US3798195A

US3798195A - Thermostable polymeric vinylidene chloride compositions

Info

Publication number: US3798195A
Application number: US00354593A
Authority: US
Inventors: R Watson
Original assignee: Dow Chemical Co
Current assignee: Dow Chemical Co
Priority date: 1973-04-26
Filing date: 1973-04-26
Publication date: 1974-03-19
Anticipated expiration: 1991-03-19

Abstract

THIS INVENTION IS DIRECTED TO COMPOSITIONS OF MATTER COMPRISING A POLYMER OF VINYLIDENE CHLORIDE AND AS A HEAT STABLIZING AGENT THEREFOR, FROM ABOUT 0.25 TO 2 PERCENT BY WEIGHT OF N,N-BIS (2-HYDROXYETHYL) GLYCINE SODIUM SALT.

Description

United States Patent Oflice 3,798,195 Patented Mar. 19, 1974 3,798,195 THERMOSTABLE POLYMERIC VINYLIDENE CHLORIDE COMPOSITIONS Richard E. Watson, Midland, Mich., assignor to The Dow Chemical Company, Midland, Mich.

No Drawing. Continuation of abandoned application Ser. No. 169,356, Aug. 5, 1971. This application Apr. 26, 1973, Ser. No. 354,593

Int. Cl. C09d 3/74 US. Cl. 260-304 R 5 Claims ABSTRACT OF THE DISCLOSURE This invention is directed to compositions of matter comprising a polymer of vinylidene chloride and as a heat stabilizing agent therefor, from about 0.25 to 2 percent by weight of N,N-bis (Z-hydroxyethyl) glycine sodium salt.

CROSS-REFERENCE TO RELATED APPLICATION This is a continuation of application Ser. No. 169,356, filed Aug. 5, 1971, now abandoned.

BACKGROUND OF THE INVENTION The polymers of vinylidene chloride have been described in patents and in other literature for many years, e.g. US. Pat. 2,558,728, issued July 3, 1951. Such polymeric bodies, and compositions containing them are herein referred to as polymeric vinylidene chloride products. It has been found that most such products tend to darken after prolonged exposure to elevated temperatures. This darkening is accompanied by a change in the other physical properties of the polymeric product and is assumed to be an evidence of partial decomposition. Because of the many desirable properties of polymeric vinylidene chloride products, it is among the objects of the present invention to overcome or to prevent the tendency of such products to darken on heating.

SUMMARY It has been discovered, which discovery forms the present invention, that the foregoing and related objects may be attained through the incorporation in polymeric vinylidene chloride products of small amounts, generally in the range of from about 0.25 to 2 percent by weight, of N,N-bis (Z-hydroxyethyl) glycine sodium salt. This compound has been found useful in polymeric vinylidenechloride products per se or in the form of lacquers of vinylidene chloride polymers whether or not such modifiers as plasticizers, light stabilizers, or coloring agents are also present.

DESCRIPTION OF THE PREFERRED EMBODIMENTS By way of example, a copolymer of about 92.5 percent vinylidene chloride, 5 percent acrylonitrile and 2.5 percent methyl methacrylate was intimately mixed with from about 1 percent by weight N,N-bis (2-hydroxyethyl) glycine. The admixture was then dissolved in a solvent mixture composed of parts by weight tetrahydrofuran and 40 parts by weight toluene in an amount sufficient to form a solution containing 15 percent by weight of copolymer. The solution was initially substantially colorless and remained so even after being aged for five (5) days at a temperature of 45 C. in the presence of a chrome coupon. Additionally, there was no observable corrosion imparted to the chrome coupon during such aging.

By way of comparison, an otherwise identical solution but wherein the N,N-bis (2-hydroxyethyl) glycine was not present, became noticeably dark brown in color during the designated aging period, and significant corrosion was imparted to the chrome coupon.

Other tests have indicated that the amount of N,N-bis (2-hydroxyethyl) glycine may be as little as 0.25 percent, especially when the thermal conditions to be encountered by the composition are not extreme. In no case has it been found advantageous or desirable to employ more than 2 percent of this compound for its stabilizing eifect. It has further been found that the stabilizing agent may be added to a solvent solution of a vinylidene chloride polymer.

What is claimed is:

1. A lacquer of a vinylidene chloride polymer stabilized against thermal degradation having in admixture therewith as the stabilizer from about 0.25 to 2 percent by weight of N,N-bis (2-hydroxyethyl) glycine, sodium salt.

2. The composition of claim 1 wherein said lacquer comprises a vinylidene chloride polymer dissolved in a mixture of tetrahydrofuran and toluene.

3. The composition of claim 2 wherein said mixture comprises about 60 parts by weight tetrahydrofuran and about 40 parts by weight of toluene.

4. The comopsition of claim 3 wherein said vinylidene chloride polymer is a copolymer of vinylidene chloride, acrylonitrile and methyl methacrylate.

5. The composition of claim 4 wherein said copolymer contains about 92.5 percent vinylidene chloride, about 5 percent acrylonitrile and about 2.5 percent methyl methacrylate.

References Cited UNITED STATES PATENTS 2,224,944 12/1940 Young 260-3 0.4 2,789,101 4/1957 Wilson 260-4575 2,558,728 7/1951 Britton et al. 260-4585 3,335,108 8/1967- Pines 26045.85 3,335,109 8/1967 Pines 26045.85 2,990,391 6/1961 Grantham 26030.4 2,941,974 6/1960 Reymann et al. 26030.4

FOREIGN PATENTS 623,971 7/1961 Canada.

HOSEA E. TAYLOR, Primary Examiner V. P. HOKE, Assistant Examiner US. Cl. X.R.

260--33.6 UA, 45.85 A