US3883411A - Electrodeposition of thick nickel deposits on permanent cathode blanks - Google Patents
Electrodeposition of thick nickel deposits on permanent cathode blanks Download PDFInfo
- Publication number
- US3883411A US3883411A US459883A US45988374A US3883411A US 3883411 A US3883411 A US 3883411A US 459883 A US459883 A US 459883A US 45988374 A US45988374 A US 45988374A US 3883411 A US3883411 A US 3883411A
- Authority
- US
- United States
- Prior art keywords
- nickel
- mandrel
- cathode
- deposit
- electrodeposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 133
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 60
- 238000004070 electrodeposition Methods 0.000 title claims description 16
- 238000004299 exfoliation Methods 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 23
- 230000003746 surface roughness Effects 0.000 claims abstract description 11
- 230000008021 deposition Effects 0.000 claims abstract description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- 238000005363 electrowinning Methods 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052719 titanium Inorganic materials 0.000 claims description 13
- 239000010935 stainless steel Substances 0.000 claims description 10
- 229910001220 stainless steel Inorganic materials 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 230000002596 correlated effect Effects 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 239000003792 electrolyte Substances 0.000 description 25
- 206010040844 Skin exfoliation Diseases 0.000 description 21
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 238000005488 sandblasting Methods 0.000 description 10
- 239000002659 electrodeposit Substances 0.000 description 9
- 239000004576 sand Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 206010014415 Electrolyte depletion Diseases 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000005270 abrasive blasting Methods 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000978 Pb alloy Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- -1 i.e. Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
Definitions
- the cathode blanks are made of chromium-containing iron base alloy, i.e., stainless steel or titanium or aluminum (including alloys rich in titanium and aluminum which behave electrochemically in a manner similar to titanium or aluminum).
- each individual cathode blank is a sheet about one millimeter thick and about one meter square.
- the edges of the cathode blank are masked, for example. with polyethelene shields or otherwise configured so as to prevent metal deposition at the edges and envclopment of the cathode blank by the deposited metal,
- the cathode blanks are placed in cells opposite anodes so that metal is deposited on both sides of the blank simultaneously to equalize stresses on the blank.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA192,114A CA1036536A (en) | 1974-02-08 | 1974-02-08 | Electrodeposition of thick nickel deposits on permanent cathode blanks |
Publications (1)
Publication Number | Publication Date |
---|---|
US3883411A true US3883411A (en) | 1975-05-13 |
Family
ID=4099130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US459883A Expired - Lifetime US3883411A (en) | 1974-02-08 | 1974-04-11 | Electrodeposition of thick nickel deposits on permanent cathode blanks |
Country Status (11)
Country | Link |
---|---|
US (1) | US3883411A (en, 2012) |
JP (1) | JPS50109819A (en, 2012) |
CA (1) | CA1036536A (en, 2012) |
DE (1) | DE2504964A1 (en, 2012) |
FI (1) | FI72151C (en, 2012) |
FR (1) | FR2260634B1 (en, 2012) |
GB (1) | GB1489984A (en, 2012) |
NO (1) | NO143388C (en, 2012) |
SE (1) | SE406941B (en, 2012) |
ZA (1) | ZA75338B (en, 2012) |
ZM (1) | ZM1075A1 (en, 2012) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4097347A (en) * | 1976-08-23 | 1978-06-27 | Packer Elliot L | Electrolytic recovery of metals |
US4147597A (en) * | 1978-02-21 | 1979-04-03 | The International Nickel Company, Inc. | Method for producing electrolytic nickel in particulate forms under condition of high and variable internal stress |
US5256708A (en) * | 1991-07-22 | 1993-10-26 | Owens-Corning Fiberglas Technology, Inc. | Unsaturated polyester resin compositions containing compatible compounds having sulfur-containing substituents |
US5256709A (en) * | 1991-07-22 | 1993-10-26 | Owens-Corning Fiberglas Technology, Inc. | Unsaturated polyester resin compositions containing compatible compounds having aromatic substituents |
US20020189953A1 (en) * | 2000-06-30 | 2002-12-19 | Guangxin Wang | Method for processing metals |
WO2006094355A1 (en) * | 2005-03-09 | 2006-09-14 | Xstrata Queensland Limited | Stainless steel electrolytic plates |
CN104073842A (zh) * | 2011-10-13 | 2014-10-01 | 金川集团有限公司 | 一种电积、电解镍的阴极板 |
US20150167142A1 (en) * | 2013-12-16 | 2015-06-18 | Airbus Operations (Sas) | Method for treatment of two surfaces of two metal parts |
RU2566119C2 (ru) * | 2011-06-23 | 2015-10-20 | Оутотек Оюй | Постоянный катод и способ обработки поверхности постоянного катода |
CN113638008A (zh) * | 2021-09-14 | 2021-11-12 | 广西银亿新材料有限公司 | 一种无钠化制备电解镍厚板的方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS531603A (en) * | 1976-06-29 | 1978-01-09 | Asahi Glass Co Ltd | Pretreatment of cathode to be used at deposition of metal by electrolysis from solution containing metal salt |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2480771A (en) * | 1946-04-12 | 1949-08-30 | Int Nickel Co | Process for the electrolytic recovery of nickel |
US2536877A (en) * | 1947-10-17 | 1951-01-02 | Anaconda Copper Mining Co | Cathode |
US2597296A (en) * | 1948-10-01 | 1952-05-20 | Int Nickel Co | Forming starting sheets for electrolytic refining of nickel |
US2646396A (en) * | 1949-03-17 | 1953-07-21 | Reginald S Dean | Method of making electroformed articles |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4846514A (en, 2012) * | 1971-10-18 | 1973-07-03 |
-
1974
- 1974-02-08 CA CA192,114A patent/CA1036536A/en not_active Expired
- 1974-04-11 US US459883A patent/US3883411A/en not_active Expired - Lifetime
-
1975
- 1975-01-16 JP JP50007394A patent/JPS50109819A/ja active Pending
- 1975-01-17 ZA ZA00750338A patent/ZA75338B/xx unknown
- 1975-01-21 FI FI750139A patent/FI72151C/fi not_active IP Right Cessation
- 1975-01-24 GB GB3123/75A patent/GB1489984A/en not_active Expired
- 1975-02-03 ZM ZM10/75A patent/ZM1075A1/xx unknown
- 1975-02-06 DE DE19752504964 patent/DE2504964A1/de not_active Withdrawn
- 1975-02-06 NO NO750387A patent/NO143388C/no unknown
- 1975-02-07 SE SE7501366A patent/SE406941B/xx unknown
- 1975-02-07 FR FR7503849A patent/FR2260634B1/fr not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2480771A (en) * | 1946-04-12 | 1949-08-30 | Int Nickel Co | Process for the electrolytic recovery of nickel |
US2536877A (en) * | 1947-10-17 | 1951-01-02 | Anaconda Copper Mining Co | Cathode |
US2597296A (en) * | 1948-10-01 | 1952-05-20 | Int Nickel Co | Forming starting sheets for electrolytic refining of nickel |
US2646396A (en) * | 1949-03-17 | 1953-07-21 | Reginald S Dean | Method of making electroformed articles |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4097347A (en) * | 1976-08-23 | 1978-06-27 | Packer Elliot L | Electrolytic recovery of metals |
US4147597A (en) * | 1978-02-21 | 1979-04-03 | The International Nickel Company, Inc. | Method for producing electrolytic nickel in particulate forms under condition of high and variable internal stress |
US5256708A (en) * | 1991-07-22 | 1993-10-26 | Owens-Corning Fiberglas Technology, Inc. | Unsaturated polyester resin compositions containing compatible compounds having sulfur-containing substituents |
US5256709A (en) * | 1991-07-22 | 1993-10-26 | Owens-Corning Fiberglas Technology, Inc. | Unsaturated polyester resin compositions containing compatible compounds having aromatic substituents |
US20020189953A1 (en) * | 2000-06-30 | 2002-12-19 | Guangxin Wang | Method for processing metals |
US20020189937A1 (en) * | 2000-06-30 | 2002-12-19 | Guangxin Wang | Apparatus for processing metals |
US6818119B2 (en) * | 2000-06-30 | 2004-11-16 | Honeywell International Inc. | Method for processing metals |
US6843896B2 (en) | 2000-06-30 | 2005-01-18 | Honeywell International Inc. | Apparatus for processing metals |
US20080095655A1 (en) * | 2005-03-09 | 2008-04-24 | Webb Wayne K | Stainless steel electrolytic plates |
US8133366B2 (en) | 2005-03-09 | 2012-03-13 | Xstrata Queensland Limited | Stainless steel electrolytic plates |
WO2006094355A1 (en) * | 2005-03-09 | 2006-09-14 | Xstrata Queensland Limited | Stainless steel electrolytic plates |
EA011667B1 (ru) * | 2005-03-09 | 2009-04-28 | Эксстрэйта Квинсленд Лимитед | Электролитические пластины из нержавеющей стали |
US7807028B2 (en) | 2005-03-09 | 2010-10-05 | Xstrata Queensland Limited | Stainless steel electrolytic plates |
US7807029B2 (en) | 2005-03-09 | 2010-10-05 | Xstrata Queensland Limited | Stainless steel electrolytic plates |
US20100314255A1 (en) * | 2005-03-09 | 2010-12-16 | Xstrata Queensland Limited | Stainless steel electrolytic plates |
US20060201586A1 (en) * | 2005-03-09 | 2006-09-14 | Xstrata Queensland Limited | Stainless steel electrolytic plates |
EP2886680A1 (en) * | 2005-03-09 | 2015-06-24 | XSTRATA Queensland Limited | Stainless steel electrolytic plates |
RU2566119C2 (ru) * | 2011-06-23 | 2015-10-20 | Оутотек Оюй | Постоянный катод и способ обработки поверхности постоянного катода |
CN104073842A (zh) * | 2011-10-13 | 2014-10-01 | 金川集团有限公司 | 一种电积、电解镍的阴极板 |
US20150167142A1 (en) * | 2013-12-16 | 2015-06-18 | Airbus Operations (Sas) | Method for treatment of two surfaces of two metal parts |
US10053761B2 (en) * | 2013-12-16 | 2018-08-21 | Airbus Operations Sas | Method for treatment of two surfaces of two metal parts |
CN113638008A (zh) * | 2021-09-14 | 2021-11-12 | 广西银亿新材料有限公司 | 一种无钠化制备电解镍厚板的方法 |
Also Published As
Publication number | Publication date |
---|---|
JPS50109819A (en, 2012) | 1975-08-29 |
SE406941B (sv) | 1979-03-05 |
NO750387L (en, 2012) | 1975-08-11 |
SE7501366L (en, 2012) | 1975-08-11 |
FR2260634B1 (en, 2012) | 1979-09-28 |
CA1036536A (en) | 1978-08-15 |
AU7742375A (en) | 1976-07-22 |
GB1489984A (en) | 1977-10-26 |
FI72151C (fi) | 1987-04-13 |
NO143388B (no) | 1980-10-20 |
NO143388C (no) | 1981-01-28 |
FR2260634A1 (en, 2012) | 1975-09-05 |
DE2504964A1 (de) | 1975-08-14 |
ZM1075A1 (en) | 1976-12-21 |
FI750139A7 (en, 2012) | 1975-08-09 |
FI72151B (fi) | 1986-12-31 |
ZA75338B (en) | 1976-01-28 |
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