US3902484A - Disposable surgical drape - Google Patents

Disposable surgical drape Download PDF

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US3902484A
US3902484A US45831574A US3902484A US 3902484 A US3902484 A US 3902484A US 45831574 A US45831574 A US 45831574A US 3902484 A US3902484 A US 3902484A
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Prior art keywords
foam material
fatty acid
surgical drape
sheet
drape
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Terry L Winters
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Kimberly-Clark Corp
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Kimberly-Clark Corp
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B46/00Surgical drapes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00Chemistry of carbon compounds
    • Y10S260/15Antistatic agents not otherwise provided for
    • Y10S260/19Non-high polymeric antistatic agents/n
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24496Foamed or cellular component
    • Y10T428/24504Component comprises a polymer [e.g., rubber, etc.]
    • Y10T428/24512Polyurethane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24752Laterally noncoextensive components

Abstract

An improved disposable surgical drape comprising a fibrous base sheet, a fluid impervious plastic layer covering at least a portion of the base sheet, the improvement comprising a sheet of flexible, normally hydrophobic, open celled foam material bonded to the outer surface of the plastic layer, the foam material being treated with the reaction product of a mineral acid and a fatty acid tertiary amine wherein the amine is partially neutralized to a fatty acid tertiary ammonium salt which renders the foam material antistatic, while providing increased rates of fluid absorption and reduced tendency for lathering when the foam material is rubbed with water present on the foam material.

Description

Winters [451 Sept. 2, 1975 DISPOSABLE SURGICAL DRAPE Inventor: Terry L. Winters, Neenah, Wis.

Assignee: Kimberly-Clark Corporation,

Neenah, Wis.

Filed: Apr. 5, 1974 Appl. No.: 458,315

Related US. Application Data Continuation of Ser. No. 223,990, Feb. 7, 1972, abandoned.

US. Cl 128/132 D; 161/145; 161/160; 161/164; 161/165; 161/190; 161/251; 260/326 N; 260/DIG. 19

Int. Cl. A6lf 13/00 Field of Search 128/132 D, 188; 161/39, 161/59, 86,88,145,164,149,151,159, 161/160, 170, 190; 260/326 N, DIG. 19

References Cited UNITED STATES PATENTS Schleede et a1 128/132 D Donnelly 128/132 D 3,738,359 6/1973 Lindquist et a1. 128/132 D Primary Examiner-Richard A. Gaudet Assistant Examiner-Henry .l. Recla Attorney, Agent, or Firm-Wolfe, Hubbard, Leydig, Voit & Osann, Ltd.

An improved disposable surgical drape comprising a fibrous base sheet, a fluid impervious plastic layer covering at least a portion of the base sheet, the improvement comprising a sheet of flexible, normally hydrophobic, open celled foam material bonded to the outer surface of the plastic layer, the foam material being treated with the reaction product of a mineral acid and a fatty acid tertiary amine wherein the amine is partially neutralized to a fatty acid tertiary ammonium salt which renders the foam material antistatic, while providing increased rates of fluid absorption and reduced tendency for lathering when the foam material is rubbed with water present on the foam material.

ABSTRACT 4 Claims, 2 Drawing Figures PATENTED I 2l975 DISPOSABLE SURGICAL DRAPE RELATED APPLICATIONS This is a continuation of application Ser. No. 223,990, filed Feb. 7, 1972, now abandoned.

Donnelly, Ser. No. 17,431, filed Mar. 9, 1970 now U.S. Pat. No. 3,668,050.

Schrading and Winters, Ser. No. 58,336, filed July 27, 1970 now U.S. Pat. No. 3,669,106.

DESCRIPTION OF THE INVENTION The present invention relates generally to disposable surgical drapes and, more particularly to surgical drapes having an absorbent foam material covering the primary operative area.

There have been many new commercial developments in disposable articles for use in hospitals, clinics, and the like, particularly with respect to surgical drapes that are intended for only a single use. Since such disposable surgical drapes are less expensive to initially produce, coupled with the fact that they need not be laundered and sterilized for repeated uses has resulted in their capturing a significant commercial market, which is generally predicted to increase as labor costs associated with laundering and other handling increase. Among the more significant recent developments in disposable surgical drapes are those drapes disclosed in the Donnelly application Ser. No. 17,431, filed Mar. 9, 1970 now U.S. Pat. No. 3,668,050 as well as the Schrading and Winters application, Ser. No. 58,336, filed July 27, 1970 now U.S. Pat. No. 3,669,106 all of which are assignee to the assignee of the present invention.

Features common to the surgical drape disclosed in these applications involve a fibrous base sheet and a sheet of fluid impervious plastic film attached to the base sheet as well as a fluid absorbent plastic foam material bonded to the plastic film in the primary operative area of the surgical drape.

Preliminary to a detailed description of the improved surgical drape of the present invention, it should be pointed out that the use of open celled foam material in at least the primary operative area, including the fenestration area of a laparotomy sheet for example, has experienced widespread acceptance, particularly when it is combined with an underlayer of fluid impervious plastic or film, since the combination is strong and abrasion resistant even when exposed to liquids and when subjected to physical contact and manipulation that are encountered during the course of an operation. A laparotomy sheet is an elongated generally rectangular sheet used to cover the patient during thoracic or abdominal surgery, and is typically about 6 to 8 feet in length and about 3 to 6 feet in width. The layer or film of fluid impervious plastic prevents the liquid encountered during operating procedures from striking through the sheet and thereby prevents passage of bacteria through the sheet. Moreover, the foam material has a high frictional coefficient that prevents dislodgement of surgical instruments, supplies and the like when placed on the surface of the sheet during an operation. The foam material is stable at conditions encountered during sterilization treatments either by steam or ethylene oxide or the like, and the combination of film and foam material has good draping characteristics which are desirable for conforming the drape to the pa tient during an operation. The open cell foam material is also fluid absorbent to minimize fluid run-off that is invariably encountered during most operations.

When drapes are used in anesthetizing locations, it is of utmost importance to prevent sparking due to the buildup of static electrical charges on the drapes, which can be hazardous since explosive anesthetizing gases and oxygen are often present in operating rooms. The governing criteria for electrical surface resistivity of fabrics used in anesthetizing locations is set forth in the Code for the Use of Flammable Anesthetics, 1960) published by the National Fire Protection Association in their publication No. 56 (hereinafter referred to as the Code). Appendix A, Section 35 1 3-Textiles, requires that the surface resistivity of the fabric should be measured at an ambient relative humidity of 50 percent and temperature of 23C by method 76-59 of the American Association of Textile Chemists and Colorists (U.S.A.C.L. 14.1 12-1961) and states that the measured value should be less than 5 X 10 ohms per square unit of the material.

Although many chemical treatments are known to provide antistatic properties when applied to hydrophobic fibers, films and other surfaces, many of such treatments have been found to be deficient in one or more respects. For example, some compounds are simply unsuitable in that they fail to provide sufficient con ductivity or, in other words, fail to lower the surface resistivity to acceptable limits or values that satisfy the hereinbefore identified standard when applied to materials used in locations that have flammable anesthetics. Other chemicals are soluble only with isopropanol, which is flammable and thus creates a hazardous environment and may require expensive explosion proof processing equipment for its use. Additionally, other antistatic agents, when applied to foam materials, exhibit a severe lathering characteristic when treated material is rubbed with water present on the material. Still other chemical treatments are unsuitable because their use during the process of treating ,the material is accompanied by the presence of irritating vapors. Simi larly, with some chemicals the resulting treated material may cause dermatological problems with patients or others coming in contact therewith.

One chemical that is available as an antistatic agent is a fatty acid tertiary amine having the structural formula:

wherein R signifies an alkyl group containing from 12 to 18 carbon atoms. While the alkyl group may be a mixture of various fatty acids, one desirable source is tallow. A tallow tertiary amine having the above structural formula is supplied by the Armour Industrial Chemical Company, Chicago, Illinois under the tradename Ethomeen T/l2. The Ethomeen T/12 tallow fatty acid is sold as an antistatic agent for use on most hydrophobic fibers and is also known to have surfactant or wetting action properties.

Another source of an antistatic agent including a fatty acid tertiary amine is sold by Paint Products Laboratory of Chicago, Illinois, under the tradename of Statex PC319. This product, comprising a fatty acid tertiary amine partially neutralized to the correspond-. ing ammonium salt, has been used, for example, as an antistatic treatment for nylon, other textiles and airplane windows. While use of this material does reduce the surface resistivity of acceptable levels when applied to foam material, the treated foam does exhibit the undesirable lathering characteristic when vigorously rubbed with water present on the foam material.

It is a primary object of the present invention to provide a disposable surgical drape having an open celled foam material on the outer surface in at least the primary operative area, wherein the foam material is treated to provide significantly improved desirable attributes.

More specifically, it is an object of the present invention to provide an improved surgical drape of the hereinbefore described type wherein the foam material is treated to equal or exceed surface resistivity values that are required for use in operating rooms or the like.

Still-another object of the present invention provides for a surgical drape wherein the foam material is treated to produce the above mentioned surface resistivity and additionally exhibits superior rates of fluid absorbency.

Yet another object is to provide a surgical drape that exhibits the above desirable attributes, but which does not exhibit sudsing or lathering characteristics when rubbed with water present on the foam material.

A still further object of the invention lies in the provision of an improved surgical drape having all of the aforementioned desirable characteristics and yet which can be produced at such a low cost as to permit disposal of the drape after a single use.

A related object is to provide an improved surgical drape that enables the use of relatively low cost hydrophobic foam material, and yet results in superior rates of fluid absorption comparable to those exhibited by more expensive hydrophillic foam material.

Other objects and advantages of the invention will become readily apparent from'the ensuing detailed description and accompanying drawings, in which:

FIG. 1 is a plan view of a surgical drape embodying the present invention; and 1 FIG. 2 is a section taken generally along the line 22 in FIG. 1.

While the invention is susceptible of various modifications and alternative forms, certain specific embodiments thereof have been shown by way of example in the drawings and will be described in detail herein. It should be understood, however, that it is not intended to limit the invention to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents and alternatives falling within the spirit and scope of the invention as expressed in the appended claims. In this connection, a laparotomy drape sheet has been shown in the drawings. It should be understood that other types of drape sheets may be used and that the invention is not limited to the type of drape sheet illustrated. Similarly, the specific embodiment of the base sheet is described as comprising outer layers of cellulosic wadding and inner layers of highly drafted fibers. It should be understood that the construction of the base sheet should not be'limited to the specific base sheet disclosed.

Turning now to the drawings, there is shown a surgical drape having a primary operative area, which is the fenestration area of the illustrated laparotomy sheet.

The drape has a fibrous base sheet 10, over which a fluid impervious plastic layer or film 11 is bonded. The film 11 may be bonded to the fibrous base sheet 10 by any suitable means, such as by means of an adhesive. The film 11 provides a fluid impervious barrier in the primary operative area so that any fluids contacting this area cannot strike through the sheet. This prevents the transfer of bacteria through the sheet and thereby helps insure that sterile conditions will be maintained in the primary operative area. It should be understood that the film must be capable of remaining stable under the conditions encountered in the particular treatment to which'the drape sheet is subjected to render it sterile, e.g., temperatures of about 270F for steam sterilization or about l60F for sterilization by means of ethylene oxide or the like.

Examples of suitable films are polyethylene e.g., 2 mil. polyethylene film manufactured by Clopay Corp, Cincinnati, Ohio; polypropylene, e.g., Extrel II available from Extrudo Film Corp, New York, New York; polyethylene methylacrylate copolymer film manufactured by Edison Plastics Company; and vinyl chloride films. The film should be substantially free of pin holes to provide the desired sterility barrier, and thus must generally be at least 0.15 mil thick.

Overlying the fluid impervious film 11 is a foam ma terial 12 which may be bonded to the film 11 by any suitable means, but preferably by meansof an adhesive. The absorbency of the open celled foam l2 prevents excessive fluid run-off and yet the absorbed fluids cannot strike through the drape because of the intermediate layer of fluid impervious film 1 l. The relatively high coefficient of friction of the foam material provides a substantially non-slip surface which prevents accidental dislodgement of surgical instruments and the like when they are placed on the surface of the foam material. In addition, the foam material 12 preferably has a low glare which is achieved in part by its open cellular structure and which may be enhanced by tinting or coloring the foam during its manufacture or subsequently. The foam thickness would generally be in the rangeof about 25 mils to about mils, and the absorbency of the foam sheet should be at least about percent by weight and for a 40 mil thick foam material preferably at least 575 percent and at least 4.5 gm/4 inch by 4 inch sample. Examples of suitable foams are 40 mil polyester polyurethane foam having a density of 1.7 lbs/ft available from Reeves Brothers Inc., New York, New York or Tenneco Chemicals Inc., New York, New York and polyether polyurethane foams.

The base sheet 10 preferably comprises outer layers of cellulosic wadding and inner layers of highly drafted fibers disposed angularly relative to each other. A spaced pattern of adhesive is disposed between each fiber layer and its. adjacent wadding layer with the fibers in each layer partially embedded in and held by the adhesive in the adjacent adhesive layer and partially embedded in and held by the adhesive in the outer adhesive layer where it extends between the fibers of its adjacent fiber layer and with a portion of the adhesive in both adhesive layers joined where the adhesive patterns are superimposed. This -material is described in more 'detail in copending Sokolowski et al 1 application Ser. No. 546,067, filed Apr. 28, 1966 now US. Pat. No. 3,484,330 and assigned to the assignee of the present invention.

Suitable adhesives foruse in bonding the foam material to the film and for bonding the film to the base sheet are preferably water resistantadhesives that are solvent based, in solvents such as, for exampleymethyl ethyl ketone or ethyl acetate. One-adhesive is a two component urethane solvent basedsystcm', available from the Chemical Division of Borden, Inc. Chicago, Illinois under the tradename MA-5750. The adhesive is suitably applied to the film at a loading of about 2 to grams per square yard and may be applied at room temperature. The adhesive is preferably applied in a spaced pattern to maintain flexibility. The pressure used to laminate the film to the foam material is rela tively light, and is just sufficient'to make good contact between the film and foam material. While the bonding of the film to the base sheet may. be performed using similar adhesive and loading, the adhesive is preferably continuous around the fenestration and around the outer periphery of the film.

In accordance with the present invention, the foam material 12 is treated with an isopropanol-water solution of a fatty acid tertiary amine, partially neutralized to a carefully controlled level to the corresponding. am monium salt to achieve the necessary surface resistivity superior'rate of fluid absorbency and yet obviate the undesirable lathering property. I

The treating solution thus includes the reaction product of a fatty acid tertiary amine having the structural formula: i 3

(wherein R signifies an alkyl group containing from 12 to 18 carbon atoms) and a mineral acid, Among the mineral acids that can be used are hydrochloric acid, sulfuric acid and phosphoric acid, although phosphoric acid is preferred. The alkyl group may consist of a single member or the amine may comprise a mixture having different alkyl groups. In the latter instance, it has been found desirable to use tallow as the source for R, viz.- the alkyl group.

In keeping with the present invention, the reaction product is preferably applied in an isopropanol water solution in sufficient quantity such that at least 0.125 gms/yd addon is applied to the surface of the foam material. Although the solution may be sprayed upon the surface of the foam material, it has been found that flexographic printing of the solution is preferred, due to the fact that quantities are more easily controlled and there is less potential for creating a health hazard in terms of explosive vapor concentrations than may be present if the solution is sprayed upon the surface of the foam material. The particular solvent in which the compound is dissolved has been found to be important. It is preferred to use an isopropanol-water solvent wherein the isopropanol comprises between about 30 and 80 percent by weight of the solvent. If less than about 30 percent isopropanol is used, it has been found difficult to dissolve the compound. If more than 80 percent isopropanol is used, the antistatic properties of the resulting drape may be decreased below acceptable limits as set forth in the hcreinbefore mentioned Code.

Since the fatty acid tertiary amine is known to be a wetting agent or surfactant, it would be expected that 6 the free amine is the cause of the lathering or sudsing characteristic. It would accordingly be assumed that the lathering characteristic would be minimized by tying up or neutralizing the free amine. Thus, it would be anticipated that the greater the extent of neutralization (causing a concomitant reduction in the pH), the less lathering or sudsing would be a problem. Contrary to expected belief, however, it has been found that neutralization must only be carried out to a certain level, because further neutralization in fact results in the unwanted lathering property in the treated drape.

To achieve the objectives of the present invention, the amounts of mineral acid and amine should thus be controlled to provide neutralization of the amine to an extent not greater than about 34 percent. In keeping with the present invention the degree of neutralization can be obtained by maintaining the. pH within carefully controlled limits. To this end, by insuring that the pH does not drop below about 7.5 (as measured by a pH meter haying water in the probes) desired neutralization will result.

Where phosphoric acid is used and the pH of the treatmentis about 7.5 or greater, it is believed that the principal reaction product'ha-s' the following structural formula I i wherein R, signifies an alkyl group containing from 12 to 18 carbon atoms. u

In accordance with a further aspect of the present invention, it. has been found that if the solution has a pH of greater than about 85, it is more difficult to dissolve the reaction product in the solvent unless the solvent contains a greater amount of isopropanol and, additionally, the reaction product tends to precipitate out. As previously mentioned, the antistatic properties of the foam may be impaired if the percentage of isopropanol in the solvent exceeds about percent.

In keeping with the present invention, it has been found that the treatment of the foam material with the above mentioned reaction product also significantly improves the rate of absorption of liquids that come in contact with the foam material. While an open celled foam material, even if it is normally hydrophobic, will absorb fluids, normally hydrophobic open celled foam material often requires considerable time before the fluid is absorbed into the cellular structure of foam material. It should be understood that the rate of absorbency of the foam material is important since any liquids that come in contact with the foam material during an operation should preferably be readily absorbed rather than remain on the foam material surface where a physician or other member of a surgical team would contact the fluid. Although polyurethane foam having some degree of hydrophilicity is commercially available, the cost of such foam is substantially greater than commercially available hydrophobic polyurethane foam material. The present invention, in addition to providing surface resistivity values within the prescribed range as required by the Code, has the additional effect of providing greatly increased rates of fluid absorption, all of which may be achieved at a much lower cost since normally hydrophobic foam material may be used.

As one specific example of treating the foam material in accordance with the present invention, a disposable surgical drape having exposed 40 mil polyester polyurethane, open celled foam material was treated with a isopropanol water solution of the reaction product of the tallow fatty acid tertiary amine and phosphoric acid with the solution being adjusted to have a pH of about 7.5. The isopropanol-water solvent contained about 40 percent isopropanol and approximately 6.2 percent solids of the tallow fatty acid tertiary amine that was about 34 percent neutralized to the tallow fatty acid ammonium salt with phosphoric acid. The solution was printed upon the outer surface of the foam material such that about 0.125 gm/yd add-on of the reaction product was present after drying to eliminate the solvent. It was found that the rate of water absorbency as measured by placing drops of water on the surface and .measuring the time required for it to be absorbed into the foam material was less than a few seconds the majority of the time as compared to in excess of 300 seconds for untreated hydrophobic polyurethane foam. Similar tests were run to measure the rate of absorption for drops of 1 percent sodium chloride solution which is generally known as saline solution often used in surgical operations. Drops of the saline solution were generally absorbed in about 1 to 7 seconds as compared to in excess of 300 seconds for untreated polyurethane foam material. Surface resistivity values of the treated foam material measured in accordance with AATCC test method 76-1969 were about 1 X 10 ohms per square unit as compared to about X ohms for nontreated foam. The foam material did not exhibit foaming when it was vigorously rubbed in the presence of water.

Thus the disposable surgical drape of the present invention has been shown to exhibit superior rates of absorption characteristics as well as satisfy the surface resistivity requirements of the National Fire Protection Association and failed to exhibit the unwanted lathering characteristics.

What is claimed is:

1. In a disposable surgical drape having a primary operative area, said drape comprising a fibrous base sheet, a fluid impervious plastic layer covering said primary operative area, the improvement comprising a sheet of flexible, normally hydrophobic, open celled foam material bonded to the outer surface of said plastic layer, said foam material having been treated with the reaction product of a mineral acid and a fatty acid tertiary amine, said fatty acid tertiary amine being neutralized less than about 34 percent to form a fatty acid tertiary ammonium salt, said fatty acid tertiary amine having the structural formula:

where R signifies an alkyl group containing from 12 to 18 carbon atoms; said compound being effective to render said foam material antistatic, while providing increased rates of fluid absorption and reduced tendency for lathering when said foam material is vigorously rubbed in the presence of water.

2. In a disposable surgical drape as defined in claim 1 wherein said reaction product is present in excess of about 0.125 gms/yd and the surface resistivity of the treated foam material is less than about 5 X 10 ohms.

3. In a surgical drape as defined in claim 1, wherein said mineral acid is selected from the group consisting of phosphoric acid, hydrochloric acid and sulfuric acid.

4. In a surgical drape as defined in claim 1 wherein said foam material is a polyurethane foam.

Claims (4)

1. IN A DISPOSABLE SURGICAL DRAPE HAVING A PRIMARY OPERATIVE AREA, SAID DRAPE COMPRISING A FIBROUS BASE SHEET, A FLUID IMPERVIOUS PLASTIC LAYER CONVERING SAID PRIMARY OPERATIVE AREA, THE IMPROVEMENT COMPRISING A SHEET OF FLEXIBLE, NORMALLY HYDROPHOBIC, OPEN CELLED FOAM MATERIAL BONDED TO THE OUTER SURFACE OF SAID PLASTIC LAYER, SAID FOAM MATERIAL HAVING BEEN TREATED WITH THE REACTION PRODUCT OF A MINERAL ACID AND A FATTY ACID TERTIARY AMINE, SAID FATTY ACID TERITARY AMINE BEING NEUTRALIZED LESS THAN ABOUT 34 PERCENT TO FORM A FATTY ACID TERTIARY AMMONIUM SALT, SAID FATTY ACID TERTIARY AMINE HAVING THE STRUCTURAL FORMULA:
2. In a disposable surgical drape as defined in claim 1 wherein said reaction product is present in excess of about 0.125 gms/yd2 and the surface resistivity of the treated foam material is less than about 5 X 1011 ohms.
3. In a surgical drape as defined in claim 1, wherein said mineral acid is selected from the group consisting of phosphoric acid, hydrochloric acid and sulfuric acid.
4. In a surgical drape as defined in claim 1 wherein said foam material is a polyurethane foam.
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Cited By (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2342713A1 (en) * 1976-03-03 1977-09-30 Johnson & Johnson operative field for cardiovascular interventions
US4565736A (en) * 1980-09-30 1986-01-21 Firma Carl Freudenberg Fibrous surgical compress with cover layer autogenously bonded to absorption layer
US4714633A (en) * 1986-06-03 1987-12-22 Nagoya Oilchemical Co., Ltd. Expanding and shrinking member
US5038798A (en) * 1990-03-19 1991-08-13 Baxter International Inc. Opthalmic drape with fluid collection pouch
US5042507A (en) * 1990-02-21 1991-08-27 Baxter International Inc. Surgical drape for ophthalmic procedures
US5131412A (en) * 1991-08-26 1992-07-21 Ellen Rankin Pediatric intravenous device
US5226815A (en) * 1992-12-07 1993-07-13 Bowman Karolen C Dental covering
US5349965A (en) * 1991-12-16 1994-09-27 Kimberly-Clark Corporation Surgical fluid evacuation system
US5457962A (en) * 1993-09-23 1995-10-17 O.R. Solutions, Inc. Sterile drape for use in making surgical slush
US5540979A (en) * 1994-05-16 1996-07-30 Yahiaoui; Ali Porous non-woven bovine blood-oxalate absorbent structure
US5809788A (en) * 1996-03-05 1998-09-22 O.R. Solutions, Inc. Surgical drape for use in forming and collecting surgical slush
US5816252A (en) * 1997-04-29 1998-10-06 O.R. Solutions, Inc. Surgical drape leak detection method and apparatus
US5857467A (en) * 1997-06-20 1999-01-12 O.R. Solutions, Inc. Reinforced surgical drapes for use with thermal treatment systems
WO1999004721A1 (en) 1997-07-28 1999-02-04 Kimberly-Clark Worldwide, Inc. Tear-away surgical drape
US5879621A (en) * 1995-04-26 1999-03-09 O.R. Solutions, Inc. Method and apparatus for ensuring sterility of surgical drapes used with surgical equipment
WO1999037234A1 (en) 1998-01-26 1999-07-29 Kimberly-Clark Worldwide, Inc. Surgical drape with attachable fluid collection pouch
US6003328A (en) * 1996-03-05 1999-12-21 O.R. Solutions, Inc. Surgical drape having securing device for attachment to thermal treatment systems
US6035855A (en) * 1997-02-25 2000-03-14 O.R. Solutions, Inc. Surgical drape for use with surgical slush machines having an automatic dislodgement mechanism
US6087636A (en) * 1997-02-27 2000-07-11 O.R. Solutions, Inc. Surgical drape and stand for use in heated thermal treatment basins
US6091058A (en) * 1995-04-26 2000-07-18 O.R. Solutions, Inc. Thermal treatment system and method for maintaining integrity and ensuring sterility of surgical drapes used with surgical equipment
US6165625A (en) * 1996-12-19 2000-12-26 Kimberly-Clark Worldwide, Inc. Method of making high intensity light resistant instrument pads
WO2001041665A1 (en) * 1998-09-25 2001-06-14 Becker Dan L Drape for multiple-tiered sterile hospital surface
US6298855B1 (en) 1999-10-22 2001-10-09 Kimberly-Clark Worldwide, Inc. Surgical drape
US6371121B1 (en) 2000-05-17 2002-04-16 O.R. Solutions, Inc. Remote controlled thermal treatment system and method for controlling the system remotely to thermally treat sterile surgical liquid
US20030124928A1 (en) * 2001-12-27 2003-07-03 Sherrod Earle H. Non-slip absorbent article
US20030154989A1 (en) * 2000-05-17 2003-08-21 Faries Durward I. Thermal treatment system and method for controlling the system to thermally treat sterile surgical liquid
US20030172937A1 (en) * 2001-10-22 2003-09-18 Faries Durward I. Medical solution thermal treatment system and method of controlling system operation in accordance with detection of solution and leaks in surgical drape containers
US20040060112A1 (en) * 2002-09-27 2004-04-01 Kimberly-Clark Worldwide, Inc. Bed pad
US6764566B1 (en) 2001-12-12 2004-07-20 Kimberly-Clark Worldwide, Inc. Nonwoven filled film laminate with barrier properties
US20040166321A1 (en) * 2003-02-21 2004-08-26 Rippl Carl G. Non-slip portable absorbent article
US20040200480A1 (en) * 2001-10-22 2004-10-14 Faries Durward I. Surgical drape with conductor and method of detecting fluid and leaks in thermal treatment system basins
US20040200483A1 (en) * 2001-10-22 2004-10-14 Faries Durward I. Surgical drape and method of detecting fluid and leaks in thermal treatment system basins
US20050022298A1 (en) * 2003-07-31 2005-02-03 De Leon Maria E. Mat featuring a removable portion
US20050022822A1 (en) * 2002-06-10 2005-02-03 Santilli Albert N. Surgical drape and method of use
US20050247169A1 (en) * 2003-11-26 2005-11-10 Faries Durward I Jr Fastening system and method of fastening objects with enhanced security
US20060065274A1 (en) * 2004-09-29 2006-03-30 Mathis Michael P Three piece drape with fluid diversion capabilities
US20060194324A1 (en) * 2001-10-22 2006-08-31 Faries Durward I Jr System and method of detecting fluid and leaks in thermal treatment system basins
US20070089753A1 (en) * 2005-09-01 2007-04-26 Faries Durward I Jr Method and apparatus for protecting sterile drapes in surgical thermal treatment systems
US7350373B1 (en) 2003-12-23 2008-04-01 O.R. Solutions, Inc. Surgical disk drape and method of dislodging surgical slush within thermal treatment system basins
US20090112138A1 (en) * 2005-07-14 2009-04-30 Bsn Medical, Inc. Water-resistant orthopedic undercast sleeve product
US20090255540A1 (en) * 2008-04-09 2009-10-15 Faries Jr Durward I Method and Apparatus for Warming Medical Solutions in a Thermal Treatment System Employing a Removable Basin
WO2009152993A1 (en) 2008-06-18 2009-12-23 Paul Hartmann Ag Surgical cover having integrated fluid barrier
US7671302B1 (en) 2004-03-23 2010-03-02 O. R. Solutions, Inc. Thermal treatment system instrument rack and method of selectively thermally treating medical instrument portions
US7728262B1 (en) 2004-03-23 2010-06-01 O.R. Solutions, Inc. Thermal treatment system instrument rack and method of selectively thermally treating medical instrument portions
US7854230B2 (en) 2001-10-22 2010-12-21 O.R. Solutions, Inc. Heated medical instrument stand with surgical drape and method of detecting fluid and leaks in the stand tray
US20130066285A1 (en) * 2011-09-14 2013-03-14 Christopher Brian Locke Reduced-pressure systems and methods employing a leak-detection member
US8710407B2 (en) 2010-09-02 2014-04-29 Ecolab Usa Inc. Selective thermal treatment of medical instrument portions with thermal treatment system instrument holder
US9737363B2 (en) 2012-08-10 2017-08-22 Avent, Inc. Sterile drape for two tiered hospital instrument table

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3190763A (en) * 1960-12-17 1965-06-22 Hoechst Ag Process for the anti-static finishing of high molecular weight compounds
US3668050A (en) * 1970-03-09 1972-06-06 Kimberly Clark Co Surgical drape
US3738359A (en) * 1971-07-19 1973-06-12 Johnson & Johnson Non-slip instrument pad

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3190763A (en) * 1960-12-17 1965-06-22 Hoechst Ag Process for the anti-static finishing of high molecular weight compounds
US3668050A (en) * 1970-03-09 1972-06-06 Kimberly Clark Co Surgical drape
US3738359A (en) * 1971-07-19 1973-06-12 Johnson & Johnson Non-slip instrument pad

Cited By (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2342713A1 (en) * 1976-03-03 1977-09-30 Johnson & Johnson operative field for cardiovascular interventions
US4565736A (en) * 1980-09-30 1986-01-21 Firma Carl Freudenberg Fibrous surgical compress with cover layer autogenously bonded to absorption layer
US4714633A (en) * 1986-06-03 1987-12-22 Nagoya Oilchemical Co., Ltd. Expanding and shrinking member
US5042507A (en) * 1990-02-21 1991-08-27 Baxter International Inc. Surgical drape for ophthalmic procedures
USRE34512E (en) * 1990-03-19 1994-01-18 Baxter International Inc. Opthalmic drape with fluid collection pouch
US5038798A (en) * 1990-03-19 1991-08-13 Baxter International Inc. Opthalmic drape with fluid collection pouch
US5131412A (en) * 1991-08-26 1992-07-21 Ellen Rankin Pediatric intravenous device
US5349965A (en) * 1991-12-16 1994-09-27 Kimberly-Clark Corporation Surgical fluid evacuation system
US5226815A (en) * 1992-12-07 1993-07-13 Bowman Karolen C Dental covering
US5457962A (en) * 1993-09-23 1995-10-17 O.R. Solutions, Inc. Sterile drape for use in making surgical slush
US5540979A (en) * 1994-05-16 1996-07-30 Yahiaoui; Ali Porous non-woven bovine blood-oxalate absorbent structure
WO1996012922A1 (en) * 1994-10-20 1996-05-02 O.R. Solutions, Inc. Sterile drape for use in making surgical slush
US6091058A (en) * 1995-04-26 2000-07-18 O.R. Solutions, Inc. Thermal treatment system and method for maintaining integrity and ensuring sterility of surgical drapes used with surgical equipment
US5879621A (en) * 1995-04-26 1999-03-09 O.R. Solutions, Inc. Method and apparatus for ensuring sterility of surgical drapes used with surgical equipment
US6255627B1 (en) 1995-04-26 2001-07-03 O.R. Solutions, Inc. Thermal treatment system and method for maintaining integrity and ensuring sterility of surgical drapes used with surgical equipment
US5809788A (en) * 1996-03-05 1998-09-22 O.R. Solutions, Inc. Surgical drape for use in forming and collecting surgical slush
US5950438A (en) * 1996-03-05 1999-09-14 O.R. Solutions, Inc. Method and apparatus for manipulating a surgical drape via an inflatable device to collect surgical slush
US6003328A (en) * 1996-03-05 1999-12-21 O.R. Solutions, Inc. Surgical drape having securing device for attachment to thermal treatment systems
US6165625A (en) * 1996-12-19 2000-12-26 Kimberly-Clark Worldwide, Inc. Method of making high intensity light resistant instrument pads
US6035855A (en) * 1997-02-25 2000-03-14 O.R. Solutions, Inc. Surgical drape for use with surgical slush machines having an automatic dislodgement mechanism
US6087636A (en) * 1997-02-27 2000-07-11 O.R. Solutions, Inc. Surgical drape and stand for use in heated thermal treatment basins
US5816252A (en) * 1997-04-29 1998-10-06 O.R. Solutions, Inc. Surgical drape leak detection method and apparatus
US5857467A (en) * 1997-06-20 1999-01-12 O.R. Solutions, Inc. Reinforced surgical drapes for use with thermal treatment systems
WO1999004721A1 (en) 1997-07-28 1999-02-04 Kimberly-Clark Worldwide, Inc. Tear-away surgical drape
US6199553B1 (en) 1998-01-26 2001-03-13 Kimberly-Clark Worldwide, Inc. Surgical drape with attachable fluid collection pouch
WO1999037234A1 (en) 1998-01-26 1999-07-29 Kimberly-Clark Worldwide, Inc. Surgical drape with attachable fluid collection pouch
WO2001041665A1 (en) * 1998-09-25 2001-06-14 Becker Dan L Drape for multiple-tiered sterile hospital surface
US6298855B1 (en) 1999-10-22 2001-10-09 Kimberly-Clark Worldwide, Inc. Surgical drape
US6860271B2 (en) 2000-05-17 2005-03-01 O.R. Solutions, Inc. Thermal treatment system and method for controlling the system to thermally treat sterile surgical liquid
US20020185136A1 (en) * 2000-05-17 2002-12-12 Faries Durward I. Remote controlled thermal treatment system and method for controlling the system remotely to thermally treat sterile surgical liquid
US6918395B2 (en) 2000-05-17 2005-07-19 O.R. Solutions, Inc. Thermal treatment system and method for controlling the system remotely to thermally treat sterile surgical liquid
US6371121B1 (en) 2000-05-17 2002-04-16 O.R. Solutions, Inc. Remote controlled thermal treatment system and method for controlling the system remotely to thermally treat sterile surgical liquid
US20030154989A1 (en) * 2000-05-17 2003-08-21 Faries Durward I. Thermal treatment system and method for controlling the system to thermally treat sterile surgical liquid
US20030172937A1 (en) * 2001-10-22 2003-09-18 Faries Durward I. Medical solution thermal treatment system and method of controlling system operation in accordance with detection of solution and leaks in surgical drape containers
US7854230B2 (en) 2001-10-22 2010-12-21 O.R. Solutions, Inc. Heated medical instrument stand with surgical drape and method of detecting fluid and leaks in the stand tray
US7418966B2 (en) 2001-10-22 2008-09-02 O. R. Solutions, Inc. Surgical drape and method of detecting fluid and leaks in thermal treatment system basins
US20040200480A1 (en) * 2001-10-22 2004-10-14 Faries Durward I. Surgical drape with conductor and method of detecting fluid and leaks in thermal treatment system basins
US6910485B2 (en) 2001-10-22 2005-06-28 O.R. Solutions, Inc. Medical solution thermal treatment system and method of controlling system operation in accordance with detection of solution and leaks in surgical drape containers
US6810881B2 (en) 2001-10-22 2004-11-02 O.R. Solutions, Inc. Medical solution thermal treatment system and method of controlling system operation in accordance with detection of solution and leaks in surgical drape containers
US20060194324A1 (en) * 2001-10-22 2006-08-31 Faries Durward I Jr System and method of detecting fluid and leaks in thermal treatment system basins
US7959860B2 (en) 2001-10-22 2011-06-14 Faries Jr Durward I System and method of detecting fluid and leaks in thermal treatment system basins
US7347210B2 (en) 2001-10-22 2008-03-25 O.R. Solutions, Inc. Surgical drape with conductor and method of detecting fluid and leaks in thermal treatment system Basins
US20040200483A1 (en) * 2001-10-22 2004-10-14 Faries Durward I. Surgical drape and method of detecting fluid and leaks in thermal treatment system basins
US6764566B1 (en) 2001-12-12 2004-07-20 Kimberly-Clark Worldwide, Inc. Nonwoven filled film laminate with barrier properties
US20030124928A1 (en) * 2001-12-27 2003-07-03 Sherrod Earle H. Non-slip absorbent article
US6911407B2 (en) 2001-12-27 2005-06-28 Kimberly-Clark Worldwide, Inc. Non-slip absorbent article
US20050022822A1 (en) * 2002-06-10 2005-02-03 Santilli Albert N. Surgical drape and method of use
US20080029102A1 (en) * 2002-06-10 2008-02-07 Santilli Albert N Surgical Drape
US7305991B2 (en) * 2002-06-10 2007-12-11 Santilli Albert N Surgical drape and method of use
US7891359B2 (en) * 2002-06-10 2011-02-22 Corbitt Jr John D Surgical drape
US20040060112A1 (en) * 2002-09-27 2004-04-01 Kimberly-Clark Worldwide, Inc. Bed pad
US20040166321A1 (en) * 2003-02-21 2004-08-26 Rippl Carl G. Non-slip portable absorbent article
US20050022298A1 (en) * 2003-07-31 2005-02-03 De Leon Maria E. Mat featuring a removable portion
US20060260443A1 (en) * 2003-11-26 2006-11-23 Faries Durward I Jr Fastening system and method of fastening objects with enhanced security
US20050247169A1 (en) * 2003-11-26 2005-11-10 Faries Durward I Jr Fastening system and method of fastening objects with enhanced security
US7350373B1 (en) 2003-12-23 2008-04-01 O.R. Solutions, Inc. Surgical disk drape and method of dislodging surgical slush within thermal treatment system basins
US20100200561A1 (en) * 2004-03-23 2010-08-12 Faries Jr Durward I Thermal Treatment System Instrument Rack and Method of Selectively Thermally Treating Medical Instrument Portions
US8148667B2 (en) 2004-03-23 2012-04-03 Ecolab Inc. Thermal treatment system instrument rack and method of selectively thermally treating medical instrument portions
US8153937B2 (en) 2004-03-23 2012-04-10 Ecolab Inc. Thermal treatment system instrument rack and method of selectively thermally treating medical instrument portions
US7671302B1 (en) 2004-03-23 2010-03-02 O. R. Solutions, Inc. Thermal treatment system instrument rack and method of selectively thermally treating medical instrument portions
US7728262B1 (en) 2004-03-23 2010-06-01 O.R. Solutions, Inc. Thermal treatment system instrument rack and method of selectively thermally treating medical instrument portions
US20060065274A1 (en) * 2004-09-29 2006-03-30 Mathis Michael P Three piece drape with fluid diversion capabilities
US7588034B2 (en) 2004-09-29 2009-09-15 Kimberly-Clark Worldwide, Inc. Three piece drape with fluid diversion capabilities
US20090112138A1 (en) * 2005-07-14 2009-04-30 Bsn Medical, Inc. Water-resistant orthopedic undercast sleeve product
US20070089753A1 (en) * 2005-09-01 2007-04-26 Faries Durward I Jr Method and apparatus for protecting sterile drapes in surgical thermal treatment systems
US8148666B2 (en) 2005-09-01 2012-04-03 Patented Medical Solutions, Llc Method and apparatus for protecting sterile drapes in surgical thermal treatment systems
US20090255540A1 (en) * 2008-04-09 2009-10-15 Faries Jr Durward I Method and Apparatus for Warming Medical Solutions in a Thermal Treatment System Employing a Removable Basin
US8789534B2 (en) 2008-04-09 2014-07-29 Patented Medical Solutions, Llc Method and apparatus for warming medical solutions in a thermal treatment system employing a removable basin
WO2009152993A1 (en) 2008-06-18 2009-12-23 Paul Hartmann Ag Surgical cover having integrated fluid barrier
JP2011524220A (en) * 2008-06-18 2011-09-01 パウル ハルトマン アクチェンゲゼルシャフト Surgical cover having a liquid barrier embedded
DE102008029051A1 (en) 2008-06-18 2009-12-24 Paul Hartmann Ag Surgical cover with integrated liquid barrier
US8710407B2 (en) 2010-09-02 2014-04-29 Ecolab Usa Inc. Selective thermal treatment of medical instrument portions with thermal treatment system instrument holder
US20130066285A1 (en) * 2011-09-14 2013-03-14 Christopher Brian Locke Reduced-pressure systems and methods employing a leak-detection member
US9622914B2 (en) * 2011-09-14 2017-04-18 Kci Licensing, Inc. Reduced-pressure systems and methods employing a leak-detection member
US9737363B2 (en) 2012-08-10 2017-08-22 Avent, Inc. Sterile drape for two tiered hospital instrument table

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