US3860427A - Quick-processable light-sensitive color photographic material - Google Patents

Quick-processable light-sensitive color photographic material Download PDF

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Publication number
US3860427A
US3860427A US318857A US31885772A US3860427A US 3860427 A US3860427 A US 3860427A US 318857 A US318857 A US 318857A US 31885772 A US31885772 A US 31885772A US 3860427 A US3860427 A US 3860427A
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United States
Prior art keywords
coupler
gelatin
photographic material
color photographic
quick
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Expired - Lifetime
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US318857A
Inventor
Shunji Matsuo
Shui Sato
Hidehiko Ishikawa
Shinichi Nakamura
Masahiko Taguchi
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Konica Minolta Inc
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Konica Minolta Inc
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Assigned to KONICA CORPORATION reassignment KONICA CORPORATION RELEASED BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: KONISAIROKU PHOTO INDUSTRY CO., LTD.
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/91Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
    • G03C1/915Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means using mechanical or physical means therefor, e.g. corona
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/775Photosensitive materials characterised by the base or auxiliary layers the base being of paper
    • G03C1/79Macromolecular coatings or impregnations therefor, e.g. varnishes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/164Rapid access processing

Definitions

  • ABSTRACT A light-sensitive silver halide photographic material which comprises a polyethylene film base which has been subjected to a corona discharge treatment having coated thereon a coupler-containing gelatin emulsion layer having a coupler-to-gelatin ratio in parts by weight of from about 1:3 to 1:5.
  • This invention relates to a light-sensitive color photographic material for quick processing which does not form opaque due to blushing.
  • a polyolefin laminate paper or a polyolefin or polyester film base which has been subjected to corona discharge treatment, is used as a support to make it possible to obtain a light-sensitive color photographic material reduced in amount of gelatin used which not only can be prevented from the above-mentioned fogging phenomenon but also can be subjected to quick processing.
  • the present invention provides a lightsensitive silver halide color photographic material which not only is protected from the above-mentioned fogging phenomenon but also is well permeated with processing solutions to make the quick processing thereof possible, is scarcely curled, and can be quickly dried.
  • the amount of gelatin used may be reduced to such an extent that the ratio of coupler to gelatin is in the range from 1:5 to 1:3. In case the coupler to gelatin ratio becomes less CONHR than 1:3, there are some cases where fog is formed.
  • the oil protect type coupler used in the present invention is represented by the general formula,
  • X is hydrogen, a halogen or a group splitting I off at the time of coupling; and A is a coupler residue having, for example, the formula,
  • the corona discharge treatment of the support used in the present invention may be carried out in such a manner that the support is moved at a rate of m/min., while applying a current of 0.75 A at an electric power 275 W, for example.
  • EXAMPLE 1 2 Grams of the exemplified coupler (27) was dissolved in a mixed solvent comprising 2 ml. of dibutyl phthalate and 6 ml. of ethyl acetate. The resulting solution was mixed with 6 ml. of a 5 percent aqueous solution of Alkanol B (a surface active agent produced by Du Pont) and ml. of a 5 percent inert gelatin solution, and the mixed solution was dispersed by means of a colloid mill to obtain a coupler dispersion. The thus obtained coupler dispersion was added to an emulsion prepared by use of 6 g. of silver nitrate and 6.5 g. of gelatin.
  • a mixed solvent comprising 2 ml. of dibutyl phthalate and 6 ml. of ethyl acetate.
  • Alkanol B a surface active agent produced by Du Pont
  • the emulsion was coated to a thickness of 3 p. on such support as shown in Table l, and was then dried to prepare a sample.
  • the sample was developed for 5 minutes, bleach-fixed for 2 minutes and water-washed for 2 minutes at 30C., and was then dried.
  • the developer and bleach-fixer used in this case were as follows:
  • EXAMPLE 2 The exemplified coupler (25) was added in the same manner as in Example 1 to a blue-sensitive emulsion in such a proportion that the coupler to gelatin ratio became 1:3. On the other hand, the exemplified coupler (l) was added in the same manner as in Example 1 to a red-sensitive emulsion in such a proportion that the coupler to gelatin ratio became 1:3. Subsequently, these two emulsions were successively coated on each of such supports as shown in Table 2 to prepare a sample.
  • Example 1 The coating was effected while forming an extremely thin gelatin layer between the resulting two lay- After heat and humidity resistance test
  • Sample Support I Baryta paper 2 Polyethylene laminate paper (subjected to corona discharge treatment) 3 Polyethylene sheet (subjected to corona discharge treatment) Foggcd Not fngged Not fogged EXAMPLE 3
  • the samples prepared in Example 1 were/subjected to development, stop-fixing, bleaching, fixing and water-washing treatments in this order, and then subjected to the same test as in Example I to obtain the same results as in Example I.
  • a light-sensitive silver halide color photographic material suitable for quick processing which comprises a support and, coated on said support, a couplercontaining photographic gelatin emulsion layer having a coupler-to-gelatin ratio in parts by weight of from about 1:3 to 1:5, said support having a polyethylene film base which has been subjected to a corona discharge treatment.

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)

Abstract

A light-sensitive silver halide photographic material which comprises a polyethylene film base which has been subjected to a corona discharge treatment having coated thereon a couplercontaining gelatin emulsion layer having a coupler-to-gelatin ratio in parts by weight of from about 1:3 to 1:5.

Description

United States Patent Matsuo et al.
[ Jan. 14, 1 975 QUlCK-PROCESSABLE LIGHT-SENSITIVE COLOR PHOTOGRAPHIC MATERIAL Inventors: Shunji Matsuo; Shui Sato, both of Tokyo; Hidehiko lshikawa, Odawara; Shinichi Nakamura, Odawara; Masahiko Taguchi, Odawara, all of Japan Assignee: Konishiroku Photo Industry Co.,
Ltd., Chuo-ku, Tokyo, Japan Filed: Dec. 27, 1972 Appl. No.: 318,857
Foreign Application Priority Data Dec. 28, 1971 Japan 46-002165 US. Cl 96/87 R, 96/48 QP, 96/56,
96/100 Int. Cl G03c 1/78 Field oi Search 96/48 QP, 87 R, 100
Primary Examiner -.I. Travis Brown Attorney, Agent, or Firm-Waters, Roditi, Schwartz & Nissen [57] ABSTRACT A light-sensitive silver halide photographic material which comprises a polyethylene film base which has been subjected to a corona discharge treatment having coated thereon a coupler-containing gelatin emulsion layer having a coupler-to-gelatin ratio in parts by weight of from about 1:3 to 1:5.
1 Claim, No Drawings QUICK-PROCESSABLE LIGHT-SENSITIVE COLOR PHOTOGRAPHIC MATERIAL This invention relates to a light-sensitive color photographic material for quick processing which does not form opaque due to blushing.
In recent years, quick processing of color photographic materials has been required. In order to make the quick processing possible, however, all the layers constituting the photographic materials, regardless of photosensitive layers and inter layers, are required to be made thinner, and thus should necessarily be reduced in amount of gelatin used. However, the reduction in amount of gelatin used results in such great disadvantages that the emulsions before and after coating are extremely deteriorated in stability and the resulting films are not uniform in thickness. This tendency is more marked in the case where an oil protect type coupler is used than in the case where an alkali dispersion type (Fischers type) or bucket type coupler is used. When the amount of gelatin is reduced in the case where an oil protect type coupler is used, the surface of film formed after coating and drying of the emulsion is gradually covered with deposits to bring about a fogging phenomenon. This phenomenon is particularly marked when quick processing is carried out at an elevated temperature of 27C. or more. The said phenomenon is not or scarcely brought about in case a Fischers type or bucket type coupler is used. In the case where an oil protect type coupler is used to carry out oil protect dispersion (which comprises dissolving a coupler in a high boiling solvent and then dispersing the resulting solution in a gelatin emulsion), therefore, it is preferable that the amount of gelatin used is increased to overcome the above-mentioned disadvantages. However, if the amount of gelatin is increased, the resulting photographic material is naturally degraded in quick processability.
In the present invention, a polyolefin laminate paper or a polyolefin or polyester film base, which has been subjected to corona discharge treatment, is used as a support to make it possible to obtain a light-sensitive color photographic material reduced in amount of gelatin used which not only can be prevented from the above-mentioned fogging phenomenon but also can be subjected to quick processing.
That is, the present invention provides a lightsensitive silver halide color photographic material which not only is protected from the above-mentioned fogging phenomenon but also is well permeated with processing solutions to make the quick processing thereof possible, is scarcely curled, and can be quickly dried.
According to the present invention, the amount of gelatin used may be reduced to such an extent that the ratio of coupler to gelatin is in the range from 1:5 to 1:3. In case the coupler to gelatin ratio becomes less CONHR than 1:3, there are some cases where fog is formed.
The oil protect type coupler used in the present invention is represented by the general formula,
wherein X is hydrogen, a halogen or a group splitting I off at the time of coupling; and A is a coupler residue having, for example, the formula,
z NHCOR l y or k"-COCHCONH-R"' (II) (III) (3) couucn cnc n The corona discharge treatment of the support used in the present invention may be carried out in such a manner that the support is moved at a rate of m/min., while applying a current of 0.75 A at an electric power 275 W, for example.
The present invention is illustrated below with reference to examples.
EXAMPLE 1 2 Grams of the exemplified coupler (27) was dissolved in a mixed solvent comprising 2 ml. of dibutyl phthalate and 6 ml. of ethyl acetate. The resulting solution was mixed with 6 ml. of a 5 percent aqueous solution of Alkanol B (a surface active agent produced by Du Pont) and ml. of a 5 percent inert gelatin solution, and the mixed solution was dispersed by means of a colloid mill to obtain a coupler dispersion. The thus obtained coupler dispersion was added to an emulsion prepared by use of 6 g. of silver nitrate and 6.5 g. of gelatin. Subsequently, the emulsion was coated to a thickness of 3 p. on such support as shown in Table l, and was then dried to prepare a sample. The sample was developed for 5 minutes, bleach-fixed for 2 minutes and water-washed for 2 minutes at 30C., and was then dried. The developer and bleach-fixer used in this case were as follows:
Developer:
N-Ethyl-N-B-methanesulfonamideothyl- 3-methyl-4-aminoaniline sulfate Anhydrous sodium sulfite Benzyl alcohol Sodium carbonate (monohydrate) 5 Potassium bromide Sodium hydroxide Pure water to make Ethylenediaminetetraacetate sodium iron salt Ammonium thiocyanate Anhydrous sodium sulfite Ammonium thiosulfite Ethylenediaminetetraacetate tetrasodium salt Pure water to make The thus treated sample was subjected for 144 hours I Table 1 After heat and humidity resistance test Sample Support ers and on the upper-most layer. The thus prepared sample was subjected to the same test as in Example 1. The results obtained were as set forth in Table 2.
Table 2 Fogged Not fogged Not fogged Somewhat fogged As is clear from Table l, the samples 2 and 3 according to the present invention formed no fog, whereas the control samples 1 and 4 formed fog.
EXAMPLE 2 The exemplified coupler (25) was added in the same manner as in Example 1 to a blue-sensitive emulsion in such a proportion that the coupler to gelatin ratio became 1:3. On the other hand, the exemplified coupler (l) was added in the same manner as in Example 1 to a red-sensitive emulsion in such a proportion that the coupler to gelatin ratio became 1:3. Subsequently, these two emulsions were successively coated on each of such supports as shown in Table 2 to prepare a sample. The coating was effected while forming an extremely thin gelatin layer between the resulting two lay- After heat and humidity resistance test Sample Support I Baryta paper 2 Polyethylene laminate paper (subjected to corona discharge treatment) 3 Polyethylene sheet (subjected to corona discharge treatment) Foggcd Not fngged Not fogged EXAMPLE 3 The samples prepared in Example 1 were/subjected to development, stop-fixing, bleaching, fixing and water-washing treatments in this order, and then subjected to the same test as in Example I to obtain the same results as in Example I.
What we claim is:
l. A light-sensitive silver halide color photographic material suitable for quick processing, which comprises a support and, coated on said support, a couplercontaining photographic gelatin emulsion layer having a coupler-to-gelatin ratio in parts by weight of from about 1:3 to 1:5, said support having a polyethylene film base which has been subjected to a corona discharge treatment.

Claims (1)

1. A LIGHT-SENSITIVE SILVER HALIDE COLOR PHOTOGRAPHIC MATERIAL SUITABLE FOR QUICK PROCESSING, WHICH COMPRISES A SUPPORT AND, COATED ON SAID SUPPORT, A COUPLER-CONTAINING PHOTOGRAPHIC GELATIN EMULSION LAYER HAVING A COUPLER-TO-GELATIN RATIO IN PARTS BY WEIGHT OF FROM ABOUT 1:3 TO 1:5, SAID SUPPORT HAVING A POLYETHYLENE FILM BASE WHICH HAS BEEN SUBJECTED TO A CORONA DISCHARGE TREATMENT.
US318857A 1971-12-28 1972-12-27 Quick-processable light-sensitive color photographic material Expired - Lifetime US3860427A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4055685A (en) * 1975-04-30 1977-10-25 Agfa-Gevaert Aktiengesellschaft Process for the improvement of the adhesion of photographic layers to a film web by means of a corona treatment
US4167414A (en) * 1978-09-28 1979-09-11 E. I. Dupont De Nemours And Company Reflective opaque polyester film base support for inverse transfer negative emulsions
US4267202A (en) * 1978-06-09 1981-05-12 Kansai Paint Co., Ltd. Method for modifying the surface properties of polymer substrates
US5425980A (en) * 1994-02-22 1995-06-20 Eastman Kodak Company Use of glow discharge treatment to promote adhesion of aqueous coats to substrate
EP0699954A2 (en) 1994-09-01 1996-03-06 Eastman Kodak Company Near atmospheric pressure treatment of polymers using helium discharges
US5618659A (en) * 1995-03-01 1997-04-08 Eastman Kodak Company Photographic element containing a nitrogen glow-discharge treated polyester substrate
EP0790525A2 (en) 1996-02-13 1997-08-20 Eastman Kodak Company Atmospheric pressure glow discharge treatment of polymeric supports to promote adhesion for photographic applications
US5789145A (en) * 1996-07-23 1998-08-04 Eastman Kodak Company Atmospheric pressure glow discharge treatment of base material for photographic applications

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5313413A (en) * 1976-07-23 1978-02-07 Mitsubishi Paper Mills Ltd Color photographic photosensitive material
DE2759100A1 (en) * 1977-12-30 1979-07-05 Agfa Gevaert Ag PROCESS FOR CURING COLOR PHOTOGRAPHIC SILVER HALOGENIDE EMULSION COATINGS
JPS60211995A (en) * 1984-04-06 1985-10-24 ダイセル化学工業株式会社 Method of forming electrode pattern
AU599573B2 (en) * 1984-08-20 1990-07-26 Konishiroku Photo Industry Co., Ltd. Method of processing light-sensitive silver halide color photographic material

Citations (6)

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US1660826A (en) * 1926-04-01 1928-02-28 Inecto Inc Method of dyeing fur
US3201250A (en) * 1959-01-12 1965-08-17 Eastman Kodak Co Dimensionally stable gelatincontaining film product
US3328167A (en) * 1959-08-10 1967-06-27 Minnesota Mining & Mfg Copy-paper
US3411908A (en) * 1964-03-10 1968-11-19 Eastman Kodak Co Photographic paper base
US3630742A (en) * 1969-10-16 1971-12-28 Eastman Kodak Co Polymeric photographic supports
US3697305A (en) * 1969-12-08 1972-10-10 Fuji Photo Film Co Ltd Method for producing a photographic element

Family Cites Families (3)

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Publication number Priority date Publication date Assignee Title
US3448000A (en) * 1964-06-10 1969-06-03 Int Paper Co Coated paper and method of producing the same
US3582333A (en) * 1968-04-08 1971-06-01 Eastman Kodak Co Method for reducing color fog in color emulsions coated on electron bombarded supports
US3582238A (en) * 1969-04-30 1971-06-01 Verbol J Devine Down hole hydraulic pump

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1660826A (en) * 1926-04-01 1928-02-28 Inecto Inc Method of dyeing fur
US3201250A (en) * 1959-01-12 1965-08-17 Eastman Kodak Co Dimensionally stable gelatincontaining film product
US3328167A (en) * 1959-08-10 1967-06-27 Minnesota Mining & Mfg Copy-paper
US3411908A (en) * 1964-03-10 1968-11-19 Eastman Kodak Co Photographic paper base
US3630742A (en) * 1969-10-16 1971-12-28 Eastman Kodak Co Polymeric photographic supports
US3697305A (en) * 1969-12-08 1972-10-10 Fuji Photo Film Co Ltd Method for producing a photographic element

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4055685A (en) * 1975-04-30 1977-10-25 Agfa-Gevaert Aktiengesellschaft Process for the improvement of the adhesion of photographic layers to a film web by means of a corona treatment
US4267202A (en) * 1978-06-09 1981-05-12 Kansai Paint Co., Ltd. Method for modifying the surface properties of polymer substrates
US4167414A (en) * 1978-09-28 1979-09-11 E. I. Dupont De Nemours And Company Reflective opaque polyester film base support for inverse transfer negative emulsions
US5576164A (en) * 1994-02-22 1996-11-19 Eastman Kodak Company Photographic element having a polyester substrate with an oxygen modified surface region
US5425980A (en) * 1994-02-22 1995-06-20 Eastman Kodak Company Use of glow discharge treatment to promote adhesion of aqueous coats to substrate
US5582921A (en) * 1994-02-22 1996-12-10 Eastman Kodak Company Use of glow discharge treatment to promote adhesion of aqueous coatings to substrate
US5538841A (en) * 1994-02-22 1996-07-23 Eastman Kodak Company Use of glow discharge treatment to promote adhesion of aqueous coatings to substrate
US5558843A (en) * 1994-09-01 1996-09-24 Eastman Kodak Company Near atmospheric pressure treatment of polymers using helium discharges
EP0699954A2 (en) 1994-09-01 1996-03-06 Eastman Kodak Company Near atmospheric pressure treatment of polymers using helium discharges
US5767469A (en) * 1994-09-01 1998-06-16 Eastman Kodak Company Near atmospheric pressure treatment of polymers using helium discharges
US5618659A (en) * 1995-03-01 1997-04-08 Eastman Kodak Company Photographic element containing a nitrogen glow-discharge treated polyester substrate
EP0790525A2 (en) 1996-02-13 1997-08-20 Eastman Kodak Company Atmospheric pressure glow discharge treatment of polymeric supports to promote adhesion for photographic applications
US5714308A (en) * 1996-02-13 1998-02-03 Eastman Kodak Company Atmospheric pressure glow discharge treatment of polymeric supports to promote adhesion for photographic applications
US5789145A (en) * 1996-07-23 1998-08-04 Eastman Kodak Company Atmospheric pressure glow discharge treatment of base material for photographic applications

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GB1395409A (en) 1975-05-29
DE2263863A1 (en) 1973-07-05
JPS4873146A (en) 1973-10-02

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Owner name: KONICA CORPORATION, JAPAN

Free format text: RELEASED BY SECURED PARTY;ASSIGNOR:KONISAIROKU PHOTO INDUSTRY CO., LTD.;REEL/FRAME:005159/0302

Effective date: 19871021