US3849840A - Method for imparting pressure sensitive adhesion to velvet type fasteners - Google Patents

Method for imparting pressure sensitive adhesion to velvet type fasteners Download PDF

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Publication number
US3849840A
US3849840A US00399114A US39911473A US3849840A US 3849840 A US3849840 A US 3849840A US 00399114 A US00399114 A US 00399114A US 39911473 A US39911473 A US 39911473A US 3849840 A US3849840 A US 3849840A
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United States
Prior art keywords
acid
weight
velvet type
parts
pressure sensitive
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US00399114A
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English (en)
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F Yamada
Y Fukuda
T Uraya
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Kanebo Ltd
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Kanebo Ltd
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    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0023—Woven or knitted fasteners
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S273/00—Amusement devices: games
    • Y10S273/30—Hooked pile fabric fastener
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T24/00—Buckles, buttons, clasps, etc.
    • Y10T24/27—Buckles, buttons, clasps, etc. including readily dissociable fastener having numerous, protruding, unitary filaments randomly interlocking with, and simultaneously moving towards, mating structure [e.g., hook-loop type fastener]
    • Y10T24/275—Buckles, buttons, clasps, etc. including readily dissociable fastener having numerous, protruding, unitary filaments randomly interlocking with, and simultaneously moving towards, mating structure [e.g., hook-loop type fastener] with feature facilitating or causing attachment of filaments to mounting surface
    • Y10T24/2758—Thermal or adhesive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T24/00—Buckles, buttons, clasps, etc.
    • Y10T24/27—Buckles, buttons, clasps, etc. including readily dissociable fastener having numerous, protruding, unitary filaments randomly interlocking with, and simultaneously moving towards, mating structure [e.g., hook-loop type fastener]
    • Y10T24/2775—Buckles, buttons, clasps, etc. including readily dissociable fastener having numerous, protruding, unitary filaments randomly interlocking with, and simultaneously moving towards, mating structure [e.g., hook-loop type fastener] having opposed structure formed from distinct filaments of diverse shape to those mating therewith
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24008—Structurally defined web or sheet [e.g., overall dimension, etc.] including fastener for attaching to external surface
    • Y10T428/24017—Hook or barb

Definitions

  • the present invention relates to a method for imparting pressure sensitive adhesion to velvet type fasteners. More particularly, it relates to a method for imparting pressure sensitive adhesion to the respective back surfaces of the male and female pieces of velvet type fasteners.
  • velvet type fastener or fastener used herein refers to the above-mentioned two kinds of fasteners.
  • the male and female pieces have been secured on woven and knitted fabrics by sewing.
  • it has been difficult to carry out such a sewing operation owing to the presence of the engagingelements of the 'male and female pieces and, in addition, the engaging elements of these pieces have many times been partly sewn in by the sewing thread.
  • the inevitable consequences of these problems have been lower securing efficiency and poorer fastening effect.
  • For thick or stiff materials such as carpet, natural or synthetic wood and shaped resinous articles, it has been very difficult or impossible to effect the above-mentioned sewing operation.
  • the principal object of the present invention is to provide a method for imparting pressure sensitive adhesion which enables a velvet type fastener to be secured easily and quickly to the material on which the fastener is used said fastener and possessing excellent adhesive strength and creep resistance in practical use.
  • the object of the present invention can be accomplished by applying an adhesive composition of the nature disclosed hereinafter to the velvet type fastener.
  • the method according to the present invention is a novel method for imparting pressure sensitive adhesion to velvet type fasteners, comprising applying to the re spective back surfaces of the male and female pieces of composition consisting of: parts by weight of a polymer, containing at least 65 percent mol of an ester of acrylic acid or methacrylic acid and from 0.2 to '5 parts by weight of a glycidyl ester of an unsaturated organic acid; from 0.5 to 5 parts by weight of a zirconyl salt of organic acid, and; from 0.01 to 0.1 part by weight of a volatile acid addition salt of an organic amine.
  • the method of the present invention can suitably impart superior and stable adhesive strength and creep resistance to the velvet type fastener.
  • the velvet type fastener to which the adhesive composition according to the present invention has been applied can be secured easily and quickly to the desired materials.
  • the velvet type fasteners composed of synthetic fi bers and usable for the method ofthe present invention include fasteners composed of the fibers such as polyamides, polyesters and polyolefins.
  • fasteners composed of the fibers such as polyamides, polyesters and polyolefins.
  • woven or knitted multifilament yarn fabrics of polyamides or polyesters may be suitably used for the loop elements and the base fabric of the.
  • female piece and woven or knitted fabrics of densified polyethylene, polypropylene or polyvinyl chloride as well as fabrics of polyamides or polyesters maybe suitably used for the base fabric of the male piece, because of their desirable properties such as tensile strength and elasticity.
  • a monofilament yarn of polyamides, polypropylene polyethylene, polyoxymethylene or the like may be suitably used in view of the necessity of excellent elasticity and rigidity.
  • the polyamides are preferably utilized for the loop elements of the female piece and the base fabrics of the male and female pieces and also polypropylene is preferably utilized for the engaging male elements of the male piece.
  • the ester of the acrylic acid or methacrylic acid usable for the adhesive composition according to the present invention includes acrylic and methacrylic esters having at least two carbon atoms in the alkyl moimonomer such as vinyl acetate, methyl methacrylate and styrene may be used.
  • the copolymers may optionally comprise unsaturated acids such as acrylic acid, methacrylic acid, crotonic acid and itaconic acid.
  • the acrylic or methacrylic ester mainly participate in the pressure sensitive adhesion. When the ester is present in an amount of less than 65 percent mol in the polymer, the pressure sensitive adhesion of the fastener with the adhesive composition applied is undesirably reduced.
  • the monomers copolymerized with the above ester participate in yielding hard polymers. The monomers serve to control the tacking, improve the cohesive adhesion and also to elevate the creep resistance, of the adhesive composition.
  • the glycidyl ester of unsaturated organic acid which is a component of and usable for the polymer in the pressure sensitive adhesive composition may be the glycidyl esters of acids such as acrylic acid, methacrylic acid and crotonic acid. These glycidyl esters impart creep resistance and thermal stability to the adhesive composition and are suitably used in an amount of from 0.2 to 5 parts based on the weight of 100 parts of the polymer.
  • the glycidyl esters also react with a zirconyl compound as described hereinafter.
  • the glycidyl esters are used in an amount of less than 0.2 parts, it is difficult to obtain appropriate cohesive adhesion and creep resistance, while when the glycidyl esters are used in an amount of more than. 5 parts, the stability of the composition and the durability of the pressure sensitivity are reduced, more or less depending on the amount of the added zirconyl compound.
  • the most important features of the method of the present invention are that a specific amount of the zirconyl salt of an organic acid is added in the composition, and that the volatile acid addition salt of the organic amine is also used as an accelerator for the reaction of the zirconyl compound with the polymer.
  • the resinous composition comprising the polymer containing mainly the acrylic or methacrylic ester and partly the glycidyl ester of unsaturated organic acid, but not comprising the above-mentioned zirconyl compound and amine compound, is known as a reactive acrylic resin.
  • These known types 'of resinous compositions are generally utilized in the flocking of textile articles.
  • these known compositions cannot be utilized for the purpose of the present invention, because they are inferior in adhesion to the fastener, in durability of the adhesion and also in creep resistance.
  • the zirconyl salts of the organic acid usable for the present invention include, for example, zirconyl acetate, zirconyl p'ropionate, zirconyl caprate and zirconyl stearate. Particularly, zirconyl salts of higher fatty acids are preferably used.
  • the suitable amount of the zirconyl salts is from 0.5 to 5 parts based on the weight of 100 parts of the polymer, while they are preferably used in a range between 70 and 120 percent, based on the weight of the glycidyl ester of unsaturated organic acid. In the case where the zirconyl compounds are used in an amount of less than 0.5 part based on the weight of 100 parts of the polymer.
  • the zirconyl compounds when used in an amount of more than 5 parts, based on the weight of parts of the polymer, durability of pressure sensitivity of the composition becomes inferior and the obtained fastener feels unpreferably hard.
  • the use of the zirconyl compounds in an amount of more than percent based on the weight of the glycidyl ester does not, to a large extent, increase the. effects for adhesion or creep resistance and, therefore, is uneconomical.
  • the adhesive composition used in the present method is stable under acidic conditions and that the composition is in the acidic pH range owing to the presence of the acid addition salt of the organic amine.
  • the composition is very stable at a pH below 6, preferably at a pH below 5.
  • the volatile acid addition salts of the organic amines include, for example, the salts of mono-, dior triethanolamine or mono-, dior tripropanolamine with acids, readily and relatively volatilized by heat, such as hydrochloric acid and acetic acid.
  • These acid addition salts exhibit acidic properties and can control the cohesive adhesion and the durability of adhesion of the resultant composition as mentioned above. Therefore, the composition containing the acid addition salts is slowly reacted while volatilizing the acid after being coated onto the fastener and produces excellent adhesion and creep resistance. When the composition is heated after being coated, it rapidly volatilizes the acid and also produces the above-mentioned effects.
  • the composition according to this invention may optionally comprise a small amount of hydrochloric acid, acetic acid or the like.
  • the acid, addition salts of organic amine are suitably used in an amount of from 0.0] to 0.1 part based on the weight of 100 parts of the polymer.
  • the amount of the acid addition salts is less than 0.01 part, the increasing of the cohesive adhesion of the composition cannot be obtained; while when the amount of the acid addition salts is more than 0.1 part, the pressure sensitivity of the adhesion is lost and the stability during. storage becomes slightly inferior.
  • the adhesive compositions usable for the method of the present invention may be prepared as follows.
  • the polymer is firstly prepared by known emulsion polymerization or solution polymerization procedures.
  • the emulsion polymerization may be effected by reacting the desired monomers as mentioned hereinbefore, at a reflux temperature or in a redox system for from 2 to l0 hours, in the presence of from 0.0l to 1 percent, based on the weight of the monomer, of a watersoluble initiator such as hydrogen peroxide, potassium persulfate and ammonium perborate andfrom 0.1 to l0 percent, based on the weight of the monomer, of an emulsifying and dispersing agent.
  • a watersoluble initiator such as hydrogen peroxide, potassium persulfate and ammonium perborate andfrom 0.1 to l0 percent, based on the weight of the monomer, of an emulsifying and dispersing agent.
  • the emulsifying and dispersing agent may be, for example, nonionic'surface active compounds such as a polyoxyethylene alkyl ether, a polyoxyethylene alkylphenyl ether and polyoxyethylene sorbitan monoalkylate; anionic surface active compounds such as sodium dodecylbenzenesulfonate and sodium lauryl sulfate; cationic surface active compounds such as polyoxyethylene laurylamine and lauryl trimethyl-ammonium chloride, and; watersoluble polymers such as polyvinyl alcohol, hydroxyethyl cellulose and carboxymethyl cellulose. These may be used alone or as a mixture. In the above reaction, nonionic'surface active compounds such as a polyoxyethylene alkyl ether, a polyoxyethylene alkylphenyl ether and polyoxyethylene sorbitan monoalkylate; anionic surface active compounds such as sodium dodecylbenzenesulfonate and sodium lauryl sulfate; cationic surface active compounds such as
  • a solution or dispersion of the volatile acid addition salt of organic amine in water, alcohols, ethers, ketones or other hydrocarbons are added and stirred so as to be uniformly mixed.
  • the desired adhesive composition can be obtained.
  • the adhesive composition this obtained may then be coated on the respective back surfaces of the male and female pieces of a velvet type fastener by conventional coating methods suchas doctor coating, roll coating and spray coating.
  • the suitable amount of the coated composition is in general between 80 and 400 g, preferable l20 and 250 g, based on the dry weight of the composition, per square meter.
  • the coated surfaces of the fastener may then be secured to a releasing paper.
  • the composition may. be coated onto a releasing paper and, after semi-drying, the coated surface of the releasing paper is secured to the respective back surfaces of the two pieces of a velvet type fastener.
  • the composition which may be sandwi'ched between the fastener and the releasing paper is dried at a temperature below 80C, preferablybelow 60C.
  • the fastener thus obtained and the releasing paper may then be rolled up together.
  • FIG. 1 is a graph showing ductility (heat flowability) of the composition heat treated at various temperatures plotted against the pH of the original composition prior to the drying and the heat treatment;
  • FIG. 2 is a partial section view of the male and the female piece of the fastener obtained by the method of the present invention.
  • ductility (heat flowability) of the composition dried at room temperature and heat treated at the indicated temperatures is plotted against the pH of the original composition prior to the drying and the heat treatment.
  • the composition was prepared by adding 2 parts by weight of zirconyl stearate to 250 parts by weight of a 40 percent emulsion of a polymer of 86 parts by weight of acrylic acid butyl ester, 12
  • a velvet type fastener according to the present invention comprises a male piece 1 and a female piece 2.
  • the male piece 1 is composed of a base fabric 3, a plurality of engaging elements 4 projecting perpendicular to the face surface of the base fabric 3, a pressure sensitive adhesive composition layer 5 covering the back surface of thebase fabric 3 and a releasing paper 6 secured provisionally to the composition layer 5.
  • Each engaging element is provided with a laterally expanded cap formed at the tip portion.
  • the engaging element may also be in a hook form.
  • the female piece 2 is composed of a base fabric 7, a plurality of upright loops 8 projecting from the face surface of the base fabric 7, a pressure sensitive adhesive composition 9 covering the back surface of the base fabric 7 and a releasing paper 10 secured provisionally to the composition layer 9.
  • excellent pressure sensitive adhesion can be imparted to velvet type fasteners composed of synthetic fibers.
  • the fasteners can beeasily and quickly secured by hand pressure to various materials such as textile fabrics, wood, synthetic resin articles, glass and metals. That is, they can be secured even to materials to which velvet type fasteners could not previously be secured by sewing or heat melting.
  • the velvet type fasteners imparted with pressure sensitive adhesion by the method of the present invention possess satisfactorily good strength of adhesion and creep resistance. On repeated usages, the fasteners do not tend to lose their adhesion to the secured materials and, also the adhesive composition does not tend to lose its adhesion to the surfaces of the fastener to which it is applied.
  • the adhesion of -the applied composition becomes greater with the aging thereof.
  • the method of the present invention can be effectively applied'to the fasteners wherein the base fabric of the male piece is composed of polyamides and the male elements thereof are composed of polypropylene.
  • the male elements composed of polypropylene do not slip out of the base fabric, a common trouble with fasteners to which conventional adhesive compositions are applied.
  • the fasteners obtained by the present method are preferably heated with an iron, hot air or the like which imparts more effective adhesion, creep resistance and wash fastness of the adhesion.
  • the heat treatment is particularly effective in the case where the fasteners are to be exposed to heavy loads or to repeated washings.
  • the fasteners advantageously have desirable softness and flexiblity even after the heat treatment, and these properties are particularly preferable when the fasteners are utilized for clothing.
  • fasteners obtained by the present method that it is not necessary to apply backings to the fasteners.
  • the fasteners possess sufficient adhesion and flexiblity as well as good dimensional stability, and these properties are advantageously improved by the abovementioned heat treatment. Therefore, backings are not needed except in the case where high dimensional stability is desired.
  • Comrylate, 3 parts of methacrylic acid glycidyl ester, 80 parts of methyl alcohol and 1 part of benzoyl peroxide were added to a three neck glass flask of 2 liters, provided with a stirrer, a reflux condenser and a thermometer, and heated at 60 to 65C for 8 hours with stirring.
  • a translucent viscous polymer solution was obtained. Then, 45 parts of 10 percent solution of zirconyl caprate in a mixture of 50 parts of ethyl acetate with 100 parts of toluole and 0.004 part of monoethanolamine hydrochloride were added to the polymer solution and the resulting mixture was stirred until whole mixture became satisfactorily homogeneous.
  • the obtained composition was of a pH of 5.7, a resin concentration of about 35 percent and pared with this, backings with thermoseuin resi a viscosity of 3,000 centi-poises.
  • the composition was such as aminoplasts or modified thermosetting resins.
  • the base fabrics of the male and female pieces utilized for clothing such as underwear, as well as for were composed of Nylon 6 yarn of 210 denier/l2 filainterior decorations and industrial materials, because ments and the engaging elements of the male piece of their excellent adhesive strength and flexiblity and were mp d O a polypropylene OrlOfilament yarn their easily detachable fastening. of 0.2 millimeter diameter, the top of the element being.
  • the friction strength was deterh e the e eurfaee of h Secured plam fabric mined by tensile test .with a Schoppers tensile tester for 40 wlth an mhmtamed at 130 Then these Spec" a sample of the fastener having an adherence dimenh were subleeted to the tests or Strength of adhe' Sion (-6.25 (25 X 25 The Stripping Strength sion, creep resistance and strength of adhesion on rewas determined at an angle of 180C by a SchOpper-S peated fastemngof the male and female pieces.
  • the retensile tester for a sample of the fastener of 2 cm width Suhs are Showh m Table and 10 cm length.
  • Monogen fatty alcohol ester, Daiichi Kogyo Seiyaku Kabushiki Kaisha, Japan
  • sitions was coated onto the releasing-surface of a silicone coated releasing paper by roll coating and the coated paper was dried at C for 6 minutes. Then, the adhesive composition thus coated was secured to the respective back surfaces of the male and female pieces of a velvet type fastener of the same type as in Example I, together with the releasing paper. and further dried at 40C for 10 minutes.0ne piece of the fastener was secured to a plywood consisting of l'auan and the other piece of the fastener was secured to a twill woven fabric composed of Nylon 6. by pressing'each piece by hand, and these were heated by hot air at 120C for l5 minutes. The obtained specimens were subjected to the tests as in Example 1. The results are shown in Table ll.
  • a method for imparting pressure sensitive adhesion to velvet type fasteners comprising applying to the respective back surfaces of the male and female pieces of a velvet type fastener composed of synthetic fibers, a composition consisting of: 100 parts by weight of a polymer, containing at least 65 percent mol of an ester of an acrylic acid or methacrylic acid and from 0.2 to
  • composition is adjusted to a pH below 6,
  • an acid selected from hydrochloric acid and acetic acid preferably below 5, and optionally by adding an acid selected from hydrochloric acid and acetic acid.
  • ester of the acrylic acid or methacrylic acid is a member selected from the group consisting of ethyl acrylate, butyl methacrylate, butyl acrylate, 2- ethylhexyl acrylate and 2-ethylhexyl methacrylate.
  • a method for imparting pressure sensitive adhesion to velvet type fasteners wherein the polymer is mainly composed of a copolymer of an ester of acrylic acid or methacrylic acid a monomer selected from the group consisting of vinyl acetate, methyl methacrylate and styrene.
  • glycidyl ester of the unsaturated organic acid is a member selected from the group consisting of acrylic acid glycidyl ester, methacrylic acid glycidyl ester, and crotonic acid glycidyl ester.
  • zirconyl salt of organic acid is a member selected from the group consisting of zirconyl acetate, zirconyl caprate and zirconyl stearate.
  • the volatile acid addition salt of the organic amine is a salt the group consisting of selected from the salts of mono-, dior triethanolamine or mono-, dior tripropanolamine with hydrochloric acid and acetic acid.
  • a velvet type fastener composed of synthetic fibres which has applied to the respective back surfaces of the male and female pieces thereof a composition consisting of: parts by weight of a polymer, containing at least 65 percent mol of an ester of an acrylic acid or methacrylic acid and from 0.2 to 5 parts by weight of a glycidyl ester of an unsaturatedorganic acid; from 0.5 to 5 parts by weight of a zirconyl salt of an organic acid, and; from 0.01 to 0.1 part by weight of a volatile acid addition salt of an organic amine.

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  • Adhesives Or Adhesive Processes (AREA)
  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US00399114A 1972-09-26 1973-09-20 Method for imparting pressure sensitive adhesion to velvet type fasteners Expired - Lifetime US3849840A (en)

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Application Number Priority Date Filing Date Title
JP9693772A JPS5333887B2 (nl) 1972-09-26 1972-09-26

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US (1) US3849840A (nl)
JP (1) JPS5333887B2 (nl)
AU (1) AU476127B2 (nl)
CA (1) CA991923A (nl)
DK (1) DK139953B (nl)
FR (1) FR2199954B1 (nl)
GB (1) GB1441328A (nl)
IT (1) IT993425B (nl)
SE (1) SE409088B (nl)

Cited By (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3938805A (en) * 1973-07-24 1976-02-17 Kei Sakuma Golf accessory
US4489115A (en) * 1983-02-16 1984-12-18 Superturf, Inc. Synthetic turf seam system
US4646397A (en) * 1984-06-18 1987-03-03 Yoshida Kogyo K. K. Surface-type fastener
US4707893A (en) * 1985-05-08 1987-11-24 Kanebo Bell-Touch, Ltd. Fabric fastener
US4761318A (en) * 1985-04-15 1988-08-02 Minnesota Mining And Manufacturing Company Loop fastener portion with thermoplastic resin attaching and anchoring layer
US4884323A (en) * 1988-01-14 1989-12-05 Velcro Industries B. V. Quiet touch fastener attachment system
US4955113A (en) * 1987-11-04 1990-09-11 Kimberly-Clark Corporation Fastening means, apparatus, and methods
US4973326A (en) * 1987-11-30 1990-11-27 Minnesota Mining And Manufacturing Company Disposable diaper with improved fastener attachment
US5012764A (en) * 1990-07-26 1991-05-07 Minnesota Mining And Manufacturing Company Animal protective collar
US5097570A (en) * 1991-01-23 1992-03-24 Bruce Gershenson Fastening system
US5100400A (en) * 1989-11-17 1992-03-31 Minnesota Mining And Manufacturing Company Disposable diaper with thermoplastic material anchored hook fastener portion
US5399409A (en) * 1992-07-16 1995-03-21 Whiteman; Gaylen L. Tacking device for attaching to textured surfaces
US5505747A (en) * 1994-01-13 1996-04-09 Minnesota Mining And Manufacturing Company Method of making an abrasive article
US5515583A (en) * 1991-12-12 1996-05-14 Kuraray Co., Ltd. Mixed hook/loop separable fastener and process for its production
US5605729A (en) * 1993-04-16 1997-02-25 Minnesota Mining And Manufacturing Company Loop fastener material storage/dispensing assembly
US5611122A (en) * 1993-07-28 1997-03-18 Minnesota Mining And Manufacturing Interengaging fastener having reduced noise generation
US5614232A (en) * 1992-05-07 1997-03-25 Minnesota Mining And Manufacturing Method of making an interengaging fastener member
US5662853A (en) * 1993-08-05 1997-09-02 Minnesota Mining Manufacturing Company Affixation member for decorating or protecting structures and methods of making same
US5671512A (en) * 1993-07-30 1997-09-30 Minnesota Mining And Manufacturing Company Interengaging fastner having reduced engagement force
US5671511A (en) * 1993-08-25 1997-09-30 Minnesota Mining And Manufacturing Company Interengaging fastener member having fabric layer
US5691026A (en) * 1993-07-27 1997-11-25 Minnesota Mining And Manufacturing Company Fastener member with a dual purpose cover sheet
US5691027A (en) * 1993-07-27 1997-11-25 Minnesota Mining And Manufacturing Company Fastener with a dual purpose cover sheet
US5699593A (en) * 1996-08-30 1997-12-23 Minnesota Mining & Manufacturing Company Loop fastening material
US5713111A (en) * 1994-07-27 1998-02-03 Minnesota Mining And Manufacturing Company Method for making an interengaging fastener having reduced engagement force
US5725423A (en) * 1994-01-13 1998-03-10 Minnesota Mining And Manufacturing Company Abrading apparatus
WO1998011007A1 (es) * 1996-09-12 1998-03-19 Jorge Luis Leija Cordero Procedimiento para manejo de envases con las tapas
US5785784A (en) * 1994-01-13 1998-07-28 Minnesota Mining And Manufacturing Company Abrasive articles method of making same and abrading apparatus
US5852855A (en) * 1989-11-17 1998-12-29 Minnesota Mining And Manufacturing Company Disposable diaper with fastener
WO1999041440A1 (en) * 1998-02-13 1999-08-19 The Regents Of The University Of California Reinforced composites including bone-shaped short fibers
US6202264B1 (en) * 1998-03-06 2001-03-20 Ykk Corporation Surface fastener made of fiber and method for manufacturing the same
US6579161B1 (en) 1994-01-13 2003-06-17 3M Innovative Properties Company Abrasive article
US6637079B1 (en) * 1989-01-31 2003-10-28 The Procter & Gamble Company Multi-layer female component for refastenable fastening device and method of making the same
US20040231208A1 (en) * 2001-06-23 2004-11-25 Pitt John Dunlop Method and apparatus for displaying advertisements on a vehicle
US20050117819A1 (en) * 2003-12-02 2005-06-02 Kingsford Howard A. Packaging closures
US20060090386A1 (en) * 2004-10-28 2006-05-04 Agripa Holdings Limited Flexible frame and mutually engageable fastening means
US20060162269A1 (en) * 2003-01-30 2006-07-27 Pacione Joseph R Anchor sheet
US20060207141A1 (en) * 2002-02-12 2006-09-21 Agripa Limited Method and apparatus for displaying advertisements on a vehicle
US20070026181A1 (en) * 2003-02-28 2007-02-01 Velcro Industries Bv, A Curacao, Netherland Antilles Corporation Fastener tapes
US7394039B2 (en) 2006-03-10 2008-07-01 Fujitsu Component Limited Keyboard and membrane switch for keyboard
US8875356B2 (en) 2011-10-06 2014-11-04 Intercontinental Great Brands Llc Mechanical and adhesive based reclosable fasteners
US20180360169A1 (en) * 2015-12-14 2018-12-20 Teijin Frontier Co., Ltd. Hook and loop fastener and textile products
US20220355746A1 (en) * 2021-05-10 2022-11-10 Bayerische Motoren Werke Aktiengesellschaft Method for Producing a Trim Part, and a Trim Part

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62111410U (nl) * 1985-12-30 1987-07-16
US4776068A (en) * 1986-10-20 1988-10-11 Velcro Industries B. V. Quiet touch fastener material
GB2303566A (en) * 1995-07-21 1997-02-26 Ykk Europ Ltd Self-sdhesive fastener
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Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2739902A (en) * 1952-08-29 1956-03-27 Carlisle Chemical Works Drier compositions
US2739905A (en) * 1952-08-29 1956-03-27 Carlisle Chemical Works Zirconyl 2-ethylhexoate
US2773850A (en) * 1952-12-20 1956-12-11 Sherwin Williams Co Fortified emulsion paints containing a zirconyl compound
US2802847A (en) * 1951-08-02 1957-08-13 Nat Lead Co Basic zirconyl soaps and method for preparing the same
US3036101A (en) * 1959-03-26 1962-05-22 Magnesium Elektron Ltd Production of zirconium soaps
US3224419A (en) * 1961-12-13 1965-12-21 Combustion Eng Vapor generator with tangential firing arrangement
US3280059A (en) * 1964-12-11 1966-10-18 Carlisle Chemical Works Latex paints containing zirconyl salts of monocarboxylic acids
US3284383A (en) * 1961-12-29 1966-11-08 Union Carbide Corp Epoxide compositions
US3284423A (en) * 1963-12-20 1966-11-08 Monsanto Co Pressure-sensitive creep-resistant resin composition
US3419587A (en) * 1964-05-20 1968-12-31 Hardman & Holden Ltd Zirconium compounds
US3423764A (en) * 1965-09-14 1969-01-28 Carl E Cassling Garment anchor
US3499102A (en) * 1968-09-09 1970-03-03 George W Gillemot Protective cover and method of anchoring same to a supporting surface
US3563953A (en) * 1965-05-19 1971-02-16 Beiersdorf Ag Curable copolymer of an alkyl acrylate,a glycidyl acrylate or methacrylate and diketene
US3574019A (en) * 1966-10-07 1971-04-06 American Velcro Inc Method of making a laminated fastening device
US3579490A (en) * 1964-08-31 1971-05-18 Ashland Oil Inc Method of producing resins for use in adhesives
US3639504A (en) * 1967-07-17 1972-02-01 Sir Soc Italiana Resine Spa Process for preparing hardened polyester resins using mixtures of organic metal derivatives of vanadium and zirconium as accelerators
US3773580A (en) * 1971-07-27 1973-11-20 American Velcro Inc Bonding fastening members to a substrate
US3773589A (en) * 1971-11-26 1973-11-20 American Can Co Can body

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2802847A (en) * 1951-08-02 1957-08-13 Nat Lead Co Basic zirconyl soaps and method for preparing the same
US2739905A (en) * 1952-08-29 1956-03-27 Carlisle Chemical Works Zirconyl 2-ethylhexoate
US2739902A (en) * 1952-08-29 1956-03-27 Carlisle Chemical Works Drier compositions
US2773850A (en) * 1952-12-20 1956-12-11 Sherwin Williams Co Fortified emulsion paints containing a zirconyl compound
US3036101A (en) * 1959-03-26 1962-05-22 Magnesium Elektron Ltd Production of zirconium soaps
US3224419A (en) * 1961-12-13 1965-12-21 Combustion Eng Vapor generator with tangential firing arrangement
US3284383A (en) * 1961-12-29 1966-11-08 Union Carbide Corp Epoxide compositions
US3284423A (en) * 1963-12-20 1966-11-08 Monsanto Co Pressure-sensitive creep-resistant resin composition
US3419587A (en) * 1964-05-20 1968-12-31 Hardman & Holden Ltd Zirconium compounds
US3579490A (en) * 1964-08-31 1971-05-18 Ashland Oil Inc Method of producing resins for use in adhesives
US3280059A (en) * 1964-12-11 1966-10-18 Carlisle Chemical Works Latex paints containing zirconyl salts of monocarboxylic acids
US3563953A (en) * 1965-05-19 1971-02-16 Beiersdorf Ag Curable copolymer of an alkyl acrylate,a glycidyl acrylate or methacrylate and diketene
US3423764A (en) * 1965-09-14 1969-01-28 Carl E Cassling Garment anchor
US3574019A (en) * 1966-10-07 1971-04-06 American Velcro Inc Method of making a laminated fastening device
US3639504A (en) * 1967-07-17 1972-02-01 Sir Soc Italiana Resine Spa Process for preparing hardened polyester resins using mixtures of organic metal derivatives of vanadium and zirconium as accelerators
US3499102A (en) * 1968-09-09 1970-03-03 George W Gillemot Protective cover and method of anchoring same to a supporting surface
US3773580A (en) * 1971-07-27 1973-11-20 American Velcro Inc Bonding fastening members to a substrate
US3773589A (en) * 1971-11-26 1973-11-20 American Can Co Can body

Cited By (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3938805A (en) * 1973-07-24 1976-02-17 Kei Sakuma Golf accessory
US4489115A (en) * 1983-02-16 1984-12-18 Superturf, Inc. Synthetic turf seam system
US4646397A (en) * 1984-06-18 1987-03-03 Yoshida Kogyo K. K. Surface-type fastener
US4761318A (en) * 1985-04-15 1988-08-02 Minnesota Mining And Manufacturing Company Loop fastener portion with thermoplastic resin attaching and anchoring layer
US4707893A (en) * 1985-05-08 1987-11-24 Kanebo Bell-Touch, Ltd. Fabric fastener
US4955113A (en) * 1987-11-04 1990-09-11 Kimberly-Clark Corporation Fastening means, apparatus, and methods
US4973326A (en) * 1987-11-30 1990-11-27 Minnesota Mining And Manufacturing Company Disposable diaper with improved fastener attachment
US4884323A (en) * 1988-01-14 1989-12-05 Velcro Industries B. V. Quiet touch fastener attachment system
US6637079B1 (en) * 1989-01-31 2003-10-28 The Procter & Gamble Company Multi-layer female component for refastenable fastening device and method of making the same
US5639327A (en) * 1989-11-17 1997-06-17 Minnesota Mining And Manufacturing Company Disposable diaper with thermoplastic material anchored hook fastener portion
US5852855A (en) * 1989-11-17 1998-12-29 Minnesota Mining And Manufacturing Company Disposable diaper with fastener
US5100400A (en) * 1989-11-17 1992-03-31 Minnesota Mining And Manufacturing Company Disposable diaper with thermoplastic material anchored hook fastener portion
US5012764A (en) * 1990-07-26 1991-05-07 Minnesota Mining And Manufacturing Company Animal protective collar
WO1992012650A1 (en) * 1991-01-23 1992-08-06 Bruce Gershenson Fastening system
US5097570A (en) * 1991-01-23 1992-03-24 Bruce Gershenson Fastening system
US5515583A (en) * 1991-12-12 1996-05-14 Kuraray Co., Ltd. Mixed hook/loop separable fastener and process for its production
US5614232A (en) * 1992-05-07 1997-03-25 Minnesota Mining And Manufacturing Method of making an interengaging fastener member
US5399409A (en) * 1992-07-16 1995-03-21 Whiteman; Gaylen L. Tacking device for attaching to textured surfaces
US5605729A (en) * 1993-04-16 1997-02-25 Minnesota Mining And Manufacturing Company Loop fastener material storage/dispensing assembly
EP0693889B2 (en) † 1993-04-16 2003-03-12 Minnesota Mining And Manufacturing Company Loop fastener material storage/dispensing assembly
US5691026A (en) * 1993-07-27 1997-11-25 Minnesota Mining And Manufacturing Company Fastener member with a dual purpose cover sheet
US5691027A (en) * 1993-07-27 1997-11-25 Minnesota Mining And Manufacturing Company Fastener with a dual purpose cover sheet
US5902427A (en) * 1993-07-27 1999-05-11 Minnesota Mining And Manufacturing Company Fastener arrangement with dual purpose cover sheet
US5611122A (en) * 1993-07-28 1997-03-18 Minnesota Mining And Manufacturing Interengaging fastener having reduced noise generation
US5671512A (en) * 1993-07-30 1997-09-30 Minnesota Mining And Manufacturing Company Interengaging fastner having reduced engagement force
US5662853A (en) * 1993-08-05 1997-09-02 Minnesota Mining Manufacturing Company Affixation member for decorating or protecting structures and methods of making same
US5671511A (en) * 1993-08-25 1997-09-30 Minnesota Mining And Manufacturing Company Interengaging fastener member having fabric layer
US6579161B1 (en) 1994-01-13 2003-06-17 3M Innovative Properties Company Abrasive article
US7044834B2 (en) 1994-01-13 2006-05-16 3M Innovative Properties Company Abrasive article
US5725423A (en) * 1994-01-13 1998-03-10 Minnesota Mining And Manufacturing Company Abrading apparatus
US5785784A (en) * 1994-01-13 1998-07-28 Minnesota Mining And Manufacturing Company Abrasive articles method of making same and abrading apparatus
US20050202770A1 (en) * 1994-01-13 2005-09-15 3M Innovative Properties Abrasive article
US5840089A (en) * 1994-01-13 1998-11-24 Minnesota Mining And Manufacturing Company Method of making an abrasive article
US6884157B2 (en) 1994-01-13 2005-04-26 3M Innovative Properties Company Abrasive article
US5505747A (en) * 1994-01-13 1996-04-09 Minnesota Mining And Manufacturing Company Method of making an abrasive article
US6579162B2 (en) 1994-01-13 2003-06-17 3M Innovative Properties Company Abrasive article
US5667540A (en) * 1994-01-13 1997-09-16 Minnesota Mining And Manufacturing Company Method of making an abrasive article
US5672186A (en) * 1994-01-13 1997-09-30 Minnesota Mining And Manufacturing Company Method of making an abrasive article
US5713111A (en) * 1994-07-27 1998-02-03 Minnesota Mining And Manufacturing Company Method for making an interengaging fastener having reduced engagement force
US5830298A (en) * 1996-08-30 1998-11-03 Minnesota Mining And Manufacturing Co. Loop fastening material
US5699593A (en) * 1996-08-30 1997-12-23 Minnesota Mining & Manufacturing Company Loop fastening material
WO1998011007A1 (es) * 1996-09-12 1998-03-19 Jorge Luis Leija Cordero Procedimiento para manejo de envases con las tapas
WO1999041440A1 (en) * 1998-02-13 1999-08-19 The Regents Of The University Of California Reinforced composites including bone-shaped short fibers
US6202264B1 (en) * 1998-03-06 2001-03-20 Ykk Corporation Surface fastener made of fiber and method for manufacturing the same
US20040231208A1 (en) * 2001-06-23 2004-11-25 Pitt John Dunlop Method and apparatus for displaying advertisements on a vehicle
US20060207141A1 (en) * 2002-02-12 2006-09-21 Agripa Limited Method and apparatus for displaying advertisements on a vehicle
US20060162269A1 (en) * 2003-01-30 2006-07-27 Pacione Joseph R Anchor sheet
US20070026181A1 (en) * 2003-02-28 2007-02-01 Velcro Industries Bv, A Curacao, Netherland Antilles Corporation Fastener tapes
US20050117819A1 (en) * 2003-12-02 2005-06-02 Kingsford Howard A. Packaging closures
US20060090386A1 (en) * 2004-10-28 2006-05-04 Agripa Holdings Limited Flexible frame and mutually engageable fastening means
US7225569B2 (en) 2004-10-28 2007-06-05 Agripa Holdings Limited Flexible frame and mutually engageable fastening means
US7394039B2 (en) 2006-03-10 2008-07-01 Fujitsu Component Limited Keyboard and membrane switch for keyboard
US8875356B2 (en) 2011-10-06 2014-11-04 Intercontinental Great Brands Llc Mechanical and adhesive based reclosable fasteners
US20180360169A1 (en) * 2015-12-14 2018-12-20 Teijin Frontier Co., Ltd. Hook and loop fastener and textile products
US20220355746A1 (en) * 2021-05-10 2022-11-10 Bayerische Motoren Werke Aktiengesellschaft Method for Producing a Trim Part, and a Trim Part

Also Published As

Publication number Publication date
FR2199954B1 (nl) 1977-05-27
JPS5333887B2 (nl) 1978-09-18
IT993425B (it) 1975-09-30
AU476127B2 (en) 1976-09-09
GB1441328A (en) 1976-06-30
AU6069673A (en) 1975-03-27
SE409088B (sv) 1979-07-30
DK139953C (nl) 1979-11-05
DK139953B (da) 1979-05-28
CA991923A (en) 1976-06-29
FR2199954A1 (nl) 1974-04-19
JPS4970742A (nl) 1974-07-09

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