US3895784A - Apparatus for and method of optimum burning of carbon monoxide in a converter - Google Patents

Apparatus for and method of optimum burning of carbon monoxide in a converter Download PDF

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US3895784A
US3895784A US309018A US30901872A US3895784A US 3895784 A US3895784 A US 3895784A US 309018 A US309018 A US 309018A US 30901872 A US30901872 A US 30901872A US 3895784 A US3895784 A US 3895784A
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carbon monoxide
converter
tuyere
signal
zone
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US309018A
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William A Kolb
Jack F Sigh
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United States Steel Corp
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United States Steel Corp
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Assigned to USX CORPORATION, A CORP. OF DE reassignment USX CORPORATION, A CORP. OF DE MERGER (SEE DOCUMENT FOR DETAILS). Assignors: UNITED STATES STEEL CORPORATION (MERGED INTO)
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/30—Regulating or controlling the blowing

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  • the improved method includes the steps of:
  • the apparatus has sensing means associated with the converter for sensing the initial effectiveness signal of the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to the converter.
  • the sensing means is then operable to monitor the continuing effectiveness signal.
  • Comparison means are connected to the sensing means for comparing the continuing effectiveness signal with the initial effectiveness signal.
  • Tuyere operating means are connected to the comparison means and the side tuyere for moving the side tuyere relative to the converter and adjusting the O flow when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide.
  • FIGURE Y APPARATUS FOR AND METHOD OF OPTIMUM BURNING OF CARBON MONOXIDE IN A CONVERTER This application is a Continuation-In-Part application of U.S. Pat. application Ser. No. 295,76l filed Oct. 6, 1972 and now abondoned by applicants.
  • a. provide an improved and novel control system which can either position the side tuyere or adjust the oxygen flow rate to the side tuyere in response to a signal which is a measure of the effectiveness of the side tuyere position and the oxygen flow rate through such side tuyere;
  • the improved method includes the steps of:
  • the apparatus has sensing means associated with the converter for sensing the initial effectiveness signal of the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to the converter.
  • the sensing means is then operable to monitor the continuing effectiveness signal.
  • Comparison means are connected to the sensing means for comparing the continuing effectiveness signal with the initial effectiveness signal.
  • Tuyere operating means are connected to the comparison means and the side tuyere for moving the side tuyere relative to the converter when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dixide.
  • FIG. 1 is a vertical cross sectional veiw of a Q-BOP type converter or vessel rotatable about a horizontal axis A-A defined by the trunnions and provided with a plurality of bottom tuyeres and the improved side tuyeres of the present invention;
  • FIG. 2 is an enlarged fragmentary vertical sectional view and showing the right hand side tuyere of FIG. I mounted in a clearance cavity within the shell and refractory lining of the converter, the ball and socket type mounting of the side tuyere on the converter shell, a manually operating turnbuckle arrangement for rotating or moving the side tuyere relative to the converter by hand, and an improved automatic tuyere operating means connected to the side tuyere and including a tuyere vertical operating means, a tuyere horizontal operating means, and a tuyere transverse operation means;
  • FIG. 3 is a vertical sectional diagrammatic view of a converter and an associated gas collecting hood and showing a preferred embodiment of a sensing means having a carbon monoxide probe inserted through the side wall of the converter adjacent the carbon monox' ide zone for sampling the carbon monoxide content adjacent such carbon monoxide zone and for producing a signal output to the improved control device of the present invention;
  • FIG. 4 is a diagrammatic wiring diagram of the control means or device of the present invention for receiving the initial effectiveness signal and the continuing effectiveness signal from the sensing means of FIG. 3, and for programming the movement of the side tuyere and the control of the oxygen flow rate to such side tuyere depending on whether the continuing effective- 3 ness signal is greater than ofrless thanan initial effectiveness signal;
  • FIG. 5 is a time chart showing the' operation at timed preselected time periods of the contacts of a timer associated with the control device for timing the operation of such control device during a single cycle of the operation of the control device;
  • FIG. 6 is a view similar to FIG. 3 of an alternative embodiment of the sensing means showing the carbon monoxide probe inserted through the gas collecting hood in the form of a lance having its sampling end adjacent the carbon monoxide zone within the converter;
  • FIG. 7 is a view similar to FIGS. 3 and 6 of another alternative embodiment of the sensing means showing a carbon monoxide probe arrangement disposed at a predetermined point within the hood and having an ox- .ygen analyzer and nitrogen analyzer for sensing the ratio oxygen to nitrogen at the predetermined probe point to indicate the amount of oxygen burned within the gascollecting hood from the air admitted between the converter and the gas collecting hood and hence the amount of carbon monoxide burned to carbon dioxide in the gas collecting hood prior to the predeter- .another alternative embodiment of the sensing means .having a-temperature probe disposed in the gas collect- ,mg hood above the jointure of such gas collecting hood and the mouth of the converter for sensing the temperature of the off gases within the gas collecting hood and for comparing the continuing effectiveness temperature signal with a programmed initial temperature set point and a programmed constant slope type standard circuit devisedto produce an output signal which is inversely proportional to the temperature sensed within the hood; and
  • FIG. 9 is a vertical sectional view of a bottom blown oxygen converter showing a submerged bottom tuyere, a side submerged tuyere, a pair of side tuyeres directed toward the carbon monoxide zone of the furnace and a pair of mouth tuyeres;
  • FIG. 10 is a vertical sectional view of an electric-arc steelmaking furnace showing a bottom vertical submerged tuyere, a submerged side tuyere, a side tuyere directed toward the carbon monoxide zone of the furnace and a mouth tuyere for the discharge spout;
  • FIG. 11 is a vertical sectional view of an open hearth furnace utilizing a vertical submerged tuyere, a side submerged tuyere, another side tuyere directed toward the carbon monoxide zone of the furnace, and a mouth tuyere for the discharge spout;
  • FIG. 12 is a vertical sectional view of a tiltable open hearth furnace having a vertical bottom submerged tuyere, a side submerged tuyere, side tuyere directed toward the carbon monoxide zone of the furnace and a mouth tuyere for the discharge spout;
  • FIG. 13 is a vertical sectional view of oscillatable hot metal mixer having a vertical bottom submerged tuyere, a pair of side submerged tuyeres, a side tuyere directed toward the carbon monoxide zone of the mixer and a mouth tuyere for the discharge spout.
  • this invention is particularly adapted for use in conjunction with a 0-80? converter and hence it has been so illustrated and will be so described.
  • a Q-BOP converter or vessel is indicated generally by the reference numeral 10.
  • this converter 10 has a metallic shell 12, a refractory brick lining 14, a mouth 16, and a bottom plug 18 containing a plurality of bottom tuyeres 20 surrounded by a plurality of concentric shroud gases pipes 22.
  • Such bottom tuyeres 20 (FIG. '1) are fed a supply of oxygen or oxygen bearing gas from "a source indicated by the legend FROM OXYGEN SUPPLY" and the shroud gas pipes 22 are fed a shroud fluid, such as propane or the like, through a T-co'nnectiori 24' (FIG. 1), extending to a shroud gas supply indicated by the legend FROM SHROUD GAS SUPPLY.
  • Such converter 10 is rotatable on trunnions 26 1) about a horizontal axis indicated by the cente rline AA and is adapted during the refining process to contain a molten metal bath 28 (FIGS. 1, 3, 6, 7,8) covered by a slag layer 30.
  • N molten metal bath 28
  • the improved side tuyeres 32 (FIGS. 1-3, 6-8) which form a part of the improved apparatus for optimum burning of carbon monoxide produced .in a carbon monoxide zone Z (FIGS. 1, 3, 6-8) to carbon dioxide thereby producing a substantially maximum amount of heat within the converter 10 to melt scrap metal (not shown) in the converter 10.
  • each side tuyere 32 is mounted to project through a clearance hole 36 (FIGS. 1, 2) in the shell 12 and refractory brick lining 14.
  • a mounting flange 38 projects from the shell 12 and carries an annular seat 40 (FIGS. 1, 2) engageable with a ball 42 (FIGS. 1, 2) and mounted on a flange 44 upstanding from a side tuyere shroud pipe 46 '(FIGS. 1, 2).
  • a T-connection 50 ('FIGS. 1, 2) is connected to a shroud gas supply indicatedby the legend FROM SHROUD GAS SUPPLY.
  • The-means utilized to provide oxygen to the side 't'uiyereoxygen pipe 46 comprises an oxygen supply pipe 52 (-FIGS. 1, 2) and an elbow 54 (FIGS. 1, 2) connecting such oxygen supply pipe 52 to the side tuyere oxygen pipe 48.
  • tuyere operating means 56 are provided for moving each side tuyere 32 vertically, horizontally, or transversely with respect to the converter 10.
  • the tuyere operating means 56 has a tuyere vertical operating means 58, suitably an electric motor 60 of the type SMO manufactured by Raco Machine Company of Bethel Park, Pennsylvania.
  • This electric motor 60 has its piston rod 62 (FIGS. 1, 2, 4) pivotably connected to a bracket 64 projecting from the underside of the side tuyere shroud pipe 46 and is operable in response to a control device 66 shown in FIG. 4 to oscillate each side tuyere 32 a predetermined amount up or down in a vertical plane by means of its ball and seat connecting 42, 44 (FIGS. 1, 2) to the converter to achieve maximum heat from the conversion of the carbon monoxide in the carbon monoxide zone Z to carbon dioxide.
  • the tuyere operating means 56 has a tuyere horizontal operating means 68 (FIGS. 1, 2, 4) having an electric motor 60a similar to the electric motor 60.
  • the electric motor 60a has its piston rod 62a pivotably secured by means of a bracket 64a to the supply pipe 52.
  • the electric motor 600 is mounted on slide guides 70 (FIG. 2) secured on the bottom of the electrical motor 60a.
  • a tuyere transverse operating means 72 (FIGS. 1, 2, 4) has another electric motor 60b with its piston rod 62b connected at its free end to a bracket 64b projecting from the elbow 54 of the side tuyere 32 so that in response to a signal from the control device 66 shown in FIG. 7, the tuyere transverse operating means 72 may move each side tuyere 32 transversely in and out in a plane with respect to the converter 10.
  • the tuyere transverse operating means shown in FIGS. 1, 2, and 4 has the electric motor 60b also mounted on a slide guide 70 to permit the horizontal reciprocable movement of the side tuyere 32 in a plane with respect to the converter 10.
  • a sensing means 74 is associated with the converter 10 for sensing an initial effectiveness signal E, (FIG. 4) of the amount of carbon monoxide in the carbon monoxide zone Z being burned to car bon dioxide at a predetermined point such as the point P (FIG. 3).
  • SENSING MEANS 74 As shown in FIG. 3, adjacent the mouth 16 of the converter 10, ambient air is admitted through an opening 76 between the mouth 16 of the converter 10 and a gas collecting hood 78.
  • the sensing means 74 has a probe 80 which projects from the point Pin the side wall of the converter 10 for sensing the amount of carbon monoxide adjacent the carbon monoxide zone Z being burned to carbon dioxide above the carbon monoxide zone C at the predetermined probe point P
  • the probe80 and gas sample preparation system may be of the type manufactured by Bailey Meter Company of Cleveland, Ohio, and transmits a gas sample by means of line C1 (FIG. 3) to a carbon monoxide analyzer 82 of the type LIRA 200 manufactured by Mine Safety Appliances Company of Pittsburgh, Pennsylvania.
  • This carbon monoxide 82 produces an output signal which is directly proportional to the amount of unburned carbon monoxide above the carbon monoxide zone Z at the predetermined probe point P and hence inversely proportional to the carbon monoxide being burned to carbon dioxide in the carbon monoxide zone Z
  • output signals from analyzer 82 are conducted by means of line L1 (FIGS. 3 and 4) to the control device 66 shown in FIG. 4 labeled Incoming Signal provide the initial effectiveness signal E,-(FIG. 4) and the continuing effectiveness signal E, (FIG. 4) which is compared to the initial effectiveness signal E, in the control device 66.
  • the effectiveness signal increases in magnitude, it indicates that less scrap melting is occurring.
  • This control device 66 (FIG. 4) has a timer 88 of the type" I-IL manufactured by Eagle Signal of Davenport,
  • the timer 88 is energized thereby closing (as shown in FIG. 5) for the period of time T,T,,, a normally open timer contact 88a in branch line Lla (FIG. 4).
  • the initial effectiveness signal E coming from the sensing means 74 (FIG. 3) is stored in a capacitor 90 in branch line LIA.
  • timer contact 88a opens and the stored initial effectiveness signal E, continues to be applied to one input terminal E of a differential amplifier 92a of type P65A manufactured by Teledyne-Philbrick of Dedham, Massachusetts. Thereafter, the continuing effectiveness signal E,. from the sensing means 74 (FIG.
  • a booster potentiometer 96a (FIG. 4, connected by line L3 to a battery 98a) has its output fed to an input terminal E (FIG. 4) of the differential amplifier 92b so that the output signal from output E of the differential amplifier 92b is fed via line L2 (FIG. 4) through a now closed timer contact 88b (during the period T T FIG. 5) and such output signal from output E of amplifier 92b is fed through a blocking diode 94b (FIG. 4) to a solenoid coil 100 of a drive mechanism 102 for a program means, such as the programmer 104 or of the type Model 250 manufactured by the Tenor Company of Milwaukee, Wisconsin.
  • a program means such as the programmer 104 or of the type Model 250 manufactured by the Tenor Company of Milwaukee, Wisconsin.
  • DRIVE MEANS 102 Upon energization of the solenoid coil 100, a rack 106 (FIG. 4) is moved against the action of a biasing spring 108 away from the biasing spring 108 to index a pinion 110 on a shaft 112 a predetermined angular distance.
  • the shaft 112 also carries a program drum 114 (FIG. 4).
  • PROGRAMMER 104 The program associated with the programmer 104 is applied to the program drum 114 by means of program pins 116( FIG. 4) which actuate in turn a plurality of program switches l18a-1 181'.
  • the timer 88 causes the timer contact 880 (FIG. 4) to close so that voltage from battery 980 is applied via lines L L L to, for example, the tuyerevertical operating means 58 (i.e., the electric motor 60) so that during such time period T -T (FIG.
  • the tuyere transverse operating means 72 i.e., the electric motor 60b
  • the tuyere transverse operating means 72 would, for example, be energized through lines L L L to move the side tuyere 32 in or out from the plane of FIG. 4 a predetermined amount to again attempt to adjust the position of the side tuyere 32 to obtain an increased amount of carbon monoxide in the carbon monoxide Zone Z being burned to carbon dioxide.
  • program switches 118e, ll8f are closed by the associated program pins 116 thereby energizing the horizontal tuyere operating means 68 (i.e., the electric motor 60a via lines L L L during the time period T T FIG. 5) the electric motor 600 moves the side tuyere 32 either in or out a predetermined amount with respect to the side wall of the converter l0.
  • Flow control means such as a control valve 124 (FIG. 4) of the type Mark I manufactured by Valtek of Provo, Utah, is disposed in the supply line 52 for controlling the flow of the oxygen or oxygen bearing gas through the supply line 52.
  • Flow sensing means such as a different pressure transmitter 126 (FIG. 4) of the type E13DI-I manufactured by The Foxboro Company of Foxboro, Massachusetts, is associated with an orifice 129 (FIG. 4) in the supply line 52 and transmits its output signal to an input terminal E of a differential amplifier 920.
  • a variable potentiometer 128 (FIG.
  • variable set point signal from the variable potentiometer 128 is fed to the input E of the differential amplifier 92c, which amplifier 920 has its output E connected to the control valve 124.
  • the electric motor is operable to increase the voltage signal of the variable potentiometer 128 so that the output signal from output E of the differential amplifier 92c opens the vcontrol valve 124 thereby increasing the flow of oxygen through the oxygen supply line 52 to the side tuyere 32.
  • the output E will be negative and the blocking diode 94a in line L2 (FIG. 4) will prevent the passage of the output signal from output E of the differential amplifier 92a through line L2 to the differential amplifier 92b, in the first control loop 93, and the blocking diode 94c in line L6 (FIG. 4) will admit such output signal from output E of differential amplifier 92a through a second oxygen control loop 132 via line L6 toinput terminal E of differential amplifier 94d.
  • the blocking diode 94c will, of course, refuse any signal form output E,,,, of amplifier 92a when the continuing effectiveness signal E is greater than the initial effectiveness signal E, during the monitoring period T7-T1 (FIG. 1).
  • a booster potentiometer 96b (FIG. 4) fed from battery 98b by line L4 provides a booster voltage to input terminal E of the differential amplifier 94d so that the output from output E of the differential amplifier 92d is fed through blocking diode 94d (FIG. 4, when the timer 88 closes the timer contact 8812, FIG. 5, during the period T9-T8, FIG. 5) thereby energizing a relay 134 in line L6 (FIG. 4).
  • Energization of the relay 134 causes closure of normally open relay contact 134a (FIG.
  • the sensing means 74 has its probe 80 affixed to a lance 136 depending from point P6 in the wall of the gascollecting hood 78 to the predeterminedprobe point P above the carbon monoxide zone Z
  • Such probe 80 is connected by the line C1 to the carbon monoxide analyzer 82.
  • the output, signal from the analyzer82 is carried, as before, by-the' line L1 to the control device 66 of FIG. 4.
  • the predetermined point P 'at whichthe probe 80 senses the carbon-monoxide content? is above the carbon monoxide zone'Z within the converter 10.
  • the probe 80 extends from a point P7 within the gas collecting hood 78 to the predetermined probe point P of the probe located a considerable distance above the opening 76 between the mouth 16 of the converter 10 and the bottom of the gas collecting hood 78.
  • the gas sample is fed by conduit C1 to a sensing means 74 including the carbon moxoxide analyzer 82, with the output of analyzer 82 being fed via line L8 to input E of differential amplifier 92e.
  • the gaseous sample is fed by the line C1 to both an oxygen analyzer 138 of the type 7803 manufactured by Leeds & Northrup of North Wales, Pennsylvania, and a nitrogen analyzer 140 of the chromatograph type manufactured by Benoix-Greenbriar of Ronceverte, West Virginia.
  • the ratio of oxygen to nitrogen at the predetermined point P indicates the amount of oxygen which has been burned in the gas collecting hood 78 prior to the predetermined probe point P
  • the output signals from the analyzers 138 and 140 are fed through respective calibrating potentiometers 142, 144 (FIG. 7) to inputs E and E respectively of a differential amplifier 92f so that the output signal from output E of such differential amplifier 92f is fed to input E of differential amplifier 92e thus calibrating the other input signal from the carbon monoxide analyzer 82 at input E of differential amplifier 922 and thereby providing from output E of amplifier 92e the initial and calibrated effectiveness signals E E via line L1 to the control device 66 (FIG. 4).
  • a temperature probe 80 enters the hood 78 at P8 and measures the temperature of the gases in the hood at the predetermined point P
  • Line L9 carries the temperature signal to one input E of differential amplifier 92g.
  • an initial temperature signal potentiometer 150 feeds through line L10 and a manually operated starting switch 148 to input E of differential amplifier 92h.
  • Branch line L11 carries such signal also through capacitor 151 and a normal rate or slope potentiometer 152,
  • the output signal form output E of amplifier 92g is fed through line L1 and blocking diode 942 which allows only positive signals to be applied to the control device 66.
  • the temperature probe 80 of FIG. 8 may be either located at the point P of FIG. 3 or disposed at P on the lance 136 of FIG. 6 or disposed at the predetermined point P of FIG. 7.
  • side tuyere 32 may be rotated manually by means of turnbuckles 156.
  • selector switch 158 may be installed in lines L2, L6 to operate the loops 93, 132, either independently of each other or together.
  • a bottom blown converter 210 having a bottom submerged tuyere 212, a side submerged tuyere 214, and a pair of side tuyeres 216 directed toward the carbon monoxide zone (CO zone).
  • This bottom blown converter 210 has a shell 218 provided with a refractory lining 220 and a mouth 222 and is rotatable on trunnions 224.
  • the tuyeres 212, 214, 216 are provided with a high temperature refractory protective covering 225 and are adapted to carry in an inner pipe either a fluid alone, such as oxygen, air, argon, or mixtures thereof, or entrained pulverized additives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (fluorspar (CaF or the like), or a blocking or deoxidizing agent (ferro manganese or the like), and in an outer pipe 215 a shroud gas, such as propane, natural gas, light fuel oil or the like.
  • a fluxing agent burned lime (CaO) or the like
  • fluorspar fluorspar
  • ferro manganese or the like a blocking or deoxidizing agent
  • the present invention is also applicable to a I-IEROULT Type electric-arc steelmaking furnace 210a provided with a bottom submerged tuyere 212a, a side submerged tuyere 214a, and a side tuyere 216a directed toward the carbon monoxide zone (CO zone) of the furnace 210a.
  • This electric-arc steelmaking furnace 210a has a shell 218a provided with a refractory lining 220a, a side door 226, a refractory roof 228 provided with electrode holes 230, a tap hole 232, and a pouring spout 234 extending from the tap hole 232.
  • the tuyeres 212, 214a are provided with a high temperature refractory protective covering 225 and are adapted to carry in an inner pipe 213 either a fluid alone, such as oxygen, air, argon, or mixtures thereof, or entrained pulverized additives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (fluorspar (CaF or the like), or a blocking or deoxidizing agent (ferro manganese or the like), and in an outer pipe 215, a shroud gas, such as propane, natural gas, light fuel oil or the like.
  • a fluxing agent burned lime (CaO) or the like
  • fluorspar fluorspar
  • ferro manganese or the like a blocking or deoxidizing agent
  • the present invention may be employed as shown in FIG. 11 with the open hearth furnace 21% having a bottom submerged tuyere 212b, a side submerged tuyere 214b, and a side tuyere 216b directed toward the carbon monoxide zone (CO zone) of the furnace 21012.
  • This open hearth furnace 21% includes a refractory lined bottom 236, a refractory lined sloping back wall 238, a refractory lined front wall 240, a charging door 242 in the wall 240, and a refractory lined roof 244.
  • a tap hole 232b opposite the charging door 242 leads to a pouring spout 234b.
  • the tuyeres 212b, 214b are provided with a high temperature refractory protective covering 225 and are adapted to carry in an inner pipe 213 either a fluid alone, such as oxygen, air, argon, or mixtures thereof, or entrained pulverized additives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (fluorspar (CaF or the like), or a blocking or deoxidizing agent (ferro manganese or the like) and in an outer pipe 215, a shroud gas, such'as gas, light fuel oil or the like.
  • a fluxing agent burneded lime (CaO) or the like
  • fluorspar fluorspar
  • fluoro manganese or the like a blocking or deoxidizing agent
  • the present invention may be employed with a tilting open hearth furnace 2100 mounted on rollers 246 arranged in a circular path for providing rotation onthe longitudinal axis of the furnace 210C for pouringythe refined steel through a tap hole 232C and a pouring spout 2340.
  • the tiltable openhea rth furnace 2106 has a bottom submerged tuyere 212C extending through a box 248.
  • a submerged side tuyere 214C and a side tuyere 2160 directed toward the carbon monoxide zone (CO zone) of the furnace 210C are employed.
  • the tilt able open hearth furnace 2106 has a refractory lined bottom 236C, refractory lined back Wall 2380, refractory lined front wall 240( (provided with a charging door "242c) and a refractory lined roof 244C.
  • the tuyeres 2 12c, 2l4c,ar e provided with a high temperature refractory covering 225 and are adapted to carry in an inner pipe 213 either a fluid alone, such as oxygen, air,
  • a fluxing agent burned lime (CaO) or the like
  • fluorspar fluorspar
  • fluoro manganese or the like a blocking or'deoxidizing agent
  • the present invention is employed with a hot metal mixer 210d having a shell 218d provided with a refractory lining 220d, and having also an inlet mouth 222d and a pouring spout 234d.
  • the mixer 210d is osditives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (flurospar (CaF or thelike), or a blocking or deoxidizing agent (ferro manganese or the like), and in an outer pipe 215,, a shroud gas, such as propane, natural gas, light fuel oil orthe like.
  • a discharge tuyere or tuyeres 32 (FIGS. 9, l0, ll,
  • .12, 13 is disposed adjacent a discharge opening, such as the mouth 22 (FIG. 9); the pouring spouts 234 (FIG. 10), 2341; (FIG. 11), 2340 (FIG. 12), and 234d (FIG. 13) to prevent the formation of skulls adjacent or on the discharge opening during the pouring operation particularly those chromium-nickel skulls produced during the refining of stainless steel.
  • the improved method also includes the step of: 1
  • 66 (FIG. 4) which can either position a side tuyere 32 or adjust the oxygen flow rate to the side tuyere 32. in response to a signal which is a measure of the effectiveness of the side tuyere position and the oxygen flo rate through such side tuyere 32;
  • sensing means associated with said converter for sensing an initial effectiveness signal of the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal;
  • comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal
  • tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in a horizontal and a vertical direction in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
  • said carbon monoxide sensing means senses the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide above said carbon monoxide zone at said predetermined point.
  • said carbon monoxide sensing means is disposed in said gas collecting hood.
  • said temperature sensing means disposed in said gas collecting hood.
  • said tuyere operating means moves said side tuyere transversely relative to said converter.
  • said tuyere operating means has a tuyere transverse operating means connected to said program means and said side tuyere;
  • said program means is operable to actuate said tuyere vertical operating means and said tuyere transverse operating means in a predetermined order.
  • timing means associated with said sensing means and said comparison means for causing the timed storage of said initial effectiveness signal.
  • timing means connected between said comparison means and said tuyere operating means for causing timed actuation of said tuyere operating means.
  • timer means connected between said program means and said tuyere operating means for the timed actuation of said program means.
  • said ap- 5 paratus is a bottom blown converter.
  • tuyere is a tuyere disposed adjacent a discharge opening of said apparatus to prevent formation of skulls adjacent said discharge opening during pouring of said molten metal.
  • sensing means associated with said converter for sensing an initial effectiveness signal of the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal;
  • comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal
  • flow control means in said supply line for controlling the flow of oxygen through said supply line
  • flow sensing means in said supply line for sensing the flow of oxygen through said supply line and for producing a flow signal
  • standard flow signal producing means for producing a standard flow signal, connected to said comparison means and operable by said comparison means
  • flow comparison means for receiving said flow signal and said standard flow signal, connected to said flow control means and adapted to position said flow control means in response to a flow output signal from said flow comparison means;
  • tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in biaxial directions in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
  • said standard flow signal producing means is operable by said comparison means when said continuing effectiveness signal is greater than said initial effectiveness signal to increase said standard flow signal, thereby increasing the flow of oxygen to said supply line.
  • timing means disposed between said standard flow signal producing means and said comparison means for causing-the timedactuation of said standard flow signal Lproducing rne'ans.
  • program means disposed between saidstandard flow signal producing ,;means and said comparison means toprogram any increase in said flow of oxygen to said side tuyere.
  • sensing -means associated with said converter for sensing an initial effective'ness signal of the amount of carbon monoxide in said carbon-'mbnixide zone beingbu'rned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal;
  • comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal
  • relay means connected to said comparison means and operable when said continuing effectiveness signal is less than said initial effectiveness signal to position said standard flow signal producing means to decrease said standard flow signal thereby decreasing the flow of oxygen to said supply line and thus conserving oxygen;
  • tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in biaxial directions in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
  • sensing means associated with said converter for sensing an initialeffectiveness signal of the amount of carbon monoxide in said carbon monoxide, zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means f being operable to monitor a continuing effective ness signal;
  • comparison means connected tolsaid sensingmearis" for comparing said continuing effectiveness signalf with said initial effectiveness signal; and tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in a transverse and a vertical direction in a predetermined order relative to said converter whensaid continuing effective ness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.

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Abstract

An improved apparatus for and method of optimum burning of carbon monoxide in a carbon monoxide zone (being fed oxygen by a side tuyere) above a molten metal bath in a converter to carbon dioxide is disclosed. The improved method includes the steps of: A. SENSING AN INITIAL EFFECTIVENESS SIGNAL OF THE AMOUNT OF CARBON MONOXIDE IN THE CARBON MONOXIDE ZONE BEING BURNED TO CARBON DIOXIDE AT A PREDETERMINED POINT RELATIVE TO THE CONVERTER; B. MONITORING A CONTINUING EFFECTIVENESS SIGNAL; C. COMPARING THE CONTINUING EFFECTIVENESS SIGNAL WITH THE INITIAL EFFECTIVENESS SIGNAL; AND D. MOVING THE SIDE TUYERE RELATIVE TO THE CONVERTER AND ADJUSTING O2 flow when all possible side tuyere positions are exhausted when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide. The apparatus has sensing means associated with the converter for sensing the initial effectiveness signal of the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to the converter. The sensing means is then operable to monitor the continuing effectiveness signal. Comparison means are connected to the sensing means for comparing the continuing effectiveness signal with the initial effectiveness signal. Tuyere operating means are connected to the comparison means and the side tuyere for moving the side tuyere relative to the converter and adjusting the O2 flow when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide.

Description

United States Patent [191 Kolb et al.
Borough; Jack F. Sigh, Crafton Borough, both of Pa.
[73] Assignee: United States Steel Corporation, Pittsburgh, Pa.
[22] Filed: Nov. 24, 1972 [21] Appl. No.: 309,018
Related US. Application Data [63] Continuation-in-part of Ser. No. 295,761, Oct. 6,
1972, abandoned,
[52] US. Cl 266/35; 266/41 [51] Int. Cl. C2lc 5/46 [58] Field of Search... 75/52, 53; 266/34 T, 35,
[56] References Cited UNITED STATES PATENTS 33,090 8/1861 Lane 266/35 327,425 9/1885 Witherow 266/40 405,766 6/1889 Bookwalter.... 266/35 411,417 9/1889 Bookwalter.... 266/35 423,612 3/1890 Ludlow 266/35 707,776 8/1902 l-leroult 266/35 2,883,279 4/1959 Graef et al. 266/34 T X 3,034,887 5/1962 Henne 266/35 X 3,372.023 3/1968 Krainer et al.. 266/35 X 3,598,386 8/1971 Murphy 266/35 FOREIGN PATENTS OR APPLICATIONS 4,920 12/1877 United Kingdom 266/35 1,235,497 5/1960 France 266/35 Primary ExaminerGerald A. Dost Attorney, Agent, or FirmDavid S. Urey [451 July 22, 1975 [57] ABSTRACT An improved apparatus for and method of optimum burning of carbon monoxide in a carbon monoxide zone (being fed oxygen by a side tuyere) above a molten metal bath in a converter to carbon dioxide is disclosed.
The improved method includes the steps of:
a. sensing an initial effectiveness signal of the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to the converter;
b. monitoring a continuing effectiveness signal;
c. comparing the continuing effectiveness signal 1 with the initial effectiveness signal; and
(1. moving the side tuyere relative to the converter and adjusting 0,, flow when all possible side tuyere positions are exhausted when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide.
The apparatus has sensing means associated with the converter for sensing the initial effectiveness signal of the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to the converter. The sensing means is then operable to monitor the continuing effectiveness signal. Comparison means are connected to the sensing means for comparing the continuing effectiveness signal with the initial effectiveness signal. Tuyere operating means are connected to the comparison means and the side tuyere for moving the side tuyere relative to the converter and adjusting the O flow when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide.
, 22 Claims, 13 Drawing Figures From Shrnu d Gas Supply PATENTEDJUL22I975 I I 3 957 4 SHEET I 2 FROM 'oxras/v SUPPLY L58 L5f From Shroud Gas Supply L415!) 56 5415a P "-60 jw FUNCTION OF con/mars CONTACTS TIMER CYCLE 01v CLOCK SAMPLE INCOM/IVG SIGNAL I..
| MONITOR/N6 INCOM/NG SIGNALS I I I I STEP PROGRAMMER 880 I ALLOW POSITIONERS, 60, 888 I g 50a, 60b TO MOVE TUYERES I I I I I I INCREASE FLOW 0F 0 880' I I OPERATE RELAY 134 70 ag I REDUCE FLOW 0F 0 I I I I I I I I 1 l I I a r r |r |r lr Time (8205.) Start Next Cycle PATENTEDJUL 22 m5 SHEET m 3:9 mQM RATENTEDJUL22 1915 13,895,784
C0 ZONE (A) FROM LINE 20 FIGURE 1 (3/ FROM LINE 22 FIGURE PHENTEBJULZZ I975 3 I 8 95 784 FIG. 1/.
242 C0 ZONE HEAkTH Ll/wg 0 f m) [51 /2 L5) L5e L (A) FROM LIA/E 20 FIGURE (8} FROM LINE 2.?
FIGURE Y APPARATUS FOR AND METHOD OF OPTIMUM BURNING OF CARBON MONOXIDE IN A CONVERTER This application is a Continuation-In-Part application of U.S. Pat. application Ser. No. 295,76l filed Oct. 6, 1972 and now abondoned by applicants.
BACKGROUND OF THE INVENTION Heretofore, conventional Q-BOP vessels or converters have been provided with side jet lances or side tuyeres. However, none of the conventional converters have been provided with a control system which can either position the side lances or adjust the oxygen flow rate to such side lances in response to a signal which is a measure of the effectiveness of the burning of the carbon monoxide generated by the process in the carbon monoxide zone above the molten metal bath in the converter. Such an automatic control system is desirable to permit the maximum scrap usage in the converter by the utilization of substantially all available heat generated in the carbon monoxide zone by the Q-BOP refining process and utilizing such maximum available heat for scrap melting.
OBJECTS OF THE INVENTION It is the general object of this invention to avoid and overcome the foregoing and other difficulties of and objections to prior art practices by the provision of an improved apparatus for and method of optimum burning of carbon monoxide within a converter to produce a substantially maximum amount of heat to melt as much scrap as possible in the converter. This improved apparatus and method:
a. provide an improved and novel control system which can either position the side tuyere or adjust the oxygen flow rate to the side tuyere in response to a signal which is a measure of the effectiveness of the side tuyere position and the oxygen flow rate through such side tuyere;
b. provide a substantially maximum amount of heat generated in the carbon monoxide zone above the mo]- ten metal bath in the vessel to permit maximum scrap usage in the refining process;
c. utilize all available heat from the refining process and the burning of the carbon monoxide in the carbon monoxide zone for scrap melting;
d. continuously monitor either the carbon monoxide content at a predetermined point relative to the converter or the temperature of the off gases above the carbon monoxide zone at such predetermined point against an initial effectiveness signal; and
e. time the operation of the initial effectiveness signal, the monitored continuing effectiveness signal, the comparison therebetween, the movement of the side tuyere relative to the converter and the change in the oxygen supply to the side tuyere as a programmed cycle.
SUMMARY OF THE INVENTION The aforesaid objects of this invention and other objects which wil become apparent as the description proceeds are achieved by providing an improved apparatus for and method of optimum burning of carbon monoxide to carbon dioxide in a carbon monoxide zone within the converter.
The improved method includes the steps of:
a. sensing an initial effectiveness signal of the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to the converter;
b, monitoring a continuing effectiveness signal;
c. comparing the continuing effectiveness signal with the initial effectiveness signal; and
d. moving the said tuyere relative to the converter when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide.
The apparatus has sensing means associated with the converter for sensing the initial effectiveness signal of the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to the converter. The sensing means is then operable to monitor the continuing effectiveness signal. Comparison means are connected to the sensing means for comparing the continuing effectiveness signal with the initial effectiveness signal. Tuyere operating means are connected to the comparison means and the side tuyere for moving the side tuyere relative to the converter when the continuing effectiveness signal is greater than the initial effectiveness signal to increase the amount of carbon monoxide in the carbon monoxide zone being burned to carbon dixide.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS For a better understanding of this invention, reference should be had to the accompanying drawings wherein like numerals of reference indicate similar parts throughout the several views and wherein:
FIG. 1 is a vertical cross sectional veiw of a Q-BOP type converter or vessel rotatable about a horizontal axis A-A defined by the trunnions and provided with a plurality of bottom tuyeres and the improved side tuyeres of the present invention;
FIG. 2 is an enlarged fragmentary vertical sectional view and showing the right hand side tuyere of FIG. I mounted in a clearance cavity within the shell and refractory lining of the converter, the ball and socket type mounting of the side tuyere on the converter shell, a manually operating turnbuckle arrangement for rotating or moving the side tuyere relative to the converter by hand, and an improved automatic tuyere operating means connected to the side tuyere and including a tuyere vertical operating means, a tuyere horizontal operating means, and a tuyere transverse operation means;
FIG. 3 is a vertical sectional diagrammatic view of a converter and an associated gas collecting hood and showing a preferred embodiment of a sensing means having a carbon monoxide probe inserted through the side wall of the converter adjacent the carbon monox' ide zone for sampling the carbon monoxide content adjacent such carbon monoxide zone and for producing a signal output to the improved control device of the present invention;
FIG. 4 is a diagrammatic wiring diagram of the control means or device of the present invention for receiving the initial effectiveness signal and the continuing effectiveness signal from the sensing means of FIG. 3, and for programming the movement of the side tuyere and the control of the oxygen flow rate to such side tuyere depending on whether the continuing effective- 3 ness signal is greater than ofrless thanan initial effectiveness signal; I
FIG. 5 is a time chart showing the' operation at timed preselected time periods of the contacts of a timer associated with the control device for timing the operation of such control device during a single cycle of the operation of the control device;
FIG. 6 is a view similar to FIG. 3 of an alternative embodiment of the sensing means showing the carbon monoxide probe inserted through the gas collecting hood in the form of a lance having its sampling end adjacent the carbon monoxide zone within the converter;
FIG. 7 is a view similar to FIGS. 3 and 6 of another alternative embodiment of the sensing means showing a carbon monoxide probe arrangement disposed at a predetermined point within the hood and having an ox- .ygen analyzer and nitrogen analyzer for sensing the ratio oxygen to nitrogen at the predetermined probe point to indicate the amount of oxygen burned within the gascollecting hood from the air admitted between the converter and the gas collecting hood and hence the amount of carbon monoxide burned to carbon dioxide in the gas collecting hood prior to the predeter- .another alternative embodiment of the sensing means .having a-temperature probe disposed in the gas collect- ,mg hood above the jointure of such gas collecting hood and the mouth of the converter for sensing the temperature of the off gases within the gas collecting hood and for comparing the continuing effectiveness temperature signal with a programmed initial temperature set point and a programmed constant slope type standard circuit devisedto produce an output signal which is inversely proportional to the temperature sensed within the hood; and
FIG. 9 is a vertical sectional view of a bottom blown oxygen converter showing a submerged bottom tuyere, a side submerged tuyere, a pair of side tuyeres directed toward the carbon monoxide zone of the furnace and a pair of mouth tuyeres;
FIG. 10 is a vertical sectional view of an electric-arc steelmaking furnace showing a bottom vertical submerged tuyere, a submerged side tuyere, a side tuyere directed toward the carbon monoxide zone of the furnace and a mouth tuyere for the discharge spout;
FIG. 11 is a vertical sectional view of an open hearth furnace utilizing a vertical submerged tuyere, a side submerged tuyere, another side tuyere directed toward the carbon monoxide zone of the furnace, and a mouth tuyere for the discharge spout;
FIG. 12 is a vertical sectional view of a tiltable open hearth furnace having a vertical bottom submerged tuyere, a side submerged tuyere, side tuyere directed toward the carbon monoxide zone of the furnace and a mouth tuyere for the discharge spout; and
FIG. 13 is a vertical sectional view of oscillatable hot metal mixer having a vertical bottom submerged tuyere, a pair of side submerged tuyeres, a side tuyere directed toward the carbon monoxide zone of the mixer and a mouth tuyere for the discharge spout.
Although the principles of this invention are broadly applicable to the control of the position of a side tuyere with respect to a converter and the control of a gaseous flow rate'to; such side tuyere, this invention is particularly adapted for use in conjunction with a 0-80? converter and hence it has been so illustrated and will be so described.
DETAILED DESCRIPTION With specific reference to the form of this invention illustrated in the drawings and referring particularly to FIG. 1, a Q-BOP converter or vessel is indicated generally by the reference numeral 10.
CONVERTER 10 As shown in FIG. 1, this converter 10 has a metallic shell 12, a refractory brick lining 14, a mouth 16, and a bottom plug 18 containing a plurality of bottom tuyeres 20 surrounded by a plurality of concentric shroud gases pipes 22. Such bottom tuyeres 20 (FIG. '1) are fed a supply of oxygen or oxygen bearing gas from "a source indicated by the legend FROM OXYGEN SUPPLY" and the shroud gas pipes 22 are fed a shroud fluid, such as propane or the like, through a T-co'nnectiori 24' (FIG. 1), extending to a shroud gas supply indicated by the legend FROM SHROUD GAS SUPPLY.
Such converter 10 is rotatable on trunnions 26 1) about a horizontal axis indicated by the cente rline AA and is adapted during the refining process to contain a molten metal bath 28 (FIGS. 1, 3, 6, 7,8) covered by a slag layer 30. N
Mounted in the side walls of the converter IO are the improved side tuyeres 32 (FIGS. 1-3, 6-8) which form a part of the improved apparatus for optimum burning of carbon monoxide produced .in a carbon monoxide zone Z (FIGS. 1, 3, 6-8) to carbon dioxide thereby producing a substantially maximum amount of heat within the converter 10 to melt scrap metal (not shown) in the converter 10.
SIDE TUYERES 32 As shown particularly in FIGS. 1 and 2, each side tuyere 32 is mounted to project through a clearance hole 36 (FIGS. 1, 2) in the shell 12 and refractory brick lining 14. In order to mount the side tuyere 32 for vertical movement with respect to the converter l0,a mounting flange 38 (FIGS. 1, 2) projects from the shell 12 and carries an annular seat 40 (FIGS. 1, 2) engageable with a ball 42 (FIGS. 1, 2) and mounted on a flange 44 upstanding from a side tuyere shroud pipe 46 '(FIGS. 1, 2).
Contained within the side tuyere shroud pipe 46 is the concentric side tuyere oxygen pipe 48 (FIGS. '1', 2). In order to supply a shroud fluid, such as propane or the like, to the annulus defined by the oxygen pipe 48 and the shroud pipe 46, a T-connection 50 ('FIGS. 1, 2) is connected to a shroud gas supply indicatedby the legend FROM SHROUD GAS SUPPLY. The-means utilized to provide oxygen to the side 't'uiyereoxygen pipe 46 comprises an oxygen supply pipe 52 (-FIGS. 1, 2) and an elbow 54 (FIGS. 1, 2) connecting such oxygen supply pipe 52 to the side tuyere oxygen pipe 48. As shown in FIGS. 1, 2, and 4, tuyere operating means 56 are provided for moving each side tuyere 32 vertically, horizontally, or transversely with respect to the converter 10.
TUYERE OPERATING MEANS 56 TUYERE VERTICAL OPERATING MEANS 58 As shown in FIGS. 1, 2 and 4, the tuyere operating means 56 has a tuyere vertical operating means 58, suitably an electric motor 60 of the type SMO manufactured by Raco Machine Company of Bethel Park, Pennsylvania. This electric motor 60 has its piston rod 62 (FIGS. 1, 2, 4) pivotably connected to a bracket 64 projecting from the underside of the side tuyere shroud pipe 46 and is operable in response to a control device 66 shown in FIG. 4 to oscillate each side tuyere 32 a predetermined amount up or down in a vertical plane by means of its ball and seat connecting 42, 44 (FIGS. 1, 2) to the converter to achieve maximum heat from the conversion of the carbon monoxide in the carbon monoxide zone Z to carbon dioxide.
TUYERE HORIZONTAL OPERATING MEANS 68 Additionally, the tuyere operating means 56 has a tuyere horizontal operating means 68 (FIGS. 1, 2, 4) having an electric motor 60a similar to the electric motor 60. The electric motor 60a has its piston rod 62a pivotably secured by means of a bracket 64a to the supply pipe 52. For the purpose of permitting the side tuyere 32 to move in and out in a horizontal plane with respect to the converter 10, the electric motor 600 is mounted on slide guides 70 (FIG. 2) secured on the bottom of the electrical motor 60a.
TUYERE TRANSVERSE OPERATING MEANS 72 In addition, a tuyere transverse operating means 72 (FIGS. 1, 2, 4) has another electric motor 60b with its piston rod 62b connected at its free end to a bracket 64b projecting from the elbow 54 of the side tuyere 32 so that in response to a signal from the control device 66 shown in FIG. 7, the tuyere transverse operating means 72 may move each side tuyere 32 transversely in and out in a plane with respect to the converter 10. The tuyere transverse operating means shown in FIGS. 1, 2, and 4 has the electric motor 60b also mounted on a slide guide 70 to permit the horizontal reciprocable movement of the side tuyere 32 in a plane with respect to the converter 10.
As shown in FIG. 3, a sensing means 74 is associated with the converter 10 for sensing an initial effectiveness signal E, (FIG. 4) of the amount of carbon monoxide in the carbon monoxide zone Z being burned to car bon dioxide at a predetermined point such as the point P (FIG. 3).
SENSING MEANS 74 As shown in FIG. 3, adjacent the mouth 16 of the converter 10, ambient air is admitted through an opening 76 between the mouth 16 of the converter 10 and a gas collecting hood 78. The sensing means 74 has a probe 80 which projects from the point Pin the side wall of the converter 10 for sensing the amount of carbon monoxide adjacent the carbon monoxide zone Z being burned to carbon dioxide above the carbon monoxide zone C at the predetermined probe point P The probe80 and gas sample preparation system may be of the type manufactured by Bailey Meter Company of Cleveland, Ohio, and transmits a gas sample by means of line C1 (FIG. 3) to a carbon monoxide analyzer 82 of the type LIRA 200 manufactured by Mine Safety Appliances Company of Pittsburgh, Pennsylvania. This carbon monoxide 82 produces an output signal which is directly proportional to the amount of unburned carbon monoxide above the carbon monoxide zone Z at the predetermined probe point P and hence inversely proportional to the carbon monoxide being burned to carbon dioxide in the carbon monoxide zone Z It will be understood as hereinafter explained in detail, that output signals from analyzer 82 are conducted by means of line L1 (FIGS. 3 and 4) to the control device 66 shown in FIG. 4 labeled Incoming Signal provide the initial effectiveness signal E,-(FIG. 4) and the continuing effectiveness signal E, (FIG. 4) which is compared to the initial effectiveness signal E, in the control device 66. It will be also understood as hereinafter explained in detail, that as the effectiveness signal increases in magnitude, it indicates that less scrap melting is occurring.
CONTROL DEVICE 66 TIMER 84 This control device 66 (FIG. 4) has a timer 88 of the type" I-IL manufactured by Eagle Signal of Davenport,
ply indicated by the legend AC SUPPLY. Upon closure of the starting switch 86, the timer 88 is energized thereby closing (as shown in FIG. 5) for the period of time T,T,,, a normally open timer contact 88a in branch line Lla (FIG. 4). Upon closure of the timer contact 88a, the initial effectiveness signal E, coming from the sensing means 74 (FIG. 3) is stored in a capacitor 90 in branch line LIA.
At the end of the above mentioned period of time T,T (FIG. 5) timer contact 88a opens and the stored initial effectiveness signal E, continues to be applied to one input terminal E of a differential amplifier 92a of type P65A manufactured by Teledyne-Philbrick of Dedham, Massachusetts. Thereafter, the continuing effectiveness signal E,. from the sensing means 74 (FIG.
3) is fed via line L1 (FIG. 4) to the other output terminal E, of the differential amplifier 92a. If during the period of time T,,T (FIG. 5) the continuing effectiveness signal E on the input terminal E, (FIG. 4) of the differential amplifier 92a is greater than the initial effect'iveness signal E, on the input terminal E (FIG. 4) of the differential amplifier 92a, an output signal E from the amplifier 92a is positive and is fed via line 12 through a blocking diode 94a to one input terminal E of another differential amplifier 92b in a first control loop 93.
FIRST CONTROL Loop 93 For the purpose of boosting the input signal from output E of amplifier 92a to input E of differential amplifier 92b, a booster potentiometer 96a (FIG. 4, connected by line L3 to a battery 98a) has its output fed to an input terminal E (FIG. 4) of the differential amplifier 92b so that the output signal from output E of the differential amplifier 92b is fed via line L2 (FIG. 4) through a now closed timer contact 88b (during the period T T FIG. 5) and such output signal from output E of amplifier 92b is fed through a blocking diode 94b (FIG. 4) to a solenoid coil 100 of a drive mechanism 102 for a program means, such as the programmer 104 or of the type Model 250 manufactured by the Tenor Company of Milwaukee, Wisconsin.
DRIVE MEANS 102 Upon energization of the solenoid coil 100, a rack 106 (FIG. 4) is moved against the action of a biasing spring 108 away from the biasing spring 108 to index a pinion 110 on a shaft 112 a predetermined angular distance. The shaft 112 also carries a program drum 114 (FIG. 4).
PROGRAMMER 104 The program associated with the programmer 104 is applied to the program drum 114 by means of program pins 116( FIG. 4) which actuate in turn a plurality of program switches l18a-1 181'.
If, for example, the twoswitches 1 18a, 1 18b (FIG. 4) are energized by their associated program pins 1 l6 during the time T T., (FIG.;4), the timer 88 causes the timer contact 880 (FIG. 4) to close so that voltage from battery 980 is applied via lines L L L to, for example, the tuyerevertical operating means 58 (i.e., the electric motor 60) so that during such time period T -T (FIG. 5), the'piston rod 62 of the electric motor 60elevates, for exampmle, the side tuyere 32 a predetermined distance relative to the converter 10 thereby attempting to increase the amount of carbon monoxide in the carbon monoxide zone Z being burned to carbon dioxide.-
If, for example, on the next cycle of the control device 66, the contacts ll8c, ll8d (FIG. 4) are similarly energized, then during such time period TS-T4 (FIG. 5) the tuyere transverse operating means 72 (i.e., the electric motor 60b) would, for example, be energized through lines L L L to move the side tuyere 32 in or out from the plane of FIG. 4 a predetermined amount to again attempt to adjust the position of the side tuyere 32 to obtain an increased amount of carbon monoxide in the carbon monoxide Zone Z being burned to carbon dioxide.
Again, if during the third cycle of operation of the control device 66, program switches 118e, ll8f are closed by the associated program pins 116 thereby energizing the horizontal tuyere operating means 68 (i.e., the electric motor 60a via lines L L L during the time period T T FIG. 5) the electric motor 600 moves the side tuyere 32 either in or out a predetermined amount with respect to the side wall of the converter l0.
Finally, if on the fourth cycle of operation of the control device 66, as the switch 118i (FIG. 4) is closed by the associated program pins 116 and if during the period of time T7-T6 (FIG. 5) the timer 88 closes the timer contact 88d (FIG. 4) a voltage is applied from the battery 98b via line L4 and line L5 to an electric motor 120, which electric motor 120 forms a part of air oxygen control loop 122 (FIG. 4).
OXYGEN CONTROL LOOP 122 Flow control means, such as a control valve 124 (FIG. 4) of the type Mark I manufactured by Valtek of Provo, Utah, is disposed in the supply line 52 for controlling the flow of the oxygen or oxygen bearing gas through the supply line 52. Flow sensing means, such as a different pressure transmitter 126 (FIG. 4) of the type E13DI-I manufactured by The Foxboro Company of Foxboro, Massachusetts, is associated with an orifice 129 (FIG. 4) in the supply line 52 and transmits its output signal to an input terminal E of a differential amplifier 920. A variable potentiometer 128 (FIG. 4) is connected by line L3 to the 'battery 98a and-has its movable arm 130 driven by the electric. motor 120. The variable set point signal from the variable potentiometer 128 is fed to the input E of the differential amplifier 92c, which amplifier 920 has its output E connected to the control valve 124. I
Thus, when the switch 1181' of the programmer 104 is closed and the timer contact 88d is closed by the timer 88 (period T T FIG. 5), the electric motor is operable to increase the voltage signal of the variable potentiometer 128 so that the output signal from output E of the differential amplifier 92c opens the vcontrol valve 124 thereby increasing the flow of oxygen through the oxygen supply line 52 to the side tuyere 32.
If, on the other hand, during the monitoring period T T (FIG. 5), the initial effectiveness signal E I on the input terminal E of the differential amplifier 92a is greater than the continuing effectiveness signal E, on the input terminal E of the differential amplifier 92a, the output E will be negative and the blocking diode 94a in line L2 (FIG. 4) will prevent the passage of the output signal from output E of the differential amplifier 92a through line L2 to the differential amplifier 92b, in the first control loop 93, and the blocking diode 94c in line L6 (FIG. 4) will admit such output signal from output E of differential amplifier 92a through a second oxygen control loop 132 via line L6 toinput terminal E of differential amplifier 94d.
The blocking diode 94c will, of course, refuse any signal form output E,,,, of amplifier 92a when the continuing effectiveness signal E is greater than the initial effectiveness signal E, during the monitoring period T7-T1 (FIG. 1).
SECOND OXYGEN CONTROL LOOP 132 In order to boost the signal received on input E of the differential amplifier 94d (FIG. 4), a booster potentiometer 96b (FIG. 4) fed from battery 98b by line L4 provides a booster voltage to input terminal E of the differential amplifier 94d so that the output from output E of the differential amplifier 92d is fed through blocking diode 94d (FIG. 4, when the timer 88 closes the timer contact 8812, FIG. 5, during the period T9-T8, FIG. 5) thereby energizing a relay 134 in line L6 (FIG. 4). Energization of the relay 134 causes closure of normally open relay contact 134a (FIG. 4) in line L4 so that a positive voltage from battery 98b is fed via line L4 to the electric control motor 120 thereby moving the arm of the variable potentiometer 128 so that control valve 124 is moved further closed thereby reducing the oxygen flow rate through the supply pipe 52 and conserving oxygen which is not required.
ALTERNATIVE EMBODIMENTS It will be understood by those skilled in the art that alternatively, as shown in FIG. 6, that the sensing means 74 has its probe 80 affixed to a lance 136 depending from point P6 in the wall of the gascollecting hood 78 to the predeterminedprobe point P above the carbon monoxide zone Z Such probe 80 is connected by the line C1 to the carbon monoxide analyzer 82. The output, signal from the analyzer82 is carried, as before, by-the' line L1 to the control device 66 of FIG. 4. The predetermined point P 'at whichthe probe 80 senses the carbon-monoxide content? is above the carbon monoxide zone'Z within the converter 10.
In FIG. 7, the probe 80 extends from a point P7 within the gas collecting hood 78 to the predetermined probe point P of the probe located a considerable distance above the opening 76 between the mouth 16 of the converter 10 and the bottom of the gas collecting hood 78. In FIG. 7, the gas sample is fed by conduit C1 to a sensing means 74 including the carbon moxoxide analyzer 82, with the output of analyzer 82 being fed via line L8 to input E of differential amplifier 92e. In order to compensate such input signal to input E of the differential amplifier 92e from the carbon monoxide analyzer 82 for the amount of carbon monoxide which is burned to carbon dioxide in the gas collecting hood 78 prior to the predetermined probe point P the gaseous sample is fed by the line C1 to both an oxygen analyzer 138 of the type 7803 manufactured by Leeds & Northrup of North Wales, Pennsylvania, and a nitrogen analyzer 140 of the chromatograph type manufactured by Benoix-Greenbriar of Ronceverte, West Virginia.
The ratio of oxygen to nitrogen at the predetermined point P (FIG. 7) indicates the amount of oxygen which has been burned in the gas collecting hood 78 prior to the predetermined probe point P The output signals from the analyzers 138 and 140 are fed through respective calibrating potentiometers 142, 144 (FIG. 7) to inputs E and E respectively of a differential amplifier 92f so that the output signal from output E of such differential amplifier 92f is fed to input E of differential amplifier 92e thus calibrating the other input signal from the carbon monoxide analyzer 82 at input E of differential amplifier 922 and thereby providing from output E of amplifier 92e the initial and calibrated effectiveness signals E E via line L1 to the control device 66 (FIG. 4).
In FIG. 8, a temperature probe 80 enters the hood 78 at P8 and measures the temperature of the gases in the hood at the predetermined point P Line L9 carries the temperature signal to one input E of differential amplifier 92g. In the standard signal device 146, an initial temperature signal potentiometer 150 feeds through line L10 and a manually operated starting switch 148 to input E of differential amplifier 92h. Branch line L11 carries such signal also through capacitor 151 and a normal rate or slope potentiometer 152,
I so that the output from potentiometer is joined at junction 154 with the output signal from output E,,,, of amplifier 9211 and fed via line L12 to input E of amplifier 92g. The standard signal device 146 produces an output proportional to the hood temperature when the scrap is being properly melted. This signal is compared with the actual temperature by differential amplifier 92g.
The output signal form output E of amplifier 92g is fed through line L1 and blocking diode 942 which allows only positive signals to be applied to the control device 66.
It will be understood from the above description that if insufficient carbon monoxide is being burned in the carbon monoxide zone Z (FIG. 8), the temperature signal from output E of a differential amplifier 92g will increase, thereby requiring adjustment of the control system by the control device 66 (FIG. 4) as hereinbefore explained.
It will also be understood by those skilled in the art that the temperature probe 80 of FIG. 8 may be either located at the point P of FIG. 3 or disposed at P on the lance 136 of FIG. 6 or disposed at the predetermined point P of FIG. 7.
As shown in FIG. 2, side tuyere 32 may be rotated manually by means of turnbuckles 156.
In order to operate the second oxygen control loop 132 independently of the first control loop 93, selector switch 158 may be installed in lines L2, L6 to operate the loops 93, 132, either independently of each other or together.
From a consideration of FIG. 9, it will be apparent that the present invention may be employed with a bottom blown converter 210 having a bottom submerged tuyere 212, a side submerged tuyere 214, and a pair of side tuyeres 216 directed toward the carbon monoxide zone (CO zone). This bottom blown converter 210 has a shell 218 provided with a refractory lining 220 and a mouth 222 and is rotatable on trunnions 224. The tuyeres 212, 214, 216 are provided with a high temperature refractory protective covering 225 and are adapted to carry in an inner pipe either a fluid alone, such as oxygen, air, argon, or mixtures thereof, or entrained pulverized additives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (fluorspar (CaF or the like), or a blocking or deoxidizing agent (ferro manganese or the like), and in an outer pipe 215 a shroud gas, such as propane, natural gas, light fuel oil or the like.
As shown in FIG. 10, the present invention is also applicable to a I-IEROULT Type electric-arc steelmaking furnace 210a provided with a bottom submerged tuyere 212a, a side submerged tuyere 214a, and a side tuyere 216a directed toward the carbon monoxide zone (CO zone) of the furnace 210a. This electric-arc steelmaking furnace 210a has a shell 218a provided with a refractory lining 220a, a side door 226, a refractory roof 228 provided with electrode holes 230, a tap hole 232, and a pouring spout 234 extending from the tap hole 232. The tuyeres 212, 214a, are provided with a high temperature refractory protective covering 225 and are adapted to carry in an inner pipe 213 either a fluid alone, such as oxygen, air, argon, or mixtures thereof, or entrained pulverized additives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (fluorspar (CaF or the like), or a blocking or deoxidizing agent (ferro manganese or the like), and in an outer pipe 215, a shroud gas, such as propane, natural gas, light fuel oil or the like.
In addition, the present invention may be employed as shown in FIG. 11 with the open hearth furnace 21% having a bottom submerged tuyere 212b, a side submerged tuyere 214b, and a side tuyere 216b directed toward the carbon monoxide zone (CO zone) of the furnace 21012. This open hearth furnace 21% includes a refractory lined bottom 236, a refractory lined sloping back wall 238, a refractory lined front wall 240, a charging door 242 in the wall 240, and a refractory lined roof 244. A tap hole 232b opposite the charging door 242 leads to a pouring spout 234b. The tuyeres 212b, 214b, are provided with a high temperature refractory protective covering 225 and are adapted to carry in an inner pipe 213 either a fluid alone, such as oxygen, air, argon, or mixtures thereof, or entrained pulverized additives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (fluorspar (CaF or the like), or a blocking or deoxidizing agent (ferro manganese or the like) and in an outer pipe 215, a shroud gas, such'as gas, light fuel oil or the like. i i
Again as shown in FIG. 12,,the present invention may be employed with a tilting open hearth furnace 2100 mounted on rollers 246 arranged in a circular path for providing rotation onthe longitudinal axis of the furnace 210C for pouringythe refined steel through a tap hole 232C and a pouring spout 2340. As shown in FIG. 11, the tiltable openhea rth furnace 2106 has a bottom submerged tuyere 212C extending through a box 248. In addition, a submerged side tuyere 214C and a side tuyere 2160 directed toward the carbon monoxide zone (CO zone) of the furnace 210C are employed. The tilt able open hearth furnace 2106 has a refractory lined bottom 236C, refractory lined back Wall 2380, refractory lined front wall 240( (provided with a charging door "242c) and a refractory lined roof 244C. The tuyeres 2 12c, 2l4c,ar e provided with a high temperature refractory covering 225 and are adapted to carry in an inner pipe 213 either a fluid alone, such as oxygen, air,
propane, natural argon, or mixtures thereof, or entrained pulverized ad ditives, therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (fluorspar (CaF or the like), or a blocking or'deoxidizing agent (ferro manganese or the like), and in an outer pipe 215, a shroud gas, such as propane, natural gas, light fuel oil or the like.
In FIG. 13, the present invention is employed with a hot metal mixer 210d having a shell 218d provided with a refractory lining 220d, and having also an inlet mouth 222d and a pouring spout 234d. The mixer 210d is osditives therein, such as a fluxing agent (burned lime (CaO) or the like), a liquefying agent (flurospar (CaF or thelike), or a blocking or deoxidizing agent (ferro manganese or the like), and in an outer pipe 215,, a shroud gas, such as propane, natural gas, light fuel oil orthe like.
A discharge tuyere or tuyeres 32 (FIGS. 9, l0, ll,
.12, 13) is disposed adjacent a discharge opening, such as the mouth 22 (FIG. 9); the pouring spouts 234 (FIG. 10), 2341; (FIG. 11), 2340 (FIG. 12), and 234d (FIG. 13) to prevent the formation of skulls adjacent or on the discharge opening during the pouring operation particularly those chromium-nickel skulls produced during the refining of stainless steel.
METHOD It will be understood from the above description of the apparatus shown in FIGS. 1-8 that an improved method of optimum burning of the carbon monoxide produced in the-carbon monoxide zone Z (FIGS. 1-3, 68) to carbon dioxide is also a part of this invention. The improved method includes the steps of:
a. sensing the initial effectiveness signal E, of the amount of carbon monoxide in the carbon monoxide zone Z being burned to carbon dioxide at a predeter mined point such as P (FIG. 3), P (FIG. 6), P (FIG. 7), and P (FIG. 8) relative to the converter 10; I
b. monitoring a continuing effectiveness signal E,;
c. comparing the continuing effectiveness signal E, with the initial effectiveness signal E,; and
(1. moving the side tuyere 32 relative to the converter 10 when the continuing effectiveness signal E is greater than the initial effectiveness signal E, to increase the amount of carbon monoxide in the carbon monoxide zone Z being burned to carbon dioxide.
In addition, a further step is comtemplated of:
a. increasing the flow of oxygen to the side tuyere 32 when the continuing effectiveness signal E, is greater than the initial effectiveness signal E, to increase the amount of carbon monoxide in the carbon monoxide zone Z being burnedtocarbon dioxide. I
Finally, the improved method also includes the step of: 1
a. decreasing the flow of oxygen to the side tuyere 32 when the continuing effectiveness signal E is less than the initial effectiveness signal E, to conserve oxygen in the refining process. i
SUMMARY OF THE ACHIEVEMENTS OFTVHE OBJECTS or THE INVENTION It will be recognized by those skilled inthe art that the objects of this invention have been achieved by providing an improved apparatus for and method of optimum burning of carbon monoxide produced in .a carbon monoxide zone within a converter to carbon dioxide, which improved apparatus and method:
a. provide an improved and novel control device. 66 (FIG. 4) which can either position a side tuyere 32 or adjust the oxygen flow rate to the side tuyere 32. in response to a signal which is a measure of the effectiveness of the side tuyere position and the oxygen flo rate through such side tuyere 32;
b. provide a substantially maximum amountof heat generated in the carbon monoxide zone 26,, above the molten metal bath 28 in the vessel 10 to permit maximum scrap usage in the refining process";
c. utilize all available heat from the refining process and the burning of the carbon monoxidein the carbon monoxide zone Z for scrap melting;
d. continuously monitor either the carbon monoxide content at a predetermined point P,, (FIGS. 3,-6- -8) relative to the converter 10 or the temperature of the off gases above the carbon monoxide zone Z 'at such-predetermined point P against an initial effectiveness sig: nal E,; and
e. time the operation of the initial effectiveness signal E,, the monitored continuing effectiveness signal E the comparison therebetween, the movement of the side tuyere 32 relative to the converter 10 and the change in the oxygen supply to the side tuyere 32 as a programmed cycle.
While in accordance with the patent statutes, preferred and alternative embodiments of this invention have been illustrated and described in detail, it is to be particularly understood that the invention is not limited thereto or thereby.
We claim:
1. Apparatus for the optimum burning of carbon monoxide produced in a carbon monoxide z'one above a molten metal bath in a converter to carbon dioxide thereby producng a substantially maximum amount of heat within said converter to melt scrap in said converter, said apparatus having:
a side tuyere mounted in said converter above the level of the molten metal bath;
means for supplying oxygen through said tuyere into said converter and into contact with carbon monoxide in said carbon monoxide zone;
sensing means associated with said converter for sensing an initial effectiveness signal of the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal;
comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal; and
tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in a horizontal and a vertical direction in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
2. The apparatus recited in claim 1 and having:
a carbon monoxide sensing means.
3. The apparatus recited in claim 2 wherein:
said carbon monoxide sensing means senses the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide above said carbon monoxide zone at said predetermined point.
4. The apparatus recited in claim 2 and having:
a gas collecting hood above a mouth of said converter; and
said carbon monoxide sensing means is disposed in said gas collecting hood.
5. The apparatus recited in claim 1 and having:
a temperature sensing means.
6. The apparatus recited in claim 5 and having:
said temperature sensing means disposed above said carbon monoxide zone.
7. The apparatus recited in claim 5 and having:
a gas collecting hood above a mouth of said converter; and
said temperature sensing means disposed in said gas collecting hood.
8. The apparatus recited in claim 1 wherein:
said tuyere operating means moves said side tuyere transversely relative to said converter.
9. The apparatus recited in claim 1 wherein:
said tuyere operating means has a tuyere transverse operating means connected to said program means and said side tuyere; and
said program means is operable to actuate said tuyere vertical operating means and said tuyere transverse operating means in a predetermined order.
10. The apparatus recited in claim 1 and having:
timing means associated with said sensing means and said comparison means for causing the timed storage of said initial effectiveness signal.
11. The apparatus recited in claim 1 and having:
timing means connected between said comparison means and said tuyere operating means for causing timed actuation of said tuyere operating means.
12. The apparatus recited in claim 1 and having:
timer means connected between said program means and said tuyere operating means for the timed actuation of said program means. 13. The apparatus recited in claim 1 wherein said ap- 5 paratus is a bottom blown converter.
14. The apparatus recited in claim 1 wherein said apparatus is an open hearth furnace.
15. The apparatus recited in claim 1 wherein said apparatus is a tiltable open hearth furnace.
16. The apparatus recited in claim 1 wherein said tuyere is a tuyere disposed adjacent a discharge opening of said apparatus to prevent formation of skulls adjacent said discharge opening during pouring of said molten metal.
17. Apparatus for the optimum burning of carbon monoxide produced in a carbon monoxide zone above a molten metal bath in a converter to carbon dioxide thereby producing a substantially maximum amount of heat within said converter to melt scrap in said converter, said apparatus having:
a side tuyere mounted in said converter above the level of the molten metal bath;
sensing means associated with said converter for sensing an initial effectiveness signal of the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal;
comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal;
a supply line connecting said side tuyere to an oxygen source;
flow control means in said supply line for controlling the flow of oxygen through said supply line;
flow sensing means in said supply line for sensing the flow of oxygen through said supply line and for producing a flow signal; standard flow signal producing means for producing a standard flow signal, connected to said comparison means and operable by said comparison means;
flow comparison means for receiving said flow signal and said standard flow signal, connected to said flow control means and adapted to position said flow control means in response to a flow output signal from said flow comparison means; and
tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in biaxial directions in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
18. The apparatus recited in claim 17 wherein:
said standard flow signal producing means is operable by said comparison means when said continuing effectiveness signal is greater than said initial effectiveness signal to increase said standard flow signal, thereby increasing the flow of oxygen to said supply line.
19. The apparatus recited in claim 18 and having:
timing means disposed between said standard flow signal producing means and said comparison means for causing-the timedactuation of said standard flow signal Lproducing rne'ans.
20. The apparatus recited-inf'claim l7 and having:
program means disposed between saidstandard flow signal producing ,;means and said comparison means toprogram any increase in said flow of oxygen to said side tuyere.
21. Apparatus for the optimum burning of carbon monoxide produced in a carbon monoxide zone above a molten metal bath in a converter to carbon dioxide thereby producing a substantially maximum amount of heat within said converter to melt scrap in said converter, said apparatus having: I i
a side tuyere mounted in said converter above the level of the molten metal bath;
means for supplying oxygen through said tuyere into said converter and into contact with carbon monoxide in said carbon monoxide zone; sensing -means associated with said converter for sensing an initial effective'ness signal of the amount of carbon monoxide in said carbon-'mbnixide zone beingbu'rned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal;"
comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal;
relay means connected to said comparison means and operable when said continuing effectiveness signal is less than said initial effectiveness signal to position said standard flow signal producing means to decrease said standard flow signal thereby decreasing the flow of oxygen to said supply line and thus conserving oxygen; and
tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in biaxial directions in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
22. Apparatus for the optimum burning of carbon monoxide produced in a carbon monoxide zone above a molten metal bath in a converter to carbon dioxide thereby producing a substantially maximum amount of heat within said converter to melt scrap in said converter, said apparatus having:
a side tuyere mounted in said converter above the level of the molten metal bath;
means for supplying oxygen through said tuyere into said converter and into contact with carbon monoxide in said carbon monoxide zone;
sensing means associated with said converter for sensing an initialeffectiveness signal of the amount of carbon monoxide in said carbon monoxide, zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means f being operable to monitor a continuing effective ness signal;
comparison means connected tolsaid sensingmearis" for comparing said continuing effectiveness signalf with said initial effectiveness signal; and tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in a transverse and a vertical direction in a predetermined order relative to said converter whensaid continuing effective ness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.

Claims (22)

1. APPARATUS FOR THE OPTIMUM BURNING OF CARBON MONOXIDE PRODUCED IN A CARBON MONOXIDE ZONE ABOVE A MOLTEN METAL BATH IN A CONVERTER TO CARBON DIOXIDE THEREBY PRODUCING A SUBSTANTIALLY MAXIMUM AMOUNT OF HEAT WITHIN SAID CONVERTER TO MELT SCRAP IN SAID CONVERTER SAID APPARATUS HAVING: A SIDE TUYERE MOUNTED IN SAID CONVERTER ABOVE THE LEVEL OF THE MOLTEN METAL BATH, MEANS FOR SUPPLYING OXYGEN THROUGH SAID TUYERE INTO SAID CONVERTER AND INTO CONTACT WITH CARBON MONOXIDE IN SAID CARBON MONOXIDE ZONE, SENSING MEANS ASSOCIATED WITH SAID CONVERTER FOR SENSING AN INITIAL EFFECTIVENESS SIGNAL OF THE AMOUNT OF CARBON MONOXIDE IN SAID CARBON MONOXIDE ZONE BEING BURNED TO CARBON DIOXIDE AT A PREDETERMINED POINT RELATIVE TO SAID CONVERTER SAID SENSING MEANS BEING OPERABLE TO MONITOR A CONTINUING EFFECTIVENESS SIGNAL, COMPARISION MEANS CONNECTED TO SAID SENSING MEANS FOR COMPARING SAID CONTINUING EFFECTIVENESS SIGNAL WITH SAID INITIAL EFFECTIVENESS SIGNAL AND TUYERE OPERATING MEANS INCLUDING PROGRAM MEANS CONNECTED TO SAID COMPARISON MEANS AND SAID TUYERE FOR MOVING SAID SIDE TUYERE IN A HORIZONTAL AND A VERTICAL DIRECTION IN A PREDETERMINED ORDER RELATIVE TO SAID CONVERTER WHEN SAID CONTINUING EFFECTIVENESS SIGNAL IS GREATER THAN SAID INITIAL EFFECTIVENESS SIGNAL TO INCREASE THE AMOUNT OF CARBON MONOXIDE IN SAID CARBON MONOXIDE ZONE BEING BURNED TO CARBON DIOXIDE.
2. The apparatus recited in claim 1 and having: a carbon monoxide sensing means.
3. The apparatus recited in claim 2 wherein: said carbon monoxide sensing means senses the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide above said carbon monoxide zone at said predetermined point.
4. The apparatus recited in claim 2 and having: a gas collecting hood above a mouth of said converter; and said carbon monoxide sensing means is disposed in said gas collecting hood.
5. The apparatus recited in claim 1 and having: a temperature sensing means.
6. The apparatus recited in claim 5 and having: said temperature sensing means disposed above said carbon monoxide zone.
7. The apparatus recited in claim 5 and having: a gas collecting hood above a mouth of said converter; and said temperature sensing means disposed in said gas collecting hood.
8. The apparatus recited in claim 1 wherein: said tuyere operating means moves said side tuyere transversely relative to said converter.
9. The apparatus recited in claim 1 wherein: said tuyere operating means has a tuyere transverse operating means connected to said program means and said side tuyere; and said program means is operable to actuate said tuyere vertical operating means and said tuyere transverse operating means in a predetermined order.
10. The apparatus recited in claim 1 and having: timing means associated with said sensing means and said comparison means for causing the timed storage of said initial effectiveness signal.
11. The apparatus recited in claim 1 and having: timing means connected between said comparison means and said tuyere operating means for causing timed actuation of said tuyere operating means.
12. The apparatus recited in claim 1 and having: timer means connected between said program means and said tuyere operating means for the timed actuation of said program means.
13. The apparatus recited in claim 1 wherein said apparatus is a bottom blown converter.
14. The apparatus recited in claim 1 wherein said apparatus is an open hearth furnace.
15. The apparatus recited in claim 1 wherein said apparatus is a tiltable open hearth furnace.
16. The apparatus recited in claim 1 wherein said tuyere is a tuyere disposed adjacent a discharge opening of said apparatus to prevent formation of skulls adjacent said discharge opening during pouring of said molten metal.
17. Apparatus for the optimum burning of carbon monoxide produced in a carbon monoxide zone above a molten metal bath in a converter to carbon dioxide thereby producing a substantially maximum amount of heat within said converter to melt scrap in said converter, said apparatus having: a side tuyere mounted in said converteR above the level of the molten metal bath; sensing means associated with said converter for sensing an initial effectiveness signal of the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal; comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal; a supply line connecting said side tuyere to an oxygen source; flow control means in said supply line for controlling the flow of oxygen through said supply line; flow sensing means in said supply line for sensing the flow of oxygen through said supply line and for producing a flow signal; standard flow signal producing means for producing a standard flow signal, connected to said comparison means and operable by said comparison means; flow comparison means for receiving said flow signal and said standard flow signal, connected to said flow control means and adapted to position said flow control means in response to a flow output signal from said flow comparison means; and tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in biaxial directions in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
18. The apparatus recited in claim 17 wherein: said standard flow signal producing means is operable by said comparison means when said continuing effectiveness signal is greater than said initial effectiveness signal to increase said standard flow signal, thereby increasing the flow of oxygen to said supply line.
19. The apparatus recited in claim 18 and having: timing means disposed between said standard flow signal producing means and said comparison means for causing the timed actuation of said standard flow signal producing means.
20. The apparatus recited in claim 17 and having: program means disposed between said standard flow signal producing means and said comparison means to program any increase in said flow of oxygen to said side tuyere.
21. Apparatus for the optimum burning of carbon monoxide produced in a carbon monoxide zone above a molten metal bath in a converter to carbon dioxide thereby producing a substantially maximum amount of heat within said converter to melt scrap in said converter, said apparatus having: a side tuyere mounted in said converter above the level of the molten metal bath; means for supplying oxygen through said tuyere into said converter and into contact with carbon monoxide in said carbon monoxide zone; sensing means associated with said converter for sensing an initial effectiveness signal of the amount of carbon monoxide in said carbon monixide zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal; comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal; relay means connected to said comparison means and operable when said continuing effectiveness signal is less than said initial effectiveness signal to position said standard flow signal producing means to decrease said standard flow signal thereby decreasing the flow of oxygen to said supply line and thus conserving oxygen; and tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in biaxial directions in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon Monoxide in said carbon monoxide zone being burned to carbon dioxide.
22. Apparatus for the optimum burning of carbon monoxide produced in a carbon monoxide zone above a molten metal bath in a converter to carbon dioxide thereby producing a substantially maximum amount of heat within said converter to melt scrap in said converter, said apparatus having: a side tuyere mounted in said converter above the level of the molten metal bath; means for supplying oxygen through said tuyere into said converter and into contact with carbon monoxide in said carbon monoxide zone; sensing means associated with said converter for sensing an initial effectiveness signal of the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide at a predetermined point relative to said converter, said sensing means being operable to monitor a continuing effectiveness signal; comparison means connected to said sensing means for comparing said continuing effectiveness signal with said initial effectiveness signal; and tuyere operating means including program means connected to said comparison means and said side tuyere for moving said side tuyere in a transverse and a vertical direction in a predetermined order relative to said converter when said continuing effectiveness signal is greater than said initial effectiveness signal to increase the amount of carbon monoxide in said carbon monoxide zone being burned to carbon dioxide.
US309018A 1972-10-06 1972-11-24 Apparatus for and method of optimum burning of carbon monoxide in a converter Expired - Lifetime US3895784A (en)

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DE2755165A1 (en) * 1977-12-10 1979-07-26 Maximilianshuette Eisenwerk Refining cast iron - by blowing oxygen into a converter full of molten iron both above and below the melt level
DE2816543A1 (en) * 1978-04-17 1979-10-25 Maximilianshuette Eisenwerk Steel mfr. from solid ferrous material esp. scrap, in converter - where bottom tuyeres are used as fuel burners to preheat charge prior to melting and oxygen refining
EP0048007A1 (en) * 1980-09-12 1982-03-24 Deutsche Voest-Alpine Industrieanlagenbau Gmbh Metallurgical melting apparatus with a pivotable nozzle or burner
US4462825A (en) * 1983-09-01 1984-07-31 United States Steel Corporation Method for increasing the scrap melting capability of metal refining processes
US6315802B1 (en) * 1995-04-13 2001-11-13 Marathon Ashland Petroleum Llc H2S production from a molten metal reactor
US6350289B1 (en) * 1995-04-13 2002-02-26 Marathon Ashland Petroleum Llc Two-zone molten metal hydrogen-rich and carbon monoxide-rich gas generation process
US9045805B2 (en) 2013-03-12 2015-06-02 Ati Properties, Inc. Alloy refining methods

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2755165A1 (en) * 1977-12-10 1979-07-26 Maximilianshuette Eisenwerk Refining cast iron - by blowing oxygen into a converter full of molten iron both above and below the melt level
DE2816543A1 (en) * 1978-04-17 1979-10-25 Maximilianshuette Eisenwerk Steel mfr. from solid ferrous material esp. scrap, in converter - where bottom tuyeres are used as fuel burners to preheat charge prior to melting and oxygen refining
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US6315802B1 (en) * 1995-04-13 2001-11-13 Marathon Ashland Petroleum Llc H2S production from a molten metal reactor
US6350289B1 (en) * 1995-04-13 2002-02-26 Marathon Ashland Petroleum Llc Two-zone molten metal hydrogen-rich and carbon monoxide-rich gas generation process
US9045805B2 (en) 2013-03-12 2015-06-02 Ati Properties, Inc. Alloy refining methods
US9683273B2 (en) 2013-03-12 2017-06-20 Ati Properties Llc Alloy refining methods

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