG. 4 there is shown an example of a liquid phase device whereas in FIG. 5, there is an e ⁇ amplc of a vapor phase device.
  • the degasser 24 of FIG. 4 has an inlet tube 23. and an outlet tube 25.
  • a flow control uti free 76 is in the liquid inlet tube 23 to the degasser 24.
  • Circular peripheral flow spill trays 77 and center flow spill trays 78 are stacked alternately and spaced vertically within the degasser 24.
  • a float 79 pivoted from the rocker arm and support 80 and hinged to the gas valve actuating rod 81 operates a valve 82 in the gas outlet 83.
  • the pum suction applied by pump 27 through outlet tube 25 applies suction through the dc gasscr 24 through restriction orifice 76.
  • the impedances of the lines, filters and sea water lift requirements before degasser 24 create the suction heat which causes the dissolved gas in the sea water to appear as small gas bubbles and evolve from the fluid it cycles radially in and out in thin sheets over the spill trays 77 and 78.
  • the evolved gases which are lighter than the fluid fill the top of degasser 25 from which they are sucked out through outlet 83 due to the vacuum created as the brine solution passes through the venturi 49.
  • Float 79 assures that the pump is always supplied with liquid and not gas since it closes the passage to the pump when the liquid level drops and opens when the liquid rises to a set level.
  • FIG. 5 the specific aspects of the degasser 30 are illustrated.
  • introduced into vapor phase degasser 30 is a mixture of evolved gas and vapor picked up by a T 84 shown in FIG. I at the outer peripheral region of condensing chamber 12. Due to the higher density of the evolved gas as compared to the vapor, the gas is concentrated near the periphery of the rotating disc due to the centrifugal force created by the rotation.
  • This mixture passes through the T 84 into a tube 85 and metering valve 86 which adjusts and optimizes the flow into the vapor degasser 30 to limit vapor loss with asso ciated system energy loss.
  • Sea water is introduced by the tube 29 into the degasser 30 whereas the water exits the degasser 30 by the tube 31.
  • the vapor and gases from tube 85 flow through the helical tube coil 87 immersed in the liquid cooling annulus 88.
  • the vapor is condensed into liquid or fresh water and collecting at the bottom of the degasser 30 whereas the evolved gas is cooled and collects in the gas space above the liquid.
  • a liquid float 89 opens a valve 90 in the outlet line 91 when liquid or water collects, and which is drawn out through the fresh water line 67 by the venturi 68.
  • Thermostatic gas valve 92 in the tube 93 allows any collected cooled gases to be removed from the system, but would block the flow of the hot vapor should there be any in the gas space.
  • a rotary dcsalting device IOI has a single rotating disc I02 which extends from a hub I03.
  • the rotating disc I02 rotates in a rotating disc chamber housing 104.
  • the rotating disc I02 is attached through the hub 103 to an armature shaft I05 of a dri ⁇ e motor I06.
  • the armature shaft 105 also drncs a gear train 107 which in turn drives the compressor fan of the compressor 108.
  • FIG. I there is a sin gle rotating circular disc I02 which is mounted on and driven by the armature shaft which is connected to the disc by means of the hub 103.
  • the rotating disc 102 as it rotates in rotating disc chamber 104 forms an evaporation chamber 109 on one side of the rotating circular disc 102 and a condensing chamber 1 10 on the other side of the disc 102.
  • collection channel means 111 are attached to the periphery of the disc 102.
  • the collec tion channel means 111 has one channel 112 to collect the brine from the evaporation chamber 109, and a second channel 113 which collects the fresh water from the condensing chamber 110.
  • each of the channels 112 and 113 Inserted into each of the collection channels is one or more stationary scooping devices 114 and 115, scooping device 114 being in channel 112 and scooping device 115 being in channel 113.
  • the scooping devices 114 and 115 are fashioned in such away as to minimize the flow disturbances associated with placing a stationary object in a moving stream of fluid.
  • a shield (not shown) may be placed on the scoops 114 and 115 in order to divert any fluid which is splattered by the scoop back onto the disc 102 or into the collection channels 112 or 113. By removing the fluids in the manner just described.
  • the seal means between the evaporation chamber 109 and the condensing chamber 110 is a wiping seal 116 which is held within a slot in the rotating disc chamber housing 104 by means of block 117.
  • the wiping seal 116 is placed on the side of the rotating disc 102 on the high pressure or condensing chamber 1 10 so as to be forced into contact with the collection channel means 111.
  • the seal means in this embodiment may be a stationary member (not shown) held by the rotating disc chamber housing 104 which extends from the housing into the fluid in one of the channels in channel means 111 and seals chamber 109 from chamber 110.
  • channel means 111 would have a separate channel filled with fluid for the stationary member to extend into so as not to disturb the fluids within channels 112 or 1 13.
  • Such a seal means provides a hydrodynamic seal similarly as described with regard to the embodiment of FIG. 1.
  • the disc 102 is constructed from very thin, highly heat conductive material. in order to increase the structural integrity of this thin disc 102, a system of supporting spokes may be used as is shown in FIG. 8. Two sets ofspokcs are shown eminating from the central hub 103 of the disc 102. Spokes 118 are at tached to a mid-radius locus of the disc 102 while an other set of spokes 119 are attached at the disc periphcry. The spokes 119 have an adjustment capability through adjustment means 120.
  • This adjustment capability is used to move the periphery of the disc 102 back and forth in an axial direction in order to adjust the pressure with which the wiping seal 116 bears on the collection channel means 111 and to eliminate wobble of the disc 102. This adjustment may also he used to rc cute the leakage and the power drawn by the wiping seal 116.
  • the flow of water to the disc 102 is different from the embodiment set forth hereinbcfore.
  • one or more mid-disc distributors 121 are attached by a plurality of post means 122 to the rotating disc 102 as shown in more detail in FIG. 9.
  • water is fed from tube 123 tangentially into the top of a Ushaped member 124 which forms the outer ring 124' of the distributor 121 at a rate preferably at or near the rotational speed of the disc 102 so that the water is essentially laid into ring 124.
  • the plurality of post means 122 are at tached at the top of the U of thc U-shapcd member 124.
  • a skirt means 125 Extending from the bottom of the U of the U shaped member 124 is a skirt means 125 which forms a second ring 125'.
  • the water overflows into a second ring 125' which also fills and overflows.
  • the water overflows ring 125" it is uniformly distributed within the distributor 121 by attaining the same rotational velocity as the disc 102 through shear between the water and the rings 124' and 125' and becomes evenly distributed around the ring by eentrifugally induced hydrostatic forces thus capable of being equally supplied to the disc 102 in all radial directions.
  • the water overflowing the second ring 125' flows onto an extended lip means 126 which is tapered to a knif edge.
  • the knife edge is inset into a depression region 127 of the disc 102. ⁇ Nhen the water reaches the knife edge it is slung by centrifugal force into the wall of the depression 127 in the disc 102. Once the water has contacted the disc 102, adhe sion forces causes it to remain in contact with the disc 102 and the centrifugal force causes the water to move radially outward in a thin, uniform film.
  • the mid-disc distributor 121 being attached to the disc 102 is rotat ing at the same speed as the disc 102 which uniquely promotes even distribution of the water on the disc 102 and enables high heat transfer on the disc 102 due to the thin. uniform film which results. W'ater is shown as being fed to the disc 102 in only two locations in FIG.
  • the sea water is drawn into the rotary desalting device 101 through an intake to a strainer 128 to remove any solid material.
  • the sea water thereafter may pass into a liquid phase dcgasser 129, the details of which may be set forth hercinbefore.
  • the water is drawn into the rotary desalting device 101 by means of pump 130 which may be driven by motor 106 through gear train 107. After the water is drawn through pump 130, the water is passed through a unique ion-exchange water pretreatment system 131 to remove dissolved or suspended material that the process will not otherwise remove.
  • the treated water then passes through pipe 132 into a tri-fluid counter-flow heat exchanger 133.
  • the sea water is heated to near its boiling temperature in the heat cschangcr 133 and then passes out of the heat exchanger 133 by pipe 134 into a motor water jacket 135 wherein the heat from the motor I06 is picked-up by the water.
  • ⁇ Nater from the motor water jacket [35 flows to a heat rcscnoir 136 containing a heater
  • heat can be easily added to the water as it passes through heat reservoir 136. especially during start-up.
  • the water exiting the heat reservoir I36 flows by line 137 where it is divided into two streams.
  • One stream 138 is controlled by a preset valve 139 which allows a fraction of the water to be supplied to the middisc distributor 121. By this means a portion of the water during the start-up provides lubrication in the form of the sea water. to get to the wiping seal I I6 and hastens systems start-up by restricting the water flow during start-up.
  • the other stream 140 is controlled by a thermostatic valve 141 which remains closed until the water reaches operating temperature.
  • the heated sea water leaves the heater resevoir I36 and flows through both lines 138 and 140. the thermostatic valve 141 being open during system equilibrium.
  • the heated sea water flowing through line 138 is introduced by a tube 123 to the mid-disc distributor 121 and flows onto the disc 102 as has been described hereinbefore.
  • Water flowing through line 140 is passed through a tube 142 directed into the depression 143 in the hub 103 of the disc 102. As the depression 143 fills, the water begins to over flow. The overflow of the water takes place uniformly, supplying water to the disc I02 equally in all radial dircctions. This uniform overflow gives rise to a uniform distribution of water on the disc 102. As can be seen by the description of the distribution of the water on to the rotating disc 102, a very thin film of water is formed uniformly on the entire rotating disc 102 increasing the heat transfer due to the extremely thin water film thickness.
  • the temperature of the disc in the evaporating chamber 109 is higher than the boiling point for sea water. at the pressure existing in the chamber 109, and accordingly. some of the sea water is converted to steam. The remaining sea water on the disc I02 becomes a more concentrated brine solution. Because of the centrifugal force imparted to the brine solution. the brine solution is slung toward the periphery of the disc 102 where it fills the collection channel 112 of the collection chan' nel means 111. The brine solution is removed from channel 112 by means of scooping device 114 and removed by a tube 144 where it passed by line I45 into the tri-fluid counter-flow heat exchanger 133. The brine solution is cooled in the heat exchanger 133 and then removed by line 146.
  • the steam generated in evaporation chamber 109 is passed through tube 147 into the gas compressor 108.
  • the gas compressor 108 may either be a multi-stage fan. or other type of single or multi-stage gas compressor.
  • a compressor 108 may be driven by a separate motor. or as shown in FIG. 6. driven by the main drive motor 106 through the gear train 107.
  • the steam after compression is in a super heated condition when it exits the compressor 108. It exits through a pipe 148 where it is passed into the condensing chamber 110.
  • the pipe 148 may be a spiral tube (not shown) wherein a small amount of fresh water may be introduced into the super heated steam leaving the compressor 108.
  • the water flowing through the spiral tube of the de-super heater is heated by the steam which flows around the tube. The water thus enters the stream of super heated steam in pipe 148 as heated water or a mixture of water and saturated steam and is readily entrained by the moving stream which has lost its super heat energy to the fresh water by the time it reaches the condensation chamber 110.
  • the advantage of such a de-super heater is that it does not necessitate introducing the de-super heating water as a finely divided sprayv
  • the compressed steam which enters the condensa tion chamber is restrained from passing around the periphery of the rotating disc 102 into the evaporation chamber 109 by the wiping seal 116.
  • the steam condenses on the rotating disc 102 where it is slung by the centrifugal forces to the periphery of the rotating disc I02 and the water collection channel 113.
  • the scooping device picks up the water and passes it through tube 114 where it is passed by line 150 to the tri-fluid counter-flow heat exchanger 133.
  • the cooled fresh water is removed from the heat exchanger 133 through pipe 151 where it is passed to a pure water storage tank (not shown).
  • the prior art discloses distillation operations with rotating cones and curved drums at low rotational speeds producing centrifugal accelerations of the water of 10s of gs
  • the present invention permits l00s or 1.000s of gs of centrifugal acceleration of water because of the design of the plane disc. seal and water distribution system.
  • This high acceleration coupled with the unique water distribution system causes a very thin. uniform water film on the disc. which in turn produces a heat transfer coefficient of about 5 times that claimed in publications related to the prior art.
  • the design of the present invention has permitted a disc heat transfer coefficient of 8.700 BTU/ft hr. F for a [6 inch diameter disc rotating at L725 RPM which produces 680 gs at the perimeter.
  • a 6 foot diameter disc rotating at this speed would produce 2.500 gs at the perimeter and a somewhat higher heat transfer coefficient. Since a contiguous film was obtained in practice on a 16 inch diameter disc turning at 3,450 RPM with a perimeter centrifugal acceleration of 2.720 gs which is approximately equal to the gs on the 6 foot disc. the 6 foot disc may be operated at the l .725 RPM speed. Because of the difficulty of spinning flexible curved drums or cones at high speed with their attendant vibration and distortion problems under load. it is not believed that the high gs are possible with the prior art. since for good heat transfer. the drums or cones must necessarily be thin and are necessarily limited in size.
  • a liquid distributor which comprises: a U-shaped means forming an outer ring; a plurality of post means for attaching said U-shaped means to a disc which are attached to the top of the U of said U-shaped means;
  • skirt means extending from the bottom of the U of said U-shaped means on the same side said post means which forms a second ring;
  • a liquid distributor according to claim 1 which further includes a tube which feeds the fluid tangentially into said outer ring.
  • a liquid distributor for distributing a liquid on a surface which comprises:
  • At least one inner annular wall attached to said skirt at a point intermediate said outer annular wall and said lip said inner annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt;
  • liquid distributor of claim 5 including means to feed liquid into the space intermediate said outer an nular wall and said inner annular wall whereby liquid fills said space overflows said inner annular wall onto said skirt and flows to said lip 7.
  • said lip is a tapered knife edge
  • At least one inner annular wall attached to said skirt at a point intermediate said outer annular wall and said lip, said inner annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt;

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The rotary desalting device relates to a machine for purifying or concentrating fluids containing dissolved materials. The rotary desalting device of the present invention utilizes one or more high speed, thin rotating discs as heat transfer surfaces between a boiling and condensing fluid. The disc or discs are rotated at such high speed that the extreme centrifugal force of hundreds of times the force of gravity reduces the insulating water film to a micro-thin liquid film wherein greatly improved heat transfer coefficients are obtained. Provided in the rotating disc chamber housing is a centrifugal liquid seal to separate the boiling and condensing chambers which is combined with a naturally pressurized fluid discharge at the disc periphery. The rotary desalting engine of the present invention also incorporates other unique and novel components such as an easily cleanable tri-liquid counter-flow spiral heat exchanger and degasser devices to prevent dissolved gas from accumulating in and blocking the purifying system.

Description

United States Patent [191 Schnitzer Sept. 9, 1975 Primary Examiner-Lloyd L. King Attorney, Agent, or FirmHubbard, Thurman, Turner & Tucker [57] ABSTRACT The rotary desalting device relates to a machine for purifying or concentrating fluids containing dissolved materials. The rotary desalting device of the present invention utilizes one or more high speed, thin rotating discs as heat transfer surfaces between a boiling and condensing fluid. The disc or discs are rotated at such high speed that the extreme centrifugal force of hundreds of times the force of gravity reduces the insulating water film to a micro-thin liquid film wherein greatly improved heat transfer coefficients are obtained. Provided in the rotating disc chamber housing is a centrifugal liquid seal to separate the boiling and condensing chambers which is combined with a naturally pressurized fluid discharge at the disc periphery. The rotary desalting engine of the present invention also incorporates other unique and novel components such as an easily cleanable tri-liquid counter-flow spiral heat exchanger and degasser devices to prevent dissolved gas from accumulating in and blocking the purifying system.
[ ROTARY DESALTING DEVICE [75] Inventor: Emanuel Schnitzer, Houston, Tex. [73] Assignees: H. B. Zachry Company, San
Antonio; Frontier Engineering Corporation, Houston, both of Tex. part interest to each [22] Filed: Dec. 26, 1973 [2l] Appl. No.: 427,793
Related US. Application Data [63] C0ntinuationin-part of Ser. No. 252,202, May ll,
l972, abandoned.
[52] U.S. Cl. 239/223 [5 1] Int. Cl B05!) 3/10; 844d 5/10; F23d/l 1/04 [58] Field of Search 239/223, 224; 202/l76, 236
[56] References Cited UNITED STATES PATENTS 2,869,]75 l/l959 Ebhinghousc 239/224 2.902123 9 1959 Nyrop 239/223 2,9l7,24l 12/1959 Waldrum. 239/223 $346,192 ll/l967 Hegc 239/223 L I L] III/l/l/l/I/ PATENTEU EP M975 sum 1 [IF 4 ROTARY DESALTING DEVICE CROSS REFERENCE TO RELATED APPLICATION This is a continuation-in-part application of Ser. No. 252.201 filed May ll. l972. entitled Rotary Desalting Engine. now abandoned.
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is directed to a rotary desalting device for purifying and/or concentrating fluids containing dissolved materials which utilizes one or more high speed. thin rotating discs as a heat transfer surface between boiling and condensing fluids. More specifically. the present invention is directed to a rotary desalting device wherein thin rotating discs are attached to a rotating hub capable of being rotated at such high speeds that the centrifugal force is hundreds of times the force of gravity causing the liquid on the rotating discs to be reduced to a micro-thin liquid film. In its more specific aspects. the rotary desalting device of the present invention may be used to convert sea Water. brackish water. or polluted fresh water into potable water.
2. Prior Art The following US. patents were cited in the parent application:
llsrjon 1.734.013 .l3h 7tl7 LIIIIHZH 199K439 RQINLUSU ZJUXJIUH 2,999.796 3.182.793 2.349331 (icrnian 62112} Currently available rotary still designs have the fol lowing disadvantages as compared to the device of the present invention.
Latham. Jr. US. Pat. No. 2.469.122. employs a trifluid counter-flow heat exchanger formed of concentric tubing in a helical spiral. This physical embodiment, however. cannot be disassembled for cleaning of corrosion and salt deposits.
Hickman. US. Pat. No. 2.734.023. utilizes a conical disc design supported from a cantilevered shaft. Because of the conical disc design. this conical disc must be quite thick since the disc supports peripherally a second disc to form a condensing chamber between the discs and/or supports peripherally axial flow compressor blades. which limits the operating speed as dis closed in Hickman to about It) times the force of gravity. Further. because the disc is supported from a cantilevered shaft with varying amounts of water. salt depos its and corrosion produced cover the inner perhiphery of the rotating condensing chamber; further. the disc is difficult to balance both initially and after some extended operation. which limits the operating speed. so that as claimed. only about l(J times the force of gravity is achieved for the liquid film on it. This film is not reduced in thickness as much as it possible for the higher rotational speeds. The combination of a thick disc and a thick liquid film results in reduced heat transfer coefficient across the disc, which. in in turn. requires greater compressor power and reduces the competitive capability of the machine. The lower operating speed produces a much thicker liquid film on the disc which results in a reduced heat transfer coefficient across the disc as compared to the device of the present invention For the closed ellipsoidal rotating shell design of Hickman. where the slope of the walls near the periphery approach parallelism with the rotational axis. corrosion and salt deposit collection result in a more severe unbalancing problem. disassembly for cleaning is difiicult for a precision balance high speed rotor, the lower centrifugal force because of the inclined slope near the rim causes longer angular rotational contact with the fluid which results in spinning up the fluid to the disc velocity and a resultant power penalty. and heat transfer is reduced with the thicker liquid film combined with the absence of relative shear velocity between the liquid film and the near periphery of the ellipsoid. In addition, for the multi-staged ellipsoid. the deletion of a center bearing in order to accommodate the internal plumbing requires a thicker walled ellipsoid for structural support and/or intensifies the unbalance problem.
Hickman. US. Pat. No. 2.894.879. utilizes a liquid seal between vapor chambers at different pressures. but since this seal is oriented such that only one times the force of gravity is exerted on the liquid. it is only capable of sealing against small pressure differences.
Hickman. US. Pat. No. 2.899.366. utilizes a degassing system vvhich compromises the system efficiency by discharging energy carrying vapor from the system with the dissolved gases.
Tidball. Ll.S. Pat. No. 3.282.798. utilizes a rubbing mechanical seal which absorbs energy through the work of friction.
In general. while some of the above patents include components similar to the present invention. none of the devices disclosed have been optimized as a system to include the right combination of components. structural design, thermal design. and fluid circuits for maxi mum efficiency operation to render them competitive to other means of producing potable water.
There is no known currently available sea water purification unit that. when reduced to a size suitable for residences. hotels or small industrial plants. is sufficiently efficient and inexpensive to buy. operate and maintain to be competitive with other potable water SULIICCS,
SUMMARY OF THE INVENTION The present invention is directed to a rotary desalting engine which utilizes one or more thin. rapidly rotating discs. The rotating disc or discs act as heat exchange surfaces which surfaces extend essentially perpendicular to the hub and axes of rotation. Further. the rotating discs form condensing and evaporation chambers within the rotating disc chamber housing. The operating speed of the thin. rapidly rotating disc produces a centrifugal force of up to several hundred times the force of gravity and results in a high liquid sheer velocity Thus. the film of liquid on the rotating disc is microthin. The rotating disc is sealed at its peripheral extremities by the liquid which comes from each side of the rotating disc with the disc spinning partially immersed in the liquid. causing the liquid to behave as a very heavy fluid and to seal the disc periphery against a high pressure differential. In its more specific aspects. the present invention has a design unique to the rotary dcsalting device to maximize the conservation of energy while producing a design of simple construction and maintenance.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is one possible embodiment of the rotary desalting device of the present invention;
FIG. 2 is one embodiment of the disc seal;
FIG. 3 is a second embodiment of the disc seal;
FIG. 4 is a degasser device specially adapted to handle the inlet fluid to be purified;
FIG. 5 is a degasser device specially designed to bandle the purified fluid;
FIG. 6 is a second embodiment of the rotary desalting device of the present invention;
FIG. 7 is an embodiment of the seal disc of the device of FIG. 6-.
FIG. 8 is a cross-section of the rotating disc of the device of FIG. 6; and,
FIG. 9 is a cross-section of a mid-disc distributor on the rotating disc of the device of FIG. 6.
DESCRIPTION OF THE PREFERRED EMBODIMENTS The rotary desalting device or engine of the present invention is specifically designed for purifying or concentrating fluids containing dissolved materials. The
rotary desalting device utilizes one or more high speed.
thin rotating discs as a heat transfer surface between a boiling and a condensing fluid utilizing a vapor com pression distillation concept. The device of the present invention may be used to purify liquids such as converting sea water. brackish water, or polluted fresh water. into potable water. The device may further be used to purify for recycling. process chemicals, or process water in industrial plants. Alternatively. the device may be used to concentrate fluids such as film developers. nuclear wastes, or other expensivcly separated material, which can be purified or concentrated such that they can be either reused or stored.
To describe the present invention, and a specific operation. namely the desalination of sea water, and referring particularly to FIG. 1. a rotary desalting device or engine I is comprised of one or more rotating discs 2 which are mounted on and driven by a hollow drum 3 which is the hub in the rotating disc chamber housing 4. The hollow drum 3 which is sealed at one end is attached to an armature shaft 5 of a drive motor 6. The
armature shaft 5 also drives a gear train 7 which in turn drives compressor fans of the compressor 8. In this embodiment. the gear train 7 and compressor 8 are between the drive motor 6 and the rotating disc chamber housing 4.
As shown in the embodiment of FIG. 1. there are two rotating circular discs 2 mounted on and driven by a hollow drum 3, which forms two evaporation chambers 10 and II. respectively. with a single condensing chamber 12 between the two discs 2. Hollow drum 3 passes through scaled bearings 13 and 14 which are positioned in the pressure tight rotating disc chamber housing 4. The hollow drum 3 is connected and keyed integrally to the armature shaft 5 by means of a spider 15 at one end of the hollow drum 3.
In this embodiment. the rotating shaft 5 is an armature shaft of an electrical induction motor. An induction type of electric motor is preferred because of the capability of its field to operate at boiling water temperatures permitting its bar-wound armature to operate at very high temperatures without burning out. This is not possible with wire wound rotor types of motors.
Also. brush type motors do not possess the required long life capability for dcsalinization that the induction motor possesses, especially at high temperatures. If ad ditional heat is required, it can be supplied by electricity. or by burning fuel. It is to be understood that the rotating shaft 5 may be driven by electrical motors, combustion motors. or in large design. even a jet engine. The motor 6 drives the shaft 5 which rotates in the bearing members 16 and I7 mounted in the housing I8 of the motor 6. The shaft 5 may pass through one or more other bearing members. but is supported at its other end and passes through bearing [9 located at the opposite (sealed) end of the hollow drum 3 from the spider 15.
Sea water is drawn into the rotary desalting engine 1 through the intake strainer 20 which may consist of a perforated chamber, screen, or particle bed filter. to remove any solid material carried in with the fluid. From the intake strainer 20, the sea water passes through the tube 21 to the pre-treatment chemical filter 22. The pretreatment chemical filter 22 may contain chemicals to prevent corrosion of the machine. remove objectionable taste or odor. or remove dissolved or suspended material that the process will not remove. From the filter 22, the sea water goes through the tube 23 to a liquid phase degasser 24. The details of the liquid phase degasser 24 will be set forth hereinafter. In this embodiment. the sea water is then passed through tube 25 into the inlet 26 of pump 27. The pump 27, as shown in FIG. 1, is mounted to the sealed end of the rotating disc chamber housing 4 at the sealed end of the rotating hollow drum 3. The shaft 5 passes through the bearing 19 and has keyed integrally thereto a water pump impeller 28. The sea water is pumped by the water pump impeller 28 through the tube 29 to a vapor phase degasser 30. the details of which will be set forth hereinafter. The sea water acquires a small temperature increase in the vapor phase degasser 30 and passes through tube 31 into a tri-fluid counter-flow heat exchanger 32. The sea water is heated to near its boiling temperature in the heat exchanger 32 wherein it is then passed out of the heat exchanger by tube 33 into a liquid jacket 34 which surrounds the motor 6. Waste heat from the motor 6 is conserved in this embodiment not only by the shaft energy of the drive motor. but also its waste heat, and the heated sea water is removed from the liquid jacket 34 by tube 35, providing maximum conservation of energy. This is one of several instances in the present invention where conservation of energy is achieved and the utilization of energy is made at the level at which it is available. The heated sea water flows through the thermostatic valve 36 which maintains the operation temperature at design level. and may be used to reduce the initial water flow to promote start-up heating. Hence. the valve 36 provides for automatic start-up and for stable operation at design temperatures in spite of raw feed fluid temperatures changing with changing seasons. purified fluid demand or otherwise.
The flow of the sea water up to this point has all been designed to preserve conservation of encrgyby utilizing all waste heat andcnergy in the system. and to optimize the system to its maximum. For the purification of sea water to become commercial. the system must be economical and must be optimized to make the device of simple construction and maintenance and sufficiently efiicicnt in its operation to be competitive even in small sizes.
For sea water purification, current desalinization machines must be extremely large and expensive to achieve economical operation. They must operate at very high pressures requiring sophisticated and expensive equipment, or use membranes or microtubes which are difficult to clean or expensive to replace. For concentrating fluids, membrane filtration equipment currently available for separating solutions is limited to light concentrations of dissolved chemicals. Currently available rotary still designs have disadvantages as compared to the proposed embodiment.
From the valve 36. the sea water flows through the tube 37 into the disc chamber housing 4 to a spray ring 38 in the evaporation chamber 10. The spray ring 38 has a number of nozzles of injector plate arrangements to spray the sea water against one of the rotating discs 2 mounted on the drum 3. Alternatively, the sea water may be flowed onto the discs 2. The sea water is sprayed as a fine mist due to the size and number of the nozzles in the spray ring 38. The temperature of the side of the disc 2 in the evaporation chamber is higher than the boiling point for sea water, at the pressure existing in the chamber 10. and accordingly, some of the sea water is converted to steam which passes through the openings 39 in the hollow drum 3. The remaining sea water on the disc 2 becomes a more concentrated brine" solution. Because of the centrifugal force imparted to the brine solution, as it approaches the rotation velocity of the disc 2, the brine solution is slung toward the periphery of the disc 2. The brine solution slung off the disc 2 flows into and fills one of the annular brine channels 40 in the rotating disc chamber housing 4. The brine solution is removed from the brine channel 40 by a tangential orifice 41 and is taken by the tube 42 to a second spray ring 43. The brine solution which is under pressure from the rotational velocity imparted to it from the disc is sprayed on the evaporation side of the second of the discs 2 in evaporation chamber ll. This second evaporation effect operates similarly to the first effect previously described. The temperature of the side of the disc in the evaporation chamber ll being higher than the salt water boiling point at the pressure existing in chamber 11 results in some of the water being converted to steam which enters drum 3 through the openings 44. A higher concen trated brine is slung off of the second disc 2 into a concentrated brine channel 45. The highly concentrated brine is removed from the brine channel 45 by a tangcntal orifice 46 and passed through the tube 47 into the tri-fluid counter-flow heat exchanger 32. The hot brine is cooled in the heat exchanger 32 and is removed from the heat exchanger 32 by tube 48 wherein it is passed through venturi 49 to a brine outlet 50. Although a dual effect design is presented above, an alternative single effect embodiment is compatible with this machine by connecting spray rings 7| and 43 in parallel to valve 36 and connecting brine outlets 41 and 46 in parallel to tube 47.
The steam generated in evaporation chambers 10 and l 1. respectively. is sucked through openings 39 and 44 in the hollow drum 3. The steam passes through the spider [5 which permits axial flow of vapor therethrough into a gas compressor 8. The gas compressor 8 may either be a multistage fan, or other type ofsingle or multi-stage gas compressor. The compressor 8 may be driven by a separate motor. or as shown in this cni (il l bodiment, driven by the main drive motor 6 through the gear train 7.
The gear train 7 which is merely illustrative has a drive gear Sl which is keyed to the shaft 5. The drive gear 51 drives the gear 52 on the idler shaft 53. The idler shaft 53 has keyed to it a gear 54 which drives the gear 55. The gear 55 drives the high speed drum 56 which supports and drives multi-stage compressor fans 57 and 58.
To prevent salt water particles from being sucked into the hollow drum 3 from the evaporation chambers 10 and 11, gravity drain mesh, fiber strainer, or centrifugal louvered droplet slingers 59 and 60, respectively, may be used to prevent salt water particles from enter ing the hollow drum 3 and the compressor 8. By using the slingcrs 59 and 60, the salt water particles are slung upon impacting the slingers inclined slats radially outwardly and back toward the rotating disc 2, while the steam passes between the slats of the slingcrs 59 and 60 into the hollow drum 3 and into the compressor 8. The compressor 8 raises the pressure and temperature of the steam. as well as the condensation temperature, and in general, results in the steam becoming superheated. This higher pressure steam at its higher temper ature is removed from the compressor 8 through the discharge duct 61 into condensing chamber 12. This high pressure steam condenses on the surfaces of rotating discs 2 which form the condensation chamber 12. The condensed fresh water is slung from the rotating discs 2 into annular fresh water channels 62 and 63. The fresh water is removed from fresh water channels 62 and 63 by radial water outlet orifices 64 and 65, respectively. The fresh water is collected in the tube 66 which is passed into tri-fluid counter-flow heat exchanger 32. The hot fresh water is removed from the heat exchanger 32 as cooler water by the tube 67 where it is passed through a venturi 68 through outlet 69 to a pure water storage tank (not shown).
Since super-heated steam is difficult to condense in spite of the low energy required to super-heat the steam. and to provide intercooling of the compressor 8 to increase the efficiency of the compressor close to adiabatic conditions, a small quantity of fresh water is metered out of tube 66 by the valve 70 and sprayed in an extremely fine mist by spray ring or set of jets 71 into the inlet of the compressor 8. The fine spray mist of fresh water de-super-heats the steam as it passes from the hollow drum 3 into the compressor 8, and brings the steam down in temperature to saturation temperature. Alternatively. water may be sprayed into the compressor 8, in which the rotary action of the blades will further divide the water into fine particles for easier evaporation during the long path length through the compressor 8 and its discharge duct 61. The addition of water to the compressor 8 serves both to de super-heat the steam and to remove some of the waste heat energy of the compressor 8 caused by friction. turbulence, or other energy losses. to increase the compressor efficiency. decrease compressor power requirements, and increase the mass flow of steam through the compressor 8. The saturation temperature of the steam at the compressor outlet 61 is higher than the saturation temperature under the pressure conditions at the inlet of the compressor 8. Accordingly. the condensing sides of the disc 2 are hotter than the sides where evaporation takes place. This results in not heat flow from the steam in the condensing chamber I2 to the steam in evaporation chambers I and II.
While an overall general description of the rotary dc salting engine of the present invention has been set forth. there are several matters relating to specific aspects of the present invention which should be set forth. The first aspect is directed to the rotating circular disc 2 which are mounted on and driven by the hollow drum 3. In the embodiment of FIG. I. there are two discs 2 which are tied together for structural integrity and geometric stability.
Around the periphery of the disc 2 are disc seal collector channels 40, 62, 63 and 45, respectively. Because fluid is forced by centrifugal force into the col lector channel, this arrangement provides a gas and liquid seal which relies solely on the hydrodynamic forces created by the disc rotation. Referring to FIGS. 2 and 3 for more detail, the disc 2 in FIG. 2 has a bifurcated terminating portion with one leg 73 extending into the channel 62. The concentrated brine solution which is slung from the disc 2 into the channel 40 forms a set of counter-rotating helical vortices in the channel 40 until it is withdrawn out of tangential orifice 41. The fluid as it begins to fill the channel 40 will be removed as it en ters the orifice 41 which controls the fluid level in the channel. In the same manner. the fresh condensed water will be slung off the disc 2 into the channel 62 and be removed from the tangental orifice 64. The portion 75 is a rise between the channels 40 and 62 which prevents fluid from passing from one channel to the other.
Referring to FIG. 3, there is an alternative arrangement of a disc seal collector. In this modification, the disc is flat at its periphery. The chambers and I2 are identical to that described in FIG. 2, as well as the channels and 62 and the orifices 41' and 64'. respectively. In this modification, the wiping seal is contained in the rotary disc housing structure and one por tion 73' extends from the limits of the channel 40' whereas a second portion of the seal 74' extends from the channel 62'. The rotary disc extends into a depression 75 in this modification.
The fluid slung off the discs 2 flows into and fills the annular channels in rotary disc chamber housing 4. The fluid, which is under pressure due to its high centrifugal force. and which is rotating in the channels as a single clockwise vortex. or dual counter-rotating helical vorti ces caused by disc-induced rotation. acts in conjunction with the disc running in the channel as a pressure seal between chambers 10 and I2 and chambers 11 and I2. The level of fluid in the channels is adjusted by the position of outlet orifices relative to the bottom of the channel. The pressure of the rotating fluid is communicated to the fluid outlet so that the disc, in effect. also acts like a second pump of a centrifugal type. If this pressure is too high because of excessive fluid rotational velocity resulting in energy waste. backward curved grooves can be cut in the disc surface to reduce the fluid rotational speed.
Another specific aspect of the present invention re latcs to the removal of dissolved or entrained gas in the system. Referring to FIG. 4, there is shown an example of a liquid phase device whereas in FIG. 5, there is an e\amplc of a vapor phase device.
Referring to FIG. 4, and utilizing the same reference numerals as in FIG. I. the degasser 24 of FIG. 4 has an inlet tube 23. and an outlet tube 25. A flow control uti free 76 is in the liquid inlet tube 23 to the degasser 24. Circular peripheral flow spill trays 77 and center flow spill trays 78 are stacked alternately and spaced vertically within the degasser 24. A float 79 pivoted from the rocker arm and support 80 and hinged to the gas valve actuating rod 81 operates a valve 82 in the gas outlet 83. The pum suction applied by pump 27 through outlet tube 25 applies suction through the dc gasscr 24 through restriction orifice 76. The impedances of the lines, filters and sea water lift requirements before degasser 24 create the suction heat which causes the dissolved gas in the sea water to appear as small gas bubbles and evolve from the fluid it cycles radially in and out in thin sheets over the spill trays 77 and 78. The evolved gases which are lighter than the fluid fill the top of degasser 25 from which they are sucked out through outlet 83 due to the vacuum created as the brine solution passes through the venturi 49. Float 79 assures that the pump is always supplied with liquid and not gas since it closes the passage to the pump when the liquid level drops and opens when the liquid rises to a set level.
Referring to FIG. 5. the specific aspects of the degasser 30 are illustrated. Using the same reference numerals as in FIG. I, introduced into vapor phase degasser 30 is a mixture of evolved gas and vapor picked up by a T 84 shown in FIG. I at the outer peripheral region of condensing chamber 12. Due to the higher density of the evolved gas as compared to the vapor, the gas is concentrated near the periphery of the rotating disc due to the centrifugal force created by the rotation. This mixture passes through the T 84 into a tube 85 and metering valve 86 which adjusts and optimizes the flow into the vapor degasser 30 to limit vapor loss with asso ciated system energy loss. Sea water is introduced by the tube 29 into the degasser 30 whereas the water exits the degasser 30 by the tube 31. In the degasser 30, the vapor and gases from tube 85 flow through the helical tube coil 87 immersed in the liquid cooling annulus 88. The vapor is condensed into liquid or fresh water and collecting at the bottom of the degasser 30 whereas the evolved gas is cooled and collects in the gas space above the liquid. A liquid float 89 opens a valve 90 in the outlet line 91 when liquid or water collects, and which is drawn out through the fresh water line 67 by the venturi 68. Thermostatic gas valve 92 in the tube 93 allows any collected cooled gases to be removed from the system, but would block the flow of the hot vapor should there be any in the gas space.
From the above description, it is obvious that both liquid and vapor phase degassers should function with a negligible energy requirement and conserve the energy available in the fluids supplied to them. This is not true with other known degassing devices which either require power consuming pumps or throw away energy by discharging heated vapor with the evolved gas.
Referring to FIG. 6, wherein another embodiment of the present invention is illustrated. a rotary dcsalting device IOI has a single rotating disc I02 which extends from a hub I03. The rotating disc I02 rotates in a rotating disc chamber housing 104. The rotating disc I02 is attached through the hub 103 to an armature shaft I05 of a dri\e motor I06. The armature shaft 105 also drncs a gear train 107 which in turn drives the compressor fan of the compressor 108.
As shown in the embodiment of FIG. I), there is a sin gle rotating circular disc I02 which is mounted on and driven by the armature shaft which is connected to the disc by means of the hub 103. The rotating disc 102 as it rotates in rotating disc chamber 104 forms an evaporation chamber 109 on one side of the rotating circular disc 102 and a condensing chamber 1 10 on the other side of the disc 102. In this embodiment of the present invention, collection channel means 111 are attached to the periphery of the disc 102. The collec tion channel means 111 has one channel 112 to collect the brine from the evaporation chamber 109, and a second channel 113 which collects the fresh water from the condensing chamber 110. The details of the collection channel means 111 and each of the channels 112 and 113 are seen in more detail in FIG. 7. Inserted into each of the collection channels is one or more stationary scooping devices 114 and 115, scooping device 114 being in channel 112 and scooping device 115 being in channel 113. The scooping devices 114 and 115 are fashioned in such away as to minimize the flow disturbances associated with placing a stationary object in a moving stream of fluid. A shield (not shown) may be placed on the scoops 114 and 115 in order to divert any fluid which is splattered by the scoop back onto the disc 102 or into the collection channels 112 or 113. By removing the fluids in the manner just described. the power loss associated with shearing of the water between a stationary channel wall and a moving disc does not occur. hi this embodiment. however. the seal means between the evaporation chamber 109 and the condensing chamber 110 is a wiping seal 116 which is held within a slot in the rotating disc chamber housing 104 by means of block 117. The wiping seal 116 is placed on the side of the rotating disc 102 on the high pressure or condensing chamber 1 10 so as to be forced into contact with the collection channel means 111. Alternatively. the seal means in this embodiment may be a stationary member (not shown) held by the rotating disc chamber housing 104 which extends from the housing into the fluid in one of the channels in channel means 111 and seals chamber 109 from chamber 110. Preferably, however. channel means 111 would have a separate channel filled with fluid for the stationary member to extend into so as not to disturb the fluids within channels 112 or 1 13. Such a seal means provides a hydrodynamic seal similarly as described with regard to the embodiment of FIG. 1.
in order to allow the heat transfer from the condens ing chamber 110 to the condensing chamber 109 to be as great as possible. the disc 102 is constructed from very thin, highly heat conductive material. in order to increase the structural integrity of this thin disc 102, a system of supporting spokes may be used as is shown in FIG. 8. Two sets ofspokcs are shown eminating from the central hub 103 of the disc 102. Spokes 118 are at tached to a mid-radius locus of the disc 102 while an other set of spokes 119 are attached at the disc periphcry. The spokes 119 have an adjustment capability through adjustment means 120. This adjustment capability is used to move the periphery of the disc 102 back and forth in an axial direction in order to adjust the pressure with which the wiping seal 116 bears on the collection channel means 111 and to eliminate wobble of the disc 102. This adjustment may also he used to rc duce the leakage and the power drawn by the wiping seal 116.
1n the embodiment of FIG. 6. the flow of water to the disc 102 is different from the embodiment set forth hereinbcfore. In this embodiment one or more mid-disc distributors 121 are attached by a plurality of post means 122 to the rotating disc 102 as shown in more detail in FIG. 9. Referring to FIG. 9, water is fed from tube 123 tangentially into the top of a Ushaped member 124 which forms the outer ring 124' of the distributor 121 at a rate preferably at or near the rotational speed of the disc 102 so that the water is essentially laid into ring 124. The plurality of post means 122 are at tached at the top of the U of thc U-shapcd member 124. Extending from the bottom of the U of the U shaped member 124 is a skirt means 125 which forms a second ring 125'. When outer ring 124 is full, the water overflows into a second ring 125' which also fills and overflows. By the time that the water overflows ring 125" it is uniformly distributed within the distributor 121 by attaining the same rotational velocity as the disc 102 through shear between the water and the rings 124' and 125' and becomes evenly distributed around the ring by eentrifugally induced hydrostatic forces thus capable of being equally supplied to the disc 102 in all radial directions. The water overflowing the second ring 125' flows onto an extended lip means 126 which is tapered to a knif edge. The knife edge is inset into a depression region 127 of the disc 102. \Nhen the water reaches the knife edge it is slung by centrifugal force into the wall of the depression 127 in the disc 102. Once the water has contacted the disc 102, adhe sion forces causes it to remain in contact with the disc 102 and the centrifugal force causes the water to move radially outward in a thin, uniform film. The mid-disc distributor 121 being attached to the disc 102 is rotat ing at the same speed as the disc 102 which uniquely promotes even distribution of the water on the disc 102 and enables high heat transfer on the disc 102 due to the thin. uniform film which results. W'ater is shown as being fed to the disc 102 in only two locations in FIG. 6, but as many distribution places as may be practical may be used. Only the minimum amount of water rcquircd to cover the disc area between distributors 121 is fed at each distributor location. By so doing. the film thickness inside the final distributor is, on the average. significantly thinner than with a single central feed point. Hence. the resistance to heat transfer caused by the excess film thickness is overcome.
To illustrate the use of the rotary desalting device 101 a process for the desalination of sea water will be described. The sea water is drawn into the rotary desalting device 101 through an intake to a strainer 128 to remove any solid material. The sea water thereafter may pass into a liquid phase dcgasser 129, the details of which may be set forth hercinbefore. The water is drawn into the rotary desalting device 101 by means of pump 130 which may be driven by motor 106 through gear train 107. After the water is drawn through pump 130, the water is passed through a unique ion-exchange water pretreatment system 131 to remove dissolved or suspended material that the process will not otherwise remove. The treated water then passes through pipe 132 into a tri-fluid counter-flow heat exchanger 133. The sea water is heated to near its boiling temperature in the heat cschangcr 133 and then passes out of the heat exchanger 133 by pipe 134 into a motor water jacket 135 wherein the heat from the motor I06 is picked-up by the water. \Nater from the motor water jacket [35 flows to a heat rcscnoir 136 containing a heater Thus. heat can be easily added to the water as it passes through heat reservoir 136. especially during start-up. The water exiting the heat reservoir I36 flows by line 137 where it is divided into two streams. One stream 138 is controlled by a preset valve 139 which allows a fraction of the water to be supplied to the middisc distributor 121. By this means a portion of the water during the start-up provides lubrication in the form of the sea water. to get to the wiping seal I I6 and hastens systems start-up by restricting the water flow during start-up. The other stream 140 is controlled by a thermostatic valve 141 which remains closed until the water reaches operating temperature.
After start-up has been achieved and the system has reached operating equilibrium. the heated sea water leaves the heater resevoir I36 and flows through both lines 138 and 140. the thermostatic valve 141 being open during system equilibrium. The heated sea water flowing through line 138 is introduced by a tube 123 to the mid-disc distributor 121 and flows onto the disc 102 as has been described hereinbefore. Water flowing through line 140 is passed through a tube 142 directed into the depression 143 in the hub 103 of the disc 102. As the depression 143 fills, the water begins to over flow. The overflow of the water takes place uniformly, supplying water to the disc I02 equally in all radial dircctions. This uniform overflow gives rise to a uniform distribution of water on the disc 102. As can be seen by the description of the distribution of the water on to the rotating disc 102, a very thin film of water is formed uniformly on the entire rotating disc 102 increasing the heat transfer due to the extremely thin water film thickness.
As the water is introduced to the rotating disc 102 due to the heat being applied to the opposite side. the
temperature of the disc in the evaporating chamber 109 is higher than the boiling point for sea water. at the pressure existing in the chamber 109, and accordingly. some of the sea water is converted to steam. The remaining sea water on the disc I02 becomes a more concentrated brine solution. Because of the centrifugal force imparted to the brine solution. the brine solution is slung toward the periphery of the disc 102 where it fills the collection channel 112 of the collection chan' nel means 111. The brine solution is removed from channel 112 by means of scooping device 114 and removed by a tube 144 where it passed by line I45 into the tri-fluid counter-flow heat exchanger 133. The brine solution is cooled in the heat exchanger 133 and then removed by line 146.
The steam generated in evaporation chamber 109 is passed through tube 147 into the gas compressor 108. The gas compressor 108 may either be a multi-stage fan. or other type of single or multi-stage gas compressor. A compressor 108 may be driven by a separate motor. or as shown in FIG. 6. driven by the main drive motor 106 through the gear train 107.
The steam after compression is in a super heated condition when it exits the compressor 108. It exits through a pipe 148 where it is passed into the condensing chamber 110. In the pipe 148 may be a spiral tube (not shown) wherein a small amount of fresh water may be introduced into the super heated steam leaving the compressor 108. The water flowing through the spiral tube of the de-super heater is heated by the steam which flows around the tube. The water thus enters the stream of super heated steam in pipe 148 as heated water or a mixture of water and saturated steam and is readily entrained by the moving stream which has lost its super heat energy to the fresh water by the time it reaches the condensation chamber 110. The advantage of such a de-super heater is that it does not necessitate introducing the de-super heating water as a finely divided sprayv The compressed steam which enters the condensa tion chamber is restrained from passing around the periphery of the rotating disc 102 into the evaporation chamber 109 by the wiping seal 116. The steam condenses on the rotating disc 102 where it is slung by the centrifugal forces to the periphery of the rotating disc I02 and the water collection channel 113. The scooping device picks up the water and passes it through tube 114 where it is passed by line 150 to the tri-fluid counter-flow heat exchanger 133. The cooled fresh water is removed from the heat exchanger 133 through pipe 151 where it is passed to a pure water storage tank (not shown).
Whereas the prior art discloses distillation operations with rotating cones and curved drums at low rotational speeds producing centrifugal accelerations of the water of 10s of gs the present invention permits l00s or 1.000s of gs of centrifugal acceleration of water because of the design of the plane disc. seal and water distribution system. This high acceleration coupled with the unique water distribution system causes a very thin. uniform water film on the disc. which in turn produces a heat transfer coefficient of about 5 times that claimed in publications related to the prior art. For example the design of the present invention has permitted a disc heat transfer coefficient of 8.700 BTU/ft hr. F for a [6 inch diameter disc rotating at L725 RPM which produces 680 gs at the perimeter. A 6 foot diameter disc rotating at this speed would produce 2.500 gs at the perimeter and a somewhat higher heat transfer coefficient. Since a contiguous film was obtained in practice on a 16 inch diameter disc turning at 3,450 RPM with a perimeter centrifugal acceleration of 2.720 gs which is approximately equal to the gs on the 6 foot disc. the 6 foot disc may be operated at the l .725 RPM speed. Because of the difficulty of spinning flexible curved drums or cones at high speed with their attendant vibration and distortion problems under load. it is not believed that the high gs are possible with the prior art. since for good heat transfer. the drums or cones must necessarily be thin and are necessarily limited in size.
The nature and objects of the present invention having been completely described and illustrated. and the best mode thereof contemplated set forth. What I wish to claim as new and useful and secure by Letters Patent is:
I. A liquid distributor which comprises: a U-shaped means forming an outer ring; a plurality of post means for attaching said U-shaped means to a disc which are attached to the top of the U of said U-shaped means;
skirt means extending from the bottom of the U of said U-shaped means on the same side said post means which forms a second ring; and
extending lip means extending from said skirt means as a tapered knife edge.
2. A liquid distributor according to claim I which furthcr includes a thin disc.
3. A liquid distributor according to claim 1 which further includes a tube which feeds the fluid tangentially into said outer ring.
4. A liquid distributor for distributing a liquid on a surface which comprises:
a circular skirt extending away from said surface with one edge of said skirt terminating adjacent said surface in spaced relationship thereby forming a lip for evenly distributing said liquid onto said surface;
an outer annular wall attached to said skirt at a point removed from said lip of said skirt. said outer annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt;
at least one inner annular wall attached to said skirt at a point intermediate said outer annular wall and said lip said inner annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt;
and means to rotate said circular skirt about its axis.
5. The liquid distributor of claim 4 wherein the height of said inner annular wall is less than the height of said outer annular wall.
6. The liquid distributor of claim 5 including means to feed liquid into the space intermediate said outer an nular wall and said inner annular wall whereby liquid fills said space overflows said inner annular wall onto said skirt and flows to said lip 7. The liquid distributor of claim 6 wherein said lip is a tapered knife edge,
8. The liquid distributor of claim 7 wherein said circular skirt is attached to said surface by a plurality of post means.
9. The liquid distributor of claim 8 wherein said surface has a circular depression adjacent said lip and said tapered knife edge is inserted into said circular depresslon,
(ill
It). The combination of a disc with at least one liquid distributor means for distributing liquid on the surface of said disc wherein said liquid distributor means includes a circular skirt extending away from the surface of said disc with one edge of said skirt terminating adjacent said disc thereby forming a lip for evenly distributing said liquid onto the surface of said disc;
an outer annular wall attached to said skirt at a point removed from said lip of said skirt. said outer annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt;
at least one inner annular wall attached to said skirt at a point intermediate said outer annular wall and said lip, said inner annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt;
and means to rotate said circular skirt about its axis 11. The combination of claim 10 wherein the height of said inner annular wall is less than the height of said outer annular wall 12. The combination of claim 11 including means to feed liquid into the space intermediate said outer annular wall and said inner annular wall whereby liquid fills said space overflows said inner annular wall onto said skirt and flows to said lip.
13. The combination of claim l2 wherein said lip is a tapered knife edge,
14. The combination of claim I]: wherein said circular skirt is attached to said disc by a plurality of post means,
15. The combination of claim 14 wherein said disc has a circular depression adjacent said lip and said ta pered knife edge is inserted into said circular depres sion

Claims (15)

1. A liquid distributor which comprises: a U-shaped means forming an outer ring; a plurality of post means for attaching said U-shaped means to a disc which are attached to the top of the U of said U-shaped means; skirt means extending from the bottom of the U of said U-shaped means on the same side as said post means which forms a second ring; and extending lip means extending from said skirt means as a tapered knife edge.
2. A liquid distributor according to claim 1 which further includes a thin disc.
3. A liquid distributor according to claim 1 which further includes a tube which feeds the fluid tangentially into said outer ring.
4. A liquid distributor for distributing a liquid on a surface which comprises: a circular skirt extending away from said surface with one edge of said skirt terminating adjacent said surface in spaced relationship thereby forming a lip for evenly distributing said liquid onto said surface; an outer annular wall attached to said skirt at a point removed from said lip of said skirt, said outer annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt; at least one inner annular wall attached to said skirt at a point intermediate said outer annular wall and said lip, said inner annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt; and means to rotate said circular skirt about its axis.
5. The liquid distributor of claim 4 wherein the height of said inner annular wall is less than the height of said outer annular wall.
6. The liquid distributor of claim 5 including means to feed liquid into the space intermediate said outer annular wall and said inner annular wall whereby liquid fills said space, overflows said inner annular wall onto said skirt and flows to said lip.
7. The liquid distributor of claim 6 wherein said lip is a tapered knife edge.
8. The liquid distributor of claim 7 wherein said circular skirt is attached to said surface by a plurality of post means.
9. The liquid distributor of claim 8 wherein said surface has a circular depression adjacent said lip and said tapered knife edge is inserted into said circular depression.
10. The combination of a disc with at least one liquid distributor means for distributing liquid on the surface of said disc wherein said liquid distributor means includes a circular skirt extending away from the surface of said disc with one edge of said skirt terminating adjacent said disc thereby forming a lip for evenly distributing said liquid onto the surface of said disc; an outer annular wall attached to said skirt at a point removed from said lip of said skirt, said outer annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt; at least one inner annular wall attached to said skirt at a point intermediate said outer annular wall and said lip, said inner annular wall extending from said skirt inwardly toward the center of the circle defined by said skirt; and means to rotate said circular skirt about its axis.
11. The combination of claim 10 wherein the height of said inner annular wall is less than the height of said outer annular wall.
12. The combination of claim 11 including means to feed liquid into the space intermediate said outer annular wall and said inner annular wall whereby liquid fills said space, overflows said inner annular wall onto said skirt and flows to said lip.
13. The combination of claim 12 wherein said lip is a tapered knife edge.
14. The combination of claim 13 wherein said circular skirt is attached to said disc by a plurality of post means.
15. The combination of claim 14 wherein said disc has a circular depression adjacent said lip and said tapered knife edge is inserted into said circular depression.
US427793A 1972-05-11 1973-12-26 Rotary desalting device Expired - Lifetime US3904122A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6500216B1 (en) * 1997-02-18 2002-12-31 Masakatsu Takayasu Method and apparatus for desalinating sea water, natural salt and fresh water
US20050045466A1 (en) * 2000-07-18 2005-03-03 Jack Bitterly Saline/sewage water reclamation system
US20100326812A1 (en) * 2002-08-07 2010-12-30 Deka Products Limited Partnership Method and Apparatus for Phase Change Enhancement

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US2869175A (en) * 1957-09-03 1959-01-20 American Rock Wool Corp Fiberizing steam ring
US2902223A (en) * 1950-06-26 1959-09-01 Niro Corp Liquid atomizers
US2917241A (en) * 1958-06-23 1959-12-15 Amchem Prod Centrifugal spray device
US3346192A (en) * 1963-12-18 1967-10-10 Hege Hermann Atomizing apparatus

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Publication number Priority date Publication date Assignee Title
US2902223A (en) * 1950-06-26 1959-09-01 Niro Corp Liquid atomizers
US2869175A (en) * 1957-09-03 1959-01-20 American Rock Wool Corp Fiberizing steam ring
US2917241A (en) * 1958-06-23 1959-12-15 Amchem Prod Centrifugal spray device
US3346192A (en) * 1963-12-18 1967-10-10 Hege Hermann Atomizing apparatus

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6500216B1 (en) * 1997-02-18 2002-12-31 Masakatsu Takayasu Method and apparatus for desalinating sea water, natural salt and fresh water
US20050045466A1 (en) * 2000-07-18 2005-03-03 Jack Bitterly Saline/sewage water reclamation system
US7540944B2 (en) * 2000-07-18 2009-06-02 Jack Bitterly Saline/sewage water reclamation system
US20100326812A1 (en) * 2002-08-07 2010-12-30 Deka Products Limited Partnership Method and Apparatus for Phase Change Enhancement
US9005393B2 (en) * 2002-08-07 2015-04-14 Deka Products Limited Partnership Method and apparatus for phase change enhancement

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