US3782979A - Spray shoe polish - Google Patents

Spray shoe polish Download PDF

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Publication number
US3782979A
US3782979A US00286247A US3782979DA US3782979A US 3782979 A US3782979 A US 3782979A US 00286247 A US00286247 A US 00286247A US 3782979D A US3782979D A US 3782979DA US 3782979 A US3782979 A US 3782979A
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Prior art keywords
wax
polish
shoe
shoe polish
plasticizer
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Expired - Lifetime
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US00286247A
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M Nevitt
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/06Other polishing compositions
    • C09G1/14Other polishing compositions based on non-waxy substances
    • C09G1/16Other polishing compositions based on non-waxy substances on natural or synthetic resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/30Materials not provided for elsewhere for aerosols

Definitions

  • This invention relates to a wax-free and silicone-free polishing composition of the aerosol type especially adapted to be sprayed on shoes for both shining and polishing shoes and effectively waterproofing the lasts thereof.
  • the present invention overcomes the disadvantage of the prior shoe polish by using in combination with ethylcellulose and diethyl phthalate as a plasticizer, a combina tion of three solvents of different boiling points which serve to assure an exceedingly high gloss with great depth and clarity and which employs a solvent inhibiter for inhibiting the cracking of the shoe leather, which leaves no wax build-up and which, in fact, smoothes out and utilizes any pigmented wax coating already on the shoe leather to re-pigment and color scuffed portions of the shoe.
  • the base used is preferably ethyl cellulose.
  • lacquer bases such as nitro cellulose have been tried but these bases have a tendency to color and stain rugs, carpets or clothing adjacent the shoes to be shined if such material is sprayed thereon.
  • ethyl cellulose as a base, it will remain suitably plastic for at least the reasonable life of the shoes when as a plasticizer, diethyl phthalate is also employed.
  • Other plasticizers have been tried but none eliminated the cracking of leather as well in the combination as did diethyl phthlate.
  • a base solvent the substance sold under the trade name Cellulose Acetate which is ethylene glycol monoacetate is employed.
  • Alcohol such as ethanol is employed which in the combination claimed immediately dissolves, spreads, disperses and evens out any carnauba wax or the like which remains on the shoes from previous polishings and fills in pits, cracks and scuffs with this material.
  • Cloroethene 111 Tricloroethane
  • Perfume may be employed as desired.
  • composition of this invention the following materials were co-mixed and packaged in an aerosol container at pressures ranging between 30 and 60 p.s.i.
  • An aerosol type wax and silicone free shoe polish for spraying onto a surface from a container in which said composition is retained under superatmospheric pressure, consisting essentially of about 2%-15% by weight of a cellulose acetate as a base, 1.5%4% of diethyl phthlate as a. plasticizer, and three solvents of differing boiling points, said three solvents being 3-24% of ethylene glycol monoacetate, 6%-11% alcohol, and 55%-26% methylene chloride, and 25% to chloroethene there being from 27.5% to 10% of propellant in said container.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Detergent Compositions (AREA)

Abstract

A SPRAY SHOE POLISH THAT IS WAX AND SILICONE FREE. ETHYL CELLULOSE IS USED AS A BASE. A PLASTICIZER AND AN INHIBITER ARE EMPLOYED AS ARE THREE SOLVENTS HAVING DIFFERENT BOILING POINTS FOR PROVIDING HIGH GLOSS, NO WAX BUILD-UP, SOLUBILITY OF PREVIOUS COATINGS, CRACK INHIBITION AND DISPERSAL OF PREVIOUSLY APPLIED WAX.

Description

States Patent 3,782,979 SPRAY SHOE POLISH Milton Nevitt, '51" Royal Way, Manhasset Hills, .New Hyde Park, N-Y. 11040 No Drawing. Continuation-impart of application Ser. No. i
189,398, Oct. 14, 1971, now Patent No. 3,704,143. This application Sept. 5, 1972, Ser. No. 286,247
" The portion of the term of the patent subsequent to Nov. 28, 1989, has been disclaimed Int. Cl. C09g N10 US. Cl. 106--5 6 Claims ABSTRACT OF THE DISCLOSURE A spray shoe polish that is wax and silicone free. Ethyl cellulose is used as a base. A plasticizer and an inhibiter are employed as are three solvents having different boiling points for providing high gloss, no wax build-up, solubility of previous coatings, crack inhibition and dispersal of previously applied wax.
REFERENCE TO RELATED APPLICATION This application is a continuation-in-part of the application of Milton Nevitt, Ser. No. 189,398, filed Oct. 14, 1971, now Pat. No. 3,704,143, for Aerosol Spray Polish.
BACKGROUND OF THE INVENTION Field of the invention This invention relates to a wax-free and silicone-free polishing composition of the aerosol type especially adapted to be sprayed on shoes for both shining and polishing shoes and effectively waterproofing the lasts thereof.
Description of the prior art In the past aerosol spray shoe polishes containing waxes such as carnauba wax :and/ or silicones have been used. These polishes have had undersirable results from continued use because of wax build-up which causes an uneven and unslightly surface, and because heretofore the use of silicones has caused cracking of the leather of the last of the shoe on which it is sprayed. Further, in the case of shoe polishes it has been generally necessary to utilize a pigment as a part of the mixture to gain an effective and pleasing shine for shoes, which pigment requires spraying only in a protected or special area decreasing the desirability of the aerosol product due to possibility of staining. Further, when a pigmented product is utilized the shoe polish is adapted for use only on shoes of one specific color.
In the past, also various anti-blotching agents such as sodium dodecylbenzene sulfonate in a solution which must be wiped off to give a reasonable gloss or buffed to provide a shine.
SUMMARY OF THE INVENTION The present invention overcomes the disadvantage of the prior shoe polish by using in combination with ethylcellulose and diethyl phthalate as a plasticizer, a combina tion of three solvents of different boiling points which serve to assure an exceedingly high gloss with great depth and clarity and which employs a solvent inhibiter for inhibiting the cracking of the shoe leather, which leaves no wax build-up and which, in fact, smoothes out and utilizes any pigmented wax coating already on the shoe leather to re-pigment and color scuffed portions of the shoe.
3,782,979 Patented Jan. 1, 1974 Ice DETAILED DESCRIPTION OF THE INVENTION The base used is preferably ethyl cellulose. Various other lacquer bases such as nitro cellulose have been tried but these bases have a tendency to color and stain rugs, carpets or clothing adjacent the shoes to be shined if such material is sprayed thereon. When using ethyl cellulose as a base, it will remain suitably plastic for at least the reasonable life of the shoes when as a plasticizer, diethyl phthalate is also employed. Other plasticizers have been tried but none eliminated the cracking of leather as well in the combination as did diethyl phthlate.
Besides the base and plasticizer, three solvents are used in the aerosol spray shoe polish to gain the desired results of this invention. As a base solvent, the substance sold under the trade name Cellulose Acetate which is ethylene glycol monoacetate is employed. As a solvent fully compatible with the thyl cellulose, alcohol, such as ethanol is employed which in the combination claimed immediately dissolves, spreads, disperses and evens out any carnauba wax or the like which remains on the shoes from previous polishings and fills in pits, cracks and scuffs with this material.
As an ultra-fast acting solvent of very low boiling point which will at least partially dissolve prior lacquer coatings of most types which had been sprayed on the shoe to be polished there is used methylene chloride. This quickly evaporating solvent has been found to be useful in that almost immediately after spraying the uppermost layer of molecules evaporate leaving a sufliciently hard coating so the wearer may immediately utilize the shoes Without fear of smudging the finish.
As the solvent inhibitor for preventing cracking of the shoe leather by slight lubrication of the surface of the shoe leather Cloroethene (111 Tricloroethane) is employed. Perfume may be employed as desired.
In the example of the composition of this invention the following materials were co-mixed and packaged in an aerosol container at pressures ranging between 30 and 60 p.s.i.
EXAMPLE I Acceptable Preferred, range, percent by percent by Material weight Weight Base: Cellulose acetate 3 2-16 Plasticizer:
Dicthyl phthlate 1. 87 1. 5-4 Ethyleneglycol monoacetate. 3. 75 3-24 Triple solvents:
Anhydrous ethanol 7. 6-11 Methylene chloride 33.75 35-26 50 Crack inhibitor: Ghloroethan 24. 98 25-9 Perfume 15 0-1. 0 Propellant 25. 00 27 5-10 EXAMPLE II Preferred, Acceptable percent by range, Material weight percent;
Base: Cellulose acetate 9. 66 8-15 Plasticizer:
Diethyl phthlate 2. 94 2-4 Ethyleneglycol monoacetate 16. 80 12-24 Triple solvents: Alcohol 40-B anhydrous 8. 40 6-11 Methylene chloride. 46. 20 55-26 Propellant 16. 00 15-20 I claim:
1. An aerosol type wax and silicone free shoe polish for spraying onto a surface from a container in which said composition is retained under superatmospheric pressure, consisting essentially of about 2%-15% by weight of a cellulose acetate as a base, 1.5%4% of diethyl phthlate as a. plasticizer, and three solvents of differing boiling points, said three solvents being 3-24% of ethylene glycol monoacetate, 6%-11% alcohol, and 55%-26% methylene chloride, and 25% to chloroethene there being from 27.5% to 10% of propellant in said container.
2. A polish as disclosed in claim 1, wherein the composition consists of 3% by weight of said base.
3. A polish as disclosed in claim 1, wherein the composition consists of 1.87% by weight of said plasticizer.
4. A polish as disclosed in claim 1, wherein the composition consists of 3.75% by weight of ethylene glycol monoacetate, 7.00% by weight of ethanol, and 33.75% by weight of methylene chloride.
5. A polish as disclosed in claim 1, wherein the composition consists of 24.98% by weight ofchloroethane.
6. A polish as disclosed in claim 1, wherein the com- 7 position consists of 3% by Weight of cellulose acetate,
UNITED STATES PATENTS 3,704,143 11/ 1972 Nevitt 1065 3,503,761 3/1970 Schumacher 1068 3,291,625 12/1966 Faraone 106196 2,857,314 10/1958 Phillips 106197 R THEODORE MORRIS, Primary Eiiaminer U.S. C1. X.R.
US00286247A 1971-10-14 1972-09-05 Spray shoe polish Expired - Lifetime US3782979A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US18939871A 1971-10-14 1971-10-14
US28624772A 1972-09-05 1972-09-05

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US3782979A true US3782979A (en) 1974-01-01

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2302039A1 (en) * 1975-02-27 1976-09-24 Sogemaric Gestion Marketing In Insecticidal aerosol compsn. contg. a liq. film former - and a mixt. of three solvents of different volatility(BR14976)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2302039A1 (en) * 1975-02-27 1976-09-24 Sogemaric Gestion Marketing In Insecticidal aerosol compsn. contg. a liq. film former - and a mixt. of three solvents of different volatility(BR14976)

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