US3776847A - Lubricating oil composition - Google Patents
Lubricating oil composition Download PDFInfo
- Publication number
- US3776847A US3776847A US00225283A US3776847DA US3776847A US 3776847 A US3776847 A US 3776847A US 00225283 A US00225283 A US 00225283A US 3776847D A US3776847D A US 3776847DA US 3776847 A US3776847 A US 3776847A
- Authority
- US
- United States
- Prior art keywords
- oil
- lubricating oil
- weight
- composition
- oils
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract description 22
- 239000010687 lubricating oil Substances 0.000 title abstract description 17
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- -1 ALKALINE EARTH METAL SALT Chemical class 0.000 abstract description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract description 7
- 239000010685 fatty oil Substances 0.000 abstract description 6
- 150000002739 metals Chemical class 0.000 abstract description 6
- 239000010688 mineral lubricating oil Substances 0.000 abstract description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- 229910000831 Steel Inorganic materials 0.000 description 11
- 239000010959 steel Substances 0.000 description 11
- 238000005098 hot rolling Methods 0.000 description 8
- 235000019484 Rapeseed oil Nutrition 0.000 description 7
- 239000003208 petroleum Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 150000001447 alkali salts Chemical class 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001379910 Ephemera danica Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- YSIQDTZQRDDQNF-UHFFFAOYSA-L barium(2+);2,3-di(nonyl)naphthalene-1-sulfonate Chemical compound [Ba+2].C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1.C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 YSIQDTZQRDDQNF-UHFFFAOYSA-L 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbased sulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/14—Group 7
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/16—Groups 8, 9, or 10
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
- C10N2060/04—Oxidation, e.g. ozonisation
Definitions
- a lubricating oil composition for the hot rolling of metals comprises (a) from about 50 to about 85% by weight of a natural fatty oil, (b) from about 0.1 to about by weight of an alkaline earth metal salt of an oil-soluble sulfonic acid and (c) from about 5 to about 49.9% by weight of a mineral lubricating oil having a viscosity index of at least 50.
- Roll performance is a measure of the extent of the useful life of a roll.
- Lubricating oils such as fatty oils and synthetic ester lubricating oils, however, can give rise to difficulties, such as spray-nozzle plugging, uncontrollable slipping on the mill and insuflicient adherence to the rolls, particularly under the severe conditions of the hot rolling of steel.
- the invention relates to a lubricating oil composition suitable for the hot rolling of metals, in particular ferrous metals such as steel.
- the invention furthermore relates to a process for the hot rolling of metals using the present compositions as such or as aqueous dispersions and to metals worked by means of this process.
- These lubricating oil compositions comprise (a) from about 50 to about 85 by weight of a natural fatty oil, (b) from about 0.1 to about 10% by weight of a basic alkaline earth metal salt of an oil-soluble petroleum sulfonic acid and (c) from about 5 to about 49.9% by weight of a mineral lubricating oil having a viscosity index of at least 50.
- One ingredient of the lubricating oil composition of the invention is a natural fatty oil.
- Suitable natural fatty oils can be of vegetable origin and they can be blown or unblown. Representative examples of such oils are rapeseed oil and cotton seed oil. Rapeseed oil is particularly preferred.
- a second ingredient of the lubricating oil composition of the invention consists of alkaline earth metal salts of oil-soluble sulfonic acids, in particular petroleum sulfonic acids.
- the alkaline earth metal salts the calcium salts are preferred.
- the salts can be neutral or basic, although the basic salts are preferred.
- Suitable oil-soluble sulfonic acids include naphthalene, benzene, and phenol sulfonic acids, as well as their alkyl-substituted derivatives, such as barium dinonylnaphthalenesulfonate.
- the basicities may range from 20 to over 1000%, and preferably from 50 to 800%.
- a third ingredient of the lubricating oil composition of the invention is a mineral lubricating oil.
- Suitable mineral lubricating oils are parafiin base and naphthene base distillate oils having a viscosity index of at least 50, preferably at least 75, and a viscosity between about 6 and 60 cs. at 60 C. They may be blended with synthetic hydrocarbon oils such as polyolefins and/or with synthetic nonhydrocarbon lubricating oils such as ester oils or polyoxyalkylenes such as polyethylene glycols.
- the lubricant compositions of the invention may contain additional additives, such as anti-oxidants, anti-foamants, anti-corrosion agents and extreme pressure agents.
- Preferred extreme pressure agents are metal hydrocarbylthiophosphates.
- the metal is preferably a polyvalent metal such as an alkaline earth metal, cadmium, zinc, iron and the like, in particular zinc.
- the hydrocarbyl group is preferably an alkyl or cycloalkylgroup having up to 30, particularly 3 to 12 carbon atoms.
- Preferred compounds are zinc dialkyl dithiophosphates in which the alkyl groups are selected from propyl, butyl, pentyl, hexyl, cyclohexyl, octyl, decyl and dodecyl groups.
- the proportions of the additional additives may range between about 0.1 and 25% by weight, based on the total composition.
- the lubricant compositions of the invention may advantageously be used as an oil/water mixture (loose dispersion) in the hot rolling of steel.
- w. rapeseed oil 5% w. basic calcium petroleum sulfonate (same as in A).
- w. rapeseed oil 5% w. basic calcium petroleum sulfonate (same as in A).
- composition of claim 1 wherein said basic salt per roll for oil D (average of 2 trials).
- Two aqueous is a basic calcium salt.
- dispersions of commercial hot steel rolling lubricants 3.
- the composition of claim 2 wherein the basicity of which were analyzed as an ester of a polyol and a C1242 said basic calcium salt is from 50 to 800% fatty acid, and as whale oil, respectively, gave roll per- 4.
- the composition of claim 1 wherein said mineral formances of about 85,000 tons per roll.
- lubricating oil has a viscosity index of at least 75.
- an aqueous dispersion of another commercial oil which 5.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB473571A GB1383198A (en) | 1971-02-16 | 1971-02-16 | Hot rolling of metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3776847A true US3776847A (en) | 1973-12-04 |
Family
ID=9782818
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00225283A Expired - Lifetime US3776847A (en) | 1971-02-16 | 1972-02-10 | Lubricating oil composition |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3776847A (enExample) |
| AU (1) | AU459736B2 (enExample) |
| BE (1) | BE779072A (enExample) |
| CA (1) | CA995652A (enExample) |
| DE (1) | DE2206932A1 (enExample) |
| FR (1) | FR2125443B1 (enExample) |
| GB (1) | GB1383198A (enExample) |
| IT (1) | IT948531B (enExample) |
| NL (1) | NL7201883A (enExample) |
| SE (1) | SE384523B (enExample) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4659488A (en) * | 1985-09-18 | 1987-04-21 | The Lubrizol Corporation | Metal working using lubricants containing basic alkaline earth metal salts |
| US5298177A (en) * | 1991-08-09 | 1994-03-29 | The Lubrizol Corporation | Functional fluid with triglycerides, detergent-inhibitor additives and viscosity modifying additives |
| US5352373A (en) * | 1992-03-05 | 1994-10-04 | Sumitomo Metal Industries, Ltd. | Lubricating composition for use in hot rolling of steels |
| EP0714974A1 (en) | 1994-12-02 | 1996-06-05 | The Lubrizol Corporation | Environmental friendly food grade lubricants from edible triglycerides containing approved additives |
| US5739088A (en) * | 1990-03-14 | 1998-04-14 | Nippon Oil Co., Ltd. | Method of lubricating an alcohol-based fuel engine with an engine oil composition |
| WO2006032012A3 (en) * | 2004-09-13 | 2006-06-08 | C M Intellectual Property And | Composition and methods for improved lubrication, pour point, and fuel performance |
| US20080221001A1 (en) * | 2004-12-14 | 2008-09-11 | C.M. Intellectual Property And Research, Inc. | Composition and Methods for Improved Lubrication, Pour Point, and Fuel Performance |
| US20080295391A1 (en) * | 2005-07-25 | 2008-12-04 | C.M. Intellectual Property And Research, Inc. | Fuel and Lubricant Additives and Methods for Improving Fuel Economy and Vehicle Emissions |
| US20090239774A1 (en) * | 2006-06-16 | 2009-09-24 | Toyota Boshoku Kabushiki Kaisha | Lubricants for use in processing of metallic material and methods for processing the metallic material using the lubricants |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE415107B (sv) * | 1978-03-07 | 1980-09-08 | Karlshamns Oljefabriker Ab | Metallbearbetningsemulsion innehallande triglyceridolja |
| JP4619266B2 (ja) * | 2005-10-31 | 2011-01-26 | トヨタ紡織株式会社 | 自動車用高張力鋼板のプレス加工用の潤滑油 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1462785A (fr) * | 1964-12-08 | 1966-04-15 | Asea Ab | Laminage à chaud d'acier |
-
1971
- 1971-02-16 GB GB473571A patent/GB1383198A/en not_active Expired
-
1972
- 1972-02-08 BE BE779072A patent/BE779072A/nl unknown
- 1972-02-10 US US00225283A patent/US3776847A/en not_active Expired - Lifetime
- 1972-02-11 IT IT20501/72A patent/IT948531B/it active
- 1972-02-14 SE SE7201743A patent/SE384523B/xx unknown
- 1972-02-14 CA CA134,661A patent/CA995652A/en not_active Expired
- 1972-02-14 AU AU38957/72A patent/AU459736B2/en not_active Expired
- 1972-02-14 DE DE19722206932 patent/DE2206932A1/de active Pending
- 1972-02-14 FR FR7204823A patent/FR2125443B1/fr not_active Expired
- 1972-02-14 NL NL7201883A patent/NL7201883A/xx unknown
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4659488A (en) * | 1985-09-18 | 1987-04-21 | The Lubrizol Corporation | Metal working using lubricants containing basic alkaline earth metal salts |
| US5739088A (en) * | 1990-03-14 | 1998-04-14 | Nippon Oil Co., Ltd. | Method of lubricating an alcohol-based fuel engine with an engine oil composition |
| US5298177A (en) * | 1991-08-09 | 1994-03-29 | The Lubrizol Corporation | Functional fluid with triglycerides, detergent-inhibitor additives and viscosity modifying additives |
| US5352373A (en) * | 1992-03-05 | 1994-10-04 | Sumitomo Metal Industries, Ltd. | Lubricating composition for use in hot rolling of steels |
| EP0714974A1 (en) | 1994-12-02 | 1996-06-05 | The Lubrizol Corporation | Environmental friendly food grade lubricants from edible triglycerides containing approved additives |
| US5538654A (en) * | 1994-12-02 | 1996-07-23 | The Lubrizol Corporation | Environmental friendly food grade lubricants from edible triglycerides containing FDA approved additives |
| WO2006032012A3 (en) * | 2004-09-13 | 2006-06-08 | C M Intellectual Property And | Composition and methods for improved lubrication, pour point, and fuel performance |
| US20080312114A1 (en) * | 2004-09-13 | 2008-12-18 | C.M. Intellectual Property And Research, Inc. | Composition and Methods for Improved Lubrication, Pour Point, and Fuel Performance |
| US20080221001A1 (en) * | 2004-12-14 | 2008-09-11 | C.M. Intellectual Property And Research, Inc. | Composition and Methods for Improved Lubrication, Pour Point, and Fuel Performance |
| US20080295391A1 (en) * | 2005-07-25 | 2008-12-04 | C.M. Intellectual Property And Research, Inc. | Fuel and Lubricant Additives and Methods for Improving Fuel Economy and Vehicle Emissions |
| US20090239774A1 (en) * | 2006-06-16 | 2009-09-24 | Toyota Boshoku Kabushiki Kaisha | Lubricants for use in processing of metallic material and methods for processing the metallic material using the lubricants |
Also Published As
| Publication number | Publication date |
|---|---|
| SE384523B (sv) | 1976-05-10 |
| CA995652A (en) | 1976-08-24 |
| GB1383198A (en) | 1975-02-05 |
| FR2125443B1 (enExample) | 1974-08-30 |
| NL7201883A (enExample) | 1972-08-18 |
| DE2206932A1 (de) | 1972-08-31 |
| BE779072A (nl) | 1972-08-08 |
| AU459736B2 (en) | 1975-04-10 |
| AU3895772A (en) | 1973-08-16 |
| IT948531B (it) | 1973-06-11 |
| FR2125443A1 (enExample) | 1972-09-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3966623A (en) | Corrosion inhibited lube oil compositions | |
| US3169923A (en) | Oil of lubricating viscosity | |
| US2455659A (en) | Oily composition | |
| EP0142078A1 (en) | Metal working lubricant | |
| US2672444A (en) | Rust preventive compositions | |
| US4517103A (en) | Lubricating compositions containing 5,5'-dithiobis(1,3,4-thiadiazole-2-thiol) | |
| US2841555A (en) | Metal nu-acyl sarcosinate thickened lubricating oils | |
| US2614077A (en) | Grease composition | |
| US3050465A (en) | Water-in-oil emulsion hydraulic fluids | |
| US4664821A (en) | Lubricant additive concentrate containing isomerized jojoba oil | |
| US3203896A (en) | Lubricating composition | |
| US4211662A (en) | Synergistic lubricating compositions | |
| DE2206932A1 (de) | Schmiermittel, insbesondere zur spanlosen Bearbeitung von Metallen | |
| US2999813A (en) | Lubricant comprising a sulfurized mineral oil and a polyvalent metal dithiocarbamate | |
| US3216939A (en) | Stabilization of lubricants | |
| US2632347A (en) | Lubricant for metal rolling mills | |
| US2813829A (en) | Grease compositions having improved yield, load bearing capacity, and low temperature properties | |
| US2914477A (en) | Emulsifiable oil | |
| US3502581A (en) | Antioxidant composition and use thereof | |
| US3359202A (en) | Lubricating compositions | |
| US2638446A (en) | Lubricant for pneumatic tools and the like | |
| US2450321A (en) | Rust-inhibiting greases | |
| US3177146A (en) | Fire-resistant hydraulic fluids | |
| US4601838A (en) | Water-soluble chlorinated fatty ester additives | |
| US2534053A (en) | Lubricating grease containing paraffin wax |