US3779207A - Apparatus for impregnating and coating fibrous strands - Google Patents

Apparatus for impregnating and coating fibrous strands Download PDF

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US3779207A
US3779207A US00171252A US3779207DA US3779207A US 3779207 A US3779207 A US 3779207A US 00171252 A US00171252 A US 00171252A US 3779207D A US3779207D A US 3779207DA US 3779207 A US3779207 A US 3779207A
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strand
coating material
filaments
combining
sponge
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G Benson
P Yakuboff
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Owens Corning
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Owens Corning Fiberglas Corp
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Assigned to WILMINGTON TRUST COMPANY, WADE, WILLIAM, J. reassignment WILMINGTON TRUST COMPANY SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: OWENS-CORNING FIBERGLAS CORPORATION
Assigned to OWENS-CORNING FIBERGLAS CORPORATION, A CORP. OF DE. reassignment OWENS-CORNING FIBERGLAS CORPORATION, A CORP. OF DE. TERMINATION OF SECURITY AGREEMENT RECORDED NOV. 13, 1986. REEL 4652 FRAMES 351-420 Assignors: WADE, WILLIAM J. (TRUSTEES), WILMINGTON TRUST COMPANY, A DE. BANKING CORPORATION
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • D06B15/08Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours by scraping
    • D06B15/085Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours by scraping by contact with the textile material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10Coating or impregnating independently of the moulding or shaping step
    • B29B15/12Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B29B15/125Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex by dipping

Definitions

  • the present invention relates generally to the con- 5 trolled application of a coating or impregnant to strands of textile filaments or other finely elongated materials.
  • producers of treated fibrous strands have constantly sought to maintain a high degree of impregnation uni- I formity while simultaneously achieving complete permeation.
  • a resiliently compressible material may be utilized to eliminate many objectionable features of strand wiping system employing fixed dies without destroying desirable attributes.
  • the resiliently compressible material is provided by an absorptive sponge in a design having an endless surface, such as a cylinder or an endless belt.
  • the impregnated or coated strand is passed across the sponge in a path which at least partially embeds the strand into the sponge.
  • the strand is completely surrounded by the sponge, and at the other extreme, the sponge only contacts one side of the strand.
  • FIG. I is a side elevation in partial section of aglass strand impregnation and coating production line which includes the impregnation apparatus of this invention.
  • FIG. 2 is a plan view of the production line shown in FIG. 1.
  • FIG. 3 is a side elevation in partial section of this invention shown in FIG. 1 with modifications featuring 0 two sponge rolls mounted in tandem and a nozzle spraying liquid onto the last sponge roll.
  • FIG. 4 is a side elevation in partial section of this in vention shown in FIG. 1 with a further modification featuring an endless sponge covered belt replacing the roll.
  • FIG. 5 is a section view of an impregnated glass strand passing over the sponge roll of this invention and illustrating one method of removing excess impregnant from the strand
  • FIG. 6 is a section view of an impregnated glass strand passing over the sponge roll of this invention and illustrating a second method of removing excess impregnant from the strand.
  • FIG. 7 is a section view of an impregnated glass strand passing over the sponge roll of this invention and illustrating a third method of removing excess impregnant from the strand.
  • FIG. 8 is a section view of a modified sponge roll to be used in this invention.
  • FIG. 9 is an end view of the modified sponge roll shown in FIG. 8.
  • FIG. 1 and FIG. 2 show more specifically a production operation wherein linear materials in the form of fibrous strands 15 are pulled from packages 11 through tension controlling devices 13.
  • the strands are then guided by grooved surfaces or pulleys 17, 23 and 27- through a reservoir of impregnating medium 21 which is held in a vat 19.
  • the strands 25, having an excess of impregnant, are then guided across the sponge surface 31 of a revolving drum 29 where the excess impregnant is removed.
  • the strands 37 having the desired amount of impregnant on them, are passed through a curing oven 39 and wound into a package 47 by a standard winding device 52.
  • the initial thread-up of the production line is manually accomplished, but thereafter, strand moving forces are supplied entirely'by the winding device.
  • strands 15 of unimpregnated fibers By way of example, the impregnation process shall be described for glass fibers, but the same process would apply for any type of textile filaments in a strand.
  • the term strand is used here to mean a primary bundle of continuous filaments combined in a single compact unit without twist as well as a bundle of twisted continuous or staple filaments. It also is used here to means plied bundles of twisted or untwisted filaments.
  • the diameter of the filaments may vary in size, but must be small enough to be flexible.
  • the number of filaments in the strand may also vary. However, a strand having a very small number of filaments becomes impractical to handle.
  • a strand having a very large number of filaments It is not known what maximum number of filaments in one strand can be completely impregnated in the impregnation line of this invention, but it is thought that as many as two thousand filaments in one bundle can be satisfactorily impregnated in the apparatus of this invention.
  • An example of a strand satisfactorily impregnated in the apparatus of this invention is one of continuous fiber glass filaments containing 408 filaments with an average diameter for each filament of 0.00036 inches and the strand having one-half twist per inch.
  • grooved surfaces 17, 23 and 27 are laterally disposed in spaced aligned relationship to thereby separately guide the strands in parallel fashion through the impregnating bath 21.
  • strands are saturated with the impregnant material to generously coat the outer surface of the composite strand as well as each individual filament.
  • the strands 15 are subjected to the impregnant long enough to accomplish the viscous work necessary in overcoming the influence of variables such as mechanical and chemical cohesiveness of the individual filaments and the impregnant.
  • the impregnant material 21 is exemplified by an elastomeric dispersion.
  • coating materials including an aqueous or non-aqueous solution of a film forming composition or a hot melt or a solvent free material which is liquid at room temperature but which may be hardened by a subsequent chemical or thermal condition may be applied equally as well by using the techniques of this invention.
  • Desirable but optional additives such as pigments, dyes, plasticizers, emulsifiers, lubricants and coupling agents may also be added.
  • impregnant and impregnation are used here to refer also to coating material and coating.
  • the strands 25 have more impregnant on them than is desired in the final impregnated strand.
  • the excessively impregnated strand is guided horizontally across the sponge surface 31 of revolving drum 29 where the excess impregnant is removed from the strand and absorbed by the sponge 31.
  • the wetted sponge is revolved by a hard-surface roll 33 which squeezes out most of the impregnant from the sponge.
  • the impregnant 35 squeezed from the sponge flows back into the vat l9 and again becomes part of the impregnant reservoir 21.
  • the sponge covered drum 29 is rotatably mounted above squeeze roll 33. It has been found advantageous to mount the shaft of the drum 29 loosely in vertical slots. The vertical positioning of the drum 29 is then determined by balancing the weight of the drum 29 with the compression resisting force of the sponge surface 31. The advantage of this arrangement is that a new drum 29 can be quickly substituted for an old one that has developed a worn sponge surface.
  • the drum can be made from any hard material, such as steel.
  • the sponge covering the drum is preferably an open cell flexible foam such as polyester or polyurethane. Other material capable of absorbing the impregnant can also be used as long as it is compressible and resilient. An, example of a satisfactory sponge is one three-eighths inches tain good results.
  • the squeeze roll 33 is rotatably mounted about a fixed axis. It is preferably driven by a conventional power source, such as an electric motor 32, through chains, V-belts, or direct drive. lts surface interaction with the sponge surface 31 of the cylinder 29 accomplishes rotation of the cylinder 29 with the result that the sponge surface 31 is continually squeezed by the roll 33.
  • the squeeze roll 33 can be made from any of several hard materials. An example of a satisfactory material is stainless steel.
  • the strands 37 having the desired amount of impregnant are advanced through the curing oven 39 where the impregnant is cured to the desired degree.
  • the heat source in the curing oven can be supplied by any conventional form of heat, such as gas combustion, electrically heated elements, micro-wave energy, etc.
  • the length of the oven is dependent upon the rate of impregnant cure and the speed of the strand passing through the oven. Curing of impregnants in this manner is well known in the art. In some cases the impregnant cure is carried out at ambient conditions, and no curing oven is required.
  • the strand 41 with cured impregnant is advanced from the curing oven 39, over guide roller 43 and wound into a package 47.
  • the winding is accomplished by a commercially available standard winding apparatus commonly used in the textile industry.
  • the winder 52 shown schematically consists of an electric motor 48 which rotates a shaft 50 upon which a collet 45 has been placed and reciprocates a traversing guide 46 back and forth along the length of the package to distribute the advancing strand 41 as it is wound into a package 47 on the rotating collet 45.
  • the winding apparatus also supplies the pulling force to advance the strand through the impregnation line.
  • the winder 52 is shown at one position only for illustrative purposes, but each position in the line would have a similar winder.
  • the tension control 13 Resisting the pull of the winding apparatus is the tension control 13, along with frictional forces developed where the strand contacts members of the impregnation line.
  • the tension control 13 is shown as a simple three finger configuration which is designed to produce the desired amount of drag on the strand when the strand is being pulled at operating speed. It may be desirable to use an adjustable tension controller, especially if the impregnation line is operated by varying speeds. Such an adjustment can be accomplished by varying the distance between the three fingers in the tension control 13 shown, as well as through use of other well known tension controllers.
  • FIG. 3 illustrates another feature of this invention.
  • the impregnation line shown in FIG. 3 is the same as that shown in FIGS. 1 and 2, but it has two sponge covered wiping drums 329 and 359. Each drum rests upon a squeeze roll 333 and 363 which turns the sponge covered wiping drum 329 and 359 and squeezes removed excess impregnant 335 and 365 from the sponges 331 and 361.
  • the second wiping drum it has been found that the strand can be advanced through the impregnation line at a faster speed than with only one wiping drum and still obtain the desired impregnation removal. It is not necessary that both sponge covered drums rotate in the same direction nor at the same speed.
  • this invention also contemplates the use of more than two sponge covered wiping drums. Three or more drums could be used to allow faster line speed operation and better control of the amount of impregnant removed. As with the use of two wiping drums, each drum in a series of three or more drums can be rotated in either direction and at a different speed from the other drums.
  • FIG. 3 also illustrates another feature of this invention. Included in the impregnation line is a spray nozzle 350 for applying a liquid 354 to the sponge 361 on the last drum 359.
  • the liquid 354 is supplied through a pipe 352 under pressure. It can be pumped, or if water is used, the usual line pressure can be used for the motivating force.
  • the function of the liquid is to prevent the removed impregnant from drying on the sponge 361 and thereby facilitate removal of the impregnant from the sponge by the squeeze roll 363.
  • FIG. 3 shows the liquid being squeezed out of the sponge along with the removed impregnant. If the liquid is of a type which will contaminate the reservoir of impregnant 321, the catch area for the removed impregnant 365 must be separated from the reservoir of impregnant 321.
  • FIG. 4 illustrates a further feature of this invention.
  • the impregnation line shown in FIG. 4 is the same as shown in FIGS. 1 and 2, but having an endless sponge belt 431 rather than a sponge covered drum.
  • the sponge belt is mounted on two spaced drums 429 and 459 which are rotatable about parallel axes. One of the drums rests upon a squeeze roll 433 with the sponge belt between. The squeeze roll 433 rotates the belt 431 and squeezes the removed excess impregnant 435 from the belt.
  • FIG. 4 shows the squeeze roll mounted below drum 429, but it could be just as well mounted below drum 459 in the location shown by the broken line.
  • the belt 431 is shown in FIG.
  • FIGS. 5, 6 and 7 illustrate three methods of impregnation removal possible with this invention.
  • the method which applies is dependent upon the compressibility and resiliency of the sponge material and the depth to which the strand is embedded into the sponge.
  • FIG. 5 illustrates a strand 525 embedded only slightly into the sponge 531. This arrangement would result when the sponge is positioned so that it barely interferes with the path of the strand. With this arrangement the sponge 531 wipes impregnant 565 from beneath the strand 525. As the impregnant is wiped off the strand, it is absorbed into the sponge 571 and carried away by the moving sponge so that a fresh sponge surface is presented to the advancing strands.
  • impregnant 5 After impregnant 5 is wiped from the bottom of the strand, the remaining impregnant on and in the strand of filaments 567 distributes to again cover the bottom of the strand, if the impregnant is not too viscous. In this manner, removal of excess impregnant from all parts of the strand can be accomplished by wiping only the bottom of the strand.
  • FIG. 6 illustrates a strand 625 deeply embedded into the sponge 631 and completely surrounded by the sponge.
  • This arrangement would result when the sponge is of an easily compressible material which is very resilient and the sponge is in a position which interferes substantially with the path of the strand and the strand is pulled with sufficient tension to overcome the resilient forces of the sponge.
  • the sponge 631 wipes impregnant 669 from the complete circumference of the strand 625 without appreciably exerting pressure on the strand so that the impregnant surrounding the internal filaments of the strand remain well impregnated.
  • the impregnant wiped from the strand 625 is absorbed in the sponge 671 and carried away by rotation of the drum so that a fresh sponge surface is presented to the strand.
  • the method of removing excess impregnant shown in FIG. 6 allows more removal for the same strand speed than that shown in FIG. 5. It might be desirable to utilize the FIG. 6 method in the first sponge covered roll 331 of FIG. 3 to remove the bulk of the excess impregnant and the FIG. method in the second sponge covered roll 361 of FIG. 3 to make a final wipe with finer control. In the event the first sponge covered drum 331 is used to remove the bulk of the excess impregnant, it will be necessary to rotate it faster than the second sponge covered drum 361 to remove the larger amount of impregnant removed from the sponge. The use of either wiping method would be determined by the material of the sponge and the height setting of the squeeze roll 333 and 363.
  • Adjustment can also be made by raising or lowering guide rolls 27 and 43 shown in FIG. 1.
  • the tension in the strand as it comes in contact with the sponge is also an important factor in determining the degree to which the strand is pulled into the sponge. Even if the strand guides are set to cause the strand path to interfere with the sponge, the strand will only ride on top of the sponge unless there is sufficient tension to pull the strand into the sponge.
  • the tension adjustment is made at the tension controller 13 of FIG. 1. The tension is adjusted to a greater amount until the desired strand depth in the sponge is obtained.
  • FIG. 7 illustrates yet another method of excess impregnant removal within the scope of this invention.
  • the strand 725 is deeply embedded into the sponge 731 as was the case in FIG. 6, but here the sponge does not completely surround the strand as it did in FIG. 6.
  • This arrangement results when the sponge is of an easily compressible material, but not as resilient as the material of FIG. 6 or when the strand path and tension do not pull the strand to the same depth into the sponge as with the method of FIG. 6.
  • the sponge must also be positioned so that it will interfere substantially with the path of the strand. With this arrangement the sponge wipes excess impregnant from the majority of the circumference of the strand, perhaps 270. The remaining portion of the excess impregnant on the top of the strand distributes to evenly coat the surface of the strand.
  • this method of excess impregnant removal can be used in combination with the method shown in FIG. or FIG. 6.
  • all three methods could be used in combination.
  • the first wipe could be taken by the method of FIG. 6, the second wipe by the method of FIG. 7, and the last wipe by the method of FIG. 5.
  • Other combinations could, of course, also be used.
  • impregnant removal by the apparatus of this invention can be accomplished in three ways.
  • the first, as already stated, is wiping.
  • the second is sucking action brought about by the cells of the sponge resiliently expanding after passing the strand contact zone.
  • the third method is drawing the impregnant from the strand by capillary action of the sponge cells.
  • the second method requires rotation of the sponge covered drum to perform, and probably, the rotation must be much faster than with the other methods of impregnant removal.
  • the first method requires rotation of the sponge covered drum only to present the strand with a fresh surface, as does the third method.
  • FIGS. 8 and 9 illustrate yet another feature of this invention.
  • FIG. 8 is a cut-away view of a modified sponge covered drum
  • FIG. 9 is an end view of the drum shown in FIG. 8.
  • the drum 829 is a hollow sealed tube with sponge covering 831.
  • On one end of the hollow shaft 875 is a removable cap 873 which can be attached by any conventional method, such as with threads.
  • the hollow shaft 875 is perforated inside of the sealed drum 829. With this arrangement, water can be poured into the end of the shaft after the cap is removed to fill the drum with water to the level desired.
  • the weight g of the sponge covered drum is adjustable.
  • the degree of sponge compression at the squeeze roll can be adjusted by adding or subtracting water from the roll. It may be found necessary to squeeze the sponge more when operating at fast strand speeds in order to remove the desired amount of absorbed impregnant from the sponge, and with this arrangement the same sponge covered roll can be used at many different speeds by adjusting the level of water in the drum.
  • Strand guide bar 27 can be moved back and forth horizontally a short distance as indicated by two-headed arrow 28 to change the path of the strand 25 across the sponge covered drum 31. In this way the operating life of the sponge will be extended because more surface of the sponge will be exposed to the strand. Movement of the strand guide bar 27 can be accomplished by a number of methods, such as a motor and cam arrangement. It is not necessary that the movement be constant and therefore, the simplest method is periodical manual indexing of the strand guide bar 27 by the operator of the apparatus. It should also be noted that the same effect can be obtained by moving the sponge covered drum 31 back and forth rather than the strand guide bar.
  • this invention is not limited to glass fibers, but applied to many varieties of textile fibers. Also, it can be readily seen that it is not limited to strands in its use. Coating of monofilaments can also be accomplished. It is further pointed out that the impregnation of the strand can also be accomplished by means other than dipping the strand into a bath of impregnant.
  • the impregnant can be sprayed onto the strand prior to the strand contacting the sponge or the impregnant can be applied to the sponge itself whereby the strand will then pick up the impregnant in metered quantities when contacting the strand.
  • Apparatus for combining a coating material with filaments of a strand comprising in combination:
  • Means for applying coating material in liquid form to said strand
  • a movable member for removing any desired excess of said coating material said member being of a resiliently compressible and absorptive material
  • Means for establishing a predetermined tension in said strand said tension being sufficient to cause said strand to compress part of said resiliently compressible and absorptive material of said member in the region of contact to cause the exterior surface of said member to substantially surround said strand for removal of excess coating material during advancement of said strand.
  • Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said means for advancing said strand along said predetermined path and means for establishing said predetermined tension in said strand causes said strand to move below the uncompressed surface regions of said member to cause said exterior surface of said member in the region of contact to completely surround said strand.
  • Apparatus for combining a coating material with filaments of a strand including means to rotate said strand about its longitudinal axis as it moves through said apparatus.
  • Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said means for applying coating material to said strand comprises a reservoir of coating material through which said strand is passed.
  • Apparatus for combining a coating material with filaments of a strand according to claim 4 wherein said means for moving said strand at a predetermined tension comprises a winder pulling said strand and a tension controller resisting movement of said strand.
  • Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said member comprises a rotatable cylinder.
  • Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said member comprises an endless belt mounted upon a pair of spaced apart cylinders rotatable about substantially parallel axes.
  • Apparatus for combining a coating material with filaments of a strand according to claim 1 including means for squeezing said member to extract the excess coating material absorbed by said member.
  • Apparatus for combining a coating material with filaments of a strand according to claim 8 including means to apply liquid to said member to dilute the excess coating material so that such material is more easily extracted from said member.
  • Apparatus for combining a coating material with filaments of a strand according to claim 8 wherein said means for squeezing said member comprises a rotatable cylinder in compressing relationship with said member.
  • Apparatus for combining a coating material with filaments of a strand according to claim 1 including means to laterally vary the path of said strand on said member.
  • Apparatus for combining a coating material with filaments of a strand comprising in combination:
  • Means for applying coating material in liquid form to said strand
  • a plurality of movable members for removing any desired excess of said coating material, each of said plurality of members being of a resiliently compressible and absorptive material;
  • Means for establishing a predetermined tension in said strand said tension being sufficient to cause said strand to compress part of said resiliently compressible and absorptive material of each of said members in the region of contact to cause the exterior surface of each of said members to substantially surround said strand for removal of excess coating material during advancement of said strand.
  • Apparatus for coating strand comprising in combination:
  • Means for applying coating material in liquid form to said strand
  • a movable endless surface for removing excess coating material from said strand said surface being of resiliently compressible and absorptive material and having a substantially greater thickness than the diameter of said strand;

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Coating Apparatus (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

Strands of textile filaments are impregnated and coated with a liquid material by passing each strand through an immersion bath and in contact with a resiliently compressible and absorptive material which wipes off excess impregnant and coating from the strand. The path and tension of the strand is adjustable to vary the depth at which the strand is embedded into the absorptive material. The absorptive material is in the form of an endless surface constantly rotating to continuously present an unsaturated portion to the strand.

Description

United States Patent 1 Benson et al.
[ Dec. 18, 1973 1 1 APPARATUS FOR IMPREGNATING AND COATING FIBROUS STRANDS [75] Inventors: Gustav E. Benson, Edgewood; Paul D. Yakuboff, Woonsocket, both of R].
[73] Assignee: Owens-Corning Fiberglas Corporation, Toledo, Ohio [22] Filed: Aug. 12, 1971 [21] Appl. No.: 171,252
[52] US. Cl. 118/109, 28/28 [51] Int. Cl B05c 11/02, D060 29/00 [58] Field of Search 118/68, 109; 28/28 [56] References Cited UNITED STATES PATENTS 1,968,687 Johnson 118/109 Roclcoff 28/28 Wagner et al. 118/68 Primary ExaminerLouis K. Rimrodt Attorney-Carl G. Staelin et al.
57 ABSTRACT 15 Claims, 9 Drawing Figures APPARATUS FOR IMPREGNATING AND COATING FIBROUS STRANDS BACKGROUND OF THE INVENTION The present invention relates generally to the con- 5 trolled application of a coating or impregnant to strands of textile filaments or other finely elongated materials. For economical and technical reasons, producers of treated fibrous strands have constantly sought to maintain a high degree of impregnation uni- I formity while simultaneously achieving complete permeation. Conventional fixed dies consisting of a small circular orifice in a hard metallic structure and employed to strip excess impregnant from moving fibrous strands have provided reasonably accurate and uniform control over the process, but from a manufacturing viewpoint the standard die system has several disadvantages. The most significant disadvantage stems from the inability of the system to function for long periods of operation without clogging. For example, the throat of the die orifice tends to accumulate a residue of dried impregnant as well as trap other solid particles such as strand fuzz and the like. These trash deposits constrict orifice diameter and account for a high incidence of strand breakage and poor impregnation quality.
Furthermore, present high production speeds coupled with the natural abrasiveness of fibrous materials, glass fibers in particular, have drastically reduced the life span of even the most durable dies. Replacement of worn or defective dies naturally require numerous process interruptions. These interruptions and those necessarily incurred for installation of different die sets for the purpose of changing product specification may be prohibitive in regard to maintaining desirable operating efficiencies.
In view of the limitations and soaring replacement costs of fixed dies, including resultant declines in operating efficiencies, it becomes apparent that this method of controlling fibrous strand coating and impregnation is no longer economically favorable.
SUMMARY OF THE INVENTION According to the present invention, it has been discovered that a resiliently compressible material may be utilized to eliminate many objectionable features of strand wiping system employing fixed dies without destroying desirable attributes. The resiliently compressible material is provided by an absorptive sponge in a design having an endless surface, such as a cylinder or an endless belt. The impregnated or coated strandis passed across the sponge in a path which at least partially embeds the strand into the sponge. Thus, at one extreme the strand is completely surrounded by the sponge, and at the other extreme, the sponge only contacts one side of the strand.
As the strand passes in contact with the sponge, excess impregnant is wiped from the strand and absorbed by the sponge. The sponge can be rotated to move the impregnant-saturated portion of the sponge away from the strand contact zone. At another location remote from the strand contact zone the impregnant-saturated portion of the sponge is squeezed to remove the absorbed impregnant. This invention includes variations which are further described in the Description of Exemplary Embodiments.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. I is a side elevation in partial section of aglass strand impregnation and coating production line which includes the impregnation apparatus of this invention.
FIG. 2 is a plan view of the production line shown in FIG. 1.
FIG. 3 is a side elevation in partial section of this invention shown in FIG. 1 with modifications featuring 0 two sponge rolls mounted in tandem and a nozzle spraying liquid onto the last sponge roll.
FIG. 4 is a side elevation in partial section of this in vention shown in FIG. 1 with a further modification featuring an endless sponge covered belt replacing the roll.
FIG. 5 is a section view of an impregnated glass strand passing over the sponge roll of this invention and illustrating one method of removing excess impregnant from the strand FIG. 6 is a section view of an impregnated glass strand passing over the sponge roll of this invention and illustrating a second method of removing excess impregnant from the strand.
FIG. 7 is a section view of an impregnated glass strand passing over the sponge roll of this invention and illustrating a third method of removing excess impregnant from the strand.
FIG. 8 is a section view of a modified sponge roll to be used in this invention.
FIG. 9 is an end view of the modified sponge roll shown in FIG. 8.
A DESCRIPTION OF EXEMPLARY EMBODIMENTS Referring now to the drawings, FIG. 1 and FIG. 2 show more specifically a production operation wherein linear materials in the form of fibrous strands 15 are pulled from packages 11 through tension controlling devices 13. The strands are then guided by grooved surfaces or pulleys 17, 23 and 27- through a reservoir of impregnating medium 21 which is held in a vat 19. The strands 25, having an excess of impregnant, are then guided across the sponge surface 31 of a revolving drum 29 where the excess impregnant is removed. Ultimately, the strands 37, having the desired amount of impregnant on them, are passed through a curing oven 39 and wound into a package 47 by a standard winding device 52. The initial thread-up of the production line is manually accomplished, but thereafter, strand moving forces are supplied entirely'by the winding device.
To more specifically describe the production process, reference is first made to the strands 15 of unimpregnated fibers. By way of example, the impregnation process shall be described for glass fibers, but the same process would apply for any type of textile filaments in a strand. The term strand is used here to mean a primary bundle of continuous filaments combined in a single compact unit without twist as well as a bundle of twisted continuous or staple filaments. It also is used here to means plied bundles of twisted or untwisted filaments. The diameter of the filaments may vary in size, but must be small enough to be flexible. The number of filaments in the strand may also vary. However, a strand having a very small number of filaments becomes impractical to handle. On the other hand, it would be difficult to completely impregnate a strand having a very large number of filaments. It is not known what maximum number of filaments in one strand can be completely impregnated in the impregnation line of this invention, but it is thought that as many as two thousand filaments in one bundle can be satisfactorily impregnated in the apparatus of this invention. An example of a strand satisfactorily impregnated in the apparatus of this invention is one of continuous fiber glass filaments containing 408 filaments with an average diameter for each filament of 0.00036 inches and the strand having one-half twist per inch.
As may be seen in FIG. 2, grooved surfaces 17, 23 and 27 are laterally disposed in spaced aligned relationship to thereby separately guide the strands in parallel fashion through the impregnating bath 21. In passing through the bath, strands are saturated with the impregnant material to generously coat the outer surface of the composite strand as well as each individual filament. To achieve complete penetration and coating, the strands 15 are subjected to the impregnant long enough to accomplish the viscous work necessary in overcoming the influence of variables such as mechanical and chemical cohesiveness of the individual filaments and the impregnant. For the purpose of illustra tion, the impregnant material 21 is exemplified by an elastomeric dispersion. Other coating materials including an aqueous or non-aqueous solution of a film forming composition or a hot melt or a solvent free material which is liquid at room temperature but which may be hardened by a subsequent chemical or thermal condition may be applied equally as well by using the techniques of this invention. Desirable but optional additives such as pigments, dyes, plasticizers, emulsifiers, lubricants and coupling agents may also be added. The terms impregnant and impregnation are used here to refer also to coating material and coating.
Emerging from the impregnant bath 21, the strands 25 have more impregnant on them than is desired in the final impregnated strand. The excessively impregnated strand is guided horizontally across the sponge surface 31 of revolving drum 29 where the excess impregnant is removed from the strand and absorbed by the sponge 31. The wetted sponge is revolved by a hard-surface roll 33 which squeezes out most of the impregnant from the sponge. The impregnant 35 squeezed from the sponge flows back into the vat l9 and again becomes part of the impregnant reservoir 21.
The sponge covered drum 29 is rotatably mounted above squeeze roll 33. It has been found advantageous to mount the shaft of the drum 29 loosely in vertical slots. The vertical positioning of the drum 29 is then determined by balancing the weight of the drum 29 with the compression resisting force of the sponge surface 31. The advantage of this arrangement is that a new drum 29 can be quickly substituted for an old one that has developed a worn sponge surface. The drum can be made from any hard material, such as steel. The sponge covering the drum is preferably an open cell flexible foam such as polyester or polyurethane. Other material capable of absorbing the impregnant can also be used as long as it is compressible and resilient. An, example of a satisfactory sponge is one three-eighths inches tain good results. However, in order to wipe, there must be some relative movement between the strand and the surface of the sponge covered drum in contact with the strand. The drum must also rotate fast enough to present a fresh surface to the strand and avoid a saturated area in the contact zone. Operating at strand speeds from 400 to 600 FPM, it has been found that drum rotation speeds of 4 to 18 RPM have worked satisfactorily.
The squeeze roll 33 is rotatably mounted about a fixed axis. It is preferably driven by a conventional power source, such as an electric motor 32, through chains, V-belts, or direct drive. lts surface interaction with the sponge surface 31 of the cylinder 29 accomplishes rotation of the cylinder 29 with the result that the sponge surface 31 is continually squeezed by the roll 33. The squeeze roll 33 can be made from any of several hard materials. An example of a satisfactory material is stainless steel.
After the excess impregnant is removed from the impregnated strands 25, the strands 37 having the desired amount of impregnant are advanced through the curing oven 39 where the impregnant is cured to the desired degree. The heat source in the curing oven can be supplied by any conventional form of heat, such as gas combustion, electrically heated elements, micro-wave energy, etc. The length of the oven is dependent upon the rate of impregnant cure and the speed of the strand passing through the oven. Curing of impregnants in this manner is well known in the art. In some cases the impregnant cure is carried out at ambient conditions, and no curing oven is required.
The strand 41 with cured impregnant is advanced from the curing oven 39, over guide roller 43 and wound into a package 47. The winding is accomplished by a commercially available standard winding apparatus commonly used in the textile industry. The winder 52 shown schematically consists of an electric motor 48 which rotates a shaft 50 upon which a collet 45 has been placed and reciprocates a traversing guide 46 back and forth along the length of the package to distribute the advancing strand 41 as it is wound into a package 47 on the rotating collet 45. The winding apparatus also supplies the pulling force to advance the strand through the impregnation line. The winder 52 is shown at one position only for illustrative purposes, but each position in the line would have a similar winder.
Resisting the pull of the winding apparatus is the tension control 13, along with frictional forces developed where the strand contacts members of the impregnation line. The tension control 13 is shown as a simple three finger configuration which is designed to produce the desired amount of drag on the strand when the strand is being pulled at operating speed. It may be desirable to use an adjustable tension controller, especially if the impregnation line is operated by varying speeds. Such an adjustment can be accomplished by varying the distance between the three fingers in the tension control 13 shown, as well as through use of other well known tension controllers.
FIG. 3 illustrates another feature of this invention. The impregnation line shown in FIG. 3 is the same as that shown in FIGS. 1 and 2, but it has two sponge covered wiping drums 329 and 359. Each drum rests upon a squeeze roll 333 and 363 which turns the sponge covered wiping drum 329 and 359 and squeezes removed excess impregnant 335 and 365 from the sponges 331 and 361. With the addition of the second wiping drum, it has been found that the strand can be advanced through the impregnation line at a faster speed than with only one wiping drum and still obtain the desired impregnation removal. It is not necessary that both sponge covered drums rotate in the same direction nor at the same speed. In fact, less impregnant will be removed from the strand by the second drum, so it would not be necessary to rotate it as fast as the first drum. It should be noted that this invention also contemplates the use of more than two sponge covered wiping drums. Three or more drums could be used to allow faster line speed operation and better control of the amount of impregnant removed. As with the use of two wiping drums, each drum in a series of three or more drums can be rotated in either direction and at a different speed from the other drums.
FIG. 3 also illustrates another feature of this invention. Included in the impregnation line is a spray nozzle 350 for applying a liquid 354 to the sponge 361 on the last drum 359. The liquid 354 is supplied through a pipe 352 under pressure. It can be pumped, or if water is used, the usual line pressure can be used for the motivating force. The function of the liquid is to prevent the removed impregnant from drying on the sponge 361 and thereby facilitate removal of the impregnant from the sponge by the squeeze roll 363. FIG. 3 shows the liquid being squeezed out of the sponge along with the removed impregnant. If the liquid is of a type which will contaminate the reservoir of impregnant 321, the catch area for the removed impregnant 365 must be separated from the reservoir of impregnant 321.
FIG. 4 illustrates a further feature of this invention. The impregnation line shown in FIG. 4 is the same as shown in FIGS. 1 and 2, but having an endless sponge belt 431 rather than a sponge covered drum. The sponge belt is mounted on two spaced drums 429 and 459 which are rotatable about parallel axes. One of the drums rests upon a squeeze roll 433 with the sponge belt between. The squeeze roll 433 rotates the belt 431 and squeezes the removed excess impregnant 435 from the belt. FIG. 4 shows the squeeze roll mounted below drum 429, but it could be just as well mounted below drum 459 in the location shown by the broken line. The belt 431 is shown in FIG. 4 as rotating in the same direction as the strand movement, but it could also be rotated in the opposite direction. In fact, rotation against the strand movement might be more desirable because a fresh unsaturated surface of belt would be presented to the strand as it progresses along the belt. On the other hand, better impregnation removal control might be obtained by keeping the strand in contact with a damp belt surface throughout the contact zone, in which case, rotation with the strand movement would be preferred. The nature of the impregnant and speed of strand movement would determine which is preferable.
FIGS. 5, 6 and 7 illustrate three methods of impregnation removal possible with this invention. The method which applies is dependent upon the compressibility and resiliency of the sponge material and the depth to which the strand is embedded into the sponge. FIG. 5 illustrates a strand 525 embedded only slightly into the sponge 531. This arrangement would result when the sponge is positioned so that it barely interferes with the path of the strand. With this arrangement the sponge 531 wipes impregnant 565 from beneath the strand 525. As the impregnant is wiped off the strand, it is absorbed into the sponge 571 and carried away by the moving sponge so that a fresh sponge surface is presented to the advancing strands. After impregnant 5 is wiped from the bottom of the strand, the remaining impregnant on and in the strand of filaments 567 distributes to again cover the bottom of the strand, if the impregnant is not too viscous. In this manner, removal of excess impregnant from all parts of the strand can be accomplished by wiping only the bottom of the strand.
As the strand is pulled from the package 11 shown in FIG. 1, a twist is created in the strand as a result of the strand being pulled from a non-rotating cylindrical package. This created twist caused the strand to rotate as it moves through the impregnation line and especially as it comes in contact with the sponge surface 31. Thus, a greater portion of the strand periphery is presented to the sponge 31 as the strand passes through the zone of contact with the sponge 31.
FIG. 6 illustrates a strand 625 deeply embedded into the sponge 631 and completely surrounded by the sponge. This arrangement would result when the sponge is of an easily compressible material which is very resilient and the sponge is in a position which interferes substantially with the path of the strand and the strand is pulled with sufficient tension to overcome the resilient forces of the sponge. With this arrangement, the sponge 631 wipes impregnant 669 from the complete circumference of the strand 625 without appreciably exerting pressure on the strand so that the impregnant surrounding the internal filaments of the strand remain well impregnated. The impregnant wiped from the strand 625 is absorbed in the sponge 671 and carried away by rotation of the drum so that a fresh sponge surface is presented to the strand. The method of removing excess impregnant shown in FIG. 6 allows more removal for the same strand speed than that shown in FIG. 5. It might be desirable to utilize the FIG. 6 method in the first sponge covered roll 331 of FIG. 3 to remove the bulk of the excess impregnant and the FIG. method in the second sponge covered roll 361 of FIG. 3 to make a final wipe with finer control. In the event the first sponge covered drum 331 is used to remove the bulk of the excess impregnant, it will be necessary to rotate it faster than the second sponge covered drum 361 to remove the larger amount of impregnant removed from the sponge. The use of either wiping method would be determined by the material of the sponge and the height setting of the squeeze roll 333 and 363. Adjustment can also be made by raising or lowering guide rolls 27 and 43 shown in FIG. 1. The tension in the strand as it comes in contact with the sponge is also an important factor in determining the degree to which the strand is pulled into the sponge. Even if the strand guides are set to cause the strand path to interfere with the sponge, the strand will only ride on top of the sponge unless there is sufficient tension to pull the strand into the sponge. The tension adjustment is made at the tension controller 13 of FIG. 1. The tension is adjusted to a greater amount until the desired strand depth in the sponge is obtained.
FIG. 7 illustrates yet another method of excess impregnant removal within the scope of this invention. In this figure, the strand 725 is deeply embedded into the sponge 731 as was the case in FIG. 6, but here the sponge does not completely surround the strand as it did in FIG. 6. This arrangement results when the sponge is of an easily compressible material, but not as resilient as the material of FIG. 6 or when the strand path and tension do not pull the strand to the same depth into the sponge as with the method of FIG. 6. In this method, the sponge must also be positioned so that it will interfere substantially with the path of the strand. With this arrangement the sponge wipes excess impregnant from the majority of the circumference of the strand, perhaps 270. The remaining portion of the excess impregnant on the top of the strand distributes to evenly coat the surface of the strand.
As with the sponge covered drum of FIG. 6, this method of excess impregnant removal can be used in combination with the method shown in FIG. or FIG. 6. In fact, all three methods could be used in combination. For example, the first wipe could be taken by the method of FIG. 6, the second wipe by the method of FIG. 7, and the last wipe by the method of FIG. 5. Other combinations could, of course, also be used.
It should be noted that impregnant removal by the apparatus of this invention can be accomplished in three ways. The first, as already stated, is wiping. The second is sucking action brought about by the cells of the sponge resiliently expanding after passing the strand contact zone. The third method is drawing the impregnant from the strand by capillary action of the sponge cells. The second method requires rotation of the sponge covered drum to perform, and probably, the rotation must be much faster than with the other methods of impregnant removal. The first method requires rotation of the sponge covered drum only to present the strand with a fresh surface, as does the third method.
FIGS. 8 and 9 illustrate yet another feature of this invention. FIG. 8 is a cut-away view of a modified sponge covered drum, and FIG. 9 is an end view of the drum shown in FIG. 8. The drum 829 is a hollow sealed tube with sponge covering 831. On one end of the hollow shaft 875 is a removable cap 873 which can be attached by any conventional method, such as with threads. The hollow shaft 875 is perforated inside of the sealed drum 829. With this arrangement, water can be poured into the end of the shaft after the cap is removed to fill the drum with water to the level desired. Thus, the weight g of the sponge covered drum is adjustable. Since the sponge covered drum is preferably mounted loosely above the squeeze roll in vertical slots, the degree of sponge compression at the squeeze roll can be adjusted by adding or subtracting water from the roll. It may be found necessary to squeeze the sponge more when operating at fast strand speeds in order to remove the desired amount of absorbed impregnant from the sponge, and with this arrangement the same sponge covered roll can be used at many different speeds by adjusting the level of water in the drum.
Referring back to FIG. 2, a further feature of this invention is illustrated. Strand guide bar 27 can be moved back and forth horizontally a short distance as indicated by two-headed arrow 28 to change the path of the strand 25 across the sponge covered drum 31. In this way the operating life of the sponge will be extended because more surface of the sponge will be exposed to the strand. Movement of the strand guide bar 27 can be accomplished by a number of methods, such as a motor and cam arrangement. It is not necessary that the movement be constant and therefore, the simplest method is periodical manual indexing of the strand guide bar 27 by the operator of the apparatus. It should also be noted that the same effect can be obtained by moving the sponge covered drum 31 back and forth rather than the strand guide bar.
Having described the particular embodiments of this invention, it is to be understood that the invention is not limited to these specific embodiments, but modifications can be made without departing from the true scope and spirit of the invention. For example, this invention is not limited to glass fibers, but applied to many varieties of textile fibers. Also, it can be readily seen that it is not limited to strands in its use. Coating of monofilaments can also be accomplished. It is further pointed out that the impregnation of the strand can also be accomplished by means other than dipping the strand into a bath of impregnant. For example, the impregnant can be sprayed onto the strand prior to the strand contacting the sponge or the impregnant can be applied to the sponge itself whereby the strand will then pick up the impregnant in metered quantities when contacting the strand. Having thus stated a few of the modifications within the scope of this invention.
We claim:
1. Apparatus for combining a coating material with filaments of a strand comprising in combination:
Means for applying coating material in liquid form to said strand;
A movable member for removing any desired excess of said coating material, said member being of a resiliently compressible and absorptive material;
Means for moving said member;
Means for advancing said strand along a predetermined path which causes said strand to contact said member; and
Means for establishing a predetermined tension in said strand, said tension being sufficient to cause said strand to compress part of said resiliently compressible and absorptive material of said member in the region of contact to cause the exterior surface of said member to substantially surround said strand for removal of excess coating material during advancement of said strand.
2. Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said means for advancing said strand along said predetermined path and means for establishing said predetermined tension in said strand causes said strand to move below the uncompressed surface regions of said member to cause said exterior surface of said member in the region of contact to completely surround said strand.
3. Apparatus for combining a coating material with filaments of a strand according to claim 1 including means to rotate said strand about its longitudinal axis as it moves through said apparatus.
4. Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said means for applying coating material to said strand comprises a reservoir of coating material through which said strand is passed.
5. Apparatus for combining a coating material with filaments of a strand according to claim 4 wherein said means for moving said strand at a predetermined tension comprises a winder pulling said strand and a tension controller resisting movement of said strand.
6. Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said member comprises a rotatable cylinder.
7. Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said member comprises an endless belt mounted upon a pair of spaced apart cylinders rotatable about substantially parallel axes.
8. Apparatus for combining a coating material with filaments of a strand according to claim 1 including means for squeezing said member to extract the excess coating material absorbed by said member.
9. Apparatus for combining a coating material with filaments of a strand according to claim 8 including means to apply liquid to said member to dilute the excess coating material so that such material is more easily extracted from said member.
10. Apparatus for combining a coating material with filaments of a strand according to claim 8 wherein said means for squeezing said member comprises a rotatable cylinder in compressing relationship with said member.
11. Apparatus for combining a coating material with filaments of a strand according to claim 10 wherein the weight of said member provides the required force to cause the compressing relationship between said member and said rotatable cylinder.
12. Apparatus for combining a coating material with filaments of a strand according to claim 11 wherein the weight of said member is adjustable 13. Apparatus for combining a coating material with filaments of a strand according to claim 1 including means to laterally vary the path of said strand on said member.
14. Apparatus for combining a coating material with filaments of a strand comprising in combination:
Means for applying coating material in liquid form to said strand;
A plurality of movable members for removing any desired excess of said coating material, each of said plurality of members being of a resiliently compressible and absorptive material;
Means for moving said members;
Means for advancing said strand along a predetermined path which causes said strand to contact each of said members; and
Means for establishing a predetermined tension in said strand, said tension being sufficient to cause said strand to compress part of said resiliently compressible and absorptive material of each of said members in the region of contact to cause the exterior surface of each of said members to substantially surround said strand for removal of excess coating material during advancement of said strand.
15. Apparatus for coating strand comprising in combination:
Means for applying coating material in liquid form to said strand;
A movable endless surface for removing excess coating material from said strand, said surface being of resiliently compressible and absorptive material and having a substantially greater thickness than the diameter of said strand;
Means for moving said surface;
Means for advancing said coated strand with sufficient tension along a path into contact with said surface to effect sufficient compression of said surface in the region of contact to cause the exterior of said surface to substantially surround said strand for removal of excess coating material during advancement of said strand.

Claims (15)

1. Apparatus for combining a coating material with filaments of a strand comprising in combination: Means for applying coating material in liquid form to said strand; A movable member for removing any desired excess of said coating material, said member being of a resiliently compressible and absorptive material; Means for moving said member; Means for advancing said strand along a predetermined path which causes said strand to contact said member; and Means for establishing a predetermined tension in said strand, said tension being sufficient to cause said strand to compress part of said resiliently compressible and absorptive material of said member in the region of contact to cause the exterior surface of said member to substantially surround said strand for removal of excess coating material during advancement of said strand.
2. Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said means for advancing said strand along said predetermined path and means for establishing said predetermined tension in said strand causes said strand to move below the uncompressed surface regions of said member to cause said exterior surface of said member in the region of contact to completely surround said strand.
3. Apparatus for combining a coating material with filaments of a strand according to claim 1 including means to rotate said strand about its longitudinal axis as it moves through said apparatus.
4. Apparatus for combining a coating material with filaments of a strand according To claim 1 wherein said means for applying coating material to said strand comprises a reservoir of coating material through which said strand is passed.
5. Apparatus for combining a coating material with filaments of a strand according to claim 4 wherein said means for moving said strand at a predetermined tension comprises a winder pulling said strand and a tension controller resisting movement of said strand.
6. Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said member comprises a rotatable cylinder.
7. Apparatus for combining a coating material with filaments of a strand according to claim 1 wherein said member comprises an endless belt mounted upon a pair of spaced apart cylinders rotatable about substantially parallel axes.
8. Apparatus for combining a coating material with filaments of a strand according to claim 1 including means for squeezing said member to extract the excess coating material absorbed by said member.
9. Apparatus for combining a coating material with filaments of a strand according to claim 8 including means to apply liquid to said member to dilute the excess coating material so that such material is more easily extracted from said member.
10. Apparatus for combining a coating material with filaments of a strand according to claim 8 wherein said means for squeezing said member comprises a rotatable cylinder in compressing relationship with said member.
11. Apparatus for combining a coating material with filaments of a strand according to claim 10 wherein the weight of said member provides the required force to cause the compressing relationship between said member and said rotatable cylinder.
12. Apparatus for combining a coating material with filaments of a strand according to claim 11 wherein the weight of said member is adjustable.
13. Apparatus for combining a coating material with filaments of a strand according to claim 1 including means to laterally vary the path of said strand on said member.
14. Apparatus for combining a coating material with filaments of a strand comprising in combination: Means for applying coating material in liquid form to said strand; A plurality of movable members for removing any desired excess of said coating material, each of said plurality of members being of a resiliently compressible and absorptive material; Means for moving said members; Means for advancing said strand along a predetermined path which causes said strand to contact each of said members; and Means for establishing a predetermined tension in said strand, said tension being sufficient to cause said strand to compress part of said resiliently compressible and absorptive material of each of said members in the region of contact to cause the exterior surface of each of said members to substantially surround said strand for removal of excess coating material during advancement of said strand.
15. Apparatus for coating strand comprising in combination: Means for applying coating material in liquid form to said strand; A movable endless surface for removing excess coating material from said strand, said surface being of resiliently compressible and absorptive material and having a substantially greater thickness than the diameter of said strand; Means for moving said surface; Means for advancing said coated strand with sufficient tension along a path into contact with said surface to effect sufficient compression of said surface in the region of contact to cause the exterior of said surface to substantially surround said strand for removal of excess coating material during advancement of said strand.
US00171252A 1971-08-12 1971-08-12 Apparatus for impregnating and coating fibrous strands Expired - Lifetime US3779207A (en)

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US3910230A (en) * 1974-03-08 1975-10-07 Harry L Mercer Apparatus for applying liquid to textile fabrics and the like
US4269138A (en) * 1979-04-23 1981-05-26 Western Electric Company, Inc. Apparatus for distributing liquid over a surface
US4349589A (en) * 1979-04-23 1982-09-14 Western Electric Co., Inc. Method for distributing liquid over a surface
US4464816A (en) * 1978-11-21 1984-08-14 Tsudakoma Kogyo Kabushiki Kaisha Sized warp divider for a sizing machine
US5382455A (en) * 1991-02-18 1995-01-17 Gerhard Boockmann Method and apparatus for imparting a sliding capacity to a wire
US6643901B1 (en) * 2000-11-01 2003-11-11 Ppg Industries Ohio, Inc. Loom beams
CN102962162A (en) * 2012-12-14 2013-03-13 西北有色金属研究院 Soaking-centrifugalizing equipment
US9926166B2 (en) * 2012-07-26 2018-03-27 Intertape Polymer Corp. Tape dispenser with improved wetting system

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US2637892A (en) * 1947-01-18 1953-05-12 Dayton Rubber Company Apparatus for impregnating textile materials
US2740373A (en) * 1954-04-08 1956-04-03 Anaconda Wire & Cable Co Wire enameling apparatus

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US1968687A (en) * 1931-10-30 1934-07-31 Johnson Steel & Wire Company I Process of and apparatus for coating wire
US2637892A (en) * 1947-01-18 1953-05-12 Dayton Rubber Company Apparatus for impregnating textile materials
US2740373A (en) * 1954-04-08 1956-04-03 Anaconda Wire & Cable Co Wire enameling apparatus

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3910230A (en) * 1974-03-08 1975-10-07 Harry L Mercer Apparatus for applying liquid to textile fabrics and the like
US4464816A (en) * 1978-11-21 1984-08-14 Tsudakoma Kogyo Kabushiki Kaisha Sized warp divider for a sizing machine
US4269138A (en) * 1979-04-23 1981-05-26 Western Electric Company, Inc. Apparatus for distributing liquid over a surface
US4349589A (en) * 1979-04-23 1982-09-14 Western Electric Co., Inc. Method for distributing liquid over a surface
US5382455A (en) * 1991-02-18 1995-01-17 Gerhard Boockmann Method and apparatus for imparting a sliding capacity to a wire
US5409535A (en) * 1991-02-18 1995-04-25 Boockmann Gmbh Apparatus for imparting a sliding capacity to a wire
US6643901B1 (en) * 2000-11-01 2003-11-11 Ppg Industries Ohio, Inc. Loom beams
US9926166B2 (en) * 2012-07-26 2018-03-27 Intertape Polymer Corp. Tape dispenser with improved wetting system
CN102962162A (en) * 2012-12-14 2013-03-13 西北有色金属研究院 Soaking-centrifugalizing equipment

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Effective date: 19870730

Owner name: OWENS-CORNING FIBERGLAS CORPORATION, FIBERGLAS TOW

Free format text: TERMINATION OF SECURITY AGREEMENT RECORDED NOV. 13, 1986. REEL 4652 FRAMES 351-420;ASSIGNORS:WILMINGTON TRUST COMPANY, A DE. BANKING CORPORATION;WADE, WILLIAM J. (TRUSTEES);REEL/FRAME:004903/0501

Effective date: 19870730