US3899973A - Ignition device for explosive charges - Google Patents
Ignition device for explosive charges Download PDFInfo
- Publication number
- US3899973A US3899973A US822413A US82241369A US3899973A US 3899973 A US3899973 A US 3899973A US 822413 A US822413 A US 822413A US 82241369 A US82241369 A US 82241369A US 3899973 A US3899973 A US 3899973A
- Authority
- US
- United States
- Prior art keywords
- percent
- combustible material
- burning velocity
- ignition device
- rigid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical group C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 12
- 239000000020 Nitrocellulose Substances 0.000 claims description 10
- 239000000446 fuel Substances 0.000 claims description 10
- 229920001220 nitrocellulos Polymers 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 230000037452 priming Effects 0.000 claims description 7
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- PZIMIYVOZBTARW-UHFFFAOYSA-N centralite Chemical compound C=1C=CC=CC=1N(CC)C(=O)N(CC)C1=CC=CC=C1 PZIMIYVOZBTARW-UHFFFAOYSA-N 0.000 claims description 4
- RUKISNQKOIKZGT-UHFFFAOYSA-N 2-nitrodiphenylamine Chemical compound [O-][N+](=O)C1=CC=CC=C1NC1=CC=CC=C1 RUKISNQKOIKZGT-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- 229960004279 formaldehyde Drugs 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- 229920001004 polyvinyl nitrate Polymers 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 abstract description 14
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002655 kraft paper Substances 0.000 description 3
- HSOOVEKLGOIEFF-UHFFFAOYSA-N ethenyl nitrate Chemical compound [O-][N+](=O)OC=C HSOOVEKLGOIEFF-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- 244000198134 Agave sisalana Species 0.000 description 1
- 241000928106 Alain Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910021346 calcium silicide Inorganic materials 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- JUINSXZKUKVTMD-UHFFFAOYSA-N hydrogen azide Chemical compound N=[N+]=[N-] JUINSXZKUKVTMD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C5/00—Fuses, e.g. fuse cords
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42C—AMMUNITION FUZES; ARMING OR SAFETY MEANS THEREFOR
- F42C19/00—Details of fuzes
- F42C19/08—Primers; Detonators
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
- H04N9/00—Details of colour television systems
- H04N9/44—Colour synchronisation
- H04N9/465—Synchronisation of the PAL-switch
Definitions
- An ignition device for igniting explosive Charges comprises a rigid combustible material having a high burn- [52] US. Cl 102/27 R; 102/70 R; 102/DIG. 1 ing velocity and a low-energy detonating fuse disposed [51] Int. Cl. F42b 7/00 on an axis therein, the gn n device n in ng no [58] Field of Search 102/38, 38 CC, 39, 46, black powder.
- Satisfactory ignition of explosive devices is a critical factor in the efficiency of performance of the charge.
- satisfactory operation of solid propergols depends very largely upon the initial phase of combustion i.e. upon the ignition of the propergol block.
- black powder is a complex mixture that quality of which may vary considerably, thus affecting the operation of the ignition devices and leading to non-reproducibility and uncertain results. Furthermore, black powder itself is particularly difficult, especially as regards safety, to manufacture and use.
- an ignition device comprising a body of a rigid combustible material of high burning velocity having a low-energy detonating fuse disposed therein, the fuse being connected to a primer by means of a priming system.
- the body is of tubular form and the lowenergy detonating fuse is disposed along its major axis, the tubular body being rigidly secured to a base member which is provided with means for securing the member in a cartridge-case base, the base member bearing the primer and the priming system for the fuse.
- a wide range of rigid combustible materials can be used for the purposes of this invention according to the burning and mechanical properties required.
- a general characteristic shared by many of these materials, however, is the heterogeneity of their structure, comprising as they do fuel elements having a high burning velocity and, in adj ition, a material which has a lower burning velocity but which imparts mechanical strength to the body as a whole.
- One example of a rigid combustible material useful in the igniters of the invention comprises one or more felt members comprising a high percentage (70 to 90 percent) of nitrocellulose having a nitrogen content of from 12.6 to 14.1 percent as the fuel element of high burning velocity and a low percentage to 30 percent) of cellulose together with a resin binder and a stabiliser as the combustible substance of lower burning speed imparting mechanical strength to the body.
- a metal in finely divided state can also be added to this mixture in order to accelerate the ignition of the charge.
- the resin binder may be an acrylic, polyvinyl, acrylonitrile, methylolated urea-formol or a forrnolmelamine resin or a combustible resin such as nitrocellulose or polyvinyl nitrate; the binder preferably being used in a proportion of from 5 to 15 percent.
- Any conventional powder stabiliser may be used with the binder, such as diphenylamine, Centralite, or nitrodiphenylamine.
- diphenylamine Centralite
- nitrodiphenylamine In the case of single-base powders, the commonest practice is to use diphenylamine in a proportion of from 0.7 to 1.2 percent, whereas with double-base powders, Centralite is used in a proportion of from 2 to 3 percent.
- Typical finely divided metals which may be included in the rigid combustible material are the reducing metals such as aluminium, beryllium and zirconium, the particle size being from 30 to 6011,
- FIG. I is a sectional elevation view of the ignition device.
- the ignition device comprises a tubular member 1, which is made of a rigid combustible material, along whose axis a low-energy detonating fuse 2 is disposed.
- Member 1 is rigidly secured to a base member 3 which is screw threaded to secure the base member in a cartridge case base.
- Member 3 also bears a priming system 4 for the fuse, an electric primer 5, and sealing means 6 to avoid gas leaks.
- Tubular member 1 is prepared from an aqueous suspension containing 81 percent nitrocellulose (having a nitrogen content of 13.35 percent), 9 percent cellulose, 9 percent acrylonitrilic latex resin binder, and l percent diphenylamine as a stabiliser.
- the suspension is squeezedrained and is then introduced into a two-shell cylindrical mould (which has perforate walls) containing an axial metal rod to form an axial channel in the moulded article for the fuse.
- work-up continues by heating the mould, the tubular member being brought to a final state of apparent density 0.6.
- Typical dimensions of the tubular member are:
- a 2mm diameter detonating fuse 2 is fitted into the axial channel.
- This fuse comprises a cylindrical lead sheath, /zmm thick, surrounding a charge of equal quantities of Penthrite and calcium silicide.
- the tubular member 1 and fuse 2 are then mounted on the base member 3 and are intro Jerusalem axially into a cartridge case.
- the resultant charge satisfies the satutory rough-handling tests and gives improved firing results compared to a conventional primer tube; it gives less variation in the initial projectile speed with a reduced maximum pressure and with a constant initial velocity.
- the rigid combustible substance was moulded to form a tubular member along whose axis the detonating fuse in disposed; clearly, however, the rigid combustible substance is not limited to such a shape and can be worked into any other required shape.
- the invention provides a more uniform velocity and pressure and a lower pressure than has previously been obtained.
- the device is well suited for high-performance equipment, especially for semi-combustible cartridge cases where the presence of an empty metal priming tube in the cartridge after ignition is undesirable.
- the combustible material used for this invention is relatively safe to handle during the manufacture of the device as the presence of water or resin binder and stabiliser reduces the danger of sudden explosion.
- Table I lists other examples or rigid combustible substances which may be used according to the invention.
- the results of comparative testing against conventional devices are given in Table II.
- the rigid combustible material comprises one or more felt members having from 70 to 90 percent of nitrocellulose with a nitrogen content of 12.6 to 14.1 percent as the fuel element of high burning velocity, and from to percent of cellulose with a resin binder and a stabiliser as the fuel elements of low burning velocity TABLEI Composition Nitrocellulose Cellulose Resin Stabiliser Metal No.
- An ignition device which comprises a low-energy energy detonating fuse, a casing about said detonating fuse, said casing consisting of a substantially rigid tubular body of a rigid combustible material of high burning velocity, said body of combustible material surrounding said detonating fuse such that said combustible material forms the sole encasement for said detonating fuse, said tubular body being self-supporting and being adapted to be disposed within a cartridge case or missile in direct contact with an explosive charge to be ignited, a base member fixedly engaged with said body, and priming means disposed within said base member in contact with said fuse.
- An ignition device in which the rigid combustible material comprises on the one imparting mechanical strength to the body.
- a device in which said resin binder is selected from the group consisting of acrylic, polyvinyl, acrylonitrile, methylolated urea-formol, formol-melamine, nitrocellulose and polyvinyl nitrate resins, and is present in an amount from 5 to 15 percent by weight.
- a device in which said stabiliser is selected from the group consisting of diphenylamine, Centralite and nitrodiphenylamine.
- tubular body comprises, by weight, 81 percent nitrocellulose having a nitrogen content of 13.35 percent, 9 percent cellulose. 9 percent of an acrylonitrilic latex resin binder and 1 percent diphenylamine.
Landscapes
- Engineering & Computer Science (AREA)
- Multimedia (AREA)
- Signal Processing (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Automotive Seat Belt Assembly (AREA)
- Ignition Installations For Internal Combustion Engines (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR152244 | 1968-05-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3899973A true US3899973A (en) | 1975-08-19 |
Family
ID=8650406
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US822413A Expired - Lifetime US3899973A (en) | 1968-05-17 | 1969-05-07 | Ignition device for explosive charges |
Country Status (10)
Country | Link |
---|---|
US (1) | US3899973A (enrdf_load_stackoverflow) |
BE (1) | BE731847A (enrdf_load_stackoverflow) |
CH (1) | CH506044A (enrdf_load_stackoverflow) |
ES (1) | ES166433Y (enrdf_load_stackoverflow) |
FR (1) | FR1593513A (enrdf_load_stackoverflow) |
GB (1) | GB1270298A (enrdf_load_stackoverflow) |
IL (1) | IL32160A (enrdf_load_stackoverflow) |
LU (1) | LU58536A1 (enrdf_load_stackoverflow) |
NL (1) | NL163868C (enrdf_load_stackoverflow) |
SE (1) | SE407977B (enrdf_load_stackoverflow) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4674405A (en) * | 1985-01-23 | 1987-06-23 | Dynamit Nobel Aktiengesellschaft | Partially combustible propellant charge igniter |
US4882994A (en) * | 1988-01-28 | 1989-11-28 | Veltman Preston Leonard | Particulate fuel components for solid propellant systems |
US5052302A (en) * | 1990-07-26 | 1991-10-01 | Olin Corporation | Unpressurized combustible primer for cannon cartridges |
WO1996011374A1 (en) * | 1994-10-06 | 1996-04-18 | Ici Australia Operations Proprietary Limited | Explosives booster and primer |
US5743559A (en) * | 1994-01-27 | 1998-04-28 | Daicel Chemical Industries, Ltd. | Inflator for air bags |
US6170399B1 (en) | 1997-08-30 | 2001-01-09 | Cordant Technologies Inc. | Flares having igniters formed from extrudable igniter compositions |
US6224099B1 (en) | 1997-07-22 | 2001-05-01 | Cordant Technologies Inc. | Supplemental-restraint-system gas generating device with water-soluble polymeric binder |
US6315847B1 (en) | 1999-01-29 | 2001-11-13 | Cordant Technologies Inc. | Water-free preparation of igniter granules for waterless extrusion processes |
KR20020057578A (ko) * | 2001-01-02 | 2002-07-12 | 송재인 | 이산화탄소 카트리지 파열장치 |
US6474239B2 (en) * | 1999-12-08 | 2002-11-05 | Giat Industries | Igniter tube for artillery ammunition |
US6860208B2 (en) * | 2001-01-04 | 2005-03-01 | Trw Inc. | Nitrocellulose gas generating material for a vehicle occupant protection apparatus |
WO2005026081A1 (en) * | 2003-09-04 | 2005-03-24 | Autoliv Asp, Inc. | Low density slurry bridge mix |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3103884A (en) * | 1962-03-16 | 1963-09-17 | Thomas Q Ciccone | Cartridge for more nearly uniform projectile velocities |
US3249049A (en) * | 1964-07-31 | 1966-05-03 | Zimmerman Theodore | Ballistic primer |
US3264993A (en) * | 1965-04-22 | 1966-08-09 | Atlantic Res Corp | Combustible cartridge case composition and process |
-
1968
- 1968-05-17 FR FR152244A patent/FR1593513A/fr not_active Expired
-
1969
- 1969-04-18 CH CH586469A patent/CH506044A/fr not_active IP Right Cessation
- 1969-04-22 BE BE731847D patent/BE731847A/xx not_active IP Right Cessation
- 1969-04-30 LU LU58536D patent/LU58536A1/xx unknown
- 1969-05-05 IL IL32160A patent/IL32160A/xx unknown
- 1969-05-07 US US822413A patent/US3899973A/en not_active Expired - Lifetime
- 1969-05-14 NL NL6907406.A patent/NL163868C/xx not_active IP Right Cessation
- 1969-05-14 ES ES1969166433U patent/ES166433Y/es not_active Expired
- 1969-05-16 GB GB25207/69A patent/GB1270298A/en not_active Expired
- 1969-12-01 SE SE6906364A patent/SE407977B/xx unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3103884A (en) * | 1962-03-16 | 1963-09-17 | Thomas Q Ciccone | Cartridge for more nearly uniform projectile velocities |
US3249049A (en) * | 1964-07-31 | 1966-05-03 | Zimmerman Theodore | Ballistic primer |
US3264993A (en) * | 1965-04-22 | 1966-08-09 | Atlantic Res Corp | Combustible cartridge case composition and process |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4674405A (en) * | 1985-01-23 | 1987-06-23 | Dynamit Nobel Aktiengesellschaft | Partially combustible propellant charge igniter |
US4882994A (en) * | 1988-01-28 | 1989-11-28 | Veltman Preston Leonard | Particulate fuel components for solid propellant systems |
US5052302A (en) * | 1990-07-26 | 1991-10-01 | Olin Corporation | Unpressurized combustible primer for cannon cartridges |
WO1992001903A1 (en) * | 1990-07-26 | 1992-02-06 | Olin Corporation | Unpressurized combustible primer for cannon cartridges |
US5743559A (en) * | 1994-01-27 | 1998-04-28 | Daicel Chemical Industries, Ltd. | Inflator for air bags |
WO1996011374A1 (en) * | 1994-10-06 | 1996-04-18 | Ici Australia Operations Proprietary Limited | Explosives booster and primer |
US6112666A (en) * | 1994-10-06 | 2000-09-05 | Orica Explosives Technology Pty. Ltd. | Explosives booster and primer |
US6224099B1 (en) | 1997-07-22 | 2001-05-01 | Cordant Technologies Inc. | Supplemental-restraint-system gas generating device with water-soluble polymeric binder |
US6170399B1 (en) | 1997-08-30 | 2001-01-09 | Cordant Technologies Inc. | Flares having igniters formed from extrudable igniter compositions |
US6315847B1 (en) | 1999-01-29 | 2001-11-13 | Cordant Technologies Inc. | Water-free preparation of igniter granules for waterless extrusion processes |
US6474239B2 (en) * | 1999-12-08 | 2002-11-05 | Giat Industries | Igniter tube for artillery ammunition |
KR20020057578A (ko) * | 2001-01-02 | 2002-07-12 | 송재인 | 이산화탄소 카트리지 파열장치 |
US6860208B2 (en) * | 2001-01-04 | 2005-03-01 | Trw Inc. | Nitrocellulose gas generating material for a vehicle occupant protection apparatus |
WO2005026081A1 (en) * | 2003-09-04 | 2005-03-24 | Autoliv Asp, Inc. | Low density slurry bridge mix |
US20050067071A1 (en) * | 2003-09-04 | 2005-03-31 | Hamilton Brian K. | Low density slurry bridge mix |
US6905562B2 (en) * | 2003-09-04 | 2005-06-14 | Autoliv Asp, Inc. | Low density slurry bridge mix |
CN100379708C (zh) * | 2003-09-04 | 2008-04-09 | 奥托里夫Asp股份有限公司 | 低密度浆料桥混合物 |
Also Published As
Publication number | Publication date |
---|---|
IL32160A0 (en) | 1970-11-30 |
NL163868B (nl) | 1980-05-16 |
LU58536A1 (enrdf_load_stackoverflow) | 1969-07-29 |
GB1270298A (en) | 1972-04-12 |
ES166433Y (es) | 1972-01-01 |
IL32160A (en) | 1973-08-29 |
CH506044A (fr) | 1971-04-15 |
DE1924627A1 (de) | 1969-12-11 |
DE1924627B2 (de) | 1976-11-11 |
NL6907406A (enrdf_load_stackoverflow) | 1969-11-19 |
FR1593513A (enrdf_load_stackoverflow) | 1970-06-01 |
ES166433U (es) | 1971-08-01 |
SE407977B (sv) | 1979-04-30 |
BE731847A (enrdf_load_stackoverflow) | 1969-10-01 |
NL163868C (nl) | 1980-10-15 |
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