US3788888A - Fiber-lubricant composition - Google Patents
Fiber-lubricant composition Download PDFInfo
- Publication number
- US3788888A US3788888A US00134858A US3788888DA US3788888A US 3788888 A US3788888 A US 3788888A US 00134858 A US00134858 A US 00134858A US 3788888D A US3788888D A US 3788888DA US 3788888 A US3788888 A US 3788888A
- Authority
- US
- United States
- Prior art keywords
- fiber
- fibers
- friction
- alkyl
- staple
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000314 lubricant Substances 0.000 title abstract description 10
- 238000009987 spinning Methods 0.000 abstract description 12
- 229920000642 polymer Polymers 0.000 abstract description 8
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract description 7
- 229920001577 copolymer Polymers 0.000 abstract description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract description 5
- 229920002994 synthetic fiber Polymers 0.000 abstract description 4
- 239000012209 synthetic fiber Substances 0.000 abstract description 4
- 150000001299 aldehydes Chemical class 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 description 48
- -1 fatty acid esters Chemical class 0.000 description 19
- 239000004094 surface-active agent Substances 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 238000004804 winding Methods 0.000 description 6
- 229920001967 Metal rubber Polymers 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 239000002216 antistatic agent Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 229920002972 Acrylic fiber Polymers 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000009960 carding Methods 0.000 description 3
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- RJTJVVYSTUQWNI-UHFFFAOYSA-N 2-ethylnaphthalene Chemical compound C1=CC=CC2=CC(CC)=CC=C21 RJTJVVYSTUQWNI-UHFFFAOYSA-N 0.000 description 2
- QIMMUPPBPVKWKM-UHFFFAOYSA-N 2-methylnaphthalene Chemical compound C1=CC=CC2=CC(C)=CC=C21 QIMMUPPBPVKWKM-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 150000002790 naphthalenes Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229940096992 potassium oleate Drugs 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- URGSMJLDEFDWNX-UHFFFAOYSA-N 1-butylnaphthalene Chemical compound C1=CC=C2C(CCCC)=CC=CC2=C1 URGSMJLDEFDWNX-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- ZMXIYERNXPIYFR-UHFFFAOYSA-N 1-ethylnaphthalene Chemical compound C1=CC=C2C(CC)=CC=CC2=C1 ZMXIYERNXPIYFR-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- LQBNOHAXLHRIQW-UHFFFAOYSA-N 2-propylnaphthalene Chemical compound C1=CC=CC2=CC(CCC)=CC=C21 LQBNOHAXLHRIQW-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 241000933336 Ziziphus rignonii Species 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- RZJRJXONCZWCBN-UHFFFAOYSA-N alpha-octadecene Natural products CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229950011260 betanaphthol Drugs 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 description 1
- QSLLXQPOVJSDAY-UHFFFAOYSA-L dipotassium;tetradecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCCCOP([O-])([O-])=O QSLLXQPOVJSDAY-UHFFFAOYSA-L 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940033623 potassium lauryl phosphate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
- Y10T428/2907—Staple length fiber with coating or impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
Definitions
- This invention relates to a fiber-lubricant composition (or spin finish for staple) suitable for use in high speed spinning. More specifically, it relates to a basic ingredient to be incorporated in a spin finish for staple and its object is to provide a fiber-lubricant composition which can increase the fiber to fiber friction and improve the interfiber cohesion between fibers while preventing the falling-out of fibers during the drawing process.
- Synthetic fibers such as polyester fibers, acrylic fibers and polyamide fibers are used in large quantities in the spinning instead of natural fibers such as wool and cotton.
- synthetic fibers there are various problems concerning lubricity, antistatic property, interfiber cohesion, etc. Particularly, the adaptability of the spinning process at a high speed has been a serious problem.
- the spinning process of synthetic staple fibers composed mainly of polyester or dry-spun acrylic fibers cannot be conducted smoothly as compared with the case of cotton, wool or acrylic fibers made by the wet spinning process, since melt-spun polyester fibers made by the melt spinning process and acrylic fibers made by the dry spinning process have a smooth surface configuration. There occur such troubles as winding up of fibers on cylinders at the carding process and winding up of fibers on the rolls at the drawing, roving and spinning processes. Occurrence of such operational troubles is greatly influenced by not only the surface state of the fibers but also the kind of surface treating agent used for the fibers.
- Surface treating agents or so-called textile lubricants are generally composed of a lubricating agent and an antistatic agent.
- the lubricating agent there are used animal oil, vegetable oil, mineral oil, fatty acid esters such as methyl oleate and butyl stearate, non-ionic surface active agents such as ethylene oxide adducts of fatty acids or fatty acid esters of higher or polyhydric alcohols, and anionic surface active agents such as alkyl sulfates, alkyl phosphates and fatty acid salts.
- non-ionic surface active agents such as ethylene oxide adducts of fatty acids or fatty acid esters of higher or polyhydric alcohols
- anionic surface active agents such as alkyl sulfates, alkyl phosphates and fatty acid salts.
- the antistatic agent there are used alkyl phosphates, alkyl sulfates, alkyl amineethylene oxide adducts, cationic surface active agents such as quaternary ammonium salts and alkyl betain'e type amphoteric surface active agents.
- alkyl phosphate salts there occurs a trouble that fibers fall on and wind up on the drawing rolls. For this reason, alkyl phosphate salts,
- the object of this invention is to provide a spinning finish or a basic ingredient therefor, which can increase the degree of interfiber cohesion of fibers while reducing the fiber to metal friction and the fiber to rubber friction, whereby falling off of fibers and winding up of fibers on the rolls can be prevented in the drawing process.
- Compounds of the above General Formula I may be synthesized by sulfonating naphthalene or a naphthalene derivative selected from the group consisting of alphana-phthol, beta-naphthol, a1pha-methyl-naphthalene, alphaethyl-naphthalene, alpha-propybnaphthalene, alpha-butylnaphthalene, beta-methyl-naphthalene, beta-ethyl-naphthalene, beta-propyl-naphthalene and beta-butyl-na-phthalene, with a concentrated sulfuric acid at 120-170 C. and condensing the sulfonated product at 150 C. under acidic conditions with formaldehyde, acetaldehyde, propionaldehyde, iso butylaldehyde or 'butylaldehyde.
- Compounds of above General Formula II are homopolymers of maleic anhydride or copolymers of maleic anhydride with a polymerizable unsaturated compound such as ethylene, butylene, isobutylene, di-isobutylene, alphaoctene, alpha-decene, alpha-octadecene, styrene, vinyl benzene and vinyl acetate.
- a polymerizable unsaturated compound such as ethylene, butylene, isobutylene, di-isobutylene, alphaoctene, alpha-decene, alpha-octadecene, styrene, vinyl benzene and vinyl acetate.
- Compounds of the above Formulas I and II may be optionally neutralized with an alkali metal such as sodium and potassium, ammonia, an amine substituted by an organic group such as ethanolamine, diethanoiamine, methylamine and dimethylamine, or a hydroxide or watersoluble salt thereof.
- an alkali metal such as sodium and potassium, ammonia
- an amine substituted by an organic group such as ethanolamine, diethanoiamine, methylamine and dimethylamine, or a hydroxide or watersoluble salt thereof.
- fiber-lubricant compounds of this invention can exhibit their properties when they are applied to fibers in an amount of ODS-1.0% by weight, preferably 0.1- 0.5 by weight.
- the treating agent of this invention may be used singly or in combination with another agent which has been used as an ingredient of a spin finish for staple, for instance, an antistatic agent.
- the following compounds may be preferably used:
- Alkyl phosphates and olyoxyethylene alkyl phosphates (to be used maily in the form of a sodium salt) (2) Polyoxyethylene alkyl sulfates (to be used mainly in the form of a sodium salt) (3) Fatty acid metal soaps such as potassium oleate (4) Non-ionic surface active agents such as poly0xyethylene alkylamines, polyoxyethylene alkylamides, polyoxyethylene alkyl ethers and olyoxyethylene alkyl esters ('5) .
- Betaine type amphoteric surfactants such as alkyl betaines and polyoxyalkyl betaines (6) Alkyl imidazoline type amphoteric surfactants (7) N-alkylaminopropionic acid type amphoteric sur- 30 fibers wind up on rubber rolls.
- Fiber-metal friction g. 38 57 Fiber-fiber friction, g 156 138 Mixing ratiio gel-cent by 60 Fiber-rubber friction, g 41 40 we g
- the embodiments of the invention in which an exclup 0011111051- sive property or priviledge is claimed are defined as non I tion II follows: Di-isobutvlene-meleicanhvdfide colwlymer 1.
- Amount applied (percent R by weight based on fiber weight) 0. 2 0. 3 0. 2 0. 3 surfflilclgeleetrie resistance 3 6X10 1 4X10 1 4 10 4 10 0 M n x x Cardtelectrification voltage, 0 0 o o
- R and R are H, OH or alkyl having from 1 to 4 carbon atoms
- R" is H or alkyl having from 1 to 3 cation.
- n is an average degree of polymerization in the range of from 3 to 10
- Me is H, alkali metal, ammonium or water-soluble substituted ammonium References Cited UNITED STATES PATENTS Schmidt 260-67 S Hill 260-67 8 Tiefethal et a]. 260--78.5 T
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45035215A JPS4841798B1 (enrdf_load_stackoverflow) | 1970-04-24 | 1970-04-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3788888A true US3788888A (en) | 1974-01-29 |
Family
ID=12435606
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00134858A Expired - Lifetime US3788888A (en) | 1970-04-24 | 1971-04-16 | Fiber-lubricant composition |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3788888A (enrdf_load_stackoverflow) |
| JP (1) | JPS4841798B1 (enrdf_load_stackoverflow) |
| DE (1) | DE2118699A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2086310B1 (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3908048A (en) * | 1972-04-07 | 1975-09-23 | Kao Corp | Method of improving interfiber cohesion of filament yarns |
| US4210700A (en) * | 1978-09-15 | 1980-07-01 | Allied Chemical Corporation | Production of polyester yarn |
| US5607540A (en) * | 1992-02-20 | 1997-03-04 | Teijin Seiki Co., Ltd. | Photoforming method and apparatus |
| US6200492B1 (en) | 1989-11-30 | 2001-03-13 | Henkel Kommanditgesellschaft Auf Aktien | Textile lubricants with improved resistance to slinging |
| CN117447367A (zh) * | 2023-10-26 | 2024-01-26 | 南京擎宇生物医药科技有限公司 | 萘系磺酸盐烷基醛甲醛缩合物及其应用 |
| CN117447365A (zh) * | 2023-10-26 | 2024-01-26 | 南京擎宇生物医药科技有限公司 | 一种萘系磺酸盐缩合物的制备方法 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05502273A (ja) * | 1989-11-30 | 1993-04-22 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | ポリマーを含有する繊維製品潤滑剤 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE648508C (de) * | 1934-12-29 | 1937-08-03 | I G Farbenindustrie Akt Ges | Verfahren zum Schlichten von Kreppgarnen |
| FR1400556A (fr) * | 1964-04-16 | 1965-05-28 | Centre Nat Rech Scient | Nouveaux polymères de l'anhydride maléique, procédé pour leur préparation et leurs applications |
-
1970
- 1970-04-24 JP JP45035215A patent/JPS4841798B1/ja active Pending
-
1971
- 1971-04-16 US US00134858A patent/US3788888A/en not_active Expired - Lifetime
- 1971-04-17 DE DE19712118699 patent/DE2118699A1/de active Pending
- 1971-04-22 FR FR717114342A patent/FR2086310B1/fr not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3908048A (en) * | 1972-04-07 | 1975-09-23 | Kao Corp | Method of improving interfiber cohesion of filament yarns |
| US4210700A (en) * | 1978-09-15 | 1980-07-01 | Allied Chemical Corporation | Production of polyester yarn |
| US6200492B1 (en) | 1989-11-30 | 2001-03-13 | Henkel Kommanditgesellschaft Auf Aktien | Textile lubricants with improved resistance to slinging |
| US5607540A (en) * | 1992-02-20 | 1997-03-04 | Teijin Seiki Co., Ltd. | Photoforming method and apparatus |
| CN117447367A (zh) * | 2023-10-26 | 2024-01-26 | 南京擎宇生物医药科技有限公司 | 萘系磺酸盐烷基醛甲醛缩合物及其应用 |
| CN117447365A (zh) * | 2023-10-26 | 2024-01-26 | 南京擎宇生物医药科技有限公司 | 一种萘系磺酸盐缩合物的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4841798B1 (enrdf_load_stackoverflow) | 1973-12-08 |
| FR2086310B1 (enrdf_load_stackoverflow) | 1974-02-15 |
| DE2118699A1 (de) | 1971-11-04 |
| FR2086310A1 (enrdf_load_stackoverflow) | 1971-12-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2324601A (en) | Sizing | |
| US2664409A (en) | Textile treating composition and method | |
| US3788888A (en) | Fiber-lubricant composition | |
| CA1128062A (en) | Oxidation stable polyoxyalkylene fiber lubricants | |
| WO1996006971A1 (en) | High cohesion fiber finishes | |
| US4317736A (en) | Soil resistant yarn finish for synthetic organic polymer yarn | |
| US4072617A (en) | Finish for acrylic fiber | |
| CN113818104A (zh) | 一种超细旦丝纺丝油剂及其制备方法 | |
| US3560382A (en) | Nylon carpet yarn finish | |
| US5370804A (en) | Neat oil finish with high lubricant content | |
| US5017658A (en) | Dyeable polypropylene fibers for clothes | |
| CA1150008A (en) | Finishes for polypropylene textile materials, process and product thereof | |
| US6200492B1 (en) | Textile lubricants with improved resistance to slinging | |
| US4632874A (en) | Filament coherency enhancing composition and textile yarns coated therewith | |
| US3888775A (en) | Oil composition for synthetic staple fibers | |
| US4242095A (en) | Yarn lubricants | |
| US5912078A (en) | Lubricant finish for textiles | |
| JPH03185180A (ja) | 沈着物を生じない仕上げ剤を有するアラミド繊維 | |
| US3434874A (en) | Acrylic fibers | |
| JPS6257984A (ja) | 防炎性合成繊維 | |
| US2767107A (en) | Antistatic treatment of hydrophobic resin articles | |
| US4033922A (en) | Synthetic sizes | |
| US3974321A (en) | Yarn sizing process and product | |
| US3368917A (en) | Coated textile yarn | |
| US2690427A (en) | Textile composition |