US3853503A - Energy absorber for laser pyrolysis - Google Patents
Energy absorber for laser pyrolysis Download PDFInfo
- Publication number
- US3853503A US3853503A US00366810A US36681073A US3853503A US 3853503 A US3853503 A US 3853503A US 00366810 A US00366810 A US 00366810A US 36681073 A US36681073 A US 36681073A US 3853503 A US3853503 A US 3853503A
- Authority
- US
- United States
- Prior art keywords
- sample
- laser
- absorber
- pyrolysis
- energy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/44—Sample treatment involving radiation, e.g. heat
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
- G01N2030/125—Preparation by evaporation pyrolising
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/25—Chemistry: analytical and immunological testing including sample preparation
- Y10T436/25875—Gaseous sample or with change of physical state
Definitions
- ABSTRACT 52 us. 01. 55/67, 23/232 c Solid and liquid Samples are Prepared analysis by 51 1m. (:1 B01d 15/08 gas'liquid chwmawgraphy Via laser-induced vaporiza- [58] Field of Search 5 5 /67, 197; 23,230 PC, tion and/or molecular fragmentation by contacting the 23/232 C, 253 PC; 219/121 L 121 LM sample with a powdered metal selected from the group consisting of iron, copper, gold, and tantalum 56] References Cited previous to subjecting same to a laser beam for pyroly- UNITED STATES PATENTS 3,475,131 10/1969 Keulemans 23/230 PC 2 Claims, N0 Drawings 1 ENERGY ABSORBER FOR LASER PYROLYSIS BACKGROUND OF THE'INVENTION This invention relates to analysis of solid or liquid materials by chromatography via laser-induced vaporization and/or molecular fragmentation. More specifically
- Gas-liquid chromatography generally involves injection of a slug of sample vapor to be analyzed into a flowing stream of inert gas, known as carrier gas.
- carrier gas inert gas
- the stream containing the slug of sample vapor is then passed to a separation zone wherein it contacts a partitioning agent which is usually coated on a particulate solid support.
- the partitioning agent often a liquid or a waxy or resinous solid, is chosen to exhibit varying degrees of affinity for the various components of the sample vapor, with the result that the emerging carrier gas stream contains zones of separated sample components.
- Another object of this invention is to provide an improved chromatographic analysis method. Another object of the invention is to provide an improved method for preparing a sample for chromatographic analysis via laser energy pyrolysis which will result in a less complex, more reproducible, or more selective result. Other objects, aspects, and the several advantages of the present invention will be come apparent upon a further reading of this disclosure and the appended claims.
- the energy absorbing material absorb energy from the laser beam, convert it to heat and subsequently transfer the heat to the sample material as efficiently as possible.
- the absorber should not cause side reactions which alter the amounts or types of products upon pyrolysis.
- the absorber of the present invention should be in intimate contact with the sample material, yet free passage of the gaseous products of pyrolysis should be allowed. Therefore, an
- ideal material should be an inert, finely divided material which is a good absorber of laser beam wavelengths.
- iron, copper, gold, and tantalum meet the above-described criteria and are particularly good energy absorbers.
- Preferable results have been obtained with iron powder which is a readily available and inexpensive material. It is also black and inert in the environment in which it is to be utilized. It is not a strong catalyst and is readily available in pure form.
- the sample In the operation of the present invention, the sample needs no further preparation than simply being pressed down onto a bed of elemental metal powder. No melting of the sample is required.
- the elemental metals of the present invention When using the elemental metals of the present invention, the relative amounts of fragment products are the same when the sample is pyrolyzed with them as they are when pyrolyzed without them.
- the elemental metals of the present invention absorb energy from any of the laser beams presently available on the market.
- the present invention provides the art with the unique ability to pyrolyze any sample via laser energy and compare the results with those obtained from any other sample regardless of the transparency of the samples. This ability was heretofore inavailable to workers in the art.
- the products of pyrolysis should be dependent only on the sample material itself and not on the particular energy absorber utilized.
- an energy absorber would be chosen which would react with the sample to produce a pyrolysis fragment product which could be easily identified and/or measured and would be characteristic of some particular structure or other characteristic of the sample material.
- the present invention provides such a method through the utilization of the elemental powders of same.
- the mean ratios were them compared using the Student T statistic.
- the number of degrees of freedom was four and the value of the Student T statistic was 2.776 for a 5 percent probability error ((1). Therefore, in the examples, if the calculated T value is greater than 2.776 or less than 2.776, the ratio means were said to be different with one chance in 20 of being in error.
- Table I illustrates a comparison of ratio means for the sample material pyrolyzed with iron and without absorber. Under the above described criteria, none of the samples were found to be different.
- Table III illustrates a comparison of acetyleneethylene ratios for various polymers pyrolyzed with carbon and with iron. In all runs, the acetyleneethylene ratio was much larger when carbon was used.
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
Solid and liquid samples are prepared for analysis by gas-liquid chromatography via laser-induced vaporization and/or molecular fragmentation by contacting the sample with a powdered metal selected from the group consisting of iron, copper, gold, and tantalum previous to subjecting same to a laser beam for pyrolysis.
Description
States Patent 1191 Folmer, Jr. Dec. 10, 1974 ENERGY ABSORBER FOR LASER 3,491,512 1/1970 Tirnmins et al. 55/67 PYROLYSIS 3,511,029 5/1970 Azarraga et al. 55/67 [75] Inventor: Orville F. Folmer, Jr., Ponca City, OTHER PUBLICATIONS Okla. Gas Chromatography Abstracts 1972: 740. Laser Py- 73 A C ml C P rolysis Gas Chromatography., Folmer, O. F. from Ss'gm "g g Anal. Chem. 43 (8) 1057-1065 1971 [22] Filed: June 1973 Primary Examiner-John Adee [2]] App], N0.: 366,810
. [57] ABSTRACT 52 us. 01. 55/67, 23/232 c Solid and liquid Samples are Prepared analysis by 51 1m. (:1 B01d 15/08 gas'liquid chwmawgraphy Via laser-induced vaporiza- [58] Field of Search 5 5 /67, 197; 23,230 PC, tion and/or molecular fragmentation by contacting the 23/232 C, 253 PC; 219/121 L 121 LM sample with a powdered metal selected from the group consisting of iron, copper, gold, and tantalum 56] References Cited previous to subjecting same to a laser beam for pyroly- UNITED STATES PATENTS 3,475,131 10/1969 Keulemans 23/230 PC 2 Claims, N0 Drawings 1 ENERGY ABSORBER FOR LASER PYROLYSIS BACKGROUND OF THE'INVENTION This invention relates to analysis of solid or liquid materials by chromatography via laser-induced vaporization and/or molecular fragmentation. More specifically, the invention relates to the preparation of such materials for laser beam pyrolysis by contacting a portion thereof with a powdered metal selected from the group consisting of iron, copper, gold, and tantalum.
The use of chromatography as an analytical tool has been increasing greatly, and the methods and apparatus available have been improving rapidly. Gas-liquid chromatography generally involves injection of a slug of sample vapor to be analyzed into a flowing stream of inert gas, known as carrier gas. The stream containing the slug of sample vapor is then passed to a separation zone wherein it contacts a partitioning agent which is usually coated on a particulate solid support. The partitioning agent, often a liquid or a waxy or resinous solid, is chosen to exhibit varying degrees of affinity for the various components of the sample vapor, with the result that the emerging carrier gas stream contains zones of separated sample components. Detection of the shape and size of such component zones, as by measuring the thermal conductivity of the emerging gas stream, completes the analysis. Comparison of the zone or peak size, shape, and sequence with those of known components under the same conditions permits the interpretation as to component'identity and even quantity. It is obvious, however, that this analytical technique requires that the sample be in gas or vapor form. Materials not readily volatilized, such as liquids or solids, have been analyzed chromatographically by pyrolyzing or thermal disintegrating the sample molecule into gaseous fragments and separating the fragments into peaks. The resulting peak trace is useful either by actually identifying the chemical species responsible for each peak or by comparison of the trace shape to' that of known material analogous to fingerprinting or voice printing.
In US. Pat. No. 3,51 1,029, it is disclosed that one of the most advantageous means of pyrolyzing solid and liquid material for chromatographic analysis is by bombarding them with laser energy. However, a very significant problem arose in the use of laser beams to pyrolysis samples because some substances were found to be transparent to the wavelength of a laser beam. These transparent materials were found to either not pyrolyze at all, or give very erratic results which were useless for subsequent analysis.
Various attempts have been made to solve this problem found in the utilization of laser energy. One wellknown method is to mix powdered carbon with the sample material and another is to apply a layer of the sample material to a cobalt glass surface. Both of these previous attempts have exhibited certain disadvantages. Among the more significant of these are: first, in regard to powdered carbon, for usable results, the carbon must be intimately mixed with the sample. This requires melting or grinding of the sample, or both, in order to adequately mix same in the carbon which is very difficult to accomplish with some materials and impossible with others. Another disadvantage in using carbon and of great significance is the fact that samples mixed with carbon give different relative amounts of fragment products upon pyrolysis with laser energy.
The relative amounts of these fragment compounds vary with the different concentrations of carbon in the sample. Therefore, in order to meaningfully compare two samples mixed with carbon, both must have the same percentage of carbon added before pyrolysis. This is true even if one of the samples is of the opaque type which could be run without carbon as an energy absorber. In regard to the cobalt glass method, it requires that the sample be softened and pressed against the glass where the previous discussed problem of melting the sample would again arise. Further, even though it is reported that the cobalt glass method is satisfactory with a ruby laser, it will not operate with a neodymiumglass laser.
It is accordingly an object of this invention to provide an improved chromatographic analysis method. Another object of the invention is to provide an improved method for preparing a sample for chromatographic analysis via laser energy pyrolysis which will result in a less complex, more reproducible, or more selective result. Other objects, aspects, and the several advantages of the present invention will be come apparent upon a further reading of this disclosure and the appended claims.
It has now been found that the objects of the present invention can be achieved, in -a process for preparing a material for subsequent analysis by pyrolyzing a portion thereof with a laser beam, by contacting said material with a powdered metal selected from the group consistingof iron, copper, gold, and tantalum prior to pyrolyzing same.
It is essential for achieving the objects of the present invention that the energy absorbing material absorb energy from the laser beam, convert it to heat and subsequently transfer the heat to the sample material as efficiently as possible. Further, the absorber should not cause side reactions which alter the amounts or types of products upon pyrolysis. Thus, the absorber of the present invention should be in intimate contact with the sample material, yet free passage of the gaseous products of pyrolysis should be allowed. Therefore, an
ideal material should be an inert, finely divided material which is a good absorber of laser beam wavelengths.
It has been found that iron, copper, gold, and tantalum, meet the above-described criteria and are particularly good energy absorbers. Preferable" results have been obtained with iron powder which is a readily available and inexpensive material. It is also black and inert in the environment in which it is to be utilized. It is not a strong catalyst and is readily available in pure form.
In the operation of the present invention, the sample needs no further preparation than simply being pressed down onto a bed of elemental metal powder. No melting of the sample is required. When using the elemental metals of the present invention, the relative amounts of fragment products are the same when the sample is pyrolyzed with them as they are when pyrolyzed without them. The elemental metals of the present invention absorb energy from any of the laser beams presently available on the market.
Through the utilization of the metals of the present invention, a sample material which is opaque enough to be pyrolyzed itself can be compared to a sample material which must be pyrolyzed on metal powder because of its transparency. Therefore, the present invention provides the art with the unique ability to pyrolyze any sample via laser energy and compare the results with those obtained from any other sample regardless of the transparency of the samples. This ability was heretofore inavailable to workers in the art.
In order to achieve good reproducible results for subsequent analysis, the products of pyrolysis should be dependent only on the sample material itself and not on the particular energy absorber utilized. Ideally for a given sample material, an energy absorber would be chosen which would react with the sample to produce a pyrolysis fragment product which could be easily identified and/or measured and would be characteristic of some particular structure or other characteristic of the sample material. The present invention provides such a method through the utilization of the elemental powders of same.
The use of the elemental metal powders of the present invention rather than compounds is critical in achieving good results, because there is sufficient energy from a laser beam to cause dissociation of compounds into very reactive component parts (i.e., radicals and ions) which would react to produce products which would not be produced were that compound not present.
The following comperative examples are shown to illustrate the improved results of the effective operation of the improved process described herein over previously utilized methods. In the following examples, Eastman Imperial green polyethylene was utilized as the sample material because it can be pyrolyzed reproducibly without an energy absorber, yet it is transparent enough to show any effects from reaction with an absorber. The laser used for pyrolysis of the sample materials was a neodymium-glass laser, the rod being 3 /i-inch long and A-inch in diameter, pumped by a xenon flash tube, and had an energy output of about 2.80 joules with a pulse duration of about 400 ,usec. In each of the runs, the largest peak was set to equal 100 and each of the other peaks calculated as the ratio the largest peak. The mean ratios were them compared using the Student T statistic. In this case, by comparing two sets of triplicates, the number of degrees of freedom was four and the value of the Student T statistic was 2.776 for a 5 percent probability error ((1). Therefore, in the examples, if the calculated T value is greater than 2.776 or less than 2.776, the ratio means were said to be different with one chance in 20 of being in error.
Table I illustrates a comparison of ratio means for the sample material pyrolyzed with iron and without absorber. Under the above described criteria, none of the samples were found to be different.
TABLE I Comparison of Fragmentation Patterns of Green Imperial Polyethylene Pyrolyzed without Absorber and on Iron Powder TABLE I-Continued Comparison of Fragmentation Patterns of Green Imperial Polyethylene Pyrolyzed without Absorber and on Iron Powder Retention MEAN PEAK RATIOS Student Time. Sec. Iron Powder Without Absorber TValue Table 11 illustrates a comparison of the sample mate rial pyrolyzed with powdered carbon and without absorber. Six of the 1 1 ratios are different under the previously described criteria.
TABLE 11 Comparison of Fragmentation Patterns of Green Imperial Polyethylene Pyrolyzed Without Absorber and on Powdered Coke The greater amount of acetylene produced when powdered coke is utilized as the absorber is a very distinctive difference from the results obtained with iron powder.
Table III illustrates a comparison of acetyleneethylene ratios for various polymers pyrolyzed with carbon and with iron. In all runs, the acetyleneethylene ratio was much larger when carbon was used.
TABLE III Acetylene-Ethylene Ratios C H C H Ratios Iron powder Carbon powder Low MW Polyethylene 1.12 5.18
High MW Polyethylene 3.53 16.1 Green Imperial Polyethylene 0.67 2.95 Silicone Rubber 1.30 8.40"
Polyvinyl Chloride 1.29 9.90"
"These were single runs. "The C l-l lllkl ratio for this sample pyrolyzed without absorber is 0.84.
is transparent to the wavelength of a laser beam.
Claims (2)
1. IN A METHOD FOR PREPARING A MATERILA FOR GAS-LIQUID CHROMATOGRAPHIC ANALYSIS BY PYROLYZING A PORTION THEREOF WITH A LASER BEAM, THE IMPROVEMENT COMPRISES PYROLYZING SAID MATERIAL WHILE IN INTIMATE CONTACT WITH A POWDERED METAL SELECTED FROM THE GROUP CONSISTING OF IRON, COPPER, GOLD AND TANTALUM.
2. The improvement of claim 1 wherein said material is transparent to the wavelength of a laser beam.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00366810A US3853503A (en) | 1973-06-04 | 1973-06-04 | Energy absorber for laser pyrolysis |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00366810A US3853503A (en) | 1973-06-04 | 1973-06-04 | Energy absorber for laser pyrolysis |
Publications (1)
Publication Number | Publication Date |
---|---|
US3853503A true US3853503A (en) | 1974-12-10 |
Family
ID=23444626
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00366810A Expired - Lifetime US3853503A (en) | 1973-06-04 | 1973-06-04 | Energy absorber for laser pyrolysis |
Country Status (1)
Country | Link |
---|---|
US (1) | US3853503A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1985004283A1 (en) * | 1984-03-15 | 1985-09-26 | Prutec Limited | Introduction of samples into a mass spectrometer |
US7004909B1 (en) | 2001-03-19 | 2006-02-28 | Pranalytica, Inc. | Diagnostic method for high sensitivity detection of component concentrations in human gas emissions |
US20060219937A1 (en) * | 2005-04-04 | 2006-10-05 | Ada Technologies, Inc. | Stroboscopic liberation and methods of use |
US20070056388A1 (en) * | 2002-11-21 | 2007-03-15 | Ada Technologies, Inc. | Stroboscopic liberation and methods of use |
US8363215B2 (en) | 2007-01-25 | 2013-01-29 | Ada Technologies, Inc. | Methods for employing stroboscopic signal amplification and surface enhanced raman spectroscopy for enhanced trace chemical detection |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3475131A (en) * | 1964-09-11 | 1969-10-28 | Perkin Elmer Ltd | Pyrolysis apparatus |
US3491512A (en) * | 1968-05-10 | 1970-01-27 | Abcor Inc | Method and apparatus for introducing samples into a gas chromatographic column |
US3511029A (en) * | 1969-07-08 | 1970-05-12 | Continental Oil Co | Method and apparatus for chromatography sample preparation |
-
1973
- 1973-06-04 US US00366810A patent/US3853503A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3475131A (en) * | 1964-09-11 | 1969-10-28 | Perkin Elmer Ltd | Pyrolysis apparatus |
US3491512A (en) * | 1968-05-10 | 1970-01-27 | Abcor Inc | Method and apparatus for introducing samples into a gas chromatographic column |
US3511029A (en) * | 1969-07-08 | 1970-05-12 | Continental Oil Co | Method and apparatus for chromatography sample preparation |
Non-Patent Citations (1)
Title |
---|
Gas Chromatography Abstracts 1972: 740. Laser Pyrolysis Gas Chromatography., Folmer, O. F. from Anal. Chem. 43 (8) 1057 1065 (1971). * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1985004283A1 (en) * | 1984-03-15 | 1985-09-26 | Prutec Limited | Introduction of samples into a mass spectrometer |
US7004909B1 (en) | 2001-03-19 | 2006-02-28 | Pranalytica, Inc. | Diagnostic method for high sensitivity detection of component concentrations in human gas emissions |
US20060217626A1 (en) * | 2001-03-19 | 2006-09-28 | Patel C Kumar N | Diagnostic method for high sensitivity detection of component concentrations in human gas emissions |
US8360974B2 (en) | 2001-03-19 | 2013-01-29 | Pranalytica, Inc. | Diagnostic method for high sensitivity detection of component concentrations in human gas emissions |
US20070056388A1 (en) * | 2002-11-21 | 2007-03-15 | Ada Technologies, Inc. | Stroboscopic liberation and methods of use |
US7833802B2 (en) * | 2002-11-21 | 2010-11-16 | Ada Technologies, Inc. | Stroboscopic liberation and methods of use |
US20060219937A1 (en) * | 2005-04-04 | 2006-10-05 | Ada Technologies, Inc. | Stroboscopic liberation and methods of use |
US8377711B2 (en) | 2005-04-04 | 2013-02-19 | Ada Technologies, Inc. | Stroboscopic liberation and methods of use |
US8363215B2 (en) | 2007-01-25 | 2013-01-29 | Ada Technologies, Inc. | Methods for employing stroboscopic signal amplification and surface enhanced raman spectroscopy for enhanced trace chemical detection |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3304159A (en) | Gas chromatographic analysis method for c, h, and n content in solid organic compounds | |
US3853503A (en) | Energy absorber for laser pyrolysis | |
Tsuge et al. | Vertical furnace-type sampling device for pyrolysis gas chromatography | |
Trussell et al. | An Overview of the Analysis off Trace Organics in Water | |
CN110646535B (en) | Non-targeted screening and quantitative detection method for multiple pesticide residues in tobacco | |
US4302422A (en) | System and process for total gaseous nonmethane organic analysis | |
Stuart et al. | Some aspects of the degradation of epoxide resins | |
Lee et al. | Separation of Isotopic Position Isomers of Tritium-Labeled Olefins by Gas Chromatography. | |
Bartlett et al. | Paper chromatography of organic mercury compounds | |
CN109900849A (en) | The determination method and system of organic additive degradation effect in a kind of gel phase | |
US3511029A (en) | Method and apparatus for chromatography sample preparation | |
Tanaka et al. | Ion-exclusin chromatography of the ammonium ion on an anion-exchange resin | |
Berens et al. | Analysis for vinyl chloride in PVC powders by head‐space gas chromatography | |
Murphy et al. | Analysis of Apollo 11 lunar samples by chromatography and mass spectrometry: Pyrolysis products, hydrocarbons, sulfur amino acids | |
Oguchi et al. | Polymer analysis using pyrolysis‐GC‐FTIR‐MS and GC‐AED | |
Uchytil | Thin-layer and high-speed liquid chromatography of the derivatives of 1, 4-phenylenediamine | |
Berezkin et al. | The development of pyrolysis gas chromatography | |
CA1143963A (en) | Microwave discharge degradation of organics for analysis | |
Juvet Jr et al. | Photolytic Degradation as a Means of Organic Structural Determination | |
Wang | Determination of polyacrylamide in polyvinyl alcohol by pyrolysis-gas chromatography with atomic emission detection | |
Nagy et al. | An evaluation of pyrolytic techniques with regard to the Apollo 11, 12 and 14 lunar samples analyses | |
US3578410A (en) | Ammonia detection,following ultraviolet radiation | |
Lyle et al. | Pyrolysis—gas chromatography of separated zones on thin-layer chromatograms: II. Application to the determination of some water-soluble vitamins | |
Rosset et al. | Analysis of nitrogen compounds in light petroleum products by ion exchange followed by gas chromatography with a hall detector and mass spectrometry | |
SU1033181A1 (en) | Method of treating polymeric sorbent for chromatography |