US3901673A - Recovery of natural gas liquids by partial condensation - Google Patents
Recovery of natural gas liquids by partial condensation Download PDFInfo
- Publication number
- US3901673A US3901673A US315535A US31553572A US3901673A US 3901673 A US3901673 A US 3901673A US 315535 A US315535 A US 315535A US 31553572 A US31553572 A US 31553572A US 3901673 A US3901673 A US 3901673A
- Authority
- US
- United States
- Prior art keywords
- stream
- inlet
- signal
- pressure
- flash tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/0605—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the feed stream
- F25J3/061—Natural gas or substitute natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
- F25J3/0635—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 1 carbon atom or more
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
- F25J3/063—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream
- F25J3/064—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/04—Mixing or blending of fluids with the feed stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/02—Mixing or blending of fluids to yield a certain product
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2280/00—Control of the process or apparatus
- F25J2280/02—Control in general, load changes, different modes ("runs"), measurements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S203/00—Distillation: processes, separatory
- Y10S203/19—Sidestream
Definitions
- This invention relates to a method and apparatus for recovery of natural gas liquids.
- the invention relates to a method and apparatus for the recovery of natural gas liquids by partial condensation, flashing, and compression.
- control system to be utilized in the recovery of natural gas liquids by partial condensation, flashing and compression.
- control system to be utilized in the recovery of natural gas liquids by partial condensation, flashing and compression.
- it relates to a method and apparatus for controlling minimum and maximum temperature of partially condensed feed hydrocarbons to a natural gas liquid recovery system.
- Condensable hydrocarbons are valuable products contained in natural gas. Refrigerating natural gas to recover a maximum of readily condensable hydrocarbons from the gas is an established practice in the industry. The most economical operation of such a process involves continuous unattended operation. The recovery of natural gas liquids involves partial condensation, flashing, and compression of flashed vapor. To assure continuous unattended operation of such a process it is necessary to have a control system which can accommodate not only minor variations in feed gas volume and composition but also serious disturbances such as mechanical malfunction of compressing means.
- a method and apparatus for controlling the minimum temperature of the partially condensed inlet feed stream to a separator which comprises; allowing inlet material that has been partially condensed by passage through a heat exchanger to separate in a separation means to produce a vapor outlet stream and a liquid outlet stream; separately passing the vapor outlet stream from the separating means in heat exchange with inlet gas to the separating means; flashing at least a portion of the liquid outlet stream from the separating means in a flash tank with both the flash tank vapor outlet and the flash tank liquid outlet separately passing from the flash tank in heat exchange with the inlet material to the separating means; and separately passing both the heat exchanged flash tank vapor and flash tank liquid to separate, pressure controlled scrubber tanks wherein the pressure is controlled by drawing vapor from the scrubber tanks to the suctions of compression means; and controlling the suction pressures to the compression means by: producing a control signal responsive to the temperature of the
- this first selected signal may be transmitted to a second selector relay which selects between this signal and a control signal responsive to the power consumption of the compression drive means and this second selected signal transmitted to the speed controller of the compression drive means and transmitting this signal as the set point to a speed controller operably associated with the compressor drive means thereby manipulating the capacity thereof and indirectly manipulating the plant inlet gas flow rate through the inlet heat exhanger.
- a method and apparatus for controlling the maximum temperature of at least partially condensed inlet feed stream to a separator comprising separating the condensate, flashing and heat exchanging the inlet stream followed by separately passing both the heat exchanged flash tank vapor and flash tank liquid to separate pressure controlled scrubber tanks as described above, wherein the pressure of the tanks is controlled by drawing vapor from the scrubber tanks to the suction of compression means, the additional steps of generating a signal corresponding to the temperature of the inlet at the separator and transmitting this signal to actuate a flow control means for bypass of inlet gas from the inlet of the heat exchange means to a residue outlet means from the partial condensation system thereby bypassing the partial condensation system with at least a portion of the inlet gas,
- a method for controlling the bypass of inlet gas around a compressor system utilizing a plurality of compressors in parallel operation comprises: sensing the compressor operating status of each compressor from the oil pressure of each compressor; generating an operational status signal when a compressor is operating to operator relay means with contacts which change the current input to a pneumatic transducer; generating a signal in the transducer which corresponds to the summation of signals from the compressors; and transmitting the transducer signal to operate a flow control means to bypass at least a portion of inlet gas around the partial condensation system in an inverse proportion to the proportion of compressors in operation as compared to the total number of compressors in the system.
- a method and apparatus are provided by which the signal from the transducer, as described above, actuates a flow control means which bypasses inlet gas around the partial condensation system so that the amount of gas flowing into the partial condensation system is in proportion to the compression capacity available at a given time, and the signal corresponding to the temperature of the inlet to the separator actuates the bypass flow control means within the range of bypass remaining, up to a total bypass of inlet.
- the apparatus and method of this invention can be used in separating petroleum gas liquid from any petroleum gas which contains condensable materials.
- liquids are condensed from field streams which flow within a constant range. Liquids condensed from the inlet stream will generally have a vaporization temperature in the range of 50 to about 80F.
- the noncondensable material is passed on to be used as fuel gas or to have lower boiling constituents removed in other equipment. The removal of liquids boiling at 65F and above facilitates the subsequent handling of material that is not condensed at this temperature.
- the apparatus of this invention and the method of this invention for operating the apparatus can best be understood in conjunction with the drawing which is a diagrammatic representation of the controlled flow of material through the partial condensation, flashing, and subsequent compression of a field feed gas to produce a condensed liquid product and separated residue gas.
- a relatively constant supply of inlet gas containing hydrocarbons having a boiling point above -6SF is introduced into line 2 at an ambient temperature which can range up to about 85F but is preferably described as being about 70F and in a pressure range of about 500-600 psig.
- the plant inlet gas at about 500 psig is passed by line 2 into the heat exchanger 52 where its temperature is dropped to within the range of 60 to 70F, preferably about -65F.
- This heat exchanged material which is now partially condensed, is passed by line 3 to a separator 54 from which noncondensed vaporous material flows through line 4 and heat exchanger 52 where, in heat exchange with the inlet gas, it is warmed back to ambient temperature and leaves the system as residue gas by line 5.
- the liquid from the separator 54 is discharged through line 6 and a control valve 78 into flash tank 56 at a reduced pressure of about 30 psig. This reduction of pressure considerably reduces the temperature of the liquid due to partial vaporization in flash tank 56.
- Vapor from the flash tank 56 is passed by line 8 through the heat exchanger 52 in heat exchange with the inlet gas and by line 9 through control valve 80 into vapor scrubber 60.
- scrubber 60 any entrained liquid is removed from the system through the scrubber base and the vapor, having been warmed to ambient temperature by heat exchange with the inlet gas, is passed through line 16 to compression means 64 and from there to be joined with the residue gas with cooling by air fin cooler 68 as desired.
- Parallel compressors may receive gas by line 17 as desired.
- the liquid from flash tank 56 is passed by line 10 to the heat exchanger 52, in heat exchange with the inlet gas, through control valve 82 and on to liquid product scrubber 58 by line 11.
- the material which is by then warmed to near ambient temperature by heat exchange with the inlet gas, is separated into liquid and vapor phases.
- the vapor phase is withdrawn through line 12 by compression means 62 and by line 13 to parallel compression means as desired where the pressure is increased to a pressure in the range of 500600 psig and passed to a product accumulator tank 70 through air fin condenser 66.
- the liquid from scrubber 58 is pumped through line 14 by pump 15 to the product accumulator tank 70.
- the liquid product can be removed from the accumulator tank through line 20 and vapor can be removed from the product accumulator tank by line 22 and thence to inlet gas line 2 for recirculation as desired.
- a measurement of the inlet temperature to separator 54 is transmitted to temperature controller 42, wherein it is compared with a minimum temperature set point signal and a control signal produced from this comparison.
- the control signal is transmitted as the set point to both pressure con trollers 44 and 46.
- Pressure controllers 44 and 46 each generate a signal responsive to the comparison of this set point with the measured pressure within each of the respective scrubbers.
- selector relay 48 which transmits the control signal produced from the higher scrubber pressure (the larger of the two signals) to the speed controller 51 via selector relay 50 (to be described below) which governs the level of operation of compressor driving engine 74 which in turn governs the compression capacity of both compressors 62 and 64 respectively on line 12 (liquid product flash scrubber gas) and line 16 (low temperature flashed gas to residue) both originating from product flash tank 56.
- the dual compressor is called upon to draw a controlled volume of gas into its suction thus controlling the balancing of the flow of low temperature gas and liquid through heat exchanger 52 from flash tank 56.
- a greater or lesser degree of heat exchange with the plant inlet gas is employed to control the temperature of the heat exchanged, partially-condensed feed material to the initial separator 54.
- a temperature controller 30 receives a measurement signal of the inlet temperature of material to separator 54. This signal is compared with the maximum temperature set point to controller 30 and a control signal is produced responsive to this comparison. This control signal is transmitted to selector relay 32 wherein the larger of this signal or that received from transducer 36 (described below) is transmitted to bypass flow controller 34 as the set point thereto. Controller 34 manipulates valve 76 in bypass line 18 to reduce the flow of plant inlet gas by passing the nonprocessable gas directly to the residue gas if limiting plant capacity conditions are encountered in terms of maximum temperature of initial separator feed or compressor availability signaled by transducer 36 as further described below. Reducing the volume of plant inlet gas flowing at ambient temperature into the heat exchanger 52 directly reduces the temperature of the partially-condensed stream in line 3.
- each of the parallel operating compressors would be equipped with its own intake manifold pressure sensing and control device 49 which would generate and transmit a control signal corresponding to a comparison of the intake manifold pressure with a maximum set point value thereof to a selector relay 50 which corresponds to selector relay 48.
- Selector relay 48 would send a parallel signal to the individual selector relay for each compressor corresponding to selector relay 50.
- These individual selector relays would then choose the lower of the two control signals from relay 48 and from individual manifold pressure controller 49 for that compressor and transmit it to speed controller 51 for the individual compressor.
- Each compressor is equipped with an operating status sensor which senses from the lubricating oil pressure (or other condition) of the individual compressor whether or not the compressor is running.
- These engine oil pressure switches 40 each generate a signal which operates a relay means 38 with a contact which changes the current input to a current-to-pneumatic transducer 36.
- the transducer 36 generates a signal which corresponds to the summation of the signals from the compressor engine oil pressure switches 40, thus transmitting a control signal corresponding to the total number of compressors running.
- the signal from transducer 36 is then transmitted to alternatively operate flow controller 34 to bypass inlet gas from line 2 through a flow control means 76 and line 18 to the residue gas line 5 as the controller functions in a manner to bypass the inlet gas in an inverse relationship to the number of compressors in operation as compared to the total number of compressors in the system. For example, if four compressors are provided, three of which are in operation with one shut down, the signal from transducer 36 will be of the magnitude corresponding to one fourth of the flow scale of controller 34 and if applied as the set point thereto by the action of selector relay 32, will result in the bypassing of one fourth of the plant inlet gas stream to the residue gas stream 5, thus feeding three fourths of the available natural gas to the liquid recovery plant.
- this system provides alternative control of the maximum temperature to the separator 54 for unattended operation, the signal from trans ducer 36 and the signal from temperature controller 30 both being transmitted to selector relay 32 which trans mits the larger signal to flow controller 34.
- the measuring, controlling and relaying devices described herein are available from a number of manufacturers of control system components and may be of the pneumatic or electrical analog type and/or the methods and apparatus of Direct Digital Control known to those skilled in this art may be employed as desired.
- a method for controlling the minimum temperature of the partially condensed inlet material stream to a separator comprising:
- a method for controlling the maximum temperature of an inlet material stream to a separator means comprising:
- the flow control means is actuated in re sponse to a signal produced from a selector relay which transmits the signal of the transducer and in addition transmits the signal of step 6 of claim 3 to actuate the bypass flow control means in response to the availability of compression means and in response to the maximum temperature of the feed stream to the separator means.
Abstract
In the recovery of natural gas liquids by partial condensation, flashing, and compression, minimum and maximum temperature control of partially condensed feed stream hydrocarbons to a product separator is imposed by a minimum temperature control system which provides the same set point to the pressure controllers on the compressor suction scrubbers for both the product and the flashed vapor produced from the liquid outlet of the product separator with one of the two output signals responsive to the pressure of the product suction scrubber or the flashed vapor suction scrubber manipulating, by way of a selective relay, the engine speed controller of the dual compressor unit taking suction from the two scrubbers; and a maximum temperature controller which controls the rate of by-pass of natural gas feed around the partial condensation-separation system unless, by means of a selective relay, compressor availability is a more limiting criterion.
Description
1451 Aug. 26, 1975 RECOVERY OF NATURAL GAS LIQUIDS BY PARTIAL CONDENSATION [75] lnventors: Carl W. Zahn; Hadwen A. Clayton,
both of Bartlesville, Okla.
[73] Assignee: Phillips Petroleum Company,
Bartlesville, Okla.
22 Filed: Dec. 15, 1972 211 App]. No.: 315,535
Primary Examiner-Norman Yudkofi Assistant Examiner-Frank Sever 5 7 ABSTRACT In the recovery of natural gas liquids by partial condensation, flashing, and compression, minimum and maximum temperature control of partially condensed feed stream hydrocarbons to a product separator is imposed by a minimum temperature control system which provides the same set point to the pressure con- [52] US. Cl. 62/21; 62/37; 62/23;
203/2. 203/1316. 18 trollers on the compressor suctlon scrubbers for both [51] Int. Cl F25j 3/00 the product and the flashed vapor produced from the [58] Field of Search 62/21 203/1316 18 liquid outlet of the product separator with one of the 203/2 two output signals responsive to the pressure of the product suction scrubber or the flashed vapor suction [56] References Cited scrubber manipulating, by way of a selective relay, the engine speed controller of the dual compressor unit UNITED STATES PATENTS taking suction from the two scrubbers; and a maxi- KltChCl'l mum t p t t ll t l th t g of by-pass of natural gas feed around the partial 2323 311966 z iz gg g 621,21 condensation-separation system unless, by means of a 5 5 12/1966 Karbosky at 621,37 selective relay, compressor availability is a more limit- 3,333,398 8/1967 Schneider 55/18 s Criterion- 3.4()7 052 10/1968 Huntrcss et al 62/21 5 Cl 1 D F, 3,527,059 9/1970 Rust et al 62/115 'awmg 32 35 COMPRESSOR 34 PC -E'SQL 3 ,MONITORING RESlDUEx In cmcunv 5! l I I I 6 1 5 4 rSEPARATOR ENGINE o"- PLANT PRESSURE 'gk SWITCHES 6 T0 SPEED CONTROL ON PARALLEL COMPRESSOR TO PARALLEL COMPRESSOR SUCTION AC CUMU LATOR ./-2O v EPRODUCT -TO PARALLEL COMPRESSOR SUCTION RECOVERY OF NATURAL GAS LIQUIDS BY PARTIAL CONDENSATION BACKGROUND OF THE INVENTION This invention relates to a method and apparatus for recovery of natural gas liquids. In one aspect the invention relates to a method and apparatus for the recovery of natural gas liquids by partial condensation, flashing, and compression. In another aspect of the invention it relates to a control system to be utilized in the recovery of natural gas liquids by partial condensation, flashing and compression. In a further aspect of the invention it relates to a method and apparatus for controlling minimum and maximum temperature of partially condensed feed hydrocarbons to a natural gas liquid recovery system.
Condensable hydrocarbons are valuable products contained in natural gas. Refrigerating natural gas to recover a maximum of readily condensable hydrocarbons from the gas is an established practice in the industry. The most economical operation of such a process involves continuous unattended operation. The recovery of natural gas liquids involves partial condensation, flashing, and compression of flashed vapor. To assure continuous unattended operation of such a process it is necessary to have a control system which can accommodate not only minor variations in feed gas volume and composition but also serious disturbances such as mechanical malfunction of compressing means.
Accordingly, it is an object of this invention to provide an improved control system for regulating the temperature of the feed stream to a separating means in a partial condensation natural gas liquid recovery system. It is another object of this invention to provide a method and apparatus for the recovery of natural gas liquids. It is still another object of this invention to provide economical method and apparatus for recovering heavy hydrocarbons from natural gas containing the same. It is a further object of this invention to provide method and apparatus for the separation of natural gas liquids from natural gas without requiring external refrigeration. It is another object of this invention to provide method and apparatus for controlling the process of separating natural gas liquids from a natural gas mixture. It is a further object of this invention to provide method and apparatus for bypassing flow around a condensation, condensate flashing, and flashed vapor comprcssion system, determining bypass volume in view of compression means availability.
Other aspects, objects and advantages of this invention will be apparent from a study of the disclosure, the drawing and the appended claims to the invention.
STATEMENT OF THE INVENTION In accordance with the present invention, in a system for the recovery of natural gas liquids by partial condensation a method and apparatus for controlling the minimum temperature of the partially condensed inlet feed stream to a separator is provided which comprises; allowing inlet material that has been partially condensed by passage through a heat exchanger to separate in a separation means to produce a vapor outlet stream and a liquid outlet stream; separately passing the vapor outlet stream from the separating means in heat exchange with inlet gas to the separating means; flashing at least a portion of the liquid outlet stream from the separating means in a flash tank with both the flash tank vapor outlet and the flash tank liquid outlet separately passing from the flash tank in heat exchange with the inlet material to the separating means; and separately passing both the heat exchanged flash tank vapor and flash tank liquid to separate, pressure controlled scrubber tanks wherein the pressure is controlled by drawing vapor from the scrubber tanks to the suctions of compression means; and controlling the suction pressures to the compression means by: producing a control signal responsive to the temperature of the separator inlet material; transmitting this control signal as the set point for the pressure controllers for both scrubber tanks; generating output signals responsive to the pressures of both of the scrubber tanks and the set point; selecting in a first selector relay the control signal produced from the higher scrubber pressure and transmitting this signal as set point for the speed controller operably associated with compressor drive means. If desired, this first selected signal may be transmitted to a second selector relay which selects between this signal and a control signal responsive to the power consumption of the compression drive means and this second selected signal transmitted to the speed controller of the compression drive means and transmitting this signal as the set point to a speed controller operably associated with the compressor drive means thereby manipulating the capacity thereof and indirectly manipulating the plant inlet gas flow rate through the inlet heat exhanger.
In an embodiment of the invention a method and apparatus for controlling the maximum temperature of at least partially condensed inlet feed stream to a separator are provided comprising separating the condensate, flashing and heat exchanging the inlet stream followed by separately passing both the heat exchanged flash tank vapor and flash tank liquid to separate pressure controlled scrubber tanks as described above, wherein the pressure of the tanks is controlled by drawing vapor from the scrubber tanks to the suction of compression means, the additional steps of generating a signal corresponding to the temperature of the inlet at the separator and transmitting this signal to actuate a flow control means for bypass of inlet gas from the inlet of the heat exchange means to a residue outlet means from the partial condensation system thereby bypassing the partial condensation system with at least a portion of the inlet gas,
In another embodiment of the invention a method for controlling the bypass of inlet gas around a compressor system utilizing a plurality of compressors in parallel operation is provided which comprises: sensing the compressor operating status of each compressor from the oil pressure of each compressor; generating an operational status signal when a compressor is operating to operator relay means with contacts which change the current input to a pneumatic transducer; generating a signal in the transducer which corresponds to the summation of signals from the compressors; and transmitting the transducer signal to operate a flow control means to bypass at least a portion of inlet gas around the partial condensation system in an inverse proportion to the proportion of compressors in operation as compared to the total number of compressors in the system.
In yet another embodiment of the invention, a method and apparatus are provided by which the signal from the transducer, as described above, actuates a flow control means which bypasses inlet gas around the partial condensation system so that the amount of gas flowing into the partial condensation system is in proportion to the compression capacity available at a given time, and the signal corresponding to the temperature of the inlet to the separator actuates the bypass flow control means within the range of bypass remaining, up to a total bypass of inlet.
The apparatus and method of this invention can be used in separating petroleum gas liquid from any petroleum gas which contains condensable materials. Generally, liquids are condensed from field streams which flow within a constant range. Liquids condensed from the inlet stream will generally have a vaporization temperature in the range of 50 to about 80F. The noncondensable material is passed on to be used as fuel gas or to have lower boiling constituents removed in other equipment. The removal of liquids boiling at 65F and above facilitates the subsequent handling of material that is not condensed at this temperature.
The apparatus of this invention and the method of this invention for operating the apparatus can best be understood in conjunction with the drawing which is a diagrammatic representation of the controlled flow of material through the partial condensation, flashing, and subsequent compression of a field feed gas to produce a condensed liquid product and separated residue gas. In the drawing, a relatively constant supply of inlet gas containing hydrocarbons having a boiling point above -6SF is introduced into line 2 at an ambient temperature which can range up to about 85F but is preferably described as being about 70F and in a pressure range of about 500-600 psig. The plant inlet gas at about 500 psig is passed by line 2 into the heat exchanger 52 where its temperature is dropped to within the range of 60 to 70F, preferably about -65F. This heat exchanged material, which is now partially condensed, is passed by line 3 to a separator 54 from which noncondensed vaporous material flows through line 4 and heat exchanger 52 where, in heat exchange with the inlet gas, it is warmed back to ambient temperature and leaves the system as residue gas by line 5. The liquid from the separator 54 is discharged through line 6 and a control valve 78 into flash tank 56 at a reduced pressure of about 30 psig. This reduction of pressure considerably reduces the temperature of the liquid due to partial vaporization in flash tank 56.
Vapor from the flash tank 56 is passed by line 8 through the heat exchanger 52 in heat exchange with the inlet gas and by line 9 through control valve 80 into vapor scrubber 60. In scrubber 60 any entrained liquid is removed from the system through the scrubber base and the vapor, having been warmed to ambient temperature by heat exchange with the inlet gas, is passed through line 16 to compression means 64 and from there to be joined with the residue gas with cooling by air fin cooler 68 as desired. Parallel compressors may receive gas by line 17 as desired.
The liquid from flash tank 56 is passed by line 10 to the heat exchanger 52, in heat exchange with the inlet gas, through control valve 82 and on to liquid product scrubber 58 by line 11. In the liquid product scrubber 58 the material, which is by then warmed to near ambient temperature by heat exchange with the inlet gas, is separated into liquid and vapor phases. The vapor phase is withdrawn through line 12 by compression means 62 and by line 13 to parallel compression means as desired where the pressure is increased to a pressure in the range of 500600 psig and passed to a product accumulator tank 70 through air fin condenser 66. The liquid from scrubber 58 is pumped through line 14 by pump 15 to the product accumulator tank 70. The liquid product can be removed from the accumulator tank through line 20 and vapor can be removed from the product accumulator tank by line 22 and thence to inlet gas line 2 for recirculation as desired.
The key to the successful operation of this system is control of the inlet temperature to the initial product separator within a specified range so that the desired separation can be made between condensed liquid product and residual gases. Although the separation of materials has been presented with a separation temperature of F, it must be borne in mind that other combinations of separator inlet pressure and controlled temperatures can be used with the apparatus and method of this invention particularly in view of differing natural gas compositions. To accomplish this broad objective, a novel combination of a minimum temperature control system with a maximum temperature control system has been developed.
Referring now to the drawing for discussion of the operation of the novel systems for the control of the inlet temperature to the separator, a measurement of the inlet temperature to separator 54 is transmitted to temperature controller 42, wherein it is compared with a minimum temperature set point signal and a control signal produced from this comparison. The control signal is transmitted as the set point to both pressure con trollers 44 and 46. Pressure controllers 44 and 46 each generate a signal responsive to the comparison of this set point with the measured pressure within each of the respective scrubbers. These pressure control signals are transmitted to selector relay 48 which transmits the control signal produced from the higher scrubber pressure (the larger of the two signals) to the speed controller 51 via selector relay 50 (to be described below) which governs the level of operation of compressor driving engine 74 which in turn governs the compression capacity of both compressors 62 and 64 respectively on line 12 (liquid product flash scrubber gas) and line 16 (low temperature flashed gas to residue) both originating from product flash tank 56. In the above described manner, the dual compressor is called upon to draw a controlled volume of gas into its suction thus controlling the balancing of the flow of low temperature gas and liquid through heat exchanger 52 from flash tank 56. In this manner a greater or lesser degree of heat exchange with the plant inlet gas is employed to control the temperature of the heat exchanged, partially-condensed feed material to the initial separator 54.
To control the maximum temperature of the partially-condensed feed to the initial separator, a temperature controller 30 receives a measurement signal of the inlet temperature of material to separator 54. This signal is compared with the maximum temperature set point to controller 30 and a control signal is produced responsive to this comparison. This control signal is transmitted to selector relay 32 wherein the larger of this signal or that received from transducer 36 (described below) is transmitted to bypass flow controller 34 as the set point thereto. Controller 34 manipulates valve 76 in bypass line 18 to reduce the flow of plant inlet gas by passing the nonprocessable gas directly to the residue gas if limiting plant capacity conditions are encountered in terms of maximum temperature of initial separator feed or compressor availability signaled by transducer 36 as further described below. Reducing the volume of plant inlet gas flowing at ambient temperature into the heat exchanger 52 directly reduces the temperature of the partially-condensed stream in line 3.
Recovery of natural gas liquids as proposed is intended for use with a compressor system utilizing a plurality of compressors in parallel operation To control the minimum temperature of the system, each of the parallel operating compressors would be equipped with its own intake manifold pressure sensing and control device 49 which would generate and transmit a control signal corresponding to a comparison of the intake manifold pressure with a maximum set point value thereof to a selector relay 50 which corresponds to selector relay 48. Selector relay 48 would send a parallel signal to the individual selector relay for each compressor corresponding to selector relay 50. These individual selector relays would then choose the lower of the two control signals from relay 48 and from individual manifold pressure controller 49 for that compressor and transmit it to speed controller 51 for the individual compressor.
Provision has also been made for bypassing plant inlet gas around the heat exchanger 52 depending on the availability of compression capacity. Each compressor is equipped with an operating status sensor which senses from the lubricating oil pressure (or other condition) of the individual compressor whether or not the compressor is running. These engine oil pressure switches 40 each generate a signal which operates a relay means 38 with a contact which changes the current input to a current-to-pneumatic transducer 36. The transducer 36 generates a signal which corresponds to the summation of the signals from the compressor engine oil pressure switches 40, thus transmitting a control signal corresponding to the total number of compressors running. The signal from transducer 36 is then transmitted to alternatively operate flow controller 34 to bypass inlet gas from line 2 through a flow control means 76 and line 18 to the residue gas line 5 as the controller functions in a manner to bypass the inlet gas in an inverse relationship to the number of compressors in operation as compared to the total number of compressors in the system. For example, if four compressors are provided, three of which are in operation with one shut down, the signal from transducer 36 will be of the magnitude corresponding to one fourth of the flow scale of controller 34 and if applied as the set point thereto by the action of selector relay 32, will result in the bypassing of one fourth of the plant inlet gas stream to the residue gas stream 5, thus feeding three fourths of the available natural gas to the liquid recovery plant. Thus this system provides alternative control of the maximum temperature to the separator 54 for unattended operation, the signal from trans ducer 36 and the signal from temperature controller 30 both being transmitted to selector relay 32 which trans mits the larger signal to flow controller 34.
Reasonable variation and modification are possible within the scope of the foregoing disclosure, the draw ing and the appended claims of this invention.
The measuring, controlling and relaying devices described herein are available from a number of manufacturers of control system components and may be of the pneumatic or electrical analog type and/or the methods and apparatus of Direct Digital Control known to those skilled in this art may be employed as desired.
We claim:
1. In the recovery of natural gas liquid by partial condensation, a method for controlling the minimum temperature of the partially condensed inlet material stream to a separator comprising:
1 passing an inlet material stream that has been partially condensed by passage through a heat exchanger into a separation means thereby producing a vapor outlet stream and a liquid outlet stream;
2. separately passing the vapor outlet stream from said separating means in heat exchange with said inlet material stream to said separating means;
3. flashing at least a portion of the liquid outlet stream from said separating means in a flash tank with both flash tank vapor outlet stream and flash tank liquid outlet stream separately passing in heat exchange with inlet material stream to said separating means;
4. separately passing both the heat exchanged flash tank vapor stream and flash tank liquid stream to separate scrubber tanks said scrubber tanks comprising means for pressure control wherein the pressure is controlled by drawing vapor from the scrubber tanks to the suction side of a plurality of compression means;
5. sensing the temperature at the separating means inlet stream and producing a signal responsive to said inlet stream temperature;
6. transmitting said signal as set point for the means for pressure control of each of the scrubber tanks;
7. generating output signals responsive to the pressure of each of the scrubber tanks; and
8. actuating a first selector relay by the signal corresponding to the higher scrubber pressure and transmitting said signal to a speed controller as set point for the compressor drive thereby controlling the flow rate of material through the inlet heat exchanger and thereby effecting control of the minimum temperature of the inlet feed stream material.
2. In the recovery of natural gas liquid by partial condensation by the method of claim 1 the additional steps of:
9. transmitting the signal produced in response to the higher scrubber pressure to a second selector relay;
l0. producing a second signal in response to the intake manifold pressure of compression means and transmitting this second signal responsive to the intake manifold pressure to said second selector relay; and
l l. actuating said second selector relay by the signal representing the lower pressure of the second signal responsive to the intake manifold pressure and the signal responsive to the scrubber pressure transmitted between said first relay to transmit said signal representing the lower pressure to a speed controller as set point for the compressor drive thereby controlling the flow rate of material through the inlet heat exchanger and thereby effecting control of the temperature of the inlet feed stream material.
3. In the recovery of natural gas liquid by partial condensation, a method for controlling the maximum temperature of an inlet material stream to a separator means comprising:
1. passing said inlet material stream that has been at least partially condensed by passage through a heat exchanger into a separating means thereby producing a vapor outlet stream and a liquid outlet stream from said separating means;
2. separately passing the vapor outlet stream from said separating means in heat exchange with the inlet material stream to said separating means;
3. flashing the liquid outlet stream from said separat ing means in a flash tank with both flash tank vapor outlet stream and flash tank liquid outlet stream separately passing in heat exchange with inlet feed stream to said separating means;
4. separately passing both the heat exchanged flash tank vapor stream and flash tank liquid stream to separate scrubber tanks said scrubber tanks comprising means for pressure control wherein the pressure is controlled by drawing vapor from the scrubber tanks to the suction side of a plurality of compression means;
5. producing a signal in response to the temperature at the inlet to the separator; and
6. transmitting said signal to actuate a flow control means for bypass of inlet gas stream from the inlet of the heat exchange means to a residue outlet means from the partial condensation system thereby bypassing the partial condensation system with at least a portion of the inlet feed stream.
4. A method of claim 3 wherein the inlet material stream is bypassed around a compressor system utilizing a plurality of compressors said bypassing controlled by:
l. generating a signal for each compressor in operation which signal operates a relay means with contacts which change the current input to a pneumatic transducer;
2. producing a signal in said transducer in response to the summation of signals from the compressors; and
3. transmitting said transducer signal to operate a flow control means to bypass at least a portion of the inlet material stream around the partial condensation system in an inverse proportion to the proportion of compressors in operation as compared to the total number of compressors in the system;
wherein the flow control means is actuated in re sponse to a signal produced from a selector relay which transmits the signal of the transducer and in addition transmits the signal of step 6 of claim 3 to actuate the bypass flow control means in response to the availability of compression means and in response to the maximum temperature of the feed stream to the separator means.
5. The method of claim 1 wherein a plurality of compressors in parallel operation is controlled by transmitting in parallel the signal selected by the first selector relay to a separate selector relay for each compression means.
Claims (30)
1. IN THE RECOVERY OF NATURAL GAS LIQUID BY PARTIAL CONDENSATION, A METHOD FOR CONTROLLING THE MINIMUN TEMPERATURE OF THE PARTIALLY CONDENSED INLET MATERIAL STREAM TO A SEPARATOR COMPRISING:
1. PASSING AN INLET MATERIAL STREAM THAT HAS BEEN PARTIALLY CONDENSED BY PASSAGE THROUGH A HEAT EXCHANGER INTO A SEPARATION MEANS THEREBY PRODUCING A VAPOR OUTPUT STREAM AND A LIQUID OUTLET STREAM,
2. SEPARATELY PASSING THE VAPOR OUTLET STREAM FROM SAID SEPARATING MEANS IN HEAT EXCHANGE WITH SAID INLET MATERIAL STREAM TO SAID SEPARATING MEANS,
2. separately passing the vapor outlet stream from said separating means in heat exchange with said inlet material stream to said separating means;
2. In the recovery of natural gas liquid by partial condensation by the method of claim 1 the additional steps of:
2. separately passing the vapor outlet stream from said separating means in heat exchange with the inlet material stream to said separating means;
2. producing a signal in said transducer in response to the summation of signals from the compressors; and
3. transmitting said transducer signal to operate a flow control means to bypass at least a portion of the inlet material stream around the partial condensation system in an inverse proportion to the proportion of compressors in operation as compared to the total number of compressors in the system; wherein the flow control means is actuated in response to a signal produced from a selector relay which transmits the signal of the transducer and in addition transmits the signal of step 6 of claim 3 to actuate the bypass flow control means in response to the availability of compression means and in response to the maximum temperature of the feed stream to the separator means.
3. In the recovery of natural gas liquid by partial condensation, a method for controlling the maximum temperature of an inlet material stream to a separator means comprising:
3. flashing the liquid outlet stream from said separating means in a flash tank with both flash tank vapor outlet stream and flash tank liquid outlet stream separately passing in heat exchange with inlet feed stream to said separating means;
3. flashing at leaSt a portion of the liquid outlet stream from said separating means in a flash tank with both flash tank vapor outlet stream and flash tank liquid outlet stream separately passing in heat exchange with inlet material stream to said separating means;
3. FLASHING AT LEAST A PORTION OF THE LIQUID OUTLET STREAM FROM SAID SEPARATING MEANS IN A FLASH TANK WITH BOTH FLASH TANK VAPOR OUTLET STREAM AND FLASH TANK LIQUID OUTLET STREAM SEPARATELY PASSING IN HEAT EXCHANGE WITH INLET MATERIAL STREAM TO SAID SEPARATING MEANS,
4. SEPARATELY PASSING BOTH THE HEAT EXCHANGED FLASH TANK VAPOR STREAM AND FLASH TANK LIQUID STREAM TO SEPARATE SCRUBBER TANKS SAID SCRUBBER TANKS COMPRISING MEANS FOR PRESSURE CONTROL WHEREIN THE PRESSURE IS CONTROLLED BY DRAWING VAPOR FROM THE SCRUBBER TANKS TO THE SUCTION SIDE OF A PLURALITY OF COMPRESSION MEANS,
4. separately passing both the heat exchanged flash tank vapor stream and flash tank liquid stream to separate scrubber tanks said scrubber tanks comprising means for pressure control wherein the pressure is controlled by drawing vapor from the scrubber tanks to the suction side of a plurality of compression means;
4. separately passing both the heat exchanged flash tank vapor stream and flash tank liquid stream to separate scrubber tanks said scrubber tanks comprising means for pressure control wherein the pressure is controlled by drawing vapor from the scrubber tanks to the suction side of a plurality of compression means;
4. A method of claim 3 wherein the inlet material stream is bypassed around a compressor system utilizing a plurality of compressors said bypassing controlled by:
5. The method of claim 1 wherein a plurality of compressors in parallel operation is controlled by transmitting in parallel the signal selected by the first selector relay to a separate selector relay for each compression means.
5. producing a signal in response to the temperature at the inlet to the separator; and
5. sensing the temperature at the separating means inlet stream and producing a signal responsive to said inlet stream temperature;
5. SENSING THE TEMPERATURE AT THE SEPARATING MEANS INLET STREAM AND PRODUCING A SIGNAL RESPONSIVE TO SAID INLET STREAM TEMPERATURE,
6. TRANSMITTING SAID SIGNAL AS SET POINT FOR THE MEANS FOR PRESSURE CONTROL OF EACH OF THE SCRUBBER TANKS,
6. transmitting said signal as set point for the means for pressure control of each of the scrubber tanks;
6. transmitting said signal to actuate a flow control means for bypass of inlet gas stream from the inlet of the heat exchange means to a residue outlet means from the partial condensation system thereby bypassing the partial condensation system with at least a portion of the inlet feed stream.
7. generating output signals responsive to the pressure of each of the scrubber tanks; and
7. GENERATING OUTPUT SIGNALS RESPONSIVE TO THE PRESSURE OF EACH OF THE SCRUBBER TANKS, AND
8. ACTUATING A FIRST SELECTOR RELAY BY THE SIGNAL CORRESPONDING TO THE HIGHER SCRUBBER PRESSURE AND TRANSMITTING SAID SIGNAL TO A SPEED CONTROLLED AS SET POINT FOR THE COMPRESSOR DRIVE THEREBY CONTROLLING THE FLOW RATE OF MATERIAL THROUGH THE INLET HEAT EXCHANGER AND THEREBY EFFECTING CONTROL OF THE MINIMUM TEMPERATURE OF THE INLET FEED STREAM MATERIAL.
8. actuating a first selector relay by the signal corresponding to the higher scrubber pressure and transmitting said signal to a speed controller as set point for the compressor drive thereby controlling the flow rate of material through the inlet heat exchanger and thereby effecting control of the minimum temperature of the inlet feed stream material.
9. transmitting the signal produced in response to the higher scrubber pressure to a second selector relay;
10. producing a second signal in response to the intake manifold pressure of compression means and transmitting this second signal responsive to the intake manifold pressure to said second selector relay; and
11. actuating said second selector relay by the signal representing the lower pressure of the second signal responsive to the intake manifold pressure and the signal responsive to the scrubber pressure transmitted between said first relay to transmit said signal representing the lower pressure to a speed controller as set point for the compressor drive thereby controlling the flow rate of material through the inlet heat exchanger and thereby effecting control of the temperature of the inlet feed stream material.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US315535A US3901673A (en) | 1972-12-15 | 1972-12-15 | Recovery of natural gas liquids by partial condensation |
| US05/579,993 US4040259A (en) | 1972-12-15 | 1975-05-22 | Recovery of natural gas liquids by partial condensation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US315535A US3901673A (en) | 1972-12-15 | 1972-12-15 | Recovery of natural gas liquids by partial condensation |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/579,993 Division US4040259A (en) | 1972-12-15 | 1975-05-22 | Recovery of natural gas liquids by partial condensation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3901673A true US3901673A (en) | 1975-08-26 |
Family
ID=23224867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US315535A Expired - Lifetime US3901673A (en) | 1972-12-15 | 1972-12-15 | Recovery of natural gas liquids by partial condensation |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3901673A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4142876A (en) * | 1975-05-22 | 1979-03-06 | Phillips Petroleum Company | Recovery of natural gas liquids by partial condensation |
| US4167455A (en) * | 1978-10-19 | 1979-09-11 | Phillips Petroleum Co. | Floating pressure control of fractionator system |
| US4182657A (en) * | 1978-10-19 | 1980-01-08 | Phillips Petroleum Company | Floating pressure control of fractionator system |
| US5141544A (en) * | 1991-04-09 | 1992-08-25 | Butts Rayburn C | Nitrogen rejection unit |
| US5375422A (en) * | 1991-04-09 | 1994-12-27 | Butts; Rayburn C. | High efficiency nitrogen rejection unit |
| EP1239246A1 (en) * | 2001-03-09 | 2002-09-11 | Linde Aktiengesellschaft | Process and apparatus for separation of a gas mixture with failsafe operation |
| US20020166134A1 (en) * | 1999-06-18 | 2002-11-07 | Field Loren J. | Cardiomyocytes with enhanced proliferative potenial, and methods for preparing and using same |
| US20030116290A1 (en) * | 2001-12-20 | 2003-06-26 | 3M Innovative Properties Company | Continuous process for controlled evaporation of black liquor |
| US6869501B2 (en) | 2001-12-20 | 2005-03-22 | 3M Innovative Properties Company | Continuous process for controlled concentration of colloidal solutions |
| US20090301133A1 (en) * | 2006-06-20 | 2009-12-10 | Fluor Technologies Corporation | Ethane Recovery Methods and Configurations for High Carbon Dioxide Content Feed Gases |
| US20120096895A1 (en) * | 2010-10-26 | 2012-04-26 | Kirtikumar Natubhai Patel | Process for separating and recovering NGLs from hydrocarbon streams |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3148966A (en) * | 1962-08-23 | 1964-09-15 | Phillips Petroleum Co | Automatic controls for the liquefaction and separation of gases |
| US3212278A (en) * | 1963-06-07 | 1965-10-19 | Phillips Petroleum Co | Fluid distribution system |
| US3225551A (en) * | 1963-03-04 | 1965-12-28 | Phillips Petroleum Co | Fractional distillation system |
| US3240023A (en) * | 1962-10-12 | 1966-03-15 | Phillips Petroleum Co | Control system for gas separation process |
| US3293869A (en) * | 1964-02-10 | 1966-12-27 | Phillips Petroleum Co | Gas liquefaction with recombining of separated gas-liquid fractions |
| US3333398A (en) * | 1967-08-01 | Absorption flow control | ||
| US3407052A (en) * | 1966-08-17 | 1968-10-22 | Conch Int Methane Ltd | Natural gas liquefaction with controlled b.t.u. content |
| US3527059A (en) * | 1968-12-26 | 1970-09-08 | Phillips Petroleum Co | Method of controlling parallel-operating refrigeration compressors |
-
1972
- 1972-12-15 US US315535A patent/US3901673A/en not_active Expired - Lifetime
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3333398A (en) * | 1967-08-01 | Absorption flow control | ||
| US3148966A (en) * | 1962-08-23 | 1964-09-15 | Phillips Petroleum Co | Automatic controls for the liquefaction and separation of gases |
| US3240023A (en) * | 1962-10-12 | 1966-03-15 | Phillips Petroleum Co | Control system for gas separation process |
| US3225551A (en) * | 1963-03-04 | 1965-12-28 | Phillips Petroleum Co | Fractional distillation system |
| US3212278A (en) * | 1963-06-07 | 1965-10-19 | Phillips Petroleum Co | Fluid distribution system |
| US3293869A (en) * | 1964-02-10 | 1966-12-27 | Phillips Petroleum Co | Gas liquefaction with recombining of separated gas-liquid fractions |
| US3407052A (en) * | 1966-08-17 | 1968-10-22 | Conch Int Methane Ltd | Natural gas liquefaction with controlled b.t.u. content |
| US3527059A (en) * | 1968-12-26 | 1970-09-08 | Phillips Petroleum Co | Method of controlling parallel-operating refrigeration compressors |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4142876A (en) * | 1975-05-22 | 1979-03-06 | Phillips Petroleum Company | Recovery of natural gas liquids by partial condensation |
| US4167455A (en) * | 1978-10-19 | 1979-09-11 | Phillips Petroleum Co. | Floating pressure control of fractionator system |
| US4182657A (en) * | 1978-10-19 | 1980-01-08 | Phillips Petroleum Company | Floating pressure control of fractionator system |
| US5141544A (en) * | 1991-04-09 | 1992-08-25 | Butts Rayburn C | Nitrogen rejection unit |
| US5375422A (en) * | 1991-04-09 | 1994-12-27 | Butts; Rayburn C. | High efficiency nitrogen rejection unit |
| US20020166134A1 (en) * | 1999-06-18 | 2002-11-07 | Field Loren J. | Cardiomyocytes with enhanced proliferative potenial, and methods for preparing and using same |
| EP1239246A1 (en) * | 2001-03-09 | 2002-09-11 | Linde Aktiengesellschaft | Process and apparatus for separation of a gas mixture with failsafe operation |
| US6598424B2 (en) | 2001-03-09 | 2003-07-29 | Linde Aktiengesellschaft | Process and apparatus for separating a gas mixture with emergency operation |
| KR100859384B1 (en) * | 2001-03-09 | 2008-09-22 | 린데 악티엔게젤샤프트 | Method and arrangement for separating gas mixture in emergency operation |
| US20030116290A1 (en) * | 2001-12-20 | 2003-06-26 | 3M Innovative Properties Company | Continuous process for controlled evaporation of black liquor |
| US6869501B2 (en) | 2001-12-20 | 2005-03-22 | 3M Innovative Properties Company | Continuous process for controlled concentration of colloidal solutions |
| US20090301133A1 (en) * | 2006-06-20 | 2009-12-10 | Fluor Technologies Corporation | Ethane Recovery Methods and Configurations for High Carbon Dioxide Content Feed Gases |
| US8567213B2 (en) * | 2006-06-20 | 2013-10-29 | Fluor Technologies Corporation | Ethane recovery methods and configurations for high carbon dioxide content feed gases |
| US20120096895A1 (en) * | 2010-10-26 | 2012-04-26 | Kirtikumar Natubhai Patel | Process for separating and recovering NGLs from hydrocarbon streams |
| US9175905B2 (en) * | 2010-10-26 | 2015-11-03 | Kirtikumar Natubhai Patel | Process for separating and recovering NGLs from hydrocarbon streams |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3901673A (en) | Recovery of natural gas liquids by partial condensation | |
| US3609983A (en) | Krypton-xenon recovery system and process | |
| US4414003A (en) | Process and apparatus for the recovery of solvents | |
| RU2188370C2 (en) | Method and device for control of condensation of hydrocarbon gas flow | |
| US4490985A (en) | Method of dehydrating natural gas | |
| US4110996A (en) | Method and apparatus for recovering vapor | |
| EP0190355B1 (en) | Apparatus for producing high-purity nitrogen gas | |
| US2526996A (en) | Method and apparatus for separating mixed gases | |
| US4142876A (en) | Recovery of natural gas liquids by partial condensation | |
| US3592017A (en) | Purging arrangement for refrigeration systems | |
| US4040259A (en) | Recovery of natural gas liquids by partial condensation | |
| NO162928B (en) | GENERATOR FOR PREPARING AIR AIR. | |
| US3894942A (en) | Volatile gasoline vapor recovery system | |
| RU2676829C1 (en) | Associated petroleum gas topping plant | |
| US3212276A (en) | Employing the heating and cooling effect of a refrigerating cycle | |
| US2924078A (en) | Process and apparatus for producing liquid oxygen | |
| US4674290A (en) | Vent control for a vessel | |
| US3148966A (en) | Automatic controls for the liquefaction and separation of gases | |
| US2476280A (en) | Apparatus for the distillation and fractionation of composite liquids and control means therefor | |
| CN107050912A (en) | A kind of vapor condensation liquid recovery system and method | |
| US3130027A (en) | Control system for fluid separation | |
| US2213338A (en) | Method and apparatus for fractionating gaseous mixtures | |
| CA1107190A (en) | Hydrocarbon recovery | |
| US4042011A (en) | Refrigeration control | |
| US2252738A (en) | Process and apparatus for removing condensates from gas |