US3756925A - The same dry lubricant coating of self replenishing type and method of making - Google Patents
The same dry lubricant coating of self replenishing type and method of making Download PDFInfo
- Publication number
- US3756925A US3756925A US00211741A US3756925DA US3756925A US 3756925 A US3756925 A US 3756925A US 00211741 A US00211741 A US 00211741A US 3756925D A US3756925D A US 3756925DA US 3756925 A US3756925 A US 3756925A
- Authority
- US
- United States
- Prior art keywords
- graphite fluoride
- coating
- graphite
- dry lubricant
- lubricant coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011248 coating agent Substances 0.000 title abstract description 36
- 238000000576 coating method Methods 0.000 title abstract description 36
- 239000000314 lubricant Substances 0.000 title abstract description 15
- 238000004519 manufacturing process Methods 0.000 title description 2
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical compound C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 abstract description 44
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 18
- 229910052751 metal Inorganic materials 0.000 abstract description 14
- 239000002184 metal Substances 0.000 abstract description 14
- 239000000758 substrate Substances 0.000 abstract description 14
- 229910052799 carbon Inorganic materials 0.000 abstract description 12
- 229910052731 fluorine Inorganic materials 0.000 abstract description 9
- 239000011737 fluorine Substances 0.000 abstract description 9
- 229910002804 graphite Inorganic materials 0.000 abstract description 7
- 239000010439 graphite Substances 0.000 abstract description 7
- 230000001050 lubricating effect Effects 0.000 abstract description 7
- 239000000843 powder Substances 0.000 abstract description 7
- 230000008021 deposition Effects 0.000 abstract description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 24
- 239000000243 solution Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 238000005299 abrasion Methods 0.000 description 12
- 238000007747 plating Methods 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 7
- 150000002605 large molecules Chemical class 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 238000005461 lubrication Methods 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 5
- -1 such as Chemical compound 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- GZSUIHUAFPHZSU-UHFFFAOYSA-N 9-ethyl-2,3-dihydro-1h-carbazol-4-one Chemical compound C12=CC=CC=C2N(CC)C2=C1C(=O)CCC2 GZSUIHUAFPHZSU-UHFFFAOYSA-N 0.000 description 3
- 230000000274 adsorptive effect Effects 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920002401 polyacrylamide Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical group S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241001517013 Calidris pugnax Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
- C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
Definitions
- a dry lubricant coating comprising graphite fluoride powder having a lubricating property dispersed in a coating metal is electrophoretically deposited on a substrate simultaneously with the electrolytic deposition of the coating metal.
- the graphite fluoride is produced by reacting carbon or graphite with fluorine at a temperature of lower than 550 C.
- This invention relates to a dry lubricant coating of a self-replenishing type, method of application thereof to the surface of an article, such as a bearing, and a coated article so obtained.
- self-replenishing type refers to the dry lubricant coating which replenishes itself its lubricating surface as it wears away during the use thereof, which will be described in detail hereinafter.
- An object of this invention is to provide a coating composition and a coating technique which allows control of how much lubricant is on the surface at any moment.
- Another object is to provide a novel coating composition which gives a lubrication coating which supplies lubrication as the substrate material Wears.
- Another object is to provide a coated article of superior lubrication properties.
- graphite fluoride With respect to the graphite fluoride referred above, it was in 1934 that Ruff and Bretschneider first discovered that graphite or carbon and fluorine combined without combination at about 420 C. to form a grey-colored solid (Zeitschrift anorg. allgem. Chem). The approximate composition of this solid was (CF where x is nearly equal to 1. They called the compound carbon monofluoride. However, in this invention we call it graphite fluoride because there are many compounds consisting of carbon and fluorine, such as, carbon tetrafiuoride and fluorocarbon polymer, such as, polytetrafluoroethylene (Teflon of E. I. du Pont de Nemours & Co.).
- the dry lubricant coating of the self-replenishing type wherein graphite flu- United States Patent ice oride particles are dispersed in a coating metal is deposited electrophoretically on a substrate simultaneously with the electrolytic deposition of the coating metal by the method which comprises subjecting the substrate to the process of codeposition in a coating bath consistin of a coating metal, graphite fluoride powder, and one or two additives having a good adsorptive activity for graphite fluoride, such as, watersoluble high molecular weight compounds, water-soluble organic solvents, and colloidal oxides.
- the codeposition of graphite fluoride powder and metal can be effected by the use of a coating bath consisting of coating metal, graphite fluoride, and one or two additives having a good adsorptive activity for graphite fluoride selected from the group of water-soluble high molecular weight compounds, water-soluble organic solvents, and colloidal oxides, wherein graphite fluoride is well dispersed in the coating bath, and further, this codeposition can be repeated with good results.
- graphite fluoride is produced by the reaction of carbon or graphite with fluorine, halogen fluoride or a mixture thereof with an inert gas at a temperature of less than 550 C.
- the configuration is as follows: fluorine is introduced between the layer lattice structure of the carbon or graphite and is chemically bonded with one remaining valence electron in the carbon atom in a covalent bond, and the molecular formula may be expressed as (CF),, and the molar ratio of carbon to fluorine is 1:1.
- the compound is a transparent white or grey solid powder.
- Graphite fluoride does not soften, nor burn at a relatively high temperature, and is stable up to the temperature of 550 C. under atmospheric pressure. Besides, it has a specific gravity of 2.00 to 2.70, is resistant to corrosion by aggressive chemicals such as acids and alkalis, and has a high electric resistance. Graphite fluoride will neither be wet with water nor with oil, and its angle of contact with water is so that it has a strong repellence to oil as well as water, and besides, a lubricating property at an elevated temperature.
- graphite fluoride has the stability to chemicals even in such an acidic solution as a plating bath so that its property as a lubricant will never be deteriorated; and it is quite stable to a frictional heat produced at the boundary lubrication and an atmospheric condition.
- graphite fluoride particles can be dispersed in water or a plating solution with one or two additives, such as, water-soluble high molecular weight compound, water-soluble organic solvent, and colloidal oxide.
- graphite fluoride particles are previously immersed in a water-soluble solvent, such as, alcohol, siloxane, dioxane, and ketone in order to substitute adsorptive gases on the surface thereof, and then the treated particles together with a slight amount of a water-soluble high molecular weight compound, such as, polyethylene glycol and polyvinyl alcohol are added into the plating bath; (2) graphite fluoride particles are adsorbed with a slight amount of colloidal oxide, such as, silicic acid anhydride and titania, and then the treated particles are added into the plating bath; and (3) graphite fluoride particles are adsorbed with a water-soluble high molecular weight compound only, and then the treated particles are added into the bath.
- a water-soluble solvent such as, alcohol, siloxane, dioxane, and ketone
- the water-soluble organic solvent includes methyl alcohol, ethyl alcohol, propyl alcohol, glycol, glycerine, siloxane, acetone, and methyl ethyl ketone, etc.
- the water-soluble high molecular weight compound includes polyethylene glycol, polyvinyl alcohol, polyamine, polyvinyl carbazol, and polyacrylamide; and one, two or more of the above compounds can be employed.
- the upper limit of the volume percentage of graphite fluoride particles to be added to the coating solution in order to produce the dry lubricant coating of the self-replenishing type of this invention is preferred to be 80% by volume.
- the codeposition of a large amount of graphite fluoride particles should be obviated so that the amount thereof should be preferred to be less than 5%.
- the amount of graphite fluoride particles to be added to the plating bath should be less than 500 g. per liter, and the preferred concentration thereof should be in the range of 0.0001 to 50 g. per liter. Further, in the practical operation of the process, a mechanical agitation of the bath has proved to be beneficial.
- the particle size of graphite fluoride should be divided as finely as possible, and less than microns. In particular, more than 80% of the particle size of graphite fluoride is preferred to be less than 0.5 micron.
- EXAMPLE 1 A solution was prepared wherein 0.3 g./l. of graphite fluoride particles having the mean particle size, 0.2 micron, in the spherical form were uniformly suspended in methyl or ethyl alcohol, and this uniform suspension is referred to A solution. Then, a nickel coating having the thickness of 25 microns was deposited on a brass sheet having the thickness of 2 mm. by the electrodeposition under the condition specified below in the plating bath of the following composition containing the above A solution:
- Codcposited surface (this Coated surface invention) (prior art) Number of rotation (70 r.p.m.). 10 10 10x10 Amount of abrasion, mg 170.4 230.3 Taber abrasion, mg./1,0fl0 cycle... 1.70 2.30 Depth of abrasion trace, micron. 13 18 Surface hardness, HMV 599 648 It is clearly shown from the above that the nickel coated surface codeposited with a small amount of graphite fluoride in accordance with this invention has increased its lubricity as well as its abrasion resistance to a remarkable degree.
- EXAMPLE 2 An aqueous dispersion of graphite fluoride was prepared by the steps of mixing one part of graphite fluoride particles, 0.25 part of colloidal anhydrous silicic acid, and two parts of polyethylene glycol No. 300 while these components were kneading under a reduced pressure for a period of one to two hours, and then adding the composition thus obtained to 50 parts of water while agitating. This aqueous dispersion is referred to B solution.
- EXAMPLE 3 A suspension solution (referred to C solution) was prepared wherein 2 g. per liter of graphite fluoride powder were dispersed in dioxane. Then, a nickel coating layer, 15 micron thick, was deposited on a steel sheet by the electrodeposition under the condition specified below in the plating bath of the following composition containing the C solution:
- graphite fluoride in a molar ratio of carbon to fluorine of 1:1, said graphite fluoride being obtained by reacting carbon or graphite with fluorine in an inert gas at a temperature lower than 550 C., and one or more dispersion promoting additives for the graphite fluoride selected from (1) a colloidal oxide selected from the group consisting of silicic acid anhydride and titania, (2) a Water-soluble organic solvent selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol, glycol, glycerine, siloxane, acetone, and methyl ethyl ketone and (3) a watersoluble high molecular weight compound selected from the group consisting of a polyethylene glycol, a polyvinyl alcohol, a polamine, a polyvinyl carbazol and a polyacrylamide.
- a colloidal oxide selected from the group consisting of silicic acid anhydride and titania
- dispersion promoting additive is selected from the group consisting of silicic acid anhydride and titania.
- dispersion promoting additive is selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol, glycol, glycerine, siloxane, acetone and methyl ethyl ketone.
- dispersion promoting additive is selected from the group consisting of a polyethylene glycol, a polyvinyl alcohol, a polyamine, a polyvinyl carbazol and a polyacrylamide.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45118726A JPS4920459B1 (enExample) | 1970-12-26 | 1970-12-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3756925A true US3756925A (en) | 1973-09-04 |
Family
ID=14743547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00211741A Expired - Lifetime US3756925A (en) | 1970-12-26 | 1971-12-23 | The same dry lubricant coating of self replenishing type and method of making |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3756925A (enExample) |
| JP (1) | JPS4920459B1 (enExample) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3830280A (en) * | 1971-01-25 | 1974-08-20 | Mallory & Co Inc P R | Rare earth flouride lubricant for die casting components |
| US4333977A (en) * | 1980-08-27 | 1982-06-08 | Waters Associates, Inc. | Wear-resistant article |
| US4342679A (en) * | 1980-08-27 | 1982-08-03 | Millipore Corporation | Wear-resistant sintered composition having an empirical formula CF1.3 comprising graphite fibers, fluonnated graphite, and PTFE |
| US4407988A (en) * | 1980-08-27 | 1983-10-04 | Millipore Corporation | Method for preparing a wear-resistant composition containing fluorinated graphite, graphite fibers and PTFE |
| US4496442A (en) * | 1980-08-14 | 1985-01-29 | Toagosel Chemical Industry Co., Ltd. | Process for generating hydrogen gas |
| US4545913A (en) * | 1983-09-23 | 1985-10-08 | Metal Leve S.A. Industria E Comercio | Plain bearings |
| US4716059A (en) * | 1987-02-26 | 1987-12-29 | Allied Corporation | Composites of metal with carbon fluoride and method of preparation |
| US4770797A (en) * | 1986-03-31 | 1988-09-13 | Allied-Signal Inc. | Carbon fluoride chloride lubricant |
| US4800027A (en) * | 1987-01-27 | 1989-01-24 | Uop | Process for continuous application of solid lubricant to moving bed particles |
| US4830889A (en) * | 1987-09-21 | 1989-05-16 | Wear-Cote International, Inc. | Co-deposition of fluorinated carbon with electroless nickel |
| US5100739A (en) * | 1990-04-26 | 1992-03-31 | Nkk Corporation | Separating sheet provided with a plurality of plating layers, excellent in strippability and having a high hardness |
| EP1369504A1 (en) * | 2002-06-05 | 2003-12-10 | Hille & Müller | Metal strip for the manufacture of components for electrical connectors |
| US11542621B1 (en) * | 2016-09-02 | 2023-01-03 | Maxterial, Inc. | Coatings and coated surfaces including low-surface energy inorganic particles |
| US12163208B2 (en) | 2021-06-18 | 2024-12-10 | Maxterial, Inc. | Hydraulic devices including coated surfaces |
| US12173166B2 (en) | 2017-09-28 | 2024-12-24 | Maxterial, Inc. | Articles including surface coatings and methods to produce them |
-
1970
- 1970-12-26 JP JP45118726A patent/JPS4920459B1/ja active Pending
-
1971
- 1971-12-23 US US00211741A patent/US3756925A/en not_active Expired - Lifetime
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3830280A (en) * | 1971-01-25 | 1974-08-20 | Mallory & Co Inc P R | Rare earth flouride lubricant for die casting components |
| US4496442A (en) * | 1980-08-14 | 1985-01-29 | Toagosel Chemical Industry Co., Ltd. | Process for generating hydrogen gas |
| US4333977A (en) * | 1980-08-27 | 1982-06-08 | Waters Associates, Inc. | Wear-resistant article |
| US4342679A (en) * | 1980-08-27 | 1982-08-03 | Millipore Corporation | Wear-resistant sintered composition having an empirical formula CF1.3 comprising graphite fibers, fluonnated graphite, and PTFE |
| US4407988A (en) * | 1980-08-27 | 1983-10-04 | Millipore Corporation | Method for preparing a wear-resistant composition containing fluorinated graphite, graphite fibers and PTFE |
| US4545913A (en) * | 1983-09-23 | 1985-10-08 | Metal Leve S.A. Industria E Comercio | Plain bearings |
| US4770797A (en) * | 1986-03-31 | 1988-09-13 | Allied-Signal Inc. | Carbon fluoride chloride lubricant |
| US4800027A (en) * | 1987-01-27 | 1989-01-24 | Uop | Process for continuous application of solid lubricant to moving bed particles |
| US4716059A (en) * | 1987-02-26 | 1987-12-29 | Allied Corporation | Composites of metal with carbon fluoride and method of preparation |
| US4830889A (en) * | 1987-09-21 | 1989-05-16 | Wear-Cote International, Inc. | Co-deposition of fluorinated carbon with electroless nickel |
| US5100739A (en) * | 1990-04-26 | 1992-03-31 | Nkk Corporation | Separating sheet provided with a plurality of plating layers, excellent in strippability and having a high hardness |
| EP1369504A1 (en) * | 2002-06-05 | 2003-12-10 | Hille & Müller | Metal strip for the manufacture of components for electrical connectors |
| WO2003104532A1 (en) * | 2002-06-05 | 2003-12-18 | Hille & Müller GMBH | Components for electrical connectors, and metal strip therefore |
| US20060094309A1 (en) * | 2002-06-05 | 2006-05-04 | Hille & Muller Gmbh | Components for electrical connectors, and metal strip therefore |
| US11542621B1 (en) * | 2016-09-02 | 2023-01-03 | Maxterial, Inc. | Coatings and coated surfaces including low-surface energy inorganic particles |
| US20230295827A1 (en) * | 2016-09-02 | 2023-09-21 | Maxterial, Inc. | Coatings and coated surfaces including low-surface energy inorganic particles |
| US12173166B2 (en) | 2017-09-28 | 2024-12-24 | Maxterial, Inc. | Articles including surface coatings and methods to produce them |
| US12163208B2 (en) | 2021-06-18 | 2024-12-10 | Maxterial, Inc. | Hydraulic devices including coated surfaces |
| US12516403B2 (en) | 2021-06-18 | 2026-01-06 | Maxterial, Inc. | Rollers and work rolls including surface coatings |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4920459B1 (enExample) | 1974-05-24 |
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