US3766994A

US3766994A - Abnormal pressure detection during drilling of a well

Info

Publication number: US3766994A
Application number: US00185600A
Authority: US
Inventors: W Fertl
Original assignee: Continental Oil Co
Current assignee: ConocoPhillips Co
Priority date: 1971-10-01
Filing date: 1971-10-01
Publication date: 1973-10-23
Anticipated expiration: 1990-10-23

Abstract

An early warning detection method for predicting abnormal formation pressure in subterranean rock strata before it is drilled. The technique is to measure the concentration of sulfate or carbonate ions in the formation being drilled, while the well is being drilled in the normally pressured rock strata existing above the abnormally pressured formations. When variations are observed in the degree of change of the amount of sulfate or carbonate ions present with depth, drilling procedures are altered to meet the requirements of the formation which is about to be penetrated by the drill bit.

Description

6 99 iC -ZB-JB OR 3076 0 I Unlted States Patent 1191 1111 3,766,994 Fertl 1451 Oct. 23, 1973 ABNORMAL PRESSURE DETECTION 3,670,8 29 6/1972 Overton 175/30 DURING DRILLING OF A WELL Primary Examiner-Marvin A. Champion [75] Inventor. Walter H. Fertl, Ponca C1ty, Okla. Assistant Examiner kichard E. Favreau [73] Assignee: Continental Oil Company, Ponca Attorney-Joseph C. Kotarski et a].

City, Okla. 22 Filed: Oct. 1, 1971 [57] ABSTRACT An early warning detection method for predicting ab- [211 App]' 185,600 normal formation pressure in subterranean rock strata before it is drilled. The technique is to measure the 52 us. c1. 175/50, 73/153 concentration of sulfate carbonate ions in the 511 1111. (:1 EZlb 47/00 matioh being drilled, While the is being drilled in [58] Field 01 Search 175/40, 50; 73/153; the normally Pressured rock Strata existing above the 324/1 abnormally pressured formations. When variations are observed in the degree of change of the amount of sul- 5 References Cited fate or carbonate ions present with depth, drilling procedures are altered to meet the requirements of the UNITED STATES PATENTS formation which isabout to be penetrated by the drill 3,368,400 2/1968 Jordan et al. 175/50 bit 2,336,613 12/1943 Horvitz 175/50 3,494,188 2/1970 Boatman 175/50 X 5 Claims, 1 Drawing Figure 8 1 11111111 1 l||ITI SULFATE CARBONATE ION ION IO Q 11 v 2 1; m 3 o E I2 I n. 11.1 o g g 5 I. 1 IL 11111' 1 11I1111i 0 IO 20 I0 I00 IONIC CONCENTRATION IN PARTS PER MILLION PATENIEDnmza nan 3,766,994

SULIL'ATE 'AbNATE' ION ION DEPTH, THOUSAND FEET I Z5 0 IO 20 I0 I00 IONIC CONCENTRATION IN PARTS PER MILLION ABNORMAL PRESSURE DETECTION DURING DRILLING OF A WELL BACKGROUND OF THE INVENTION 1. Field of the Invention This invention involves a method of detecting abnormally pressured formations as a well is drilling through subsurface rock formations containing zones having normal and abnormal formation fluid pressures. More particularly, the invention involves the detection and prediction of impending pressure changes well ahead of the drill bit, i.e., 200 to 1500 feet prior to actually drilling the pressure changes. This forewarning of impending pressure changes is vital so that engineering preparations can be altered for successfully drilling the well safely and efficiently through the pressure change to the desired depth. Other pressure detection systems presently in use in the drilling industry do not permit a guaranteed prediction of formation pressure changes not yet drilled.

2. Description of the Prior Art When a well is drilled, normal pressures, i.e., hydrostatic pressures, exist to some unknown depth where transition to abnormal pressures might be encountered. In the normally pressured zones, formation pressure increases at a constant rate with increasing depth. This rate of increase is approximately 0.465 pounds per square inch per foot of depth, and is the equivalent to the pressure exerted at the base of a column of water containing 80,000 ppm total solids. Abnormal pressures either are less than (underpressured) or greater than (geopressured) this pressure gradient increase of 0.465 psi/ft.

In many geographical areas, such as the Gulf Coast of the United States, abnormal pressures are encountered. Of particular importance are geopressures since these are very common and can cause very severe drilling problems. When geopressures are encountered, they must be drilled with a weighted drilling fluid that exerts a pressure exceeding that of the geopressured zone or else the shale and fluids in the abnormal pressured zone, i.e., oil, gas, and/or water, will flow into the well bore and possibly cause a catastrophic blowout or drill string sticking. Numerous causes for' geopressures have been postulated. One such cause is that shales and sands that are being buried deeper because of additional deposition on top must compact to stay at normal pressure. These shales and sands can only compact, however, if the associated water is allowed to leak off. If this water cannot bleed off, the formations will exhibit geopressures i.e., high fluid pressures.-

Underpressures, although much less frequently encountered compared to geopressures, have been found in areas of oil and/or gas production where pressure in the formations is depleted through the years by production.

Drilling wells in any formation pressure environment requires the weight of the drilling mud to be balanced against the pressure of the formation being drilled. The fastest and most efficient drilling rates are obtained when an overbalance of mud to formation pressure is held to a minimum. The penetration rate begins to decrease dramatically when overbalances exceed about 300 psi more than formation pressures at 10,000 to 12,000 feet. This is only about 0.5 pound/gal. excess mud weight. Further it is dangerous to drill with mud weight pressures that exceed formation pressures by about 1000 psi which is about 2.0 pounds/gal. excess mud weight at 10,000 to 12,000 feet since this high a differential pressure can cause the formations to fracture or break down with loss of the mud column into the formation. When mud is lost in one zone, the entire mud column drops decreasing the hydrostatic mud head and overbalance across other zones and even probably getting into an underbalanced condition across these other zones. When this happens, the differential pressure of higher formation pressure than mud pressure will allow flow of formation fluid into the well bore. This can literally cause the entire mud column to be blown out of the hole resulting in a catastrophic blowout and loss of the hole, drilling rig, and endangering the lives of the rig personnel.

Also when m'ud weight pressure to formation pressure is excessive as when overbalance exceeds about l000'psi, there is a tendency for the drill pipe to stick due to this differential pressure. To get unstuck sometimes can be very expensive or even impossible with presenttechnology; thus the well has to be abandoned with great financial loss.

' It can be seen that the drilling of wells through abnormal pressures require great engineering skill. The knowledge of impending abnormal pressures enables the drilling engineer to prepare and perform the drilling in a safe and efficient engineering manner, since he is aware of the impending difficulties and problems.

Present methods used in pressure detection such as wire line logs, i.e., electric, acoustic, density, all require temporarily suspending drilling operations to acquire the logs. Further, wire line logs must be considered as after-the-fact since they have the inherent drawback that the abnormal pressures can only be detected after the zone has been drilled. In many instances, getting pressure information at this time is too late as drilling problems such as pipe sticking and well blowouts occur when the abnormal pressure zones are being penetrated. V

Other methods of abnormal pressure detection while drilling include bulk density measurements of the drilled shale cuttings, drill penetration rate, torque or drag on the drill pipe, mud pump pressure, mud pit level changes, measurement of gas in mud system and clay mineral changes. These methods for pressure detection are generally faster than the wire line logging techniques, but they all have the same drawback in that none of these guarantee the ahead-of-bit prediction in all cases.

The drilling industry is in need of a method for predicting and detecting abnormal pressure zones prior to drilling into them. It is an object of this invention to provide a method of predicting and detecting pressure changes before drilling them. It is another object to drill geopressured formations without danger of a blowout. It is also an object of this invention to keep mud weights at a safe minimum during drilling so that loss of circulation does not occur. It is a further object to drill abnormal pressured formations at a high penetration rate without ceasing drilling operations to detect such abnormal pressures. Other objects, advantages and features of this invention, will become obvious from the following specification and appended claims.

SUMMARY OF INVENTION This invention involves a method of drilling a well through subsurface rock strata containing abnormal formation pressures at some unknown depth. The normally pressured (hydrostatic pressured) portions of the strata are drilled according to well known techniques in which a drilling fluid is circulated in the borehole. While drilling the normally pressured rock, the drilling fluid is maintained at a relatively low weight, i.e., balanced against or slightly above hydrostatic pressure, so that fast and economic drilling can be accomplished. During this drilling operation the concentration of the sulfate or carbonate ions contained in the formation is system-actically and periodically or continuously determined. This is done by measuring at the surface the activity or concentration of either the sulfate ion or the carbonate ion in the drilling mud, cores or shale drill cuttings removed from the well at various depth intervals. In the normally pressured formations the concentration of the sulfate and carbonateions changes only slightly with increasing depth. However, several hundred feet above a geopressured interval the concentration of these ions begins to either increase or decrease rapidly. When this change in activity occurs, it is a signal that a geopressured zone lines somewhat below the drill bit in yet undrilled rock strata. Thus, this early warning of impending geopressure permits the drilling engineers to start controlled drilling procedures. These procedures, such as keeping a constant rotary speed and weight on the bit while monitoring penetration rate, will alert the driller when the geopressure is reached since the penetration rate will begin to increase under these controlled procedures at this time and the geopressures will not be masked by uncontrolled conditions. The weight of drilling fluid can then be adjusted to compensate for the change in formation pressure. Drilling a well in the above described method provides the fastest and most efficient drilling, but most important permits the safest drilling. Controlled drilling procedures require special precautions which makes their use throughout the entire drilling operation technically difficult and uneconomical.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a graphical representation ofthe concentration of sulfate and carbonate ions in formation samples at various depths.

DESCRIPTION OF THEPREFERRED EMBODIMENTS The drilling fluid used in this process may be an aqueous or oil base drilling mud, air or mist. Where a drilling mud is used, the pressure of the column of drilling mud against the formation is increased by increasing the density of the drilling mud as by adding to the mud barium sulfate or some other weighting agent. If air or mist drilling is being employed, the pressure is increased by increasing the amount of air being compressed.

Formation fluids contain a wide variety of water soluble ions. Among such ions are the sulfate ion and the carbonate ions. In normally pressured formations the concentration or activity of the sulfate and carbonate ions is relatively constant with increasing depth. This invention is based on the discovery that, formations immediately above geopressured zones are an exception to the general rule in that they contain a lower than expected concentration or activity of sulfate and/or carbonate ions. The reason for this phenomenonis not known with certainty. It has been postulated that water is squeezed out of shales as they compact due to the weight of overlying sediments. However, the shales act as a filtration membrane and the water that is squeezed out is fresh leaving the ions behind in the shale and therefore increasing the shale ion concentration or activity. Since overpressured shales are undercompacted for their depths they still contain considerably more water and the soluble ion concentration or activity is less than in highly compacted shales. When compacted shales with the high ion concentration or activity overlie the undercompacted shales with low soluble ion concentration, or activity, the shales tend to try to come to ionic equilibrium by ion diffusion from the concentrated solution to the dilute solution (normal pressure interval to the abnormal pressure interval) in opposition to the membrane filtration effect. This in theory creates the interval of 200 to 1500 feet above the geopressure zone where diffusion of ions has caused a freshening of formations waters. This invention therefore has developed a procedure to detect this zone of freshening waters above the abnormal pressure.

The water-soluble ions monitored may be either cationic, such as sodium, potassium, calcium, magnesium and the like, or anions, such as a halide for example chloride, iodide, bromide or fluoride, phosphate, carbonate, sulfate, chlorate, and the like.

It has been found that the carbonate ion concentration does in fact decrease in the interval immediately above a geopressured zone just as the abve theory would predict. However the sulfate ion concentration was found to increase over this same interval. The reason for this difierence in behavior is not well understood. However, regardless of whether the concentration increases or decreases, the significant fact is that the concentration changes from the concentration found at shallower depths and this change is a readily identifiable indication of the approach of the drill bit to an abnormally pressured zone. This change is especially evident from a simple plot of sulfate or carbonate ion concentration versus depth as is shown in the Figure.

During drilling operations a drilling fluid is pumped into the borehole and circulated past the drill bit. Cuttings and possibly formation fluids are picked up by the drilling fluid and circulated to the surface. Thus the material coming out of the borehole consists of a mixture of drilling fluid, formation fluids and cuttings. Sometimes a coring or sidewall sampling apparatus is lowered downhole and a formation core or sidewall samples removed. The sulfate ion and/or carbonate ion concentration may be measured on any or all of these materials either separately or in combination.

Any of the well known analytical methods for determining sulfate and carbonate ion concentration may be used. If drilling fluid is used for the determination, a representative sample is collected as the drilling fluid is circulated out of the well. The sample is then filtered to remove the solid particles and the sulfate and/or carbonate ion concentration of the filtrate determined. If cuttings, cores or sidewall samples of the formation are to be used for the detennination the samples are removed from the well, washed to remove drilling fluid, ground to a fine particle size, mixed with water, blended for a short time to achieve good mixing and filtered to remove the solid particles. The sulfate and/or carbonate ion concentration of the filtrate is determined. Alternatively sulfate and carbonate ion concenslurries circulated out of the borehole.

The sulfate ion concentration may conveniently be determined by turbidimetric or gravimetric methods using the barium ion, generally as barium chloride. If the sulfate ion concentration is relatively low, titration with the barium ion produces a cloudy solution which can be compared with known standards. If the sulfate ion concentration is relatively high, titration with the barium ion produces a precipitate which is filtered and weighed. Another method of determining sulfate is precipitation of the sulfate as C l-I,,N,H, SO by benzidine in slightly acid solutions. Still another method of determining sulfate is by indirect determination using ethylenediamine tetracetic acid, EDTA, or any other.

suitable chelating agent. An excess of standard barium ion solution is added and back titrated with the chelating agent.

The carbonate ion concentration can be determined by titration with an acid such as an hydrochloric acid solution to a pH of 8 using phenolphthalein as an indicator. Any otherknown analytical method may also be used.

EXAMPLE A well was drilled on the Louisiana Gulf Coast in an area where geopressures are often encountered at a depth somewhere below 8,000 feet. The well was drilled to 8,000 feet using known techniques of balancing drilling mud pressure against formation pressure. At depths below 8,000 feet the concentration of both sulfate ions and carbonate ions in well cuttings was determined. The drilling mud stream circulated out of the borehole was passed over a shale shaker. At every 30 foot interval of increased depth a quart of cuttings passing through a 10 mesh screen (U.S. Standard Sieve Series) and retained on a 40 mesh screen were removed from the shale shaker. A knowledge of the depth at which the well was drilling when the samples were taken, the annular mud velocity and the penetration rate allowed calculation of the depth from which the cuttings originated. Drilling mud was washed from the cuttings with fresh water and excess water blotted from the cuttings with a towel. The cuttings were then dried on a hot plate at 230F for 20 minutes. A 10 gram sample of dry cuttings was cooled, mixed with 100 milliliters of distilled water and blended for 5 minutes in an electric micro-blender cell. The concentration of sulfate ions in the resulting slurry was determined by adding an excess of barium chloride solution, filtrating and weighing the barium sulfate precipitate which formed and calculating the concentration of sulfate ion.

The concentration of carbonate ions in the resulting slurry was determined by titrating the same with a hydrochloric acid solution to a pH of 8 using phenolphthalein as a color indicator.

The Figure is a plot of the concentration of various sulfate ions and carbonate ions in the slurry at various depths. It can be seen that the concentration of both ions was relatively constant from just below 8,000 feet to about 13,000 feet. From 13,000 feet to about 13,200 feet the sulfate ionic concentration decreased sharply. From about 13,200 feet to about 13,400 feet the sulfate ion concentration increased sharply. From just above 13,000 feet to about 13,500 feet the carbonate ion concentration increased sharply. From 13,500 feet to 14,000 feet the carbonate ion concentration decreased sharply. Thus the sharp change in both of these indicators which began about 13,000 feet indicated the approach of a high pressure zone. The well had been drilled from 9,000 feet with a drilling mud having a weight of 10 pounds per gallon. When the approach of a high pressure zone was indicated by the changes in anionic concentration controlled drilling procedures were instigated. A constant rotary speed and weight on the drill bit was maintained while the penetration rate was monitored. When the penetration rate began to increase at a depth of about 13,5 00 feet, the weight of the drilling mud was increased to 17 pounds per gallon. The well was then'drilled to the total desired depth of about 15,000 feet without difficulty. 7

The foregoing discussion and description have been made in connection with preferred specific embodiments of the processfor detecting geopressure zones during drilling of a well. However it is to be understood that the discussion and description of the invention is only intended to illustrate and teach those skilled in the art how to practice the process and is not to, unduly limit the scope of the invention which is defined and claimed hereafter. For example in addition to making measurements of the concentration of sulfate and/or carbonate ions in a slurry made from shale cuttings, such measurements may be made on slurries made using formation samples taken with a sidewall cutting apparatus or on the filtrate of of such slurries. Further measurements may be made on samples of the drilling fluid stream being circulated into or out of the borehole.

Measurements may be made by periodically sampling the material being circulated out of the borehole, or, as in the case of testing the drilling fluid, continuously with the results conveniently being plotted on a strip chart recorder connected to the measuring apparatus.

In the claims:

l. A method for detecting the approach of an underlying abnormally pressured zone while drilling a well in normally pressured zones of a subterranean strata comprising:

a. drilling the normally pressured zones with a drilling fluid whose pressure is balanced against the subterranean strata pressure,

b. monitoring the concentration of the sulfate ion or the carbonate ion in the subterranean strata being drilled,

0. when the rate of change of concentration of the sulfate ion or the carbonate ion with depth begins to change, instituting controlled drilling procedures, and

d. when the abnormally pressured zone is penetrated, adjusting the drilling fluid pressure to balance the same against the pressure in the abnormally pressured zone.

2. The method of claim 1 wherein the controlled drilling procedures instituted comprise keeping a constant rotary speed and weight on the bit while monitoring the penetration rate.

3. The method of claim 1 wherein the concentration of sulfate ion or carbonate ion is measured continually on samples of formation circulated from the well.

4. A method for detecting the approach of an underlying geopressure zone while drilling normally pressured subterranean strata comprising:

7 8 a. drilling the normally pressured subterranean strata d. when the controlled drilling procedures indicate a drilling fluid Whose Pressure is balanced that a geopressured zone has been penetrated, inagamst the Subterranean strata Pressure creasing the drilling fluid pressure to balance the b. monitoring the concentration of the sulfate ion or gfi zz m the subterranean strata bemg 5. The method of claim 4 wherein the controlled drilc. when the concentration of sulfate ion or carbonate ling procedures instituted comprise keeping a constant ion in the subterranean strata begins to change raprotary speed and weight on the bit While monitoring the idly with change in depth, instituting controlled Penetration ratedrilling procedures, and 10 same against the pressure in the geopressured zone.

Claims

1. A method for detecting the approach of an underlying abnormally pressured zone while drilling a well in normally pressured zones of a subterranean strata comprising: a. drilling the normally pressured zones with a drilling fluid whose pressure is balanced against the subterranean strata pressure, b. monitoring the concentration of the sulfate ion or the carbonate ion in the subterranean strata being drilled, c. when the rate of change of concentration of the sulfate ion or the carbonate ion with depth begins to change, instituting controlled drilling procedures, and d. when the abnormally pressured zone is penetrated, adjusting the drilling fluid pressure to balance the same against the pressure in the abnormally pressured zone.

4. A method for detecting the approach of an underlying geopressure zone while drilling normally pressured subterranean strata comprising: a. drilling the normally pressured subterranean strata with a drilling fluid whose pressure is balanced against the subterranean strata pressure, b. monitoring the concentration of the sulfate ion or the carbonate ion in the subterranean strata being drilled, c. when the concentration of sulfate ion or carbonate ion in the subterranean strata begins to change rapidly with change in depth, instituting controlled drilling procedures, and d. when the controlled drilling procedures indicate that a geopressured zone has been penetrated, increasing the drilling fluid pressure to balance the same against the pressure in the geopressured zone.

5. The method of claim 4 wherein the controlled drilling procedures instituted comprise keeping a constant rotary speed and weight on the bit while monitoring the penetration rate.