US3900633A - Patterned transfer sheet - Google Patents
Patterned transfer sheet Download PDFInfo
- Publication number
- US3900633A US3900633A US342584A US34258473A US3900633A US 3900633 A US3900633 A US 3900633A US 342584 A US342584 A US 342584A US 34258473 A US34258473 A US 34258473A US 3900633 A US3900633 A US 3900633A
- Authority
- US
- United States
- Prior art keywords
- microcapsules
- light
- weight
- pressure
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003094 microcapsule Substances 0.000 claims abstract description 83
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 41
- 229920000642 polymer Polymers 0.000 claims abstract description 32
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims description 65
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 17
- 229920002367 Polyisobutene Polymers 0.000 claims description 11
- 229920000896 Ethulose Polymers 0.000 claims description 10
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 10
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 10
- -1 polyethylene, tetrafluorethylene Polymers 0.000 claims description 9
- 239000000020 Nitrocellulose Substances 0.000 claims description 8
- 229920001220 nitrocellulos Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000003849 aromatic solvent Substances 0.000 claims description 7
- 239000011088 parchment paper Substances 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 230000003381 solubilizing effect Effects 0.000 claims description 7
- 239000008096 xylene Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 6
- 230000002522 swelling effect Effects 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000003944 tolyl group Chemical group 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000005453 ketone based solvent Substances 0.000 claims description 3
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000011164 primary particle Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims 1
- 239000000123 paper Substances 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 229920006254 polymer film Polymers 0.000 description 8
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000012447 hatching Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1733—Decalcomanias applied under pressure only, e.g. provided with a pressure sensitive adhesive
- B44C1/1737—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff on a substrate unsuitable for direct deposition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1704—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1405—Capsule or particulate matter containing [e.g., sphere, flake, microballoon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
- Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2813—Heat or solvent activated or sealable
Definitions
- a transfer sheet according to the invention comprises a light-transmitting temporary support sheet carrying a plurality of elements or points which together form a transferable pattern, coated with a coating of polymer containing microcapsules whose content liberated by rupture of the microcapsules under transfer pressure reacts with a top layer of pressure-sensitive adhesive to adhere and transfer the elements of pattern to a receptor surface.
- the sheet carrying the pattern was cut out coat lely by means of scissors so as to form a piece which, when applied onto the surface to be shaded, would have parts overlapping the contours of said surface.
- Said piece was applied with its adhesive surface against the surface of paper to be shaded and was adhered to the latter by the pressure-sensitive adhesive.
- the draftsman followed the outer edge of the surface to be shaded and cut the patterned plastic piece.
- the overlapping portions of the pattern applied were then removed This cutting operation required a great skill from the draftsman. It was necessary to estimate exactly the pressure to be applied on the sharp cutting stylus to pierce and cut out the patterned piece. Often, not only the patterned piece but also the underlying receptor surface of paper was cut out.
- patterned sheets often are used in making architectural drafts. These drafts made on tracing paper or similar sheets are duplicated several times.
- the duplicating machine comprises a cylinder of glass with which said patterned sheets are contacted. Said cylinder may reach temperatures up to 125C. It has often been found that even under temperatures below 100C, the pressure-sensitive adhesive coating of said sheets became less cohesive. For that reason, the pattern was detached from the paper and was either transferred onto the glass cylinder or moved on the paper.
- One object of this invention is a new form of patterned sheet, wherein the pattern or any selected portion thereof can be transferred and adhered to a receptor surface under a pressure such as applied by means of a pencil or a spatula, the adhesion of the transferred pattern to the receptor surface, which may be of tracing paper or of similar material, being unaffected by contact at temperatures up to 150C.
- a patterned sheet comprising a lighttransmitting temporary support having printed thereon a pattern of the kind described, the elements or points of the pattern being of a printing ink having two main components, at least the areas of said elements, and preferably the entire pattem-carrying surface of the support.
- microcapsules being covered with a light-transmitting film made of one of the main components of the ink and containing dispersed microcapsules, said microcapsules containing a solvent of said light-transmitting film, said solvent having no solubilizing action on the temporary support and the ink of the pattern, said film being covered with a coating of pressure-sensitive adhesive whose components are miscible with said film and are soluble in the solvent of the microcapsules.
- the light-transmitting support is transparent and characterized by a surface tension less than 36 dynes/cm and an insolubility at room temperature in the solvent contained in the microcapsules.
- the temporary support may be polyethylene, tetrafluorethylene, polypropylene, polyethylene terephthalate, artificial parchment paper coated with silicone.
- the ink printed on the temporary support to form the pattern comprises pigments.
- the first main component is a polymer soluble in the solvent contained in the microcapsules and the second main component is a substance which reduces the solubility of the first main component in said solvent and may be a resin or another polymer.
- the mixture of the two main components is adjusted in such a way that the action of the solvent may not dissolve the ink and can at most swell the ink so that each printed point or element keeps its shape and the pigments or dyestuffs may not escape from the binders by transfer.
- the ink when the solvent contained in the microcapsules is toluene or xylene, the ink may be composed as follows:
- Pigments Carbon black Soluble polymer (first main component): low viscosity ethylhydroxyethyl cellulose 40
- Insoluble polymer second main component: nitrocellulose V2 second 60
- Glycerophthalic resin with 52% of soy bean oil 58 cobalt naphthenate l and lead naphthenate I
- the ink composition is adjusted so as to adhere moderately to the temporary support.
- the film of light-transmitting unplastified polymer covering the printed pattern is of the same nature as the first main component of the ink of the pattern, namely the polymer soluble in the solvent of the microcapsules.
- Microcapsules having a diameter less than microns are embedded in said light-transmitting polymer film and contain a solvent for said polymer.
- the polymer film in which the microcapsules are embedded should be sheared at the places where the pressure is applied. Such effect was noted when the weight of microcapsules reaches at least 40% of the weight of the polymer.
- the amount of solvent should be sufficient for dissolving or softening the polymer and the fine layer of pressure-sensitive adhesive superimposed thereto to a sufficient extent for obtaining a new combination of adhesive whose characteristics will be given hereafter.
- This effect is obtained when the weight of microcapsules reaches at least 40% of the weight of the polymer and when the volume content of solvent of the microcapsules reaches at least 85% of the total volume of the microcapsules.
- the solvent is, of course, selected depending on the polymer of said light-transmitting film.
- said polymer when the solvent of the microcapsules is toluene, said polymer may be ethylhydroxyethylcellulose or chlorinated rubber; when the solvent is acetone, said polymer may be nitrocellulose.
- Suitable microcapsules are described in Applicants US. Pat. No. 3,728,210.
- the adhesion to the receptor surface appears not satisfactory everywhere. Indeed, when the microcapsules are ruptured, a more or less important part of the solvents is directly absorbed by the receptor surface so that the polymer is not always sufficiently softened and adheres very weakly.
- the pressure-sensitive adhesive should be as follows: soluble in the solvent of the microcapsules; compatible with the polymer containing the microcapsules; applied as a layer whose thickness is not greater than one-third of the thickness of the light-transmitting polymer layer (this ratio does not take into account the diameter of the microcapsules contained in the polymer).
- the rate of solubility of the pressuresensitive adhesive in the solvent of the microcapsules is less than the rate of solubility of the light-transmittin g polymer film which contains the microcapsules.
- the instantaneous adhesion and the definitive adhesion of a pressure-sensitive adhesion are almost identical to one another and the cohesion of said adhesive does not change.
- the light-transmitting polymer film and the pressuresensitive adhesive react with one another which causes an important modification of the adhesion of the adhesive after transfer.
- the definitive adhesion becomes substantially greater than that of the original adhesive which is no longer pressure-sensitive.
- the cohesion of the transformed adhesive is also increased to a higher level.
- the transferred and transformed adhesive keeps its adhesion unaffected at temperatures up to C eg when the patterned film transferred on tracing paper is brought into contact with the hot cylinder of a draft-duplicating machine.
- a support sheet 1 carries on its one surface called front surface, printed elements 2 of ink forming a pattern of shades, hatchings, hachures, crosshatches, grains, stipples, textile design. It is to be understood that these elements are not necessarily identical with one another and are distributed on the front surface of the support sheet.
- the purpose of the transfer operation is to detach any selected portion of the pattern, thus comprising at least one and often a plurality of elements 2, from the support 1 and to transfer said portion of the pattern onto a receptor surface, eg. the area of a tracing paper on which shades are to be provided, by contacting said front surface with said receptor surface and applying a local pressure on the back surface of the support in the area where transfer is desired.
- the front surface of the support 1 has a layer of light-transmitting polymer film 3 containing microcapsules 4.
- the polymer of said layer 3 is similar to one of the main components of the elements 2 so that the layer 3 and the elements 2 adhere strongly to one another.
- the materials of the elements 2 and layer 3 are selected for adhering moderately to the support.
- a layer 5 of the pressure-sensitive adhesive covers the layer 3 of polymer and forms thus the top layer of the transfer sheet. When a local transfer pressure is applied as described above, the transferable part becomes adhered to the receptor surface within the limits of the area of pressure.
- the microcapsules rupture, their solvent content permits the transferable part to shear along the limits of the area of pressure and within said limits causes the pressuresensitive adhesive to interact with the polymer layer 3 to make a stronger adhesive as described above.
- the transferable part is separated from the support 1 in said area of pressure so that the pattern is transferred to the extent desired.
- Pigments Carbon black Polymers: Ethylhydroxyethyk cellulose 60 Nitrocellulose V2 second 30 Solvents: Ethylglycol 170 Butylglycol 100 Xylene 30 After drying of the ink, the temporary ,support and the ink elements of pattern are covered with a transparent coating composed as follows:
- a patterned transfer sheet carrying on one surface thereof a plurality of elements or points which together form patterns, any selected portion of one or more of said patterns, being transferable and adherable to a receptor surface, comprising 1. a light-transmitting temporary support, carrying on its surface,
- an unplasticized transferable film comprising:
- a pigmented layer forming the elements or points of the patterns and being composed of a printing ink with two main components
- a light-transmitting layer formed of one of the main components of said ink and containing dispersed microcapsules covering at least the portion of the pattern carrying surface of said temporary support, said microcapsules containing a solvent for said light-transmitting film with said solvent having at the very most a swelling action on said printing ink and no solubilizing action on the tempo rary support, and
- a transfer sheetas inclaim l in which the first main component of the ink is a polymer soluble in the solvent contained in the microcapsules and the second main component of the ink is a substance which reduces the solubility of the first main component in said solvent, the ratio between the first and second main component being such that said solvent contained in the microcapsules cannot, dissolve the ink.
- an unplasticized transferable film comprising:
- a pigmented layer forming the elements or points of the patterns and being composed of a printing ink with two main components
- a light-transmitting layer formed of one of the main components of said ink and containing dispersed microcapsules covering at least the portion of the pattern carrying surface of said temporary support, said microcapsules containing a solvent for said light-transmitting film with said solvent having at the very most a swelling action on said printing ink and no solubilizing action on the temporary support, and
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1449172A GB1423506A (en) | 1972-03-28 | 1972-03-28 | Transfer sheet |
Publications (1)
Publication Number | Publication Date |
---|---|
US3900633A true US3900633A (en) | 1975-08-19 |
Family
ID=10042163
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US342584A Expired - Lifetime US3900633A (en) | 1972-03-28 | 1973-03-19 | Patterned transfer sheet |
Country Status (5)
Country | Link |
---|---|
US (1) | US3900633A (enrdf_load_stackoverflow) |
BE (1) | BE795727A (enrdf_load_stackoverflow) |
DE (1) | DE2315295A1 (enrdf_load_stackoverflow) |
FR (1) | FR2178591A5 (enrdf_load_stackoverflow) |
GB (1) | GB1423506A (enrdf_load_stackoverflow) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4089547A (en) * | 1976-07-21 | 1978-05-16 | Reprographic Materials, Inc. | Manifold receptor sheets and processes therefor |
US4103053A (en) * | 1976-04-09 | 1978-07-25 | Myron Barehas | Pressure sensitive laminate and method of forming same |
US4505976A (en) * | 1983-02-15 | 1985-03-19 | Johnson & Johnson Products, Inc. | Stoma seal adhesive |
US4675253A (en) * | 1985-05-08 | 1987-06-23 | The Charles Stark Draper Laboratory, Inc. | Method and patterns for making flat plane seamed garments |
US4677015A (en) * | 1984-12-28 | 1987-06-30 | Nippon Seiki Co., Ltd. | Transfer sheet |
US20040123943A1 (en) * | 2002-12-12 | 2004-07-01 | Chih-Lung Chang | Image transfer medium and process for producing same |
US20090280304A1 (en) * | 2008-05-07 | 2009-11-12 | Ko-Yuan Tseng | Method for defining regions of differing porosity of a nitrocellulose film on a substrate |
US20120293578A1 (en) * | 2011-05-17 | 2012-11-22 | Seiko Epson Corporation | Ink set for ink jet recording, recording apparatus, and recorded matter |
US20150128326A1 (en) * | 2013-11-12 | 2015-05-14 | Tattees, LLC | Tattoo-Revealing Garment |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3635746A (en) * | 1966-10-19 | 1972-01-18 | Mac Karlan | Dry transfer and method |
US3684544A (en) * | 1968-06-21 | 1972-08-15 | Jean Gustave Jules Piron | Process for making a dry transfer material |
US3728210A (en) * | 1969-06-27 | 1973-04-17 | J Piron | Dry transfer |
US3741787A (en) * | 1968-08-07 | 1973-06-26 | R Tordjman | Dry decalcomania |
-
0
- BE BE795727D patent/BE795727A/xx not_active IP Right Cessation
-
1972
- 1972-03-28 GB GB1449172A patent/GB1423506A/en not_active Expired
-
1973
- 1973-02-26 FR FR7306785A patent/FR2178591A5/fr not_active Expired
- 1973-03-19 US US342584A patent/US3900633A/en not_active Expired - Lifetime
- 1973-03-27 DE DE2315295A patent/DE2315295A1/de active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3635746A (en) * | 1966-10-19 | 1972-01-18 | Mac Karlan | Dry transfer and method |
US3684544A (en) * | 1968-06-21 | 1972-08-15 | Jean Gustave Jules Piron | Process for making a dry transfer material |
US3741787A (en) * | 1968-08-07 | 1973-06-26 | R Tordjman | Dry decalcomania |
US3728210A (en) * | 1969-06-27 | 1973-04-17 | J Piron | Dry transfer |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4103053A (en) * | 1976-04-09 | 1978-07-25 | Myron Barehas | Pressure sensitive laminate and method of forming same |
US4089547A (en) * | 1976-07-21 | 1978-05-16 | Reprographic Materials, Inc. | Manifold receptor sheets and processes therefor |
US4505976A (en) * | 1983-02-15 | 1985-03-19 | Johnson & Johnson Products, Inc. | Stoma seal adhesive |
US4677015A (en) * | 1984-12-28 | 1987-06-30 | Nippon Seiki Co., Ltd. | Transfer sheet |
US4675253A (en) * | 1985-05-08 | 1987-06-23 | The Charles Stark Draper Laboratory, Inc. | Method and patterns for making flat plane seamed garments |
US7118644B2 (en) | 2002-12-12 | 2006-10-10 | Chih-Lung Chang | Image transfer medium and process for producing same |
US20040123943A1 (en) * | 2002-12-12 | 2004-07-01 | Chih-Lung Chang | Image transfer medium and process for producing same |
US20070095462A1 (en) * | 2002-12-12 | 2007-05-03 | Chih-Lung Chang | Image transfer medium and process for producing same |
US20090280304A1 (en) * | 2008-05-07 | 2009-11-12 | Ko-Yuan Tseng | Method for defining regions of differing porosity of a nitrocellulose film on a substrate |
US20120293578A1 (en) * | 2011-05-17 | 2012-11-22 | Seiko Epson Corporation | Ink set for ink jet recording, recording apparatus, and recorded matter |
US8807729B2 (en) * | 2011-05-17 | 2014-08-19 | Seiko Epson Corporation | Ink set for ink jet recording, recording apparatus, and recorded matter |
US20150128326A1 (en) * | 2013-11-12 | 2015-05-14 | Tattees, LLC | Tattoo-Revealing Garment |
US9427035B2 (en) * | 2013-11-12 | 2016-08-30 | Tattees, LLC | Tattoo-revealing garment |
Also Published As
Publication number | Publication date |
---|---|
DE2315295A1 (de) | 1973-10-25 |
FR2178591A5 (enrdf_load_stackoverflow) | 1973-11-09 |
GB1423506A (en) | 1976-02-04 |
BE795727A (fr) | 1973-08-21 |
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