US3890533A - Thermal emission type electron gun - Google Patents
Thermal emission type electron gun Download PDFInfo
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- US3890533A US3890533A US377812A US37781273A US3890533A US 3890533 A US3890533 A US 3890533A US 377812 A US377812 A US 377812A US 37781273 A US37781273 A US 37781273A US 3890533 A US3890533 A US 3890533A
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- filament
- wehnelt electrode
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- 238000010894 electron beam technology Methods 0.000 abstract description 12
- 238000010586 diagram Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 201000009310 astigmatism Diseases 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/06—Electron sources; Electron guns
- H01J37/063—Geometrical arrangement of electrodes for beam-forming
Definitions
- ABSTRACT A thermal emisssion type electron gun of improved design embodying an improved Wehnelt electrode and an improved filament arrangement with respect to the Wehnelt electrode thereby ensuring the generation of an electron beam having a high degree of parallelism, high density and uniformity.
- the thermal emission type electron gun presently in use is inescapable of satisfying all the above requirements. hence the quality of the microscope image leaves a lot to be desired.
- the reason for this, I have found is primarily related to the improper shape of the Wehnelt electrode and the improper position of the filament with respect to the Wehnelt electrode in prior art devices.
- An advantage of this invention is to provide a thermal emission type electron gun capable of generating an electron beam having the required high degree of parallelism, high density and uniformity by improving the shape of the Wehnelt electrode and rearranging the filament with respect to the Wehnelt electrode.
- a further advantage of this invention is to increase the effective working life of the filament.
- this invention is characterized in part by the fact that the distance H between the tip of the filament and the lower rim of the Wehnelt electrode opening through which the electron beam passes typically satisfies the relations 0.40 S H s 0.8D, where D is the diameter of the Wehnelt electrode opening.
- the distance between the filament and the Wehnelt electrode is large enough to prevent microdischarge, thereby prolonging the effective working life of the filament.
- a beam having high density and uniformity enables a low magnification image to be displayed with uniform brightness. It also eliminates the need to adjust the stigmator because beam astigmatism remains almost constant regardless of any change in the accelerating voltage or image magnification.
- FIG. 1 is a schematic diagram showing a conventional thermal emission type electron gun
- FIGS. 2 and 3 are schematic diagrams for explaining the characteristics of the electron beam obtained by the electron gun shown in FIG. 1:
- FIG. 4 is a drawing showing the essential part of the electron gun according to this invention.
- FIGS. 5, 6, and 7 are schematic diagrams for explaining the characteristics ofthe electron beam obtained by the electron gun according to this invention.
- an electron gun chamber 1 is mounted upon the microscope column (not shown) and an insulator 2 is filled with insulating pitch 3.
- a high voltage cable 4 is partially buried in the solidified insulating pitch 3.
- Lead wires 5, 6, and 7 constitute the electrical conducting path of the high voltage cable 4.
- One end of said lead wires 5 and 6 and lead wire 7 is connected to a filament heating source 8 and a DC. high voltage source 9, respectively.
- the opposite ends of the respective lead wires being connected to rods 10, 11 and 12.
- a filament 13 is connected to rods 10 and 11, said filament being heated by alternating current generated by the filament heating source 8 which is applied via lead wires 5 and 6 and said rods 10 and 11.
- a Wehnelt electrode 14 is threadably secured to a member 15 fixed to the insulator 2.
- the electrode is supplied with a negative high voltage generated by the DC. high voltage source 9 which is applied via lead wire 7, rod 12 and the member 15. Resistor 16 connected between lead wires 6 and 7 serves as a bias resistor, in order to control the electrons emitted from the filament by varying the bias voltage.
- A represents the beam crossover point under the condition that the filament tip aligns with the lower rim of the Wehnelt opening, said crossover point being formed by the electrostatic field generated between the filament and an anode 17.
- FIG. 2 shows the image of the hairpin filament produced by the prior art thermal emission type electron gun described in FIG. I under comparatively low filament temperature conditions.
- the filament image consists of a slightly elliptical bright area at the center and two peripheral bright areas which are more or less crescent shaped.
- FIG. 3 shows the beam intensity distribution curve of the filament image shown in FIG. 2. As indicated by the curve, the beam intensity is strongest at the center of the image and weakens markedly in the peripheral areas. Accordingly, in order to obtain an electron beam having a high degree of parallelism, high density and uniformity, it is necessary to slice off a large portion of the electron beam by inserting a baffle having small diameter lens aperture therein in the beam path.
- FIG. 4 is a schematic drawing showing the shape of the Wehnelt electrode and the postition of the filament with respect to the Wehnelt according to this invention.
- the side of the Wehnelt electrode 18 facing the anode is convex and the distance H between the tip of the filament and the lower rim of the Wehnelt electrode opening satisfies the relation 0.4D 5 H 5 0.8D (0.4D less than or equal to H, H less than or equal to 0.8D) where D is the diameter of the Wehnelt electrode opening.
- the Wehnelt electrode By satisfying the above condition, excellent results are assured.
- the vertical angle 8 of said cone-shaped position should preferably satisfy the relation 30 S B s 90 (beta greater than or equal to 30, beta less than or equal to 90) and the height b of the cylindrical surface should preferably satisfy the relation 0.2D s b s 0.8D (b less than or equal to (12D, b greater than or equal to 0.8D).
- FIG. 5 shows the trajectory of the electron beam emitted from the gun filament according to this invention. It will be noted that the angle of beam diversion beyond the crossover point is minimal thereby ensuring the high degree of parallelism.
- FIGS. 6 and 7 show the filament image produced by the thermal emission type gun according to this invention and the corresponding beam intensity distribution curve under comparatively low filament temperature.
- the beam intensity distribution curve is the flat topped curve as shown in FIG. 7, because the filament image consists of a very slightly elliptical bright area at the center and a ring-shaped bright area as shown in FIG. 6. Therefore, the electron gun according to this invention generates an electron beam having high density and uniformity.
- a thermal emission type electron gun comprising a filament for emitting thermal electrons, an anode arranged to face said filament, a voltage source for supplying high potential difference between said filament and anode, a Wehnelt electrode having an opening the rein through which said electrons pass, said Wehnelt electrode arranged between said filament and anode, the side of said Wehnelt electrode facing the anode being convex, and means for supplying a potential to maintain the Wehnelt electrode at a negative potential with respect to the filament, the improvement comprising the distance I-l between the tip of the filament and the lower rim of the Wehnelt opening satisfying the relation 0.4D s H S (18D where D is the diameter of the opening the Wehnelt electrode, and the surface of the Wehnelt electrode near the opening being substantially cylindrical and the surface about the opening facing the filament being substantially cone-shaped and the angle B of said cone-shaped portion with the axis of the cylindrical opening satisfying the relation 30s B S 2.
- a thermal emission type electron gun comprising a filament for emitting thermal electrons, an anode arranged to face said filament, a voltage source for supplying high potential different between said filament and anode, a Wehnelt electrode having an opening therein through which said electrons pass, said Wehnelt electrode arranged between said filament and anode, the side of said Wehnelt electrode facing the anode being convex, and means for supplying a potential to maintain the Wehnelt electrode at a negative potential with respect to the filament, the improvement comprising the distance H between the tip of the filament and the lower rim of the Wehnelt opening satisfying the relation 0.4D H S 0.8D where D is the diameter of the opening in the Wehnelt electrode and the surface of the Wehnelt electrode near the opening being substantially cylindrical and the surface about the opening facing the filament being substantially cone-shaped and the height b of said cylindrical surface satisfying the relation 02D 5 b s 0.8D.
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Electron Sources, Ion Sources (AREA)
Abstract
A thermal emisssion type electron gun of improved design embodying an improved Wehnelt electrode and an improved filament arrangement with respect to the Wehnelt electrode thereby ensuring the generation of an electron beam having a high degree of parallelism, high density and uniformity.
Description
United States Patent 1 1 11 1 3,890,533
Tanaka June 17, 1975 THERMAL EMISSION TYPE ELECTRON 3.1851882 5/[965 Dryden et al. .1 3l3/83 R 3,225,248 [2/1965 Schelfels 315/31 R GUN inventor: Akira Tanaka, Akishima,Japan Nihon Denshi Kabushiki Kaisha, Tokyo, Japan Filed: July 9, 1973 Appl. No.: 377,812
Assignee:
Foreign Application Priority Data Aug. 8, 1972 Japan 47-83891 References Cited UNITED STATES PATENTS 7/1964 Hahn 315/31 R Primary Examiner-Maynard R. Wilbur Assistant Examiner-J. M. Potenza Attorney. Agent. or FirmWebb, Burden, Robinson & Webb {57] ABSTRACT A thermal emisssion type electron gun of improved design embodying an improved Wehnelt electrode and an improved filament arrangement with respect to the Wehnelt electrode thereby ensuring the generation of an electron beam having a high degree of parallelism, high density and uniformity.
3 Claims, 7 Drawing Figures PATENTEDJUN 17 ms 7 3,890,533 sum 1 HLAMENT HEATlNtz SOURCE D.C.HH:H VOLTAGE SOURCE PRIOR ART g 2:1 2' 3 g PoSITIoN P05! TIDN THERMAL EMISSION TYPE ELECTRON GUN This invention relates to a thermal emission type electron gun. Electron beam sources used in electron microscopes are required to generate an electron beam having a high order of brightness, a high degree of parallelism, and high density and uniformity, in order to ensure a high quality image.
However, the thermal emission type electron gun presently in use is inescapable of satisfying all the above requirements. hence the quality of the microscope image leaves a lot to be desired. The reason for this, I have found is primarily related to the improper shape of the Wehnelt electrode and the improper position of the filament with respect to the Wehnelt electrode in prior art devices.
An advantage of this invention, therefore, is to provide a thermal emission type electron gun capable of generating an electron beam having the required high degree of parallelism, high density and uniformity by improving the shape of the Wehnelt electrode and rearranging the filament with respect to the Wehnelt electrode.
A further advantage of this invention is to increase the effective working life of the filament.
Briefly, this invention is characterized in part by the fact that the distance H between the tip of the filament and the lower rim of the Wehnelt electrode opening through which the electron beam passes typically satisfies the relations 0.40 S H s 0.8D, where D is the diameter of the Wehnelt electrode opening.
By satisfying the above relation, the distance between the filament and the Wehnelt electrode is large enough to prevent microdischarge, thereby prolonging the effective working life of the filament.
This and other characteristics of this invention, as above mentioned enable the overall performance of electron microscopes to be improved in many ways.
For example, it has been confirmed from my experimental work that a well-paralleled beam enables thick specimens to be observed due to the increased penetrating power. The resultant decrease in electron scatter in the specimen reduces specimen contamination and heat damage. Also, particularly in the case of biological specimens, phase contrast makes it possible to separate the specimen structure image from the image noise, due to increased focal depth.
At the same time, a beam having high density and uniformity enables a low magnification image to be displayed with uniform brightness. It also eliminates the need to adjust the stigmator because beam astigmatism remains almost constant regardless of any change in the accelerating voltage or image magnification.
Further features ofthis invention will become apparent from the following detailed description considered in conjunction with the accompanying drawings in which:
FIG. 1 is a schematic diagram showing a conventional thermal emission type electron gun;
FIGS. 2 and 3 are schematic diagrams for explaining the characteristics of the electron beam obtained by the electron gun shown in FIG. 1:
FIG. 4 is a drawing showing the essential part of the electron gun according to this invention;
FIGS. 5, 6, and 7 are schematic diagrams for explaining the characteristics ofthe electron beam obtained by the electron gun according to this invention.
Referring to FIG. 1, an electron gun chamber 1 is mounted upon the microscope column (not shown) and an insulator 2 is filled with insulating pitch 3. A high voltage cable 4 is partially buried in the solidified insulating pitch 3. Lead wires 5, 6, and 7 constitute the electrical conducting path of the high voltage cable 4. One end of said lead wires 5 and 6 and lead wire 7 is connected to a filament heating source 8 and a DC. high voltage source 9, respectively. The opposite ends of the respective lead wires being connected to rods 10, 11 and 12. A filament 13 is connected to rods 10 and 11, said filament being heated by alternating current generated by the filament heating source 8 which is applied via lead wires 5 and 6 and said rods 10 and 11. A Wehnelt electrode 14 is threadably secured to a member 15 fixed to the insulator 2. The electrode is supplied with a negative high voltage generated by the DC. high voltage source 9 which is applied via lead wire 7, rod 12 and the member 15. Resistor 16 connected between lead wires 6 and 7 serves as a bias resistor, in order to control the electrons emitted from the filament by varying the bias voltage. A represents the beam crossover point under the condition that the filament tip aligns with the lower rim of the Wehnelt opening, said crossover point being formed by the electrostatic field generated between the filament and an anode 17.
FIG. 2 shows the image of the hairpin filament produced by the prior art thermal emission type electron gun described in FIG. I under comparatively low filament temperature conditions. As shown in the figure, the filament image consists of a slightly elliptical bright area at the center and two peripheral bright areas which are more or less crescent shaped. FIG. 3 shows the beam intensity distribution curve of the filament image shown in FIG. 2. As indicated by the curve, the beam intensity is strongest at the center of the image and weakens markedly in the peripheral areas. Accordingly, in order to obtain an electron beam having a high degree of parallelism, high density and uniformity, it is necessary to slice off a large portion of the electron beam by inserting a baffle having small diameter lens aperture therein in the beam path. In so doing, however, a proportional amount of beam current is lost, This, of course, means that if a large beam current is required, it is necessary to rearrange the position of the Wehnelt electrode so as to make the filament protrude from the lower rim of the Wehnelt electrode opening and also to increase the bias voltage between the filament and Wehnelt electrode. However, by so doing, the effective working life of the filament is curtailed due to microdischarge between the filament and the Wehnelt electrode.
FIG. 4 is a schematic drawing showing the shape of the Wehnelt electrode and the postition of the filament with respect to the Wehnelt according to this invention. The side of the Wehnelt electrode 18 facing the anode is convex and the distance H between the tip of the filament and the lower rim of the Wehnelt electrode opening satisfies the relation 0.4D 5 H 5 0.8D (0.4D less than or equal to H, H less than or equal to 0.8D) where D is the diameter of the Wehnelt electrode opening.
By satisfying the above condition, excellent results are assured. However, in order to further improve the overall performance of the thermal emission type electron gun with respect to the objectives and claims of this invention, it is necessary to machine the Wehnelt electrode to provide a cylindrical surface for the beam pass-through opening and to make the surface of the Wehnelt electrode near the opening facing the filament substantially cone-shaped (conical). Moreover, the vertical angle 8 of said cone-shaped position should preferably satisfy the relation 30 S B s 90 (beta greater than or equal to 30, beta less than or equal to 90) and the height b of the cylindrical surface should preferably satisfy the relation 0.2D s b s 0.8D (b less than or equal to (12D, b greater than or equal to 0.8D).
FIG. 5 shows the trajectory of the electron beam emitted from the gun filament according to this invention. It will be noted that the angle of beam diversion beyond the crossover point is minimal thereby ensuring the high degree of parallelism.
FIGS. 6 and 7 show the filament image produced by the thermal emission type gun according to this invention and the corresponding beam intensity distribution curve under comparatively low filament temperature. In this condition, the beam intensity distribution curve is the flat topped curve as shown in FIG. 7, because the filament image consists of a very slightly elliptical bright area at the center and a ring-shaped bright area as shown in FIG. 6. Therefore, the electron gun according to this invention generates an electron beam having high density and uniformity.
Having thus set forth my invention as required by the Patent Laws, what is desired by Letters Patent are set forth in the following claims.
I claim:
1. In a thermal emission type electron gun comprising a filament for emitting thermal electrons, an anode arranged to face said filament, a voltage source for supplying high potential difference between said filament and anode, a Wehnelt electrode having an opening the rein through which said electrons pass, said Wehnelt electrode arranged between said filament and anode, the side of said Wehnelt electrode facing the anode being convex, and means for supplying a potential to maintain the Wehnelt electrode at a negative potential with respect to the filament, the improvement comprising the distance I-l between the tip of the filament and the lower rim of the Wehnelt opening satisfying the relation 0.4D s H S (18D where D is the diameter of the opening the Wehnelt electrode, and the surface of the Wehnelt electrode near the opening being substantially cylindrical and the surface about the opening facing the filament being substantially cone-shaped and the angle B of said cone-shaped portion with the axis of the cylindrical opening satisfying the relation 30s B S 2. The improvement'in a thermal emission type electron gun as set forth in claim 1 in which the height b of said cylindrical surface satisfies the relation 0.2D b s 0.8D.
3. In a thermal emission type electron gun comprising a filament for emitting thermal electrons, an anode arranged to face said filament, a voltage source for supplying high potential different between said filament and anode, a Wehnelt electrode having an opening therein through which said electrons pass, said Wehnelt electrode arranged between said filament and anode, the side of said Wehnelt electrode facing the anode being convex, and means for supplying a potential to maintain the Wehnelt electrode at a negative potential with respect to the filament, the improvement comprising the distance H between the tip of the filament and the lower rim of the Wehnelt opening satisfying the relation 0.4D H S 0.8D where D is the diameter of the opening in the Wehnelt electrode and the surface of the Wehnelt electrode near the opening being substantially cylindrical and the surface about the opening facing the filament being substantially cone-shaped and the height b of said cylindrical surface satisfying the relation 02D 5 b s 0.8D.
Claims (3)
1. In a thermal emission type electron gun comprising a filament for emitting thermal electrons, an anode arranged to face said filament, a voltage source for supplying high potential difference between said filament and anode, a Wehnelt electrode having an opening therein through which said electrons pass, said Wehnelt electrode arranged between said filament and anode, the side of said Wehnelt electrode facing the anode being convex, and means for supplying a potential to maintain the Wehnelt electrode at a negative potential with respect to the filament, the improvement comprising the distance H between the tip of the filament and the lower rim of the Wehnelt opening satisfying the relation 0.4D < OR = H < OR = 0.8D where D is the diameter of the opening the Wehnelt electrode, and the surface of the Wehnelt electrode near the opening being substantially cylindrical and the surface about the opening facing the filament being substantially cone-shaped and the angle Beta of said coneshaped portion with the axis of the cylindrical opening satisfying the relation 30* < OR = Beta < OR = 90*.
2. The improvement in a thermal emission type electron gun as set forth in claim 1 in which the height b of said cylindrical surface satisfies the relation 0.2D < or = b < or = 0.8D.
3. In a thermal emission type electron gun comprising a filament for emitting thermal electrons, an anode arranged to face said filament, a voltage source for supplying high potential different between said filament and anode, a Wehnelt electrode having an opening therein through which said electrons pass, said Wehnelt electrode arranged between said filament and anode, the side of said Wehnelt electrode facing the anode being convex, and means for supplying a potential to maintain the Wehnelt electrode at a negative potential with respect to the filament, the improvement comprising the distance H between the tip of the filament and the lower rim of the Wehnelt opening satisfying the relation 0.4D < or = H < or = 0.8D where D is the diameter of the opening in the Wehnelt electrode and the surface of the Wehnelt electrode near the opening being substantially cylindrical and the surface about the opening facing the filament being substantially cone-shaped and the height b of said cylindrical surface satisfying the relation 0.2D < or = b < or = 0.8D.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP47083891A JPS58148B2 (en) | 1972-08-22 | 1972-08-22 | Denshijiyuu |
Publications (1)
Publication Number | Publication Date |
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US3890533A true US3890533A (en) | 1975-06-17 |
Family
ID=13815254
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US377812A Expired - Lifetime US3890533A (en) | 1972-08-22 | 1973-07-09 | Thermal emission type electron gun |
Country Status (4)
Country | Link |
---|---|
US (1) | US3890533A (en) |
JP (1) | JPS58148B2 (en) |
FR (1) | FR2197230B1 (en) |
GB (1) | GB1430964A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3150848A1 (en) * | 1980-12-27 | 1982-08-19 | Denki Kagaku Kogyo K.K., Tokyo | ELECTRONIC CANNON FOR GREAT BRIGHTNESS |
US4695773A (en) * | 1981-12-18 | 1987-09-22 | The Perkin-Elmer Corporation | Field emission gun electrode geometry for improved focus stability |
US4910442A (en) * | 1985-01-25 | 1990-03-20 | National Institute For Researches In Inorganic Materials | Field emission type electron gun |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5075765A (en) * | 1973-11-06 | 1975-06-21 | ||
JPS576790B2 (en) * | 1974-05-13 | 1982-02-06 | ||
JPH0648619B2 (en) * | 1989-04-20 | 1994-06-22 | 北海道電力株式会社 | Electron gun device |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3141993A (en) * | 1959-12-24 | 1964-07-21 | Zeiss Jena Veb Carl | Very fine beam electron gun |
US3185882A (en) * | 1961-01-16 | 1965-05-25 | Eitel Mccullough Inc | Electron discharge device including cathode-focus electrode assemblies therefor |
US3225248A (en) * | 1961-05-27 | 1965-12-21 | United Aircraft Corp | Device for producing a high-intensity beam of charge carriers of small aperture |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL51299C (en) * | 1938-07-16 | |||
US3383536A (en) * | 1964-09-22 | 1968-05-14 | Westinghouse Electric Corp | Cathode ray tube generating circular beam by lineal filament critically spaced from circular aperture |
-
1972
- 1972-08-22 JP JP47083891A patent/JPS58148B2/en not_active Expired
-
1973
- 1973-06-28 GB GB3093573A patent/GB1430964A/en not_active Expired
- 1973-07-09 US US377812A patent/US3890533A/en not_active Expired - Lifetime
- 1973-08-21 FR FR7330340A patent/FR2197230B1/fr not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3141993A (en) * | 1959-12-24 | 1964-07-21 | Zeiss Jena Veb Carl | Very fine beam electron gun |
US3185882A (en) * | 1961-01-16 | 1965-05-25 | Eitel Mccullough Inc | Electron discharge device including cathode-focus electrode assemblies therefor |
US3225248A (en) * | 1961-05-27 | 1965-12-21 | United Aircraft Corp | Device for producing a high-intensity beam of charge carriers of small aperture |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3150848A1 (en) * | 1980-12-27 | 1982-08-19 | Denki Kagaku Kogyo K.K., Tokyo | ELECTRONIC CANNON FOR GREAT BRIGHTNESS |
US4695773A (en) * | 1981-12-18 | 1987-09-22 | The Perkin-Elmer Corporation | Field emission gun electrode geometry for improved focus stability |
US4910442A (en) * | 1985-01-25 | 1990-03-20 | National Institute For Researches In Inorganic Materials | Field emission type electron gun |
Also Published As
Publication number | Publication date |
---|---|
FR2197230A1 (en) | 1974-03-22 |
FR2197230B1 (en) | 1976-09-17 |
DE2336851A1 (en) | 1974-03-21 |
GB1430964A (en) | 1976-04-07 |
JPS58148B2 (en) | 1983-01-05 |
JPS4940475A (en) | 1974-04-16 |
DE2336851B2 (en) | 1976-08-12 |
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