US3846205A - Method for producing laminated materials of fibers - Google Patents

Method for producing laminated materials of fibers Download PDF

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US3846205A
US3846205A US00079707A US7970770A US3846205A US 3846205 A US3846205 A US 3846205A US 00079707 A US00079707 A US 00079707A US 7970770 A US7970770 A US 7970770A US 3846205 A US3846205 A US 3846205A
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web
fibers
fiber
split
adhesive binder
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M Yazawa
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Polymer Processing Research Institute Ltd
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Polymer Processing Research Institute Ltd
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    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/47—Processes of splitting film, webs or sheets
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet

Definitions

  • FIG. IA is a diagrammatic representation of FIG. IA.
  • This invention relates to a method for producing a nonwoven material whose spread fiber distribution is partially fixed with an adhesive binder forming a pattern, and lamination thereof.
  • the split-fiber from such a stretched film can be obtained in the form of a fiat web of interconnected fibers which can be spread to a wider desired width than that of the original stretched film
  • the present inventor perceived that if several webs of split fibers are piled, while they are spread and elongated without substantial slacking. to a suitable thickness and their fiber distribution is fixed with an adhesive binder, products, especially suitable for packaging and having strength higher than those obtained by the use of conventional thermoplastic cut fibers, can be obtained at a low cost.
  • the split fibers are so difiicult for handling, there has not been known even a single prior art in whichthe manufacture of non-woven materials from the split fibers is disclosed.
  • a US. patent application entitled, Method for Producing Plastic Materials Reinforced With Split Fibers was filed by the inventor on Nov. 11, 1967 as US. Patent Application No. 682,598, now abandoned.
  • the said invention relates mainly to a method for producing reinforced film incorporated with splitfiber and its application, in which when incorporated splitfiber is rather smaller in quantity than that of film as an adhesive binder, the product is generally of higher practical value.
  • the reason is that if the adhesive binder is so amply supplied in a state of a film on one surface of the split-fiber web that it covers almost all over the surfaces of fibers of the spread split-fiber uniformly, but if the fibrous layer is thick, fibers on one side which the film is in contact, are fixed well to each other with ample supply of the adhesive binder there, whereas fibers nearer to the other side are less permeated with the adhesive binder, leading to incomplete adhesion there and as a result, fibers on this side tend to become fiuffy, hence a product without fluff cannot be obtained unless the quantity of the film as the adhesive binder is increased.
  • tenacity of a fibrous laminate increases with the increasing quantity of incorporated split-fiber and so, if the film laminate, incorporated with split-fiber of the said invention, is used for making heavy duty bags, which require high tenacity, the quantity or thickness of film to be applied must be increased to such an extent as to lose pliability of the product and so it becomes unsuitable for practical application.
  • FIG. 1 shows the forms of filaments, bristles or tapes of a polymer applied as an adhesive binder, being piled on before or after pressure-adhering to a web of split-fiber or its laminate in longitudinal, lateral or slanting stripes 1A; being in longitudinal stripes, 1B in lateral stripes, 1C
  • FIG. 2 is a schematic drawing showing one feature of the present invention in which warp and weft fiber layers are crossed.
  • the prefixed web of split-fiber is used as a weft, that is, in the course of travelling the warp fed from a roll under a tension, the weft fed from another roll is blown out over the warp at regular intervals by the same length as the width of it through a duct by a rapid current of fluid, in such a way that the warp and the weft cross at right or oblique angle to each other, then the blowing of fluid is stopped, the blown out weft is cut and deposited upon the warp by the guidance of suction from a suction box installed under the travelling warp web.
  • an additional adhesive binder may be placed upon said warp before the weft is blown out.
  • Piled warp and weft are fixed with an adhesive binder according to the second feature of the present invention to construct the cross arrangement of warp and 'weft webs.
  • FIG. 3 shows the process where split-fiber webs on which an adhesive binder is distributed are subjected to pressure-adhering and, further, given a pattern of network, texture of concave and convex figures on the surface of the product obtained above by embossing with metal net belts, fabric belts or rollers having an uneven surface, after the said fiber webs are preheated on a heated drum insulated with a backing canvas.
  • the term split fiber does not mean shortweb, substantially endless, consisting of interconnected fibers, showing a network structure on spreading widthwise, each of which fibers lies in parallel with the longitudinal direction of the web, is arranged side by side in a single layer, and has generally a tenacity of from two to seven grams per denier and a thickness of from ten to several tens deniers and obtained by incompletely sub dividing a uniaxially stretched (oriented) film of a fiber fonming organic polymeric material along the longitudinal direction of the web into interconnecting fibers, for instance, by cutting it with a tap-shaped cutter, by splitting it with a brush shaped cutter, or by slide-rubbing it under a tension on a revolving file.
  • a non-woven material consisting of one or more webs of split-fiber, elongated length-wise without slacking, each web of which has been spread to a definite width wider than its original width, is piled one upon another to give a definite thickness, is hereinunder referred shortly as a 'warped fiber.
  • filaments, bristles, tapes or as powder of an adhesive binder polymer, having a lower softening temperature than the heat resisting temperature of said fiber are distributed on the warped fiber in longitudinal, lateral, or slanting stripes, as shown in FIG.
  • shaped adhesive binder 1, for example, (a) in longitudinal stripes, (b) in lateral stripes, (c) in wavy stripes, (d) in a ladder pattern, and (e) in a lattice pattern, or the shaped product of the adhesive binder polymer in a network form or in the state of a perforated film (hereinafter referred as shaped adhesive binder for simplicity) is piled on said warped fiber, and tapes of the adhesive binder are usually laid on their salvages to fix them, and then the whole is subjected to pressure-adhering to for-m into a web of non-woven material at a temperature lower than the heat resisting temperature of the fiber but within the range of the softening temperature of the adhesive binder polymer to fix preliminarily the fiber distribution.
  • warped fiber easy to handle in a subsequent processing step can be obtained by only pressure-adhering at a temperature in the softening range and lower than the heat resisting temperature of the fiber without using an adhesive binder so as to temporarily attain fixing of the fiber arrangement, and it is usually more convenient to wind up the product thus obtained on a beam, as it is, because no fiufling or no confusion of fibers takes place on unwinding or rewinding it in a subsequent processing step.
  • This preparatory procedure is one of the features of the present invention.
  • two or more webs of the warped fibers, for nonwoven material obtained by the above-mentioned method are piled to a desired thickness in such a manner that the fibers of each web are parallel to those of others, or if necessary shaped adhesive binder in inserted addi tionally into the boundary surfaces of each web in the above-mentioned way, and the distribution of the fibers of the webs is fixed by pressure-adhesion on heating at a temperature lower than the heat-resisting temperature of the fibers but within the softening temperature range of the adhesive binder polymer or in another case a temporarily fixed preparatory product for the subsequent step, is prepared by pressure-adhering only the fibers on heat ing at their softening point without using adhesive binder.
  • This laminate of webs of the non-woven material affords a useful material for strong flexible strings, bands, or tapes when slitted along the main fiber axis so as to give desired width.
  • the webs of warped fibers, or sheet-like material, obtained by the above-mentioned method, or their laminates are piled up in such a combination of weft and warp that their fibers cross each other perpendicularly or obliquely, and if necessary, with an additional shaped adhesive binder being distributed on the boundary or upper and lower surfaces of them as in the method of the first feature, and the Whole is subjected to pressure-adhering integrally on heating at a temperature lower than the heat resisting temperature of the fibers so that only the parts of fibers which are fully impregnated with a softened shaped adhesive binder are firmly fixed, thereby producing a laminate, having parts consisting of loosely gathered fibers encircled by edges of firmly fixed parts with a shaped adhesive binder, and containing a larger quantity of fibers relative to the total laminate, which is strong and pliable for its thickness.
  • the laminated product obtained by the method of the present invention which contains -120 g./m. of fibers and 20 40 g./m. of the adhesive binder polymer in the state of a lattice or network which effects firm adhesion at the places where the binder polymer is located, has suflicient gas permeability for rice or barley bags, having suflicient tenacity for them and can take the place of the fabric of -200 g./m. made of the same kind of stretched tapes or the fabric of 500-600 g./m. made of jute.
  • the fourth feature in the above-mentioned method for producing a laminated product composed of weft and warp fibers, during the process where the web of warped fiber or non-woven material described in the first feature is travelling under a tension as a warp with a certain width, another web of non-woven material, or its laminate described in the second feature is blown out, as a weft, at regular intervals by the length corresponding to the width of the warp through a flat duct, then the blowing thereof is stopped, and it is cut and then laid directly or indirectly on the travelling web of warp.
  • the fiber distribution of web of weft used in the present invention is not disturbed even when the web of weft is cut by a length necessary as a weft by a suitable method in spite of inconvenience of split-fiber for handling because of its limpness and non-stiffness and structure which allows air to pass through easily.
  • the web of weft used in the present invention is guided by the current of a fluid with an apparatus shown in FIG. 2 by the method of the fourth feature, it can be fed at regular intervals only by the length corresponding to the width of the warp web without disturbing its fibers and laid on the web of warp after it is cut. That is, in FIG.
  • a web of warp 1, wound up with their distribution fixed by the methods of the first and the second features, is delivered to a pinch roller 2 at a fixed velocity and introduced into a flat duct 3 via a slit 4 and compressed air of several tenth atmosphere gauge is supplied to the duct at the upper and lower parts of its head, 5 and 6, so that the web in the duct is blown horizontally out of the end of a duct, 7, into the atmosphere.
  • the opening at the end of the duct is shut with a valve 8 to stop the blow of the fluid and the web simultaneously and at the same time the web is cut along the edge of the warp web 10 with a cutting knife or a melt cutter 9 as a web of Weft, while the blown Web of weft is going down in a substantially elongated state by gravitation.
  • the travelling web of warp 10 is made to move perpendicularly to the surface of paper and just below the blown web of weft and a suction box 13 with a perforated plate or a screen 12 is installed below 10.
  • the internal pressure of the suction box 13 is reduced, and then the cut web of weft fibers is sucked right down and placed on the travelling web of warp.
  • the end of the duct is opened again to blow air and then the web of weft, 14, which is fed continuously with a pinch roller 2 and accumulated before the entrance of the duct, while the blow is suspended, is sucked into the duct and blown toward the outlet, and then the Web of Weft accumulated between the pinch roller and the entrance of the duct advances, leaving a portion of the web subjected to a tension and straightened.
  • a weft and a Warp can be combined with each other to form their laminate (cross lamination).
  • the above-mentioned method is for combining them directly.
  • they can be combined indirectly by another method in which the web of weft, blown out from the fiat duct and cut by a length equal to the web is made to stick electrostatically to a metal plate or a rake-shaped arm and then transferred from it at regular intervals onto the warp travelling with charge of opposite electricity. If it is necessary to add an adhesive binder, a shaped adhesive binder can be laid between webs of weft and warp.
  • This method of piling webs of weft and warp by blowing is advantageous in not disturbing the distribution of fibers because it is already fixed by the methods of the first and the second features, even if the flow of the fluid applied is considerably turbulent.
  • the method of FIG. 2 is adopted for combining a weft and a warp which are prearranged independently by the use of warping machine, respectively without using any binder in place of what are prepared according to the first and the second feature of this invention and thus combined weft and warp fibers are subjected to pressure-adhering on heating with an adhesive binder in the form of a shaped product e.g. net or strip form. Such a method is also included in the scope of the present invention.
  • the shaped products of an optional adhesive binder polymer having a lower softening temperature than heat resisting temperature of the fibers can be used.
  • an adhesive binder which is a polymer of the same kind or is selected from the group consisting of copolymers containing the same constituent monomer as that of the polymer of the fibers (hereinunder shortly referred as a polymer of the same kind or group as that of the split fiber) but has a softening temperature lower than the heat resisting temperature of the split-fiber because of non-oriented state of molecules or being a copolymer, can be used to attain greater inter-fiber adhesion by utilizing the strong afiinity of the binder to fibers.
  • the heat resisting temperature of high density polyethylene filament or split-fiber for example, is 125-127 C. but the tape-like shaped product of low density polyethylene is softened completely at -115 C. and can adhere to polyethylene split-fiber firmly by way of welding as the result of which a very strong laminated product can be obtained. This fact has been confirmed experimentally.
  • the heat resisting temperature of the split-fiber obtained from stretched polypropylene film is about 150 C.
  • non-stretched film thereof containing much of amorphous ingredient and thus having a lower softening temperature was used as an adhesive binder for said split-fiber, a very strong laminated product was obtained by pressure-adhering on heating at 140-145 C.
  • Example 1 when the web of split-fibers of polypropylene was subjected to pressure-adhering on heating at -130 C. using high pressure polyethylene film as an adhesive binder, the resultant product does not appear to be different from the above, but when it was placed under load for testing its strength, the fibers were separated easily from the film, and the strength of the resultant laminated product was almost equal to that of the split-fiber incorporated, showing a small increase only by the sizing effect of the adhesive binder used.
  • Example 1 the product obtained using the shaped products of an adhesive binder made from the polymer of the same kind or group as that of the split-fiber used was compared in strength with that obtained using an adhesive binder made from a different kind of polymer.
  • the tenactiy was calculated as mean values of those obtained by dividing the strength (measured with a Schopper-type tester) of pieces of the product out in 50 mm. width, only with the total deniers of split-fiber contained in the loaded direction of each piece, weft or warp direction separately.
  • the tenacity of film of PE. or P.P., used was about 0.8 g./d.
  • split-fiber of polyacrylonitrile containing more than 85% of acrylonitrile
  • film of polyvinyl chloride vs. split-fiber of the copolymer of 60% vinyl chloride and 40% acrylonitrile
  • film of polyvinyl chloride unstretched or externally or internally plasticized
  • vs. splitfiber of polyvinyl chloride and film of lower softening point polyester vs. split-fiber of ordinary polyester.
  • films of the polymers of the same kinds or group suitable as an adhesive binder whose softening temperature are lower than the heat-resisting temperature of the respective split-fiber can be found easily.
  • unoriented or oriented film, or metal foil is laid on the web of warped fiber, the non-woven material, or the multipiled product obtained by the methods of the first, second, third and fifth features and subjected to pressure-adhering on heating to produce pliable and water-proof laminates, and also paper is laid on and subjected to pressure-adhering on heating similarly to the above to attain printability, slip prevention and antistatic effect owing to the nature of paper surface.
  • the multipiled products obtained by the methods of the first, second, third and sixth features in the state of being heated at a temperature lower than the heatresisting temperature of the split-fiber but within the range of the softening point of the adhesive binder polymer, and being clamped between screen belts or cloth belts, are passed between pressure rollers or embossing rollers so as to be pressure-adhered as above-mentioned under a high pressure, whereby they are impressed with a network or texture pattern or the uneven pattern of the embossing rollers, and products are obtained which appear as if they were woven, having a slip preventing effect by the impressed unevenness of their surface and being more pliable than before.
  • the products of the first, second and third features are embossed, gas permeable products having a very high practical and commercial value, can be obtained.
  • FIG. 3 shows the process wherein a web of the nonwoven material of the first feature, the laminate of the non-woven material of the second feature or the multipiled product of the third feature travelling as a web 21 and if necessary, incorporated with additional shaped adhesive binder laid on said web or laminate, before pressure-adhered on heating, is passed between a hot surface of a heating drum 23 and a backing canvas 22 which covers the principal part of the heating surface of the drum or if necessary, moved in series over the surfaces of many heating drums of this kind, one by one, during which process it is heated at a temperature, lower than the heat resisting temperature of the splitfiber but within the range of the softening temperature of the adhesive binder polymer, then fixed integrally by pressure-adhering directly or indirectly through the backing canvas with a pressure roller 24 and if necessary, before cooled, is pressed again by passing through embossing rollers 25, or metal net or cloth belts 26 in a heating chamber 27 so as to be impressed with a network or cloth texture pattern or the uneven pattern of
  • the pressure roller 24 is used only for preliminary pressure adhesion and pressure adhesion can be mainly effected by embossing or by another bank of heated powerful pressure rolls.
  • the surface of the embossing roller is preferably of rubber, when a cloth belt is used, it may be of metal, and when uneven pattern is given only with embossing rollers, metal rollers having uneven surfaces are used.
  • heating must be effected at a higher temperature as close as possible to the heat resisting temperature of the split-fiber but at a higher pressure, heating is effected at a lower temperature.
  • the multipiled product composed mainly of warp fiber among the products obtained by the methods of the first, second, third, sixth and seventh feature, is cut longitudinally to produce strings, bands and tapes, which are very pliable and heat-sealable and scarcely break laterally in virtue of the adhesive binder or a small quantity of weft fiber mixed with them.
  • the product even if it contains a large quantity of warp fiber which dominates strength of the product, is very pliable because it has parts composed of fibers alone together with parts firmly jointed by pressure-adhering with an ahesive binder and moreover even if film is laminated on its surface, it is only on its surface, so harmful effect is not given to pliability.
  • thermoplastic film laminated on its surface gives a heat-sealing property and paper or metal foil laminated on its surface enhances the appearance and the commercial value and a combination eifect of physical properties of the laminated component is brought about to the product.
  • the products obtained by the methods of the first, second, and third features can be used as the core fibers of shaped products of cement, because a fluid mixed with cement can pass the laminated products easily when the adhesive binder for fixing the distribution of weft and warp fiber is placed with greater intervals. Especially they are effective in improving the impact resistance of such thin products of cement as slates or tiles.
  • fibers of heat-treated polyvinyl alcohol, partially hydrolyzed acrylonitrile, polyvinyl chloride, and polyamides which are highly polar give better results than those of polyolefins and polyesters.
  • the heat resisting temperature of fibers means the highest temperature at which the fibers maintained at a fixed length, are heated for a time, without accompaniment of reduction of strength or if any without accompaniment of such an extent of reduction of strength which may be harmful to their commercial value.
  • the softening temperature of a fiber or a shaped product of an adhesive binder means the range of temperature in which a plastic deformation to an arbitrary shape occurs under its working perssure and time.
  • the melting point is defined as the temperature at which the mutual transfer of the center of gravity of the molecules takes place freely among them during said deformation.
  • density increases and the softening temperature rises by several or ten-odd degree for some polymers. Needless to speak of, if a plasticizer is added to the product, its softening (melting) temperature falls.
  • shaped products of polymers usable for adhesive binders there are illustrated those of the polymers of the same kinds or the polymers selected from the group consisting of copolymers containing the same constituentmonomer as the polymer of split-fiber used in the present invention, which has a high aflinity to the fibers and lower 10 softening temperature than the fiber, or those of the thermoplastic polymers which have Cl, COOH, -OAc, CONH or OH radicals in their side chains and are highly adherent.
  • Illustrative fibers used in the present invention include split-fiber prepared from stretched films of polyethylene, polypropylene, polyvinyl chloride, polyvinyl alcohol, polyacrylonitrile, polyvinylidene chloride, fluorine-containing polymers, nylon, polyesters, cellulose esters, and the copolymers of their groups.
  • a wide web of split fiber can be obtained easily and at a low cost from wide stretched film and the split fibers obtained immediately after splitting can be easily and uniformly spread and each fiber of them is arranged regularly in a network, so if its fiber distribution is subjected to fixing with an adhesve binder by the method of the first feature continuously and wound on a beam, flufiing will not take place thereafter at unwinding or rewinding process. Accordingly, they can be used conveniently in constructing the laminate of weft and warp.
  • untwisted split fibers they are stronger, when their single fibers are thicker in size and smaller in number, while they are weaker when the single fibers are finer in size and larger in number.
  • their tenacity approaches that of the original stretched film.
  • the denier of their single fibers should be larger than that of split fibers for clothing or upholstery uses because damage caused by fiuffing in the final product is less.
  • the teeth of the cutter and splitter or the thickness of the stretched film is controlled.
  • stretched film 15-20 microns thick, is split into a web of fine fibers of 10-20 denier and for making rice or barley bags, the thickness of the stretched film is 30-50 microns and the denier of the single fiber is 30-100 denier.
  • split fibers having single fibers of as fine as 10-20 denier are used.
  • the tubular film of high density polyethylene was collapsed fiat and cut at its selvages to make 2 pieces of film, 200 mm. wide and 160 microns thick (:10% tolerance in thickness) both of which were wound at the same time on a bobbin.
  • Five of such a bobbin were arranged in parallel, each two pieces of such films laid one over another were passed, without being touched each other, through boiling water so as to stretch by 6 times and then all of the films are arranged in parallel side by side and while they were moving on rollers, one by one in series, installed in an oven heated at 115120 C., they were stretched by 10 times the original length in total and while they were travelling at a velocity of m./min.
  • the distribution of spread fibers were fixed in wavy form with the bristles of high pressure polyethylene as an adhesive binder, leaving unfixed portions of fibers between nighboring wavy pattern of the adhesive binder polymer and the resultant product was wound on a beam-winding bobbin, as it was.
  • the fixed web of fibers, thus wound up contained about 30 g./m. of split-fiber and about 10 g./m. of the adhesive binder polymer.
  • weft fiber prepared similarly to the above were laid by using the cross-laminating apparatus of FIG. 2 and then the resultant product composed of weft and warp fibers was fixed with adhesive binder by pressure-adhering together after preheated at 115 C. with the pressure-adhering apparatus of FIG. 3 and embossed at a pressure of 50 kg./cm. by passing it through between metal network belts of meshes.
  • the fibers of the product were forced to gather from the projected parts of the net belt to the recessed parts of it and thus the surface of the product had unevenness like a woven fabric, and the parts composed only of fibers were fixed, though incompletely, and the product thus obtained appeared as if woven.
  • the boundary surfaces of the webs would not come off owing to the adhesive binder spread toward both sides.
  • This product of laminated weft and warp fibers weighed about 80 g./rn. containing about 75% of fibers. Its tenacity was 50 kg. or more per width of 50 mm. and its elongation was -40%, and it was strong enough for a rice or barley bag (for which purpose the strength of Si) kg. per width of 50 mm. is necessary).
  • the adhesive binder was spread evenly within the width of 3-4 mm, adhering the fibers to each other in the net-like way.
  • the parts composed of fibers only which were not in contact with the adhesive binder polymer were shaped like deformed squares, the sides of which are about 2025 mm. long and through which air could be passed freely.
  • a sampling pipe 7-8 mm.
  • the product of the present invention may be incorporated with a UV absorber or colored with some pigment, or paper may be laminated on it before the entire material is subjected to pressure-adhering together on heating, by the method of the sixth feature hereof.
  • a UV absorber or colored with some pigment or paper may be laminated on it before the entire material is subjected to pressure-adhering together on heating, by the method of the sixth feature hereof.
  • non-oriented or oriented film may be laminated on it.
  • the content g./m. of split-fiber may be reduced and then film may be laminated on it.
  • the webs of fiber adhere to each other completely with an ample quantity of an adhesive binder at certain intervals, and so even if fibers become flui'fy on the other surface of the film because of its thickness, it can be used practically without troubles.
  • the laminated or embossed product, obtained by the method of the present invention which contains generally 50-90% of fiber can be sewn and when film is laminated on its surface, it can be jointed by the heat-sealing method.
  • the bands or tapes obtained by the method of the eight feature become heat-sealable if the Webs of warped fibers are piled up upto a necessary thickness and films are laminated on their surface and then the entire material is subjected to pressure-adhering.
  • the web of warped fiber laminated with film or paper on it can be used as the raw-stuff for an adhesive tape containing a rubber-type adhesive.
  • the laminate of Warped fibers or the product of laminated weft and Warp obtained by the method of the present invention, in which the webs of split-fiber are so fixed that the product has parts firmly jointed by pressure adhesion with a shaped adhesive binder polymer and parts composed of fibers alone, has a high content of fiber and is pliable for its thickness and very strong in virtue of its good fiber distribution arranged in one or two principal directions, that is weft or warp, which fibers are in the state substantially elongated lengthwise without slacking.
  • stretched film or woven fabric of stretched tapes was laminated with unstretched film by pressureadhesion or by extrusion-lamination, or coated with an emulsion before dried, and then laminated with unstretched film by pressure-adhesion.
  • split fiber has larger surface areas, it gives firmer adhesion.
  • adhesion is firm inspite of the fact that adhesion is made only locally at places where the adhesive binder polymer is located in a pattern, and gas permeability is effected and pliability is increased, thus the characteristic advantage of the present invention is further evidenced.
  • the product of the present invention contains longer interconnected fibers of split fibers, so it can be used for producing the products which needs special high strength.
  • a following remedy may often be useful: i.e. a suitable adhesive binder in emulsion form is sprayed only onto the surface of the product or an half-finished product and dried up, and, if necessary, set on heating for preventing the flufiing of the surface.
  • a method for producing a flexible gas permeable nonwoven material consisting of at least one Web of split fibers which comprises arranging side by side the split fibers of at least one web of split fibers having a network structure, elongated lengthwise without substantial slacking and substantially parallel to each other; laying on the said web of split fibers a preformed solid shaped pattern of adhesive binder polymer which covers the surface of the said web of split fibers only locally those portions of said web which underly said shaped pattern of adhesive and; thereafter pressure adhering the resulting assembly to bind said adhesive and said web so as to leave loose and unfixed parts amid firmly fixed fiber parts, said shaped adhesive binder having a softening temperature range lower than the heat resisting temperature of said web said pressure-adhering being effected by heating said materials at a temperature lower than the heat resisting temperature of the said web but within the softening temperature range of the said adhesive binder.
  • said adhesive binder is chiefly composed of the same polymer as that of the split-fiber and has a lower softening temperature range than the heat resisting temperature of the split-fiber.
  • said adhesive binder is chiefly composed of a polymer selected from a group of copolymer, one of the main constituent monomers of which copolymer is the same as that of the principal constituent monomer of the split fiber, and which copolymer has a lower softening temperature range than the heat resisting temperature of the split-fiber.
  • a method according to claim 12, wherein the arrangement of layers of the sheet-like material is carried out by blowing a first sheet-like material as a weft, through a fiat duct by a rapid current of a fluid upon a second sheet-like material, as a warp, during the travelling step of the warp by the length corresponding to the width of the second, as measured along the direction of blowing of the fluid, stopping the blowing of the fluid, cutting the first along the edge of the second to fall on the second, and repeating the above-mentioned procedure at a given interval.
  • a method according to claim 1 wherein a flexible gas permeable non-woven laminated material of webs of split fibers is produced by laminating one face of a first web of split fibers to one face of at least one additional web of split fibers, by means of a solid shaped patterned adhesive laid on said face of the first web prior to disposing said additional web thereon.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Nonwoven Fabrics (AREA)
US00079707A 1967-06-05 1970-10-09 Method for producing laminated materials of fibers Expired - Lifetime US3846205A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4419304A (en) * 1980-07-15 1983-12-06 Western Electric Company, Inc. Method for forming seals with heat shrinkable materials
US4532169A (en) * 1981-10-05 1985-07-30 Ppg Industries, Inc. High performance fiber ribbon product, high strength hybrid composites and methods of producing and using same
US4630729A (en) * 1984-07-27 1986-12-23 Firma Dixie Union Verpackungen Gmbh Package, for example, for surgical instruments and products
US5008489A (en) * 1989-10-25 1991-04-16 Facile Holdings, Inc. Electrical cables and serpentine pattern shielding tape therefor
US5162150A (en) * 1991-08-20 1992-11-10 Milliken Research Corporation Duct tape
US5362360A (en) * 1992-06-26 1994-11-08 International Business Machines Corporation Method and product for extruding materials that exhibit anisotropic properties by means of reciprocating die surfaces
US5667864A (en) * 1995-06-07 1997-09-16 Landoll; Leo M. Absorbant laminates and method of making same
US20090239009A1 (en) * 2005-10-04 2009-09-24 Toyo Boseki Kabushiki Kaisha Bag having controlled oxygen-permeability
US20120111162A1 (en) * 2010-11-04 2012-05-10 Karl Mayer Malimo Textilmaschinenfabrik Gmbh Device and method for producing monoaxial or multiaxial scrims
US10005255B2 (en) * 2013-03-04 2018-06-26 Finetrack Long fiber nonwoven fabric and laminate of fabrics having long fiber nonwoven fabric

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3639199A (en) * 1969-04-21 1972-02-01 Cons Paper Bahamas Ltd Reinforced laminate product
US3705070A (en) * 1969-07-22 1972-12-05 Hercules Inc Nonwoven fabric and process for preparing

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4419304A (en) * 1980-07-15 1983-12-06 Western Electric Company, Inc. Method for forming seals with heat shrinkable materials
US4532169A (en) * 1981-10-05 1985-07-30 Ppg Industries, Inc. High performance fiber ribbon product, high strength hybrid composites and methods of producing and using same
US4630729A (en) * 1984-07-27 1986-12-23 Firma Dixie Union Verpackungen Gmbh Package, for example, for surgical instruments and products
US5008489A (en) * 1989-10-25 1991-04-16 Facile Holdings, Inc. Electrical cables and serpentine pattern shielding tape therefor
US5162150A (en) * 1991-08-20 1992-11-10 Milliken Research Corporation Duct tape
US5362360A (en) * 1992-06-26 1994-11-08 International Business Machines Corporation Method and product for extruding materials that exhibit anisotropic properties by means of reciprocating die surfaces
US5667864A (en) * 1995-06-07 1997-09-16 Landoll; Leo M. Absorbant laminates and method of making same
US20090239009A1 (en) * 2005-10-04 2009-09-24 Toyo Boseki Kabushiki Kaisha Bag having controlled oxygen-permeability
US20120111162A1 (en) * 2010-11-04 2012-05-10 Karl Mayer Malimo Textilmaschinenfabrik Gmbh Device and method for producing monoaxial or multiaxial scrims
US10005255B2 (en) * 2013-03-04 2018-06-26 Finetrack Long fiber nonwoven fabric and laminate of fabrics having long fiber nonwoven fabric

Also Published As

Publication number Publication date
FR1554510A (xx) 1969-01-17

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