US3809583A - Solid agent for boriding metals - Google Patents

Solid agent for boriding metals Download PDF

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US3809583A
US3809583A US00253515A US25351572A US3809583A US 3809583 A US3809583 A US 3809583A US 00253515 A US00253515 A US 00253515A US 25351572 A US25351572 A US 25351572A US 3809583 A US3809583 A US 3809583A
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boriding
boron
metals
powder
solid agent
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US00253515A
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H Krzyminski
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DEUTSCHE GOLD und SILBER SCHEIDEANSTALT DT
Evonik Operations GmbH
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Degussa GmbH
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/68—Boronising
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/68—Boronising
    • C23C8/70—Boronising of ferrous surfaces

Definitions

  • the boriding of steels which leads to very hard surface layers and therefore continually is finding greater use in the solution of problems of wearing out in prefabricated parts and tools is preferably carried out in a boron yielding powder.
  • This process requires only a small expenditure for apparatus.
  • the component parts are arranged in a box and surrounded with the boron yielding powder. After that the box is pushed into a suitable furnace and treated for several hours at temperatures of the order of 800 to 1100 C. After that the box is taken out of the furnace, cooled 01f and then emptied.
  • boriding powder there are used mixtures which consist of a boron yielding constituent, as for example, amorphous boron, crystalline boron, ferroboron, boron carbide, borax and mixtures of these materials. There can also be present activating additives. Finally there can be added to these boriding powders fillers or diluents. Through the boriding there arise layers which can be formed of the ductile Fe B or the more brittle FeB or both. An adjustment in the proportion of FeB to Fe B in many cases is desirable.
  • the quality of the boride layer can be so regulated that the boriding powders contain lower or higher concentrations of the boron yielding agent or are variably strongly activated. Also the quality of the steel of the part to be borided has an influence on the composition of the boriding powder, so that also control of the boriding powder composition in view of the choice of steel appears desirable.
  • the second severe disadvantage is the fact that the desired regulation of the boriding action is realized only poorly in practice due to the change of the concentration of the boriding constituent because the suggested mixtures on occasion incline to separate into their components.
  • the product does not tend to sinter together in carrying out the boriding treatment. After carrying out the boriding treatment and cooling off it can be easily discharged from the boxes and is immediately suitable for a further use. Besides the composition, once it is produced by mixing, remains constant even after frequent used and this is true even if the individual granules become mechanically abraded during the multiple use.
  • boron yielding constituent there can be employed any of the conventional materials such as amorphous boron, crystalline boron, ferroboron, boron carbide, boric anhydride and borax or mixtures of these materials in any proportion.
  • activating materials there can be used those customary in the art, e.g. ammonium, alkaline metal and alkaline earth metal halides such as ammonium chloride, potassium chloride, sodium chloride, calcium chloride, barium chloride, potassium fluoride, barium fluoride, magnesium fluoride, sodium bromide, sodium fluoride and calcium bromide as well as mixtures thereof.
  • ammonium chloride potassium chloride, sodium chloride, calcium chloride, barium chloride, potassium fluoride, barium fluoride, magnesium fluoride, sodium bromide, sodium fluoride and calcium bromide as well as mixtures thereof.
  • the composition can also contain the customary diluents such as graphite, silicon carbide, aluminum oxide and other stable compounds.
  • the amount of activating agent is usually between 2 and 15%.
  • the amount of boron containing material is usually at least 10% of the composition and usually 30 to weight percent, preferably 82 weight percent. When a diluent is employed, it is used in an amount of 5 to 88%.
  • the binder there can be used in place of charcoal tar other carbonaceous materials such as organic oils.
  • the binder is usually used to provide carbon in an amount of 2 to 40% of the composition.
  • the annealing of the pressed materials to remove volatile materials can take place at 400 to 600 0., preferably 450 C. for 0.5 to 2 hours.
  • the pressing can be done at pressures of 2 to 25 kg./crn.
  • the boriding treatment can take place as is customary at 800 to 1100 C.
  • the boriding treatment is primarily adapted to the boriding of iron and steel but can be used to boride other metals such as nickel and molybdenum.
  • a cylindrical granulate 2 composed of boron carbide composition 4 bound together by a carbon framework 6.
  • the granules usually have a height of 2 to 6 mm. and diameter of 1.5 to 4 mm.
  • EXAMPLE 2 The experiment was carried out as in Example 1. However, in each new treatment 15% of fresh boriding agent of the described type was added. As a result in all cases (i.e. the four samples) the thickness of the boriding layer was 230 to 240 millimicrons.
  • a solid agent for boriding metals comprising a pressed granulate of intimately mixed boron providing compound and activator.
  • a boriding agent according to claim 1 wherein the boron providing compound is selected from the group consisting of amorphous boron, crystalline boron, ferroboron, boron carbide and borax.
  • a boriding agent according to claim 1 wherein the granulate is annealed to 400 to 600 C.
  • a boriding agent according to claim 1 wherein the activating agent is selected from the group consisting of potassium chloride, sodium chloride, ammonium-ehloride, calcium chloride, barium fluoride and magnesium fluoride.
  • a boriding agent according to claim 1 wherein the boron containing material is 10 to 90 weight percent of the granulate.
  • a boriding agent according to claim 8 wherein the carbon content of the granulate is between 2 and weight percent.
  • a boriding agent according to claim 1 wherein the particle size of the boriding product is 0.4 to 12 mm.

Abstract

A SOLID AGENT FOR THE BORIDING OF METALS, ESPECIALLY STEEL AND IRON IS MADE BY INTIMATELY MIXING BORON YEILDING COMPOUNDS AND ACTIVATORS AND JOINTLY PRESSING TO A GRANYLATE.

Description

y 1 H. KRZYMINSKI 3,809,583
SOLID AGENT FOR BORIDING METALS Filed May 15, 1972 United States Patent @1 3,809,583 Patented May 7, 1974 3,809,583 SOLID AGENT FOR BORIDING METALS Harald Krzyminski, Konigstein, Germany, assignor to Deutsche Goldund Silber-Scheideanstalt vormals Roessler, Frankfurt am Main, Germany Filed May 15, 1972, Ser. No. 253,515 Claims priority, application Germany, June 1, 1971, P 21 27 096.2 Int. Cl. C23c 9/00 US. Cl. 148-635 12 Claims ABSTRACT OF THE DISCLOSURE A solid agent for the boriding of metals, especially steel and iron is made by intimately mixing boron yielding compounds and activators and jointly pressing to a granulate.
The boriding of steels which leads to very hard surface layers and therefore continually is finding greater use in the solution of problems of wearing out in prefabricated parts and tools is preferably carried out in a boron yielding powder. This process requires only a small expenditure for apparatus. To carry out the process the component parts are arranged in a box and surrounded with the boron yielding powder. After that the box is pushed into a suitable furnace and treated for several hours at temperatures of the order of 800 to 1100 C. After that the box is taken out of the furnace, cooled 01f and then emptied.
As boriding powder there are used mixtures which consist of a boron yielding constituent, as for example, amorphous boron, crystalline boron, ferroboron, boron carbide, borax and mixtures of these materials. There can also be present activating additives. Finally there can be added to these boriding powders fillers or diluents. Through the boriding there arise layers which can be formed of the ductile Fe B or the more brittle FeB or both. An adjustment in the proportion of FeB to Fe B in many cases is desirable. The quality of the boride layer can be so regulated that the boriding powders contain lower or higher concentrations of the boron yielding agent or are variably strongly activated. Also the quality of the steel of the part to be borided has an influence on the composition of the boriding powder, so that also control of the boriding powder composition in view of the choice of steel appears desirable.
The previously used boriding powders, however, have two severe disadvantages in practice.
One of these is that the pulverulent, carbon black like powder mixtures are very disagreeable to handle. Because of their small apparent densityit is often diflicult to compress the powder sufiiciently tight in the boxes. Besides the powder sinters together during the annealing treatment as a result of which it is difiicult to take the parts out after the conclusion of the treatment. In many cases therefore there has been a change to let the boxes cool off in air to about 200 C. after the annealing treatment and then to place them in a container filled with hot water in order to soften the strongly sintered powder. The parts are then withdrawn from the black sludge to which the powder has been converted and still need a thorough final purification by intensive washing or brushing. This process has the limitation that the very expensive boriding powder cannot be used again although from the chemical composition a repeated use would be theoretically possible. A further use would assume that the boriding agent, which had become a sludge, would be dried and ground. This cumbersome and expensive process has no relation manner.
The second severe disadvantage is the fact that the desired regulation of the boriding action is realized only poorly in practice due to the change of the concentration of the boriding constituent because the suggested mixtures on occasion incline to separate into their components.
These disadvantages are removed according to the invention by intimately mixing the boron providing compounds and activators and jointly pressing them to a granulate. For the production of the boriding powder, for example, the named constituents are first mixed in powdered form and then mixed with a charcoal tar so that a pasty mass is formed which can be pressed or molded. By pressing with the help of a suitable tool there are produced small cylindrical objects which then are annealed at 450 C. As a result all volatile constituents escape and there remains behind a relatively solid framework of free carbon in which are embedded the various constituents of the boriding powder.
The product of the invention eliminates the described disadvantages of the prior art.
On the one hand the product does not tend to sinter together in carrying out the boriding treatment. After carrying out the boriding treatment and cooling off it can be easily discharged from the boxes and is immediately suitable for a further use. Besides the composition, once it is produced by mixing, remains constant even after frequent used and this is true even if the individual granules become mechanically abraded during the multiple use.
As the boron yielding constituent there can be employed any of the conventional materials such as amorphous boron, crystalline boron, ferroboron, boron carbide, boric anhydride and borax or mixtures of these materials in any proportion.
As activating materials there can be used those customary in the art, e.g. ammonium, alkaline metal and alkaline earth metal halides such as ammonium chloride, potassium chloride, sodium chloride, calcium chloride, barium chloride, potassium fluoride, barium fluoride, magnesium fluoride, sodium bromide, sodium fluoride and calcium bromide as well as mixtures thereof.
The composition can also contain the customary diluents such as graphite, silicon carbide, aluminum oxide and other stable compounds. The amount of activating agent is usually between 2 and 15%. The amount of boron containing material is usually at least 10% of the composition and usually 30 to weight percent, preferably 82 weight percent. When a diluent is employed, it is used in an amount of 5 to 88%.
As the binder there can be used in place of charcoal tar other carbonaceous materials such as organic oils. The binder is usually used to provide carbon in an amount of 2 to 40% of the composition. The annealing of the pressed materials to remove volatile materials can take place at 400 to 600 0., preferably 450 C. for 0.5 to 2 hours. The pressing can be done at pressures of 2 to 25 kg./crn.
The boriding treatment can take place as is customary at 800 to 1100 C. The boriding treatment is primarily adapted to the boriding of iron and steel but can be used to boride other metals such as nickel and molybdenum.
Unless otherwise indicated all parts and percentages are by weight.
The invention will be understood best in connection with the drawing wherein the single figure shows a granule of the present invention.
Referring more specifically to the drawing there is formed a cylindrical granulate 2 composed of boron carbide composition 4 bound together by a carbon framework 6. The granules usually have a height of 2 to 6 mm. and diameter of 1.5 to 4 mm.
3 EXAMPLE 1 For boriding there was produced a granular product consisting of 66% boron carbide (B C), 16% borax, 10% potassium fluoride and 8% carbon. The granular product was prepared by intimately mixing 66 parts of boron carbide, 16 parts borax, 10 parts potassium fluoride and 40 parts of charcoal tar, pressing into small cylinders (about 4 mm. high and 2.7 mm. diameter at 20 kg./cm. and then annealing at 450 C. for 1 hour. A sample of steel Ck l5, normalized was borided by treatment for hours at 900 C. with this product. The boriding was carried out 4 times successively with the same product. In the first experiment there was produced a layer thickness of 240 millimicrons while in the fourth experiment this declined to 190 millimicrons.
EXAMPLE 2 The experiment was carried out as in Example 1. However, in each new treatment 15% of fresh boriding agent of the described type was added. As a result in all cases (i.e. the four samples) the thickness of the boriding layer was 230 to 240 millimicrons.
What is claimed is:
1. A solid agent for boriding metals comprising a pressed granulate of intimately mixed boron providing compound and activator. 1
2. A boriding agent according to claim 1 wherein the boron providing compound is selected from the group consisting of amorphous boron, crystalline boron, ferroboron, boron carbide and borax.
3. A boriding agent according to claim 1 wherein the granulate is annealed to 400 to 600 C.
4. A boriding agent according to claim 3 wherein the granulate is annealed at 450 C.
5. A boriding agent according to claim 1 wherein the activating agent is selected from the group consisting of potassium chloride, sodium chloride, ammonium-ehloride, calcium chloride, barium fluoride and magnesium fluoride.
6. A boriding agent according to claim 1 wherein the boron containing material is 10 to 90 weight percent of the granulate.
7. A boriding agent according to claim 6 wherein the boron containing material is 82 weight percent of the granulate.
8. A boriding agent according to claim 1 wherein a carbonaceous material is used as a binder.
9. A boriding agent according to claim 8 wherein the binder is charcoal tar.
10. A boriding agent according to claim 8 wherein the carbon content of the granulate is between 2 and weight percent.
11. A boriding agent according to claim 1 wherein the particle size of the boriding product is 0.4 to 12 mm.
12. A boriding agent according to claim 11 wherein the particle size is 2 to 3 mm.
References Cited UNITED STATES PATENTS 1,709,247 4/1929 Chambers 14819 X 1,853,369 4/1932 Marshall 148-6 3,090,702 5/1963 Commanday et a1. 1l7107.2 P
RALPH S. KENDALL, Primary Examiner US. Cl. X.R. 148-6, 6.3
US00253515A 1971-06-01 1972-05-15 Solid agent for boriding metals Expired - Lifetime US3809583A (en)

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DE2127096A DE2127096C3 (en) 1971-06-01 1971-06-01 Process for boronizing metals, in particular steel and iron

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AT (1) AT313666B (en)
BR (1) BR7203538D0 (en)
DE (1) DE2127096C3 (en)
FR (1) FR2139869B1 (en)
GB (1) GB1384171A (en)
IT (1) IT954646B (en)
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3936327A (en) * 1972-09-07 1976-02-03 Elektroschmelzwerk Kempten Gmbh Boriding composition
WO1983000106A1 (en) * 1981-07-02 1983-01-20 Turbine Metal Technology Inc Erosion resistant tubular apparatus for handling slurries
US4637837A (en) * 1984-08-23 1987-01-20 Elektroschmelzwerk Kempten Gmbh Process for boriding metals and metal alloys by means of solid boriding agents
US4806175A (en) * 1983-06-25 1989-02-21 Korber Ag Method of surface hardening ferrous workpieces
US6245162B1 (en) * 1998-07-09 2001-06-12 Houghton Durferrit Gmbh Boriding agent
US20050208213A1 (en) * 2002-11-15 2005-09-22 University Of Utah Research Foundation Titanium boride coatings on titanium surfaces and associated methods
US20070018139A1 (en) * 2005-05-10 2007-01-25 Chandran K S R Nanostructured titanium monoboride monolithic material and associated methods
US20100176339A1 (en) * 2009-01-12 2010-07-15 Chandran K S Ravi Jewelry having titanium boride compounds and methods of making the same
US20130243955A1 (en) * 2012-03-14 2013-09-19 Andritz Iggesund Tools Inc. Process and apparatus to treat metal surfaces
US10870912B2 (en) 2017-03-14 2020-12-22 Bwt Llc Method for using boronizing reaction gases as a protective atmosphere during boronizing, and reaction gas neutralizing treatment
US11192792B2 (en) 2017-03-14 2021-12-07 Bwt Llc Boronizing powder compositions for improved boride layer quality in oil country tubular goods and other metal articles

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2361017C3 (en) * 1973-12-04 1985-12-05 Vac-Hyd Processing Gmbh, 2358 Kaltenkirchen Method for boronizing the surface of a metallic workpiece
US4555326A (en) * 1984-05-17 1985-11-26 Betz Laboratories, Inc. Methods and compositions for boronizing metallic surfaces

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3936327A (en) * 1972-09-07 1976-02-03 Elektroschmelzwerk Kempten Gmbh Boriding composition
WO1983000106A1 (en) * 1981-07-02 1983-01-20 Turbine Metal Technology Inc Erosion resistant tubular apparatus for handling slurries
US4389439A (en) * 1981-07-02 1983-06-21 Turbine Metal Technology, Inc. Erosion resistant tubular apparatus for handling slurries
US4806175A (en) * 1983-06-25 1989-02-21 Korber Ag Method of surface hardening ferrous workpieces
US4637837A (en) * 1984-08-23 1987-01-20 Elektroschmelzwerk Kempten Gmbh Process for boriding metals and metal alloys by means of solid boriding agents
US6245162B1 (en) * 1998-07-09 2001-06-12 Houghton Durferrit Gmbh Boriding agent
US7264682B2 (en) 2002-11-15 2007-09-04 University Of Utah Research Foundation Titanium boride coatings on titanium surfaces and associated methods
US20050208213A1 (en) * 2002-11-15 2005-09-22 University Of Utah Research Foundation Titanium boride coatings on titanium surfaces and associated methods
US20070018139A1 (en) * 2005-05-10 2007-01-25 Chandran K S R Nanostructured titanium monoboride monolithic material and associated methods
US7459105B2 (en) 2005-05-10 2008-12-02 University Of Utah Research Foundation Nanostructured titanium monoboride monolithic material and associated methods
US7501081B2 (en) 2005-05-10 2009-03-10 University Of Utah Research Foundation Nanostructured titanium monoboride monolithic material and associated methods
US20100176339A1 (en) * 2009-01-12 2010-07-15 Chandran K S Ravi Jewelry having titanium boride compounds and methods of making the same
US20130243955A1 (en) * 2012-03-14 2013-09-19 Andritz Iggesund Tools Inc. Process and apparatus to treat metal surfaces
US8894770B2 (en) * 2012-03-14 2014-11-25 Andritz Iggesund Tools Inc. Process and apparatus to treat metal surfaces
US9068260B2 (en) 2012-03-14 2015-06-30 Andritz Iggesund Tools Inc. Knife for wood processing and methods for plating and surface treating a knife for wood processing
US10870912B2 (en) 2017-03-14 2020-12-22 Bwt Llc Method for using boronizing reaction gases as a protective atmosphere during boronizing, and reaction gas neutralizing treatment
US11192792B2 (en) 2017-03-14 2021-12-07 Bwt Llc Boronizing powder compositions for improved boride layer quality in oil country tubular goods and other metal articles

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FR2139869B1 (en) 1976-08-06
GB1384171A (en) 1975-02-19
SE379558B (en) 1975-10-13
BR7203538D0 (en) 1973-05-10
FR2139869A1 (en) 1973-01-12
DE2127096A1 (en) 1972-12-14
IT954646B (en) 1973-09-15
AT313666B (en) 1974-02-25
DE2127096B2 (en) 1978-11-02
JPS5121383B1 (en) 1976-07-02
DE2127096C3 (en) 1980-11-06

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